JP2014114354A - 冷凍機油組成物および冷凍機用作動流体組成物 - Google Patents
冷凍機油組成物および冷凍機用作動流体組成物 Download PDFInfo
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- JP2014114354A JP2014114354A JP2012268308A JP2012268308A JP2014114354A JP 2014114354 A JP2014114354 A JP 2014114354A JP 2012268308 A JP2012268308 A JP 2012268308A JP 2012268308 A JP2012268308 A JP 2012268308A JP 2014114354 A JP2014114354 A JP 2014114354A
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- refrigerant
- refrigerator
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- 230000000379 polymerizing effect Effects 0.000 description 1
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- APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical group [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 description 1
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- ISIJQEHRDSCQIU-UHFFFAOYSA-N tert-butyl 2,7-diazaspiro[4.5]decane-7-carboxylate Chemical compound C1N(C(=O)OC(C)(C)C)CCCC11CNCC1 ISIJQEHRDSCQIU-UHFFFAOYSA-N 0.000 description 1
- 125000001973 tert-pentyl group Chemical group [H]C([H])([H])C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
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- PPEZWDDRWXDXOQ-UHFFFAOYSA-N tributoxy(sulfanylidene)-$l^{5}-phosphane Chemical compound CCCCOP(=S)(OCCCC)OCCCC PPEZWDDRWXDXOQ-UHFFFAOYSA-N 0.000 description 1
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 description 1
- XTTGYFREQJCEML-UHFFFAOYSA-N tributyl phosphite Chemical compound CCCCOP(OCCCC)OCCCC XTTGYFREQJCEML-UHFFFAOYSA-N 0.000 description 1
- IMFACGCPASFAPR-UHFFFAOYSA-N tributylamine Chemical compound CCCCN(CCCC)CCCC IMFACGCPASFAPR-UHFFFAOYSA-N 0.000 description 1
- GAJQCIFYLSXSEZ-UHFFFAOYSA-L tridecyl phosphate Chemical compound CCCCCCCCCCCCCOP([O-])([O-])=O GAJQCIFYLSXSEZ-UHFFFAOYSA-L 0.000 description 1
- OHRVKCZTBPSUIK-UHFFFAOYSA-N tridodecyl phosphate Chemical compound CCCCCCCCCCCCOP(=O)(OCCCCCCCCCCCC)OCCCCCCCCCCCC OHRVKCZTBPSUIK-UHFFFAOYSA-N 0.000 description 1
- IVIIAEVMQHEPAY-UHFFFAOYSA-N tridodecyl phosphite Chemical compound CCCCCCCCCCCCOP(OCCCCCCCCCCCC)OCCCCCCCCCCCC IVIIAEVMQHEPAY-UHFFFAOYSA-N 0.000 description 1
- SWZDQOUHBYYPJD-UHFFFAOYSA-N tridodecylamine Chemical compound CCCCCCCCCCCCN(CCCCCCCCCCCC)CCCCCCCCCCCC SWZDQOUHBYYPJD-UHFFFAOYSA-N 0.000 description 1
- ZATMWXRIJNLIBA-UHFFFAOYSA-N triheptadecyl phosphate Chemical compound CCCCCCCCCCCCCCCCCOP(=O)(OCCCCCCCCCCCCCCCCC)OCCCCCCCCCCCCCCCCC ZATMWXRIJNLIBA-UHFFFAOYSA-N 0.000 description 1
- GSURLQOINUQIIH-UHFFFAOYSA-N triheptyl phosphate Chemical compound CCCCCCCOP(=O)(OCCCCCCC)OCCCCCCC GSURLQOINUQIIH-UHFFFAOYSA-N 0.000 description 1
- PPBMHSGZZYZYBO-UHFFFAOYSA-N triheptyl phosphite Chemical compound CCCCCCCOP(OCCCCCCC)OCCCCCCC PPBMHSGZZYZYBO-UHFFFAOYSA-N 0.000 description 1
- KENFVQBKAYNBKN-UHFFFAOYSA-N trihexadecyl phosphate Chemical compound CCCCCCCCCCCCCCCCOP(=O)(OCCCCCCCCCCCCCCCC)OCCCCCCCCCCCCCCCC KENFVQBKAYNBKN-UHFFFAOYSA-N 0.000 description 1
- SFENPMLASUEABX-UHFFFAOYSA-N trihexyl phosphate Chemical compound CCCCCCOP(=O)(OCCCCCC)OCCCCCC SFENPMLASUEABX-UHFFFAOYSA-N 0.000 description 1
- QXJQHYBHAIHNGG-UHFFFAOYSA-N trimethylolethane Chemical compound OCC(C)(CO)CO QXJQHYBHAIHNGG-UHFFFAOYSA-N 0.000 description 1
- ZOPCDOGRWDSSDQ-UHFFFAOYSA-N trinonyl phosphate Chemical compound CCCCCCCCCOP(=O)(OCCCCCCCCC)OCCCCCCCCC ZOPCDOGRWDSSDQ-UHFFFAOYSA-N 0.000 description 1
- QUTZUATVZPXUJR-UHFFFAOYSA-N trinonyl phosphite Chemical compound CCCCCCCCCOP(OCCCCCCCCC)OCCCCCCCCC QUTZUATVZPXUJR-UHFFFAOYSA-N 0.000 description 1
- FDGZUBKNYGBWHI-UHFFFAOYSA-N trioctadecyl phosphate Chemical compound CCCCCCCCCCCCCCCCCCOP(=O)(OCCCCCCCCCCCCCCCCCC)OCCCCCCCCCCCCCCCCCC FDGZUBKNYGBWHI-UHFFFAOYSA-N 0.000 description 1
- QOQNJVLFFRMJTQ-UHFFFAOYSA-N trioctyl phosphite Chemical compound CCCCCCCCOP(OCCCCCCCC)OCCCCCCCC QOQNJVLFFRMJTQ-UHFFFAOYSA-N 0.000 description 1
- OEOJDBBVRPAIDK-UHFFFAOYSA-N tripentadecyl phosphate Chemical compound CCCCCCCCCCCCCCCOP(=O)(OCCCCCCCCCCCCCCC)OCCCCCCCCCCCCCCC OEOJDBBVRPAIDK-UHFFFAOYSA-N 0.000 description 1
- QJAVUVZBMMXBRO-UHFFFAOYSA-N tripentyl phosphate Chemical compound CCCCCOP(=O)(OCCCCC)OCCCCC QJAVUVZBMMXBRO-UHFFFAOYSA-N 0.000 description 1
- CVWUIWZKLYGDNJ-UHFFFAOYSA-N tripentyl phosphite Chemical compound CCCCCOP(OCCCCC)OCCCCC CVWUIWZKLYGDNJ-UHFFFAOYSA-N 0.000 description 1
- IKXFIBBKEARMLL-UHFFFAOYSA-N triphenoxy(sulfanylidene)-$l^{5}-phosphane Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=S)OC1=CC=CC=C1 IKXFIBBKEARMLL-UHFFFAOYSA-N 0.000 description 1
- XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 description 1
- YFTHZRPMJXBUME-UHFFFAOYSA-N tripropylamine Chemical compound CCCN(CCC)CCC YFTHZRPMJXBUME-UHFFFAOYSA-N 0.000 description 1
- KOWVWXQNQNCRRS-UHFFFAOYSA-N tris(2,4-dimethylphenyl) phosphate Chemical compound CC1=CC(C)=CC=C1OP(=O)(OC=1C(=CC(C)=CC=1)C)OC1=CC=C(C)C=C1C KOWVWXQNQNCRRS-UHFFFAOYSA-N 0.000 description 1
- HQUQLFOMPYWACS-UHFFFAOYSA-N tris(2-chloroethyl) phosphate Chemical compound ClCCOP(=O)(OCCCl)OCCCl HQUQLFOMPYWACS-UHFFFAOYSA-N 0.000 description 1
- XHTMGDWCCPGGET-UHFFFAOYSA-N tris(3,3-dichloropropyl) phosphate Chemical compound ClC(Cl)CCOP(=O)(OCCC(Cl)Cl)OCCC(Cl)Cl XHTMGDWCCPGGET-UHFFFAOYSA-N 0.000 description 1
- QQBLOZGVRHAYGT-UHFFFAOYSA-N tris-decyl phosphite Chemical compound CCCCCCCCCCOP(OCCCCCCCCCC)OCCCCCCCCCC QQBLOZGVRHAYGT-UHFFFAOYSA-N 0.000 description 1
- SVETUDAIEHYIKZ-IUPFWZBJSA-N tris[(z)-octadec-9-enyl] phosphate Chemical compound CCCCCCCC\C=C/CCCCCCCCOP(=O)(OCCCCCCCC\C=C/CCCCCCCC)OCCCCCCCC\C=C/CCCCCCCC SVETUDAIEHYIKZ-IUPFWZBJSA-N 0.000 description 1
- 150000003648 triterpenes Chemical class 0.000 description 1
- WYFGCJADJYRNAK-UHFFFAOYSA-N tritetradecyl phosphate Chemical compound CCCCCCCCCCCCCCOP(=O)(OCCCCCCCCCCCCCC)OCCCCCCCCCCCCCC WYFGCJADJYRNAK-UHFFFAOYSA-N 0.000 description 1
- XEQUZHYCHCGTJX-UHFFFAOYSA-N tritridecyl phosphate Chemical compound CCCCCCCCCCCCCOP(=O)(OCCCCCCCCCCCCC)OCCCCCCCCCCCCC XEQUZHYCHCGTJX-UHFFFAOYSA-N 0.000 description 1
- SUZOHRHSQCIJDK-UHFFFAOYSA-N triundecyl phosphate Chemical compound CCCCCCCCCCCOP(=O)(OCCCCCCCCCCC)OCCCCCCCCCCC SUZOHRHSQCIJDK-UHFFFAOYSA-N 0.000 description 1
- UKPASDNOVTUNJT-UHFFFAOYSA-N triundecyl phosphite Chemical compound CCCCCCCCCCCOP(OCCCCCCCCCCC)OCCCCCCCCCCC UKPASDNOVTUNJT-UHFFFAOYSA-N 0.000 description 1
- WMYJOZQKDZZHAC-UHFFFAOYSA-H trizinc;dioxido-sulfanylidene-sulfido-$l^{5}-phosphane Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([S-])=S.[O-]P([O-])([S-])=S WMYJOZQKDZZHAC-UHFFFAOYSA-H 0.000 description 1
- QFKMMXYLAPZKIB-UHFFFAOYSA-N undecan-1-amine Chemical compound CCCCCCCCCCCN QFKMMXYLAPZKIB-UHFFFAOYSA-N 0.000 description 1
- 125000002948 undecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000010913 used oil Substances 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
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- C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
- C09K5/02—Materials undergoing a change of physical state when used
- C09K5/04—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa
- C09K5/041—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems
- C09K5/044—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems comprising halogenated compounds
- C09K5/045—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems comprising halogenated compounds containing only fluorine as halogen
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- C10M141/00—Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential
- C10M141/10—Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential at least one of them being an organic phosphorus-containing compound
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- C10M171/00—Lubricating compositions characterised by purely physical criteria, e.g. containing as base-material, thickener or additive, ingredients which are characterised exclusively by their numerically specified physical properties, i.e. containing ingredients which are physically well-defined but for which the chemical nature is either unspecified or only very vaguely indicated
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- C09K2205/00—Aspects relating to compounds used in compression type refrigeration systems
- C09K2205/10—Components
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- C09K2205/126—Unsaturated fluorinated hydrocarbons
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- C09K2205/24—Only one single fluoro component present
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- C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
- C10M2203/106—Naphthenic fractions
- C10M2203/1065—Naphthenic fractions used as base material
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- C10M2205/22—Alkylation reaction products with aromatic type compounds, e.g. Friedel-crafts
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- C10M2207/026—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings with tertiary alkyl groups
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- C10M2207/04—Ethers; Acetals; Ortho-esters; Ortho-carbonates
- C10M2207/042—Epoxides
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- C10M2207/28—Esters
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- C10M2207/2835—Esters of polyhydroxy compounds used as base material
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- C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/04—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to an alcohol or ester thereof; bound to an aldehyde, ketonic, ether, ketal or acetal radical
- C10M2209/043—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to an alcohol or ester thereof; bound to an aldehyde, ketonic, ether, ketal or acetal radical used as base material
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- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
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- C10M2209/105—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing three carbon atoms only
- C10M2209/1055—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing three carbon atoms only used as base material
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- C10M2219/08—Thiols; Sulfides; Polysulfides; Mercaptals
- C10M2219/082—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms
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- C10M2219/087—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Derivatives thereof, e.g. sulfurised phenols
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- C10M2223/041—Triaryl phosphates
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- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2020/00—Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
- C10N2020/09—Characteristics associated with water
- C10N2020/097—Refrigerants
- C10N2020/101—Containing Hydrofluorocarbons
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- C—CHEMISTRY; METALLURGY
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- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/10—Inhibition of oxidation, e.g. anti-oxidants
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/30—Refrigerators lubricants or compressors lubricants
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Abstract
【解決手段】本発明は、潤滑油基油、下記一般式(1)で表される化合物およびリン化合物を含有する不飽和フッ化炭化水素用冷凍機油組成物を提供する。また、本発明は、潤滑油基油、下記一般式(1)で表される化合物、リン化合物および不飽和フッ化炭化水素冷媒を含有する冷凍機用作動流体組成物を提供する。
[式中、R1およびR2は同一でも異なっていてもよく、それぞれ炭化水素基を示し、m、n、pおよびqは同一でも異なっていてもよく、それぞれm+n,p+qの合計が0〜5となる0〜5の整数を示す。ただし、nまたはqの少なくともいずれか一方は1以上である。また、tおよびuは同一でも異なっていてもよく、それぞれ0〜10の整数を示す。]
【選択図】なし
Description
(式中、R1およびR2は同一でも異なっていてもよく、それぞれ炭化水素基を示し、m、n、pおよびqは同一でも異なっていてもよく、それぞれm+n,p+qの合計が0〜5となる0〜5の整数を示す。ただし、nまたはqの少なくともいずれか一方は1以上である。また、tおよびuは同一でも異なっていてもよく、それぞれ0〜10の整数を示す。)
本発明の第1実施形態に係る不飽和フッ化炭化水素用冷凍機油組成物は、潤滑油基油、下記一般式(1)で表される化合物およびリン化合物を含有する。
(式中、R1およびR2は同一でも異なっていてもよく、それぞれ炭化水素基を示し、m、n、pおよびqは同一でも異なっていてもよく、それぞれm+n,p+qの合計が0〜5となる0〜5の整数を示す。ただし、nまたはqの少なくともいずれか一方は1以上である。また、tおよびuは同一でも異なっていてもよく、それぞれ0〜10の整数を示す。)
[式中、R3,R4およびR5は同一でも異なっていてもよく、それぞれ水素原子または炭素数1〜8の炭化水素基を示し、R6は炭素数1〜10の二価の炭化水素基または炭素数2〜20の二価のエーテル結合酸素含有炭化水素基を示し、R7は炭素数1〜20の炭化水素基を示し、rは前記ポリビニルエーテルについてのrの平均値が0〜10となるような数を示し、R3〜R7は構造単位毎に同一であっても異なっていてもよく、一の構造単位においてrが2以上である場合には、複数のR6Oは同一でも異なっていてもよい。]
R11−N=C=N−R12 (3)
(式中、R11およびR12は同一でも異なっていてもよく、それぞれ水素原子、炭化水素基、または窒素原子もしくは酸素原子を含有する炭化水素基を示す。)
[式中、R20、R21およびR22はそれぞれ水素原子または炭素原子数1〜10のアルキル基を示す。]
[式中、R23は水素原子または炭素数1〜10のアルキル基を示し、R24は水素原子、炭素数1〜10のアルキル基または上記一般式(4)で表される基を示し、R24が上記一般式(4)で表される基である場合、R20、R21およびR22の炭素数の合計は10以下であり、R25、R26およびR27は同一でも異なっていてもよく、それぞれ水素原子または炭素数1〜10のアルキル基を示し、R25、R26およびR27の炭素数の合計は10以下であり、nは2以上の整数である。]
本発明の第2実施形態に係る冷凍機用作動流体組成物は、潤滑油基油、上記一般式(1)で表される化合物(スルフィド化合物)、リン化合物及び不飽和フッ化炭化水素冷媒を含有する。なお、本実施形態に係る冷凍機用作動流体組成物には、上記第1実施形態に係る冷凍機油組成物と、不飽和フッ化炭化水素冷媒とを含有する態様が包含される。また、本実施形態において、潤滑油基油、一般式(1)で表される化合物、リン化合物及びそれ以外の添加剤、冷凍機油組成物の物性等は第1実施形態の場合と同様であり、ここでは重複する説明を省略する。冷凍機用作動流体組成物における添加剤の含有量は、冷凍機油組成物全量を基準とした換算値が第1実施形態に示した好ましい範囲内となるように選定することが望ましい。
実施例1〜12および比較例1〜14においては、それぞれ以下に示す基油1〜6および添加剤1〜10を用いて試料油を調製した。得られた各試料油の性状を以下に示す。なお、試験前の各試料油の酸価はすべて0.01mgKOH/gであった。
(基油)
基油1:ポリエチレンプロピレングリコールモノメチルエーテル(40℃における動粘度:73.2mm2/s、重量平均分子量:1700)
基油2:ポリプロピレングリコールジメチルエーテル(40℃における動粘度:46.5mm2/s、重量平均分子量:1100)
基油3:ポリビニルエーテル(40℃における動粘度:66.4mm2/s、重量平均分子量:910)
基油4:ペンタエリスリトールと2−エチルヘキサン酸/3,5,5−トリメチルヘキサン酸(50/50モル%)とのテトラエステル(40℃における動粘度:68.3mm2/s)
基油5:ナフテン系鉱油(40℃における動粘度:31.0mm2/s)
基油6:直鎖型アルキルベンゼン(40℃における動粘度:8.2mm2/s)
(添加剤)
添加剤1:4,4’−チオビス(3−メチル−6−ターシャリーブチルフェノール)
添加剤2:4,4’−チオビス(2,6−ジ−ターシャリーブチルフェノール)
添加剤3:ビス(3,5−ジ−ターシャリーブチル−4−ハイドロキシベンジル)スルフィド
添加剤4:ジヘキシルアシッドホスフェートのモノ(C11〜C14混合アルキル)アミン塩
添加剤5:トリクレジルホスフェート
添加剤6:2,6−ジ−ターシャリー−ブチル−p−クレゾール
添加剤7:p−ターシャリー−ブチルフェニルグリシジルエーテル
添加剤8:2−エチルヘキシルグリシジルエーテル
添加剤9:グリシジル−2,2−ジメチルオクタノエート
添加剤10:4,4’−ジチオビス(2,6−ジ−ターシャリーブチルフェノール)
添加剤11:4,4’−メチレンビス(3−メチル−6−ターシャリーブチルフェノール)
水分を100質量ppm以下に調整した試料油(初期色相L0.5)30gと、2,3,3,3−テトラフルオロプロペン30gと、触媒(鉄、銅、アルミの各線)とを200mlのステンレス製オートクレーブに封入した後、175℃に加熱して2週間保持し試験した。試験後は冷凍機油組成物の酸価を測定した。得られた結果を表1〜5に示す。
ASTM D2670に準拠し、2,3,3,3−テトラフルオロプロペン10L/hを試料油に吹き込みながら、油温80℃、荷重250LBにて1時間試験を行い、試験後のピン摩耗量を測定した。得られた結果を表1〜5に示す。
Claims (6)
- 一般式(1)において、tおよびuが0である化合物を含有する、請求項1に記載の冷凍機油組成物。
- リン化合物が、リン酸エステル、チオリン酸エステル、酸性リン酸エステル、酸性リン酸エステルのアミン塩、塩素化リン酸エステルおよび亜リン酸エステルからなる群より選ばれる少なくとも1種である、請求項1または2に記載の冷凍機油組成物。
- 一般式(1)において、tおよびuが0である化合物を含有する、請求項4に記載の冷凍機用作動流体組成物。
- リン化合物が、リン酸エステル、チオリン酸エステル、酸性リン酸エステル、酸性リン酸エステルのアミン塩、塩素化リン酸エステルおよび亜リン酸エステルからなる群より選ばれる少なくとも1種である、請求項4または5に記載の冷凍機用作動流体組成物。
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PCT/JP2013/081943 WO2014087903A1 (ja) | 2012-12-07 | 2013-11-27 | 冷凍機油組成物および冷凍機用作動流体組成物 |
US14/649,269 US20150307761A1 (en) | 2012-12-07 | 2013-11-27 | Refrigerant-oil composition and cooling-equipment working-fluid composition |
EP13861185.0A EP2930230A4 (en) | 2012-12-07 | 2013-11-27 | COOLING OIL COMPOSITION AND WORKING FLUID COMPOSITION FOR A COOLING DEVICE |
CN201380063601.0A CN104903431A (zh) | 2012-12-07 | 2013-11-27 | 冷冻机油组合物和冷冻机用工作流体组合物 |
KR1020157014107A KR20150093669A (ko) | 2012-12-07 | 2013-11-27 | 냉동기유 조성물 및 냉동기용 작동 유체 조성물 |
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Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0091828A1 (en) * | 1982-04-14 | 1983-10-19 | Hitachi, Ltd. | Process for producing rigid polyurethane foams |
JPH02242888A (ja) * | 1989-03-07 | 1990-09-27 | Idemitsu Kosan Co Ltd | 圧縮型冷凍機用潤滑油及びその製造方法 |
JPH03200895A (ja) * | 1989-12-28 | 1991-09-02 | Nippon Oil Co Ltd | 非塩素系フロン冷媒用冷凍機油 |
JPH03217495A (ja) * | 1990-01-23 | 1991-09-25 | Idemitsu Kosan Co Ltd | ポリカ―ボネート系合成潤滑油 |
JPH06128578A (ja) * | 1992-06-04 | 1994-05-10 | Idemitsu Kosan Co Ltd | 圧縮型冷凍機用潤滑油 |
JP2001226690A (ja) * | 2000-02-18 | 2001-08-21 | Japan Energy Corp | 冷凍装置用潤滑油組成物及び冷凍装置 |
JP2006512426A (ja) * | 2002-10-25 | 2006-04-13 | ハネウェル・インターナショナル・インコーポレーテッド | フッ素置換オレフィンを含有する組成物 |
WO2006094303A2 (en) * | 2005-03-04 | 2006-09-08 | E.I. Dupont De Nemours And Company | Compositions comprising a fluoroolefin |
WO2006103190A1 (de) * | 2005-03-29 | 2006-10-05 | Basf Aktiengesellschaft | VERFAHREN ZUR GEWINNUNG EINES STROMES VON KOHLENWASSERSTOFFEN, ENTHALTEND 4 BIS 12 KOHLENSTOFFATOME PRO MOLEKÜL, MIT ERHÖHTEM ANTEIL AN LINEAREN α-OLEFINEN |
Family Cites Families (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4812246A (en) * | 1987-03-12 | 1989-03-14 | Idemitsu Kosan Co., Ltd. | Base oil for lubricating oil and lubricating oil composition containing said base oil |
KR100288029B1 (ko) * | 1998-01-21 | 2001-04-16 | 다니구찌 이찌로오, 기타오카 다카시 | HFC-32, HFC-125 또는 HFC-134a를 사용하는 냉동기용 윤활유 조성물 |
LT1735400T (lt) * | 2004-04-16 | 2018-04-25 | Honeywell International Inc. | Panašios į azeotropinį mišinį tetrafluorpropeno ir pentafluorpropeno kompozicijos |
US7704931B2 (en) * | 2004-12-10 | 2010-04-27 | Chemtura Corporation | Lubricant compositions stabilized with multiple antioxidants |
US8535556B2 (en) * | 2006-03-30 | 2013-09-17 | E I Du Pont De Nemours And Company | Compositions comprising iodotrifluoromethane and stabilizers |
CN105154012B (zh) * | 2006-09-01 | 2018-07-20 | 科慕埃弗西有限公司 | 氟烯烃用的酚稳定剂 |
WO2008027517A1 (en) * | 2006-09-01 | 2008-03-06 | E. I. Du Pont De Nemours And Company | Thiol and thioether stabilizers for fluoroolefins |
ES2705488T3 (es) * | 2006-09-01 | 2019-03-25 | Chemours Co Fc Llc | Estabilizadores que contienen fósforo para fluoroolefinas |
US20080157023A1 (en) * | 2006-11-14 | 2008-07-03 | Samuels George J | Fluorocarbon stabilizers |
CN101970018A (zh) * | 2007-09-28 | 2011-02-09 | 纳幕尔杜邦公司 | 离子液体稳定剂组合物 |
JP5612250B2 (ja) * | 2008-03-07 | 2014-10-22 | 出光興産株式会社 | 冷凍機用潤滑油組成物 |
JP5689428B2 (ja) * | 2012-02-22 | 2015-03-25 | Jx日鉱日石エネルギー株式会社 | 冷凍機油組成物及びその製造方法、冷凍機用作動流体組成物 |
-
2012
- 2012-12-07 JP JP2012268308A patent/JP5946755B2/ja active Active
-
2013
- 2013-11-27 EP EP13861185.0A patent/EP2930230A4/en not_active Withdrawn
- 2013-11-27 KR KR1020157014107A patent/KR20150093669A/ko active Search and Examination
- 2013-11-27 US US14/649,269 patent/US20150307761A1/en not_active Abandoned
- 2013-11-27 WO PCT/JP2013/081943 patent/WO2014087903A1/ja active Application Filing
- 2013-11-27 CN CN201380063601.0A patent/CN104903431A/zh active Pending
- 2013-12-06 TW TW102144994A patent/TWI527897B/zh active
Patent Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0091828A1 (en) * | 1982-04-14 | 1983-10-19 | Hitachi, Ltd. | Process for producing rigid polyurethane foams |
JPH02242888A (ja) * | 1989-03-07 | 1990-09-27 | Idemitsu Kosan Co Ltd | 圧縮型冷凍機用潤滑油及びその製造方法 |
JPH03200895A (ja) * | 1989-12-28 | 1991-09-02 | Nippon Oil Co Ltd | 非塩素系フロン冷媒用冷凍機油 |
JPH03217495A (ja) * | 1990-01-23 | 1991-09-25 | Idemitsu Kosan Co Ltd | ポリカ―ボネート系合成潤滑油 |
JPH06128578A (ja) * | 1992-06-04 | 1994-05-10 | Idemitsu Kosan Co Ltd | 圧縮型冷凍機用潤滑油 |
JP2001226690A (ja) * | 2000-02-18 | 2001-08-21 | Japan Energy Corp | 冷凍装置用潤滑油組成物及び冷凍装置 |
JP2006512426A (ja) * | 2002-10-25 | 2006-04-13 | ハネウェル・インターナショナル・インコーポレーテッド | フッ素置換オレフィンを含有する組成物 |
WO2006094303A2 (en) * | 2005-03-04 | 2006-09-08 | E.I. Dupont De Nemours And Company | Compositions comprising a fluoroolefin |
WO2006103190A1 (de) * | 2005-03-29 | 2006-10-05 | Basf Aktiengesellschaft | VERFAHREN ZUR GEWINNUNG EINES STROMES VON KOHLENWASSERSTOFFEN, ENTHALTEND 4 BIS 12 KOHLENSTOFFATOME PRO MOLEKÜL, MIT ERHÖHTEM ANTEIL AN LINEAREN α-OLEFINEN |
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
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JP7488817B2 (ja) | 2019-07-05 | 2024-05-22 | Eneos株式会社 | 冷凍機用作動流体組成物、冷凍機油及び冷凍機 |
WO2023074686A1 (ja) * | 2021-10-27 | 2023-05-04 | 友光商事株式会社 | 冷媒圧縮式冷凍サイクル装置用作動媒体および該作動媒体を用いた冷凍サイクル装置 |
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WO2014087903A1 (ja) | 2014-06-12 |
EP2930230A1 (en) | 2015-10-14 |
EP2930230A4 (en) | 2015-12-09 |
TW201435081A (zh) | 2014-09-16 |
TWI527897B (zh) | 2016-04-01 |
KR20150093669A (ko) | 2015-08-18 |
JP5946755B2 (ja) | 2016-07-06 |
US20150307761A1 (en) | 2015-10-29 |
CN104903431A (zh) | 2015-09-09 |
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