JP2013509490A - アルカリ金属および炭化水素を使用した石油原料の改質 - Google Patents
アルカリ金属および炭化水素を使用した石油原料の改質 Download PDFInfo
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Abstract
本方法は、石油原料(102)にアルカリ金属(108)及び改質剤炭化水素(106)を反応させる。アルカリ金属は、ヘテロ原子及び/又は1つ以上の重金属の一部と反応して、石油原料から分離可能な無機相を形成する。改質剤炭化水素は、石油原料(102)に結合し、生成物の炭素数を増加させる。生成物の炭素数の増加は、改質石油原料(116)エネルギー値を増加させる。
【選択図】図1
Description
Na3N+3H2S→3NaHS+NH3
石油原料は、Uintah Basin(米国ユタ州東部産)由来の(抽出された)石油原料を使用した。この石油原料は、硫黄および窒素を含むシェール油から成っていた。この石油原料は、遠心分離により固体分を除去した。遠心分離された石油原料は、以下の組成を有していた。
石油原料は、Uintah Basin(米国ユタ州東部産)由来の(抽出された)石油原料を使用した。この石油原料は、硫黄および窒素を含むシェール油から成っていた。この石油原料は、遠心分離により固体分を除去した。遠心分離された石油原料は、以下の組成を有していた。
石油原料は、Uintah Basin(米国ユタ州東部産)由来の(抽出された)上記と異なる石油原料を使用した。この石油原料は、硫黄および窒素を含むシェール油から成っていた。この石油原料は、遠心分離により固体分を除去した。遠心分離された石油原料は、以下の組成を有していた。
Claims (21)
- 少なくとも1つの炭素原子から成り、ヘテロ原子および/または1種以上の重金属を含む石油原料を所定量得る工程と、上記所定量の石油原料をアルカリ金属および改質剤炭化水素と反応させる反応工程と、分離工程とから成る石油原料の改質方法であって、上記反応工程において、上記改質剤炭化水素が少なくとも1つの炭素原子と少なくとも1つの水素原子とから成り、上記アルカリ金属は上記ヘテロ原子および/または1種以上の重金属と反応して1種以上の無機生成物を形成し、上記改質剤炭化水素が上記石油原料と反応して改質された石油原料を製造し、改質された石油原料の炭素原子数は改質前の石油原料の炭素原子数よりも多く、上記分離工程において改質された石油原料から上記無機生成物を分離することを特徴とする石油原料の改質方法。
- 上記アルカリ金属が、リチウム、ナトリウム及び/又はこれらのアロイから成る請求項1に記載の石油原料の改質方法。
- 上記改質剤炭化水素が、天然ガス、シェールガス及び/又はこれらの混合物である請求項1に記載の石油原料の改質方法。
- 上記改質剤炭化水素が、メタン、エタン、プロパン、ブタン、ペンタン、エテン、プロペン、ブテン、ペンテン、ジエン類、これらの異性体および/またはこれらの混合物から成る請求項1に記載の石油原料の改質方法。
- 上記反応が、約250psiを超える圧力下で行われる請求項1に記載の石油原料の改質方法。
- 上記反応が、約2500psi未満の圧力下で行われる請求項1に記載の石油原料の改質方法。
- 上記反応が、約室温より高い温度で行われる請求項1に記載の石油原料の改質方法。
- 上記反応が、約450℃未満の温度で行われる請求項1に記載の石油原料の改質方法。
- 上記反応が、上記アルカリ金属の融点よりも高く450℃未満の温度で行われる請求項6に記載の石油原料の改質方法。
- 上記反応において触媒を使用し、当該触媒がモリブデン、ニッケル、コバルト、これらのアロイ、酸化モリブデン、酸化ニッケル、酸化コバルト又はこれらの組合せから成る請求項1に記載の石油原料の改質方法。
- 上記無機生成物が、改質された石油原料から成る有機相から分離可能な相を形成する請求項1に記載の石油原料の改質方法。
- 更に、分離工程において、分離器にフラックスを添加する工程を含む請求項1に記載の石油原料の改質方法。
- 上記所定量の石油原料、アルカリ金属および改質剤炭化水素の反応において水素ガスを使用しない請求項1に記載の石油原料の改質方法。
- 改質された石油原料の水素対炭素の比率が、改質前の石油原料の水素対炭素の比率より大きい請求項1に記載の石油原料の改質方法。
- 改質された石油原料は、改質前の石油原料よりも大きなエネルギーを有する請求項1に記載の石油原料の改質方法。
- 改質された石油原料のヘテロ元素対炭素の比率が、改質前の石油原料のヘテロ元素対炭素の比率より小さい請求項1に記載の石油原料の改質方法。
- 更に、上記無機生成物からアルカリ金属を再生する工程を含む請求項1に記載の石油原料の改質方法。
- 少なくとも1つの炭素原子から成り、ヘテロ原子および/または1種以上の重金属を含む所定量の石油原料と、アルカリ金属と、少なくとも1つの炭素原子と少なくとも1つの水素原子とから成る改質剤炭化水素とから成る反応器であって、上記アルカリ金属は上記ヘテロ原子および/または1種以上の重金属と反応して1種以上の無機生成物を形成し、上記改質剤炭化水素が上記石油原料と反応して改質された石油原料を製造し、改質された石油原料の炭素原子数は改質前の石油原料の炭素原子数よりも多く、改質された石油原料のヘテロ元素対炭素の比率が改質前の石油原料のヘテロ元素対炭素の比率より小さいことを特徴とする反応器。
- 更に反応器が触媒を含み、当該触媒がモリブデン、ニッケル、コバルト、これらのアロイ、酸化モリブデン、酸化ニッケル、酸化コバルト又はこれらの組合せから成る請求項18に記載の反応器。
- 反応器に水素ガスを添加されない請求項18に記載の反応器。
- 上記アルカリ金属が、リチウム、ナトリウム及び/又はこれらのアロイから成り、上記改質剤炭化水素が、天然ガス、シェールガス、メタン、エタン、プロパン、ブタン、ペンタン、エテン、プロペン、ブテン、ペンテン、ジエン類、これらの異性体および/またはこれらの混合物から成る請求項18に記載の反応器。
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US25736909P | 2009-11-02 | 2009-11-02 | |
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PCT/US2010/054984 WO2011053919A2 (en) | 2009-11-02 | 2010-11-01 | Upgrading of petroleum oil feedstocks using alkali metals and hydrocarbons |
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EP (1) | EP2496669B1 (ja) |
JP (1) | JP5720055B2 (ja) |
KR (1) | KR101736753B1 (ja) |
CN (2) | CN102597177B (ja) |
BR (1) | BR112012010344A2 (ja) |
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JP2016521303A (ja) * | 2013-04-15 | 2016-07-21 | フィールド アップグレーディング リミテッド | アルカリ金属反応炭化水素からアルカリ金属塩を分離する方法 |
WO2018074009A1 (ja) * | 2016-10-19 | 2018-04-26 | 国立研究開発法人物質・材料研究機構 | アンモニアを合成する方法、および、その装置 |
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CN102597177A (zh) | 2012-07-18 |
CA2769863A1 (en) | 2011-05-05 |
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KR20120114227A (ko) | 2012-10-16 |
WO2011053919A3 (en) | 2011-09-22 |
US20110100874A1 (en) | 2011-05-05 |
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US8828220B2 (en) | 2014-09-09 |
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CA2769863C (en) | 2017-02-28 |
ES2656073T3 (es) | 2018-02-23 |
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CN104818047A (zh) | 2015-08-05 |
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