JP2014502039A - 薄膜太陽電池用のケステライト層の製造方法 - Google Patents

薄膜太陽電池用のケステライト層の製造方法 Download PDF

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JP2014502039A
JP2014502039A JP2013535365A JP2013535365A JP2014502039A JP 2014502039 A JP2014502039 A JP 2014502039A JP 2013535365 A JP2013535365 A JP 2013535365A JP 2013535365 A JP2013535365 A JP 2013535365A JP 2014502039 A JP2014502039 A JP 2014502039A
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substrate
layer
deposited
sulfur
tin
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JP2014502039A5 (https=
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ワン、ケイア
スプラティク、グーハ
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International Business Machines Corp
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International Business Machines Corp
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    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10FINORGANIC SEMICONDUCTOR DEVICES SENSITIVE TO INFRARED RADIATION, LIGHT, ELECTROMAGNETIC RADIATION OF SHORTER WAVELENGTH OR CORPUSCULAR RADIATION
    • H10F10/00Individual photovoltaic cells, e.g. solar cells
    • H10F10/10Individual photovoltaic cells, e.g. solar cells having potential barriers
    • H10F10/16Photovoltaic cells having only PN heterojunction potential barriers
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10FINORGANIC SEMICONDUCTOR DEVICES SENSITIVE TO INFRARED RADIATION, LIGHT, ELECTROMAGNETIC RADIATION OF SHORTER WAVELENGTH OR CORPUSCULAR RADIATION
    • H10F77/00Constructional details of devices covered by this subclass
    • H10F77/10Semiconductor bodies
    • H10F77/12Active materials
    • H10F77/128Active materials comprising only Group I-II-IV-VI kesterite materials, e.g. Cu2ZnSnSe4 or Cu2ZnSnS4
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10PGENERIC PROCESSES OR APPARATUS FOR THE MANUFACTURE OR TREATMENT OF DEVICES COVERED BY CLASS H10
    • H10P14/00Formation of materials, e.g. in the shape of layers or pillars
    • H10P14/20Formation of materials, e.g. in the shape of layers or pillars of semiconductor materials
    • H10P14/22Formation of materials, e.g. in the shape of layers or pillars of semiconductor materials using physical deposition, e.g. vacuum deposition or sputtering
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10PGENERIC PROCESSES OR APPARATUS FOR THE MANUFACTURE OR TREATMENT OF DEVICES COVERED BY CLASS H10
    • H10P14/00Formation of materials, e.g. in the shape of layers or pillars
    • H10P14/20Formation of materials, e.g. in the shape of layers or pillars of semiconductor materials
    • H10P14/26Formation of materials, e.g. in the shape of layers or pillars of semiconductor materials using liquid deposition
    • H10P14/265Formation of materials, e.g. in the shape of layers or pillars of semiconductor materials using liquid deposition using solutions
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10PGENERIC PROCESSES OR APPARATUS FOR THE MANUFACTURE OR TREATMENT OF DEVICES COVERED BY CLASS H10
    • H10P14/00Formation of materials, e.g. in the shape of layers or pillars
    • H10P14/20Formation of materials, e.g. in the shape of layers or pillars of semiconductor materials
    • H10P14/29Formation of materials, e.g. in the shape of layers or pillars of semiconductor materials characterised by the substrates
    • H10P14/2901Materials
    • H10P14/2922Materials being non-crystalline insulating materials, e.g. glass or polymers
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10PGENERIC PROCESSES OR APPARATUS FOR THE MANUFACTURE OR TREATMENT OF DEVICES COVERED BY CLASS H10
    • H10P14/00Formation of materials, e.g. in the shape of layers or pillars
    • H10P14/20Formation of materials, e.g. in the shape of layers or pillars of semiconductor materials
    • H10P14/32Formation of materials, e.g. in the shape of layers or pillars of semiconductor materials characterised by intermediate layers between substrates and deposited layers
    • H10P14/3202Materials thereof
    • H10P14/3236Materials thereof being chalcogenide semiconducting materials not being oxides, e.g. ternary compounds
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10PGENERIC PROCESSES OR APPARATUS FOR THE MANUFACTURE OR TREATMENT OF DEVICES COVERED BY CLASS H10
    • H10P14/00Formation of materials, e.g. in the shape of layers or pillars
    • H10P14/20Formation of materials, e.g. in the shape of layers or pillars of semiconductor materials
    • H10P14/32Formation of materials, e.g. in the shape of layers or pillars of semiconductor materials characterised by intermediate layers between substrates and deposited layers
    • H10P14/3202Materials thereof
    • H10P14/3241Materials thereof being conductive materials
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10PGENERIC PROCESSES OR APPARATUS FOR THE MANUFACTURE OR TREATMENT OF DEVICES COVERED BY CLASS H10
    • H10P14/00Formation of materials, e.g. in the shape of layers or pillars
    • H10P14/20Formation of materials, e.g. in the shape of layers or pillars of semiconductor materials
    • H10P14/32Formation of materials, e.g. in the shape of layers or pillars of semiconductor materials characterised by intermediate layers between substrates and deposited layers
    • H10P14/3242Structure
    • H10P14/3244Layer structure
    • H10P14/3248Layer structure consisting of two layers
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10PGENERIC PROCESSES OR APPARATUS FOR THE MANUFACTURE OR TREATMENT OF DEVICES COVERED BY CLASS H10
    • H10P14/00Formation of materials, e.g. in the shape of layers or pillars
    • H10P14/20Formation of materials, e.g. in the shape of layers or pillars of semiconductor materials
    • H10P14/34Deposited materials, e.g. layers
    • H10P14/3402Deposited materials, e.g. layers characterised by the chemical composition
    • H10P14/3424Deposited materials, e.g. layers characterised by the chemical composition being Group IIB-VIA materials
    • H10P14/3428Sulfides
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10PGENERIC PROCESSES OR APPARATUS FOR THE MANUFACTURE OR TREATMENT OF DEVICES COVERED BY CLASS H10
    • H10P14/00Formation of materials, e.g. in the shape of layers or pillars
    • H10P14/20Formation of materials, e.g. in the shape of layers or pillars of semiconductor materials
    • H10P14/34Deposited materials, e.g. layers
    • H10P14/3402Deposited materials, e.g. layers characterised by the chemical composition
    • H10P14/3436Deposited materials, e.g. layers characterised by the chemical composition being chalcogenide semiconductor materials not being oxides, e.g. ternary compounds
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/50Photovoltaic [PV] energy

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  • Photovoltaic Devices (AREA)
  • Physical Vapour Deposition (AREA)
  • Physical Deposition Of Substances That Are Components Of Semiconductor Devices (AREA)
JP2013535365A 2010-10-26 2011-10-19 薄膜太陽電池用のケステライト層の製造方法 Pending JP2014502039A (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US12/911,833 2010-10-26
US12/911,833 US8440497B2 (en) 2010-10-26 2010-10-26 Fabricating kesterite solar cells and parts thereof
PCT/EP2011/068254 WO2012055737A2 (en) 2010-10-26 2011-10-19 Kesterite layer fabrication for thin film solar cells

Publications (2)

Publication Number Publication Date
JP2014502039A true JP2014502039A (ja) 2014-01-23
JP2014502039A5 JP2014502039A5 (https=) 2014-08-07

Family

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JP2013535365A Pending JP2014502039A (ja) 2010-10-26 2011-10-19 薄膜太陽電池用のケステライト層の製造方法

Country Status (5)

Country Link
US (1) US8440497B2 (https=)
JP (1) JP2014502039A (https=)
CN (1) CN103180969A (https=)
DE (1) DE112011102890T5 (https=)
WO (1) WO2012055737A2 (https=)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20120318361A1 (en) * 2011-06-20 2012-12-20 Alliance For Sustainable Energy, Llc Manufacturing thin films with chalcogen species with independent control over doping and bandgaps
US20130217211A1 (en) * 2012-02-21 2013-08-22 Aqt Solar, Inc. Controlled-Pressure Process for Production of CZTS Thin-Films
US8586457B1 (en) * 2012-05-17 2013-11-19 Intermolecular, Inc. Method of fabricating high efficiency CIGS solar cells
US9153729B2 (en) * 2012-11-26 2015-10-06 International Business Machines Corporation Atomic layer deposition for photovoltaic devices
US9349906B2 (en) 2014-09-27 2016-05-24 International Business Machines Corporation Anneal techniques for chalcogenide semiconductors
US9917216B2 (en) * 2014-11-04 2018-03-13 International Business Machines Corporation Flexible kesterite photovoltaic device on ceramic substrate
CN105679878A (zh) * 2014-11-17 2016-06-15 中国电子科技集团公司第十八研究所 一种共蒸发制备铜锌锡硫硒薄膜太阳电池吸收层的方法
US10032949B2 (en) * 2015-11-09 2018-07-24 International Business Machines Corporation Photovoltaic device based on Ag2ZnSn(S,Se)4 absorber
CN105470113B (zh) * 2015-11-20 2018-07-10 中国电子科技集团公司第十八研究所 一种CZTSSe薄膜太阳电池吸收层的制备方法
KR20170097440A (ko) * 2016-02-18 2017-08-28 전영권 태양전지 및 그 제조방법
PL241410B1 (pl) * 2019-02-11 2022-09-26 Akademia Górniczo-Hutnicza im. Stanisława Staszica w Krakowie Sposób wytwarzania proszkowego kesterytu typu Cu<sub>₂</sub>SnZnS<sub>₄</sub>
PL241416B1 (pl) * 2019-02-11 2022-09-26 Akademia Górniczo-Hutnicza im. Stanisława Staszica w Krakowie Sposób wytwarzania proszkowego kesterytu typu Cu₂SnZnS₄, przeznaczonego do produkcji warstw czynnych w cienkowarstwowych ogniwach fotowoltaicznych
CN110867383B (zh) * 2019-11-21 2023-05-30 中国电子科技集团公司第十八研究所 一种三步硫化工艺制备铜锌锡硫薄膜吸收层的方法
CN114864752A (zh) * 2022-06-15 2022-08-05 金陵科技学院 一种改善柔性CZTSSe薄膜太阳能电池吸收层残余应力的方法及应用

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008078619A (ja) * 2006-08-24 2008-04-03 National Institute Of Advanced Industrial & Technology 半導体薄膜の製造方法、半導体薄膜の製造装置、光電変換素子の製造方法及び光電変換素子
JP2010245238A (ja) * 2009-04-03 2010-10-28 Promatic Kk 光電変換装置およびその製造方法ならびに硫化物焼結体ターゲットの製造方法

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4543162B2 (ja) * 2001-09-05 2010-09-15 独立行政法人産業技術総合研究所 ZnOSSe混晶半導体
US7518207B1 (en) * 2004-03-19 2009-04-14 The United States Of America As Represented By The Secretary Of The Navy Molecular beam epitaxy growth of ternary and quaternary metal chalcogenide films
US20110017289A1 (en) * 2009-07-24 2011-01-27 Electronics And Telecommunications Research Institute Cigs solar cell and method of fabricating the same
AU2010343092A1 (en) * 2009-12-28 2012-08-16 Nanosolar, Inc. Low cost solar cells formed using a chalcogenization rate modifier
CN101824638B (zh) * 2010-05-06 2012-12-19 深圳丹邦投资集团有限公司 一种电化学沉积铜锌锡硒半导体薄膜材料的方法

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008078619A (ja) * 2006-08-24 2008-04-03 National Institute Of Advanced Industrial & Technology 半導体薄膜の製造方法、半導体薄膜の製造装置、光電変換素子の製造方法及び光電変換素子
JP2010245238A (ja) * 2009-04-03 2010-10-28 Promatic Kk 光電変換装置およびその製造方法ならびに硫化物焼結体ターゲットの製造方法

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
JPN5014000935; WANG K.: 'THERMALLY EVAPORATED CU2ZNSNS4 SOLAR CELLS' APPLIED PHYSICS LETTERS V97 N14, 20101005, P143508-1 - 143508-3, AMERICAN INSTITUTE OF PHYSICS *
JPN6014029997; 星野 雄斗 et al.: '多元同時真空蒸着法によるCu2ZnSnS4薄膜の成長と評価(III)' 第57回応用物理学関係連合講演会講演予稿集 , 20100303, 20p-TE-8 *

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Publication number Publication date
CN103180969A (zh) 2013-06-26
DE112011102890T5 (de) 2013-06-06
US20120100664A1 (en) 2012-04-26
WO2012055737A3 (en) 2012-12-27
US8440497B2 (en) 2013-05-14
WO2012055737A2 (en) 2012-05-03

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