JP2014007310A - 炭化珪素半導体装置の製造方法および炭化珪素半導体装置 - Google Patents
炭化珪素半導体装置の製造方法および炭化珪素半導体装置 Download PDFInfo
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- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 title claims abstract description 69
- 229910010271 silicon carbide Inorganic materials 0.000 title claims abstract description 69
- 239000004065 semiconductor Substances 0.000 title claims abstract description 49
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 32
- 238000000034 method Methods 0.000 claims abstract description 42
- 239000012535 impurity Substances 0.000 claims abstract description 32
- 238000010438 heat treatment Methods 0.000 claims abstract description 26
- 238000005468 ion implantation Methods 0.000 claims abstract description 15
- 230000003213 activating effect Effects 0.000 claims abstract description 4
- 230000000149 penetrating effect Effects 0.000 claims abstract description 4
- 238000005530 etching Methods 0.000 claims description 36
- 239000000758 substrate Substances 0.000 claims description 33
- 239000013078 crystal Substances 0.000 claims description 29
- 239000002131 composite material Substances 0.000 claims description 17
- 150000002500 ions Chemical class 0.000 claims description 6
- 230000003746 surface roughness Effects 0.000 claims description 6
- 230000001590 oxidative effect Effects 0.000 claims description 4
- 230000000704 physical effect Effects 0.000 claims description 3
- 238000009413 insulation Methods 0.000 abstract 1
- 239000010410 layer Substances 0.000 description 108
- 230000004913 activation Effects 0.000 description 13
- 125000004429 atom Chemical group 0.000 description 11
- 238000001020 plasma etching Methods 0.000 description 10
- 239000007789 gas Substances 0.000 description 9
- 238000004630 atomic force microscopy Methods 0.000 description 7
- 230000015556 catabolic process Effects 0.000 description 7
- 239000011229 interlayer Substances 0.000 description 6
- 230000003647 oxidation Effects 0.000 description 6
- 238000007254 oxidation reaction Methods 0.000 description 6
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 5
- 238000000137 annealing Methods 0.000 description 5
- 230000005684 electric field Effects 0.000 description 5
- 230000001681 protective effect Effects 0.000 description 5
- 239000000370 acceptor Substances 0.000 description 4
- 239000012159 carrier gas Substances 0.000 description 4
- 230000000737 periodic effect Effects 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 239000000460 chlorine Substances 0.000 description 3
- 230000007547 defect Effects 0.000 description 3
- 229910052814 silicon oxide Inorganic materials 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- 230000005540 biological transmission Effects 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000005229 chemical vapour deposition Methods 0.000 description 2
- 229910001882 dioxygen Inorganic materials 0.000 description 2
- 230000005669 field effect Effects 0.000 description 2
- 125000005843 halogen group Chemical group 0.000 description 2
- 238000002513 implantation Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 229910052698 phosphorus Inorganic materials 0.000 description 2
- 239000011574 phosphorus Substances 0.000 description 2
- 239000012495 reaction gas Substances 0.000 description 2
- 230000000007 visual effect Effects 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 238000007429 general method Methods 0.000 description 1
- 239000001307 helium Substances 0.000 description 1
- 229910052734 helium Inorganic materials 0.000 description 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
- 238000009616 inductively coupled plasma Methods 0.000 description 1
- 239000012212 insulator Substances 0.000 description 1
- 238000010884 ion-beam technique Methods 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 238000005268 plasma chemical vapour deposition Methods 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
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Abstract
【解決手段】炭化珪素から作られ第1の導電型を有する第1の層121が形成される。第1の層121上に位置し第1の導電型と異なる第2の導電型を有する第2の層122と、第2の層122上に位置し第1の導電型を有する第3の層123とが形成される。第2および第3の層122、123を形成する工程は、不純物イオン注入を行う工程と、不純物イオン注入によって注入された不純物を活性化するための熱処理を行う工程とを含む。熱処理を行う工程の後に、第3の層123および第2の層122を貫通する側壁を有し、第1の層121に至る底部を有するトレンチTRが形成される。トレンチTRの側壁を覆うゲート絶縁膜201が形成される。
【選択図】図1
Description
まずステップS31(図4)として、図8に示すように、n領域123およびコンタクト領域124上にマスク層247が形成される。マスク層247は、トレンチTR(図1)の位置に対応する位置においてn領域の一部を露出する開口部を有する。マスク層247としては、たとえばシリコン酸化膜などの絶縁膜を用いることができる。シリコン酸化膜は、プラズマCVD法などの堆積法によって形成することもできるが、熱酸化法によって形成することが好ましい。またマスク層247の開口部の形成は、エピタキシャル基板100に対するマスク層247のエッチング比が高い条件を用いたRIE(Reactive Ion Etching)を用いることが好ましい。
本実施の形態によれば、トレンチTRの側壁上においてチャネル面をなす表面SW(図1)が、ステップS22の活性化熱処理(図4)の後に形成される。よって、いったん形成されたチャネル面が活性化熱処理によって乱されることがない。これによりチャネル抵抗が抑制される。よってオン抵抗を小さくすることができる。
上述したように、トレンチTR(図1)の側壁はp型ボディ層122上において、チャネル面としての表面SWを有する。表面SWは好ましくは特殊面を有する。以下、この「特殊面」の詳細について説明する。
一般に、ポリタイプ4Hの炭化珪素単結晶を(000−1)面から見ると、図19に示すように、Si原子(またはC原子)は、A層の原子(図中の実線)と、この下に位置するB層の原子(図中の破線)と、この下に位置するC層の原子(図中の一点鎖線)と、この下に位置するB層の原子(図示せず)とが繰り返し設けられている。つまり4つの層ABCBを1周期としてABCBABCBABCB・・・のような周期的な積層構造が設けられている。
Claims (10)
- 炭化珪素半導体装置の製造方法であって、
炭化珪素から作られ第1の導電型を有する第1の層を形成する工程と、
前記第1の層上に位置し前記第1の導電型と異なる第2の導電型を有する第2の層と、前記第2の層上に位置し前記第1の導電型を有する第3の層とを形成する工程とを備え、前記第2および第3の層を形成する工程は、不純物イオン注入を行う工程と、前記不純物イオン注入によって注入された不純物を活性化するための熱処理を行う工程とを含み、前記炭化珪素半導体装置の製造方法はさらに
前記熱処理を行う工程の後に、前記第3の層および前記第2の層を貫通する側壁を有し、前記第1の層に至る底部を有するトレンチを形成する工程と、
前記トレンチの前記側壁を覆うゲート絶縁膜を形成する工程と、
前記ゲート絶縁膜上にゲート電極を形成する工程とを備える、炭化珪素半導体装置の製造方法。 - 前記不純物イオン注入を行う工程は、前記第2の導電型を前記第2の層に付与するための不純物を注入する工程と、前記第1の導電型を前記第3の層に付与するための不純物を注入する工程とを含む、請求項1に記載の炭化珪素半導体装置の製造方法。
- 前記トレンチを形成する工程は、前記第3の層上に、前記第3の層の一部を露出する開口部を有するマスク層を形成する工程と、前記マスク層を用いた、物理的作用を有する予備エッチングを行う工程と、前記予備エッチングを行う工程の後に、熱エッチングを行う工程とを含む、請求項1または2に記載の炭化珪素半導体装置の製造方法。
- 前記トレンチの底部を酸化することによって犠牲酸化膜を形成する工程と、前記犠牲酸化膜を除去する工程とをさらに備える、請求項1〜3のいずれか1項に記載の炭化珪素半導体装置の製造方法。
- 前記トレンチの前記底部への不純物イオン注入なしに前記ゲート絶縁膜および前記ゲート電極が形成される、請求項1〜4のいずれか1項に記載の炭化珪素半導体装置の製造方法。
- 第1の導電型を有する第1の層と、前記第1の層上の、前記第1の導電型と異なる第2の導電型を有する第2の層と、前記第2の層上の、前記第1の導電型を有する第3の層とを含む炭化珪素基板を備え、前記炭化珪素基板には、前記第3の層および前記第2の層を貫通する側壁を有し、前記第1の層に至る底部を有するトレンチが設けられており、前記第2の層は前記トレンチの前記側壁上において、表面粗さとして2nm以下のRMSを有する表面を有し、さらに
前記トレンチの前記側壁を覆うゲート絶縁膜と、
前記ゲート絶縁膜上のゲート電極とを備える、炭化珪素半導体装置。 - 前記第2の層は、ポリタイプ4Hの六方晶の結晶構造を有する炭化珪素から作られ、前記第2の層の前記表面は、面方位{0−33−8}を有する第1の面を含む、請求項6に記載の炭化珪素半導体装置。
- 前記表面は前記第1の面を微視的に含み、前記表面はさらに、面方位{0−11−1}を有する第2の面を微視的に含む、請求項7に記載の炭化珪素半導体装置。
- 前記第1および第2の面は、面方位{0−11−2}を有する複合面を構成している、請求項8に記載の炭化珪素半導体装置。
- 前記表面は{000−1}面に対して巨視的に62°±10°のオフ角を有する、請求項9に記載の炭化珪素半導体装置。
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
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JP2012142622A JP2014007310A (ja) | 2012-06-26 | 2012-06-26 | 炭化珪素半導体装置の製造方法および炭化珪素半導体装置 |
CN201380026644.1A CN104321876A (zh) | 2012-06-26 | 2013-04-19 | 用于制造碳化硅半导体器件的方法和碳化硅半导体器件 |
PCT/JP2013/061600 WO2014002589A1 (ja) | 2012-06-26 | 2013-04-19 | 炭化珪素半導体装置の製造方法および炭化珪素半導体装置 |
EP13810423.7A EP2866265A4 (en) | 2012-06-26 | 2013-04-19 | METHOD FOR PRODUCING A SILICON CARBIDE SUBSTITUTE COMPONENT AND SILICON CARBIDE SEMICONDUCTOR COMPONENT |
US13/901,310 US20130341648A1 (en) | 2012-06-26 | 2013-05-23 | Method for manufacturing silicon carbide semiconductor device and silicon carbide semiconductor device |
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US (1) | US20130341648A1 (ja) |
EP (1) | EP2866265A4 (ja) |
JP (1) | JP2014007310A (ja) |
CN (1) | CN104321876A (ja) |
WO (1) | WO2014002589A1 (ja) |
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JP2021082689A (ja) * | 2019-11-18 | 2021-05-27 | 富士電機株式会社 | 炭化珪素半導体装置および炭化珪素半導体装置の製造方法 |
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JP5954140B2 (ja) * | 2012-11-29 | 2016-07-20 | 住友電気工業株式会社 | 炭化珪素半導体装置 |
JP5649152B1 (ja) * | 2013-04-30 | 2015-01-07 | パナソニック株式会社 | 半導体装置及びその製造方法 |
JP6357869B2 (ja) * | 2014-05-20 | 2018-07-18 | 住友電気工業株式会社 | 炭化珪素半導体装置の製造方法 |
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JP2021082689A (ja) * | 2019-11-18 | 2021-05-27 | 富士電機株式会社 | 炭化珪素半導体装置および炭化珪素半導体装置の製造方法 |
Also Published As
Publication number | Publication date |
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EP2866265A1 (en) | 2015-04-29 |
CN104321876A (zh) | 2015-01-28 |
EP2866265A4 (en) | 2016-01-13 |
US20130341648A1 (en) | 2013-12-26 |
WO2014002589A1 (ja) | 2014-01-03 |
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