JP2014019646A5 - - Google Patents
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- Publication number
- JP2014019646A5 JP2014019646A5 JP2012156512A JP2012156512A JP2014019646A5 JP 2014019646 A5 JP2014019646 A5 JP 2014019646A5 JP 2012156512 A JP2012156512 A JP 2012156512A JP 2012156512 A JP2012156512 A JP 2012156512A JP 2014019646 A5 JP2014019646 A5 JP 2014019646A5
- Authority
- JP
- Japan
- Prior art keywords
- independently
- carbons
- ring
- fluorine
- replaced
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- 150000001875 compounds Chemical class 0.000 claims description 24
- -1 1,4-phenylene, 1,4-phenylene Chemical group 0.000 claims description 23
- 239000000203 mixture Substances 0.000 claims description 10
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 claims 18
- 229910052731 fluorine Inorganic materials 0.000 claims 18
- 239000011737 fluorine Substances 0.000 claims 18
- 125000000217 alkyl group Chemical group 0.000 claims 16
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 14
- 229910052739 hydrogen Inorganic materials 0.000 claims 14
- 239000001257 hydrogen Substances 0.000 claims 14
- 125000003342 alkenyl group Chemical group 0.000 claims 10
- 229910052736 halogen Inorganic materials 0.000 claims 9
- 150000002367 halogens Chemical class 0.000 claims 9
- 239000004973 liquid crystal related substance Substances 0.000 claims 9
- 125000004955 1,4-cyclohexylene group Chemical group [H]C1([H])C([H])([H])C([H])([*:1])C([H])([H])C([H])([H])C1([H])[*:2] 0.000 claims 7
- 125000005714 2,5- (1,3-dioxanylene) group Chemical group [H]C1([H])OC([H])([*:1])OC([H])([H])C1([H])[*:2] 0.000 claims 4
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims 2
- 125000003302 alkenyloxy group Chemical group 0.000 claims 2
- 125000003545 alkoxy group Chemical group 0.000 claims 2
- 229910052801 chlorine Inorganic materials 0.000 claims 2
- 239000000460 chlorine Substances 0.000 claims 2
- 125000001140 1,4-phenylene group Chemical group [H]C1=C([H])C([*:2])=C([H])C([H])=C1[*:1] 0.000 claims 1
- 239000003963 antioxidant agent Substances 0.000 claims 1
- 230000003078 antioxidant effect Effects 0.000 claims 1
- 125000004432 carbon atom Chemical group C* 0.000 claims 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 claims 1
- 0 C*c1c(C)*ccc1* Chemical compound C*c1c(C)*ccc1* 0.000 description 13
- SUTQSIHGGHVXFK-UHFFFAOYSA-N 1,2,2-trifluoroethenylbenzene Chemical compound FC(F)=C(F)C1=CC=CC=C1 SUTQSIHGGHVXFK-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- DYLIWHYUXAJDOJ-OWOJBTEDSA-N (e)-4-(6-aminopurin-9-yl)but-2-en-1-ol Chemical compound NC1=NC=NC2=C1N=CN2C\C=C\CO DYLIWHYUXAJDOJ-OWOJBTEDSA-N 0.000 description 2
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 2
- OZAIFHULBGXAKX-VAWYXSNFSA-N AIBN Substances N#CC(C)(C)\N=N\C(C)(C)C#N OZAIFHULBGXAKX-VAWYXSNFSA-N 0.000 description 2
- GUUVPOWQJOLRAS-UHFFFAOYSA-N Diphenyl disulfide Chemical compound C=1C=CC=CC=1SSC1=CC=CC=C1 GUUVPOWQJOLRAS-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- MZRVEZGGRBJDDB-UHFFFAOYSA-N N-Butyllithium Chemical compound [Li]CCCC MZRVEZGGRBJDDB-UHFFFAOYSA-N 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 150000001499 aryl bromides Chemical class 0.000 description 2
- XJHCXCQVJFPJIK-UHFFFAOYSA-M caesium fluoride Chemical compound [F-].[Cs+] XJHCXCQVJFPJIK-UHFFFAOYSA-M 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000011541 reaction mixture Substances 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- JQXJBXVWVPVTOO-UHFFFAOYSA-L 4-diphenylphosphanylbutyl(diphenyl)phosphane;palladium(2+);dichloride Chemical compound Cl[Pd]Cl.C=1C=CC=CC=1P(C=1C=CC=CC=1)CCCCP(C=1C=CC=CC=1)C1=CC=CC=C1 JQXJBXVWVPVTOO-UHFFFAOYSA-L 0.000 description 1
- RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 239000012300 argon atmosphere Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- UUAGAQFQZIEFAH-UHFFFAOYSA-N chlorotrifluoroethylene Chemical group FC(F)=C(F)Cl UUAGAQFQZIEFAH-UHFFFAOYSA-N 0.000 description 1
- 238000004440 column chromatography Methods 0.000 description 1
- LTYMSROWYAPPGB-UHFFFAOYSA-N diphenyl sulfide Chemical compound C=1C=CC=CC=1SC1=CC=CC=C1 LTYMSROWYAPPGB-UHFFFAOYSA-N 0.000 description 1
- BLHLJVCOVBYQQS-UHFFFAOYSA-N ethyllithium Chemical compound [Li]CC BLHLJVCOVBYQQS-UHFFFAOYSA-N 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000012044 organic layer Substances 0.000 description 1
- 239000005297 pyrex Substances 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 229910000033 sodium borohydride Inorganic materials 0.000 description 1
- 239000012279 sodium borohydride Substances 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- NHDIQVFFNDKAQU-UHFFFAOYSA-N tripropan-2-yl borate Chemical compound CC(C)OB(OC(C)C)OC(C)C NHDIQVFFNDKAQU-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2012156512A JP2014019646A (ja) | 2012-07-12 | 2012-07-12 | フルオロビニル基を有する液晶化合物、液晶組成物および液晶表示素子 |
| US13/938,912 US8956551B2 (en) | 2012-07-12 | 2013-07-10 | Liquid crystal compound having fluorovinyl group, liquid crystal composition and liquid crystal display device |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2012156512A JP2014019646A (ja) | 2012-07-12 | 2012-07-12 | フルオロビニル基を有する液晶化合物、液晶組成物および液晶表示素子 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2014019646A JP2014019646A (ja) | 2014-02-03 |
| JP2014019646A5 true JP2014019646A5 (enExample) | 2015-05-21 |
Family
ID=49945781
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2012156512A Pending JP2014019646A (ja) | 2012-07-12 | 2012-07-12 | フルオロビニル基を有する液晶化合物、液晶組成物および液晶表示素子 |
Country Status (2)
| Country | Link |
|---|---|
| US (1) | US8956551B2 (enExample) |
| JP (1) | JP2014019646A (enExample) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10314763B2 (en) * | 2013-12-31 | 2019-06-11 | Teeny Clean, Llc | Eyelid care appliance |
| KR20180134851A (ko) * | 2016-04-27 | 2018-12-19 | 디아이씨 가부시끼가이샤 | 네마틱 액정 조성물 및 이를 사용한 액정 표시 소자 |
| JP6805698B2 (ja) * | 2016-10-04 | 2020-12-23 | Dic株式会社 | E−オレフィン化合物の製造方法 |
| WO2018066371A1 (ja) * | 2016-10-04 | 2018-04-12 | Dic株式会社 | E-オレフィン化合物の製造方法 |
| DE102018202805B4 (de) | 2017-10-04 | 2022-10-20 | Adidas Ag | Verbund-Sportartikel |
| CN116814276B (zh) * | 2023-06-06 | 2025-08-29 | 烟台显华科技集团股份有限公司 | 正介电各向异性液晶组合物及液晶显示器件 |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5308542A (en) | 1990-03-13 | 1994-05-03 | Merck Patent Gesellschaft Mit Beschrankter Haftung | 4,4'-disubstituted 2',3-difluorobisphenyls and a liquid-crystalline medium |
| JP2932101B2 (ja) * | 1991-03-26 | 1999-08-09 | 株式会社大塚製薬工場 | 血漿濾過法及びその装置 |
| DE4217248B4 (de) | 1991-06-05 | 2005-06-16 | Merck Patent Gmbh | Vinylverbindungen |
| DE69208351T2 (de) * | 1991-09-30 | 1996-06-13 | Hoffmann La Roche | Halovinylderivate |
| JPH09291050A (ja) * | 1996-04-25 | 1997-11-11 | Sumitomo Chem Co Ltd | フルオロビニレン誘導体、それを含有する液晶組成物および液晶素子 |
| JPH10204435A (ja) * | 1996-11-22 | 1998-08-04 | Sumitomo Chem Co Ltd | 液晶組成物およびこれを用いた液晶素子 |
-
2012
- 2012-07-12 JP JP2012156512A patent/JP2014019646A/ja active Pending
-
2013
- 2013-07-10 US US13/938,912 patent/US8956551B2/en active Active
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