JP2013503682A - 工業用途に有用な電気分解装置及び方法 - Google Patents
工業用途に有用な電気分解装置及び方法 Download PDFInfo
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- JP2013503682A JP2013503682A JP2012527431A JP2012527431A JP2013503682A JP 2013503682 A JP2013503682 A JP 2013503682A JP 2012527431 A JP2012527431 A JP 2012527431A JP 2012527431 A JP2012527431 A JP 2012527431A JP 2013503682 A JP2013503682 A JP 2013503682A
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- Prior art keywords
- hydrogen peroxide
- peracid
- circuit
- acid
- carboxylic acid
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Abstract
【選択図】図1
Description
本願の開示内容は、工業用途、詳細には無菌包装用途に有用な電池の使用に関する。
食料品、飲料品及び乳製品市場では、常温保存可能な包装された液体及び半液体食料が豊富に存在する。常温保存可能な食料は、有用な保存期間を有しながらシール容器内において安全に貯蔵され、かつ非冷蔵貯蔵条件下で販売されることができるように処理されている食品である。これらの食料は、缶詰のスープから高酸性化炭酸飲料及びスポーツドリンクまで多岐にわたる。常温保存可能な食料を製造するために様々な技術が使用されている。そのような技術の一つは無菌包装である。典型的な無菌包装手順では、液体食品が加熱殺菌される一方で、食品包装が個別に化学殺菌される。次に、殺菌食品及び殺菌包装はまとめられ、殺菌条件下で殺菌封止される。結果として、常温保存可能な食品が得られる。
下記で定義される用語については、異なる定義が特許請求の範囲又は本明細書中のどこかで示されない限りは、これらの定義が適用されるものとする。
最初に、驚くべきことに、分割セル中の電気の使用が、過酸組成物中の過酸化水素を選択的に分解するのに特に有効であることが発見された。また、そのような電気分解プロセスが、無菌充填操作などの工業的操作に使用されるときに特に有利であることも発見された。
約0.00001質量%〜約0.5質量%の過酸化水素;
約0.1質量%〜約20.0質量%のC1〜C10カルボン酸;及び
約0.1質量%〜約2.0質量%のC1〜C10過酸
であることができる。
約0.00001質量%〜約0.5質量%の過酸化水素;
約0.1質量%〜約20.0質量%のC1〜C10カルボン酸;及び
約0.1質量%〜約2.0質量%のC1〜C10過酸
であることができる。
約0.00001質量%〜約0.5質量%の過酸化水素;
約0.1質量%〜約20.0質量%のC1〜C10カルボン酸;及び
約0.1質量%〜約2.0質量%のC1〜C10過酸
であることができる。
約0.00001質量%〜約0.5質量%の過酸化水素;
約0.1質量%〜約20.0質量%のC1〜C10カルボン酸;及び
約0.1質量%〜約2.0質量%のC1〜C10過酸
であることができる。
本開示内容では、抗菌組成物中の複数の所望の成分を選択的に分解するために分割セルを使用する。ある実施形態では、分割セルは、過酸、カルボン酸及び過酸化水素を含む組成物中の過酸化水素を分解する。分割セル中の電気は、過酸化水素を水及び酸素へ酸化する。電気の使用は、それが容易に適用され、制御可能であり、再循環している組成物中に第二の化学物質を導入する必要がないので好ましい。このプロセスに第二の化学物質を含有させることは、第二の用量制御、ハンドリング、監視及び第二の化学物質の予想可能な残留物に関する追加の規制認可を必要とするので好ましくない。
約0.00001質量%〜約0.5質量%の過酸化水素;
約0.1質量%〜約20.0質量%のC1〜C10カルボン酸;及び
約0.1質量%〜約2.0質量%のC1〜C10過酸
であることができる。
抗菌組成物は過酸化水素を含む。過酸化水素(H2O2)は、その低分子量(34.014g/モル)のために高比率の活性酸素を有し、かつ弱酸性、透明及び無色の液体であるために、本方法により処理されることができる多数の物質と混合可能であるという利点を提供する。
本開示内容の過酸抗菌組成物は、カルボン酸も含む。カルボン酸としては、式R−(COOH)n{式中、Rは、水素、アルキル、アルケニル、脂環式基、アリール、ヘテロアリール、又は複素環式基でよく、そしてnは1、2、又は3である}の任意の化合物が挙げられる。好ましくは、Rとしては、水素、アルキル、又はアルケニルが挙げられる。
本組成物は過酸も含む。過酸は、当技術分野ではペルカルボン酸、ペルオキシ酸、及びペルオキシカルボン酸としても知られている。
所望により、組成物を強化するために、組成物は、安定化剤、ヒドロトロープ、界面活性剤、消泡剤、腐食防止剤、レオロジー改質剤、染料、及び香料を含む追加の含有物を含むことができる。
所望により、組成物は、過酸及び過酸化水素を安定化し、かつ組成物内の構成成分の早過ぎる酸化を防止するために、安定化剤を含むことができる。
所望により、組成物は、ヒドロトロープカップリング剤又は可溶化剤を含むことができる。そのような材料は、組成物が相を安定かつ単純な高活性水溶液形態に確実に保てるように、使用されることができる。そのようなヒドロトロープ可溶化剤又はカップリング剤は、相安定性を維持するが、好ましくない複合相互作用にはならない濃度で使用されることができる。
所望により、組成物は、界面活性剤、又は複数の界面活性剤の混合物を含むことができる。界面活性剤としては、市販されているアニオン性、非イオン性、カチオン性及び両イオン性界面活性剤、並びにそれらの混合物を挙げることができる。実施形態では、界面活性剤は、非イオン性又はアニオン性界面活性剤を含む。界面活性剤の検討のためには“Kirk-Othmer, Encyclopedia of Chemical Technology,Third Edition,volume 8,pages 900-912”を参照されたい。
スルホナート、例えばアルキルスルホナート、アルキルベンゼンスルホナート(例えば、鎖状ドデシルベンゼンスルホン酸又はそれらの塩)、アルキルアリールスルホナート、スルホン酸化された脂肪酸エステルなど;スルフェート、例えば硫酸化アルコール、硫酸化アルコールエトキシレート、硫酸化アルキルフェノール、アルキルスルフェート、スルホスクシネート、アルキルエーテルスルフェートなど;並びにリン酸エステル、例えばアルキルリン酸エステル、エトキシ化アルコールリン酸エステルなどを含むことができる。好ましいアニオン性物質としては、ナトリウムアルキルアリールスルホナート、アルキルベンゼンスルホナート(例えば、鎖状ドデシルベンゼンスルホン酸又はそれらの塩)などが挙げられる。
所望により、組成物は消泡剤を含むことができる。一般に、消泡剤は、シリカ及びシリコーン;脂肪族酸又はエステル;アルコール;スルフェート又はスルホナート;アミン又はアミド;ハロゲン化化合物、例えばフルオロクロロ炭化水素など;植物油、ワックス、鉱油並びにそれらの硫酸化誘導体;並びにホスフェート及びリン酸エステル、例えばアルキル及びアルカリ性ジホスフェート、とりわけトリブチルホスフェート;並びにそれらの混合物を含むことができる。
所望により、組成物は腐食防止剤を含むことができる。有用な腐食防止剤としては、ポリカルボン酸、例えば短鎖カルボキシル二塩基酸、三塩基酸、及びリン酸エステル並びにそれらの組み合わせなどが挙げられる。有用なリン酸エステルとしては、アルキルリン酸エステル、モノアルキルアリールリン酸エステル、ジアルキルアリールリン酸エステル、トリアルキルアリールリン酸エステル、及びそれらの混合物、例えばヴィトコ・ケミカル社(Witco Chemical Company)から入手可能なEmphos PS 236などが挙げられる。他の有用な腐食防止剤としては、トリアゾール、例えばベンゾトリアゾール、トリルトリアゾール及びメルカプトベンゾチアゾールなど、並びにホスホネートとの組み合わせ、例えば1−ヒドロキシエチリデン−1,1−ジホスホン酸、並びに界面活性剤、例えばオレイン酸ジエタノールアミド及びナトリウムココアンホヒドロキシプロピルスルホナートなどが挙げられる。有用な腐食防止剤としては、ジカルボン酸などのポリカルボン酸が挙げられる。好ましい酸としては、アジピン酸、グルタル酸、コハク酸及びそれらの混合物が挙げられる。最も好ましいものは、アジピン酸、グルタル酸及びコハク酸の混合物であり、その混合物は、BASF社により名称「SOKALAN(登録商標) DCS」として販売されている原料である。
所望により、組成物は1つ以上のレオロジー改質剤を含むことができる。有用な水溶性又は水分散性レオロジー改質剤は、無機物又は有機物として分類されることができる。さらに、有機増粘剤は、天然ポリマー及び合成ポリマーに細分化されることができ、さらに後者は、合成天然物を主成分とするもの及び合成石油を主成分とするものに細分化される。
所望により、組成物は、様々な染料、香料を含む着臭剤、及び他の審美性強化剤を含むことができる。好ましい染料としては、FD&C染料、D&C染料などが挙げられる。
実施例1(単一セル実験)
実施例1では、単槽電池がペルオキシ酢酸(「POAA」)の存在下で過酸化水素を選択的に分解する能力を試験した。この実施例のために、2つの1インチ×3インチ×0.25インチの導電性グラファイト電極を、15%POAA平衡濃縮物のサンプルから形成されたPOAA溶液を含む単一ビーカーに入れて保持した。ビーカーをマグネチックスターラー(stirplate)上に置き、これらの電極をワイヤーにより可変出力電源に接続した。試験期間中は試験装置を室温に保った。
実施例2では、分割電気セルがPOAAの存在下で過酸化水素を選択的に分解する能力を比較した。この実験は、アノード及びカソードを2つの別のビーカーに分けたことを除いて、実施例1の実験と同様であった。
Claims (24)
- (a)過酸化水素、カルボン酸及び過酸を含む抗菌組成物を提供する工程;
(b)該抗菌組成物と流体連通している分割セルを提供する工程
を含む、抗菌組成物中で過酸化水素を選択的に分解する方法。 - 前記分割セルを使用して、少なくとも500ppmの前記過酸化水素を15分未満で分解する工程を含む、請求項1に記載の方法。
- 前記分割セルを使用して、前記過酸化水素、前記カルボン酸及び前記過酸の所定量を維持する工程を含む、請求項1に記載の方法。
- 前記過酸化水素、前記カルボン酸及び前記過酸の所定量は:
(i)約0.00001質量%〜約0.5質量%の過酸化水素;
(ii)約0.1質量%〜約20.0質量%のC1〜C10カルボン酸;及び
(iii)約0.1質量%〜約2.0質量%のC1〜C10過酸
である、請求項3に記載の方法。 - 前記分割セルは、塩橋を用いて互いに電気接続している第一の回路及び第二の回路を含み、該第一の回路は、アノードを含み、該第二の回路は、カソードを含み、該アノード及び該カソードは、該第一の回路と該第二の回路の間に電位を送る電源に接続されており;該第一の回路は、前記抗菌組成物を含み、そして第二の回路は、前記抗菌組成物から電子を受け入れることができる還元溶液を含む、請求項1に記載の方法。
- 前記過酸化水素、前記カルボン酸又は前記過酸の量を監視する工程、並びに前記電位を調整して、前記過酸化水素、前記カルボン酸及び前記過酸の所定量を維持する工程をさらに含む、請求項5に記載の方法。
- 無菌包装法の一部分である、請求項1に記載の方法。
- 前記電位は、調整器により調整される、請求項6に記載の方法。
- 塩橋を用いて互いに電気接続している第一の回路及び第二の回路を含む分割セルであって、該第一の回路はアノードを含み、そして該第二の回路はカソードを含む、分割セル;
該第一の回路と該第二の回路の間に電位を送る電源;
を含む、抗菌組成物中の過酸化水素、カルボン酸及び過酸の所定量を維持するための装置であって、該第一の回路は抗菌組成物を含み、該抗菌溶液は、過酸化水素、カルボン酸及び過酸の所定量を含み;該第二の回路は還元溶液を含み、そして該還元溶液は、該抗菌溶液から電子を受け入れ、かつ該塩橋を介して該第一の回路中へ電流を送ることができる、装置。 - 前記過酸化水素、前記カルボン酸及び前記過酸の所定量は:
(i)約0.00001質量%〜約0.5質量%の過酸化水素;
(ii)約0.1質量%〜約20.0質量%のC1〜C10カルボン酸;及び
(iii)約0.1質量%〜約2.0質量%のC1〜C10過酸
である、請求項9に記載の装置。 - 前記カルボン酸は、酢酸、オクタン酸及びそれらの混合物から成る群から選択され、そして前記過酸は、過酢酸、過オクタン酸及びそれらの混合物から成る群から選択される、請求項9に記載の装置。
- 過酸化水素又は過酸の量を測定し、前記電位を調整して過酸化水素、カルボン酸及び過酸の所定量を維持する調整器をさらに含む、請求項9に記載の装置。
- 溜め槽;
殺菌領域;
複数の所望の成分の所定量を含む抗菌組成物を該溜め槽から該殺菌領域へ送達する第一のライン;
該殺菌領域から該溜め槽又はドレーンへ該抗菌組成物を戻す第二のライン;
該溜め槽、該第一のライン又は該第二のラインに組み込まれている分割セルであって、該抗菌組成物中の複数の所望の成分の所定量を維持する分割セル;
該殺菌領域へすすぎ液を送達する第三のライン;
該殺菌領域から使用済みすすぎ液を送り出す第四のライン;及び
該第四のラインに組み込まれている単一セルであって、使用済みすすぎ液中の複数の所望の成分の所定量を分解する単一セル
を含む、無菌包装装置。 - 前記抗菌組成物の複数の所望の成分は、過酸化水素、カルボン酸及び過酸であり、
そして前記使用済みすすぎ液の複数の所望の成分は、過酸化水素及び過酸である、請求項13に記載の無菌包装装置。 - 無菌であるか、又は保存期間の長い充填装置によって包装を殺菌する方法であって:
(a) (i)過酸化水素;
(ii)カルボン酸;及び
(iii)過酸;
を含む抗菌組成物を溜め槽中で形成する工程;
(b)無菌ラインを用いて該溜め槽から包装へ該抗菌組成物を送達する工程;
(c)食品包装に入れられた最終食品を非冷蔵貯蔵条件下での供給販売に適したものにするために十分な量で、該組成物を包装ライン上の食品包装の表面へ適用する工程;
(d)分割セルを該包装ラインに組み込む工程;並びに
(e)該分割セルを用いて、該抗菌組成物中の過酸化水素、カルボン酸及び過酸の所定量を維持する工程
を含む方法。 - 前記分割セルは:
塩橋を用いて互いに流体連通している第一の回路及び第二の回路であって、該第一の回路はアノードを含み、そして該第二の回路はカソードを含む、第一の回路及び第二の回路;並びに
該第一の回路と該第二の回路の間に電位を送る電源;
を含み、該第一の回路は、前記抗菌組成物を含み、該第二の回路は、該第二の回路と流体連通している還元溶液を含み、そして該還元溶液は、該抗菌組成物から電子を受け入れ、かつ塩橋を介して該第一の回路中へ電流を送ることができる、請求項15に記載の方法。 - 過酸化水素、カルボン酸又は過酸の量を感知するセンサーからの測定値に応じて、前記分割セルを駆動する工程をさらに含む、請求項15に記載の方法。
- 時間を基準として前記分割セルを駆動する工程をさらに含む、請求項15に記載の方法。
- 前記過酸化水素、前記カルボン酸及び前記過酸の所定量は:
(i)約0.00001質量%〜約0.5質量%の過酸化水素;
(ii)約0.1質量%〜約20.0質量%のC1〜C10カルボン酸;及び
(iii)約0.1質量%〜約2.0質量%のC1〜C10過酸
である、請求項15に記載の方法。 - 前記カルボン酸は、酢酸、オクタン酸及びそれらの混合物から成る群から選択され、そして前記過酸は、過酢酸、過オクタン酸及びそれらの混合物から成る群から選択される、請求項15に記載の方法。
- (f)前記抗菌組成物を前記食品包装の表面に適用してから、すすぎ液を前記食品包装の表面に適用する工程;
(g)前記過酸化水素及び前記過酸を含む使用済みすすぎ液を集める工程;
(h)すすぎラインを用いて前記食品包装から該使用済みすすぎ液を送り出す工程;
(i)単一セルを該すすぎラインに組み込む工程;並びに
(j)単一セルを用いて、該使用済みすすぎ液中の前記過酸化水素及び前記過酸の所定量を分解する工程
をさらに含む、請求項15に記載の方法。 - (a)過酸化水素及び過酸を含む溶液を提供する工程;並びに
(b)該溶液と流体連通している単一電解槽を提供して、該過酸化水素及び該過酸の所定量を分解する工程
を含む、溶液中の過酸化水素及び過酸を非選択的に分解する方法。 - 前記溶液は、無菌包装の適用に由来するすすぎ液である、請求項22に記載の方法。
- 前記溶液は産業廃液である、請求項22に記載の方法。
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CN102481014A (zh) | 2012-05-30 |
JP6342870B2 (ja) | 2018-06-13 |
US8828316B2 (en) | 2014-09-09 |
JP5878470B2 (ja) | 2016-03-08 |
US20110052445A1 (en) | 2011-03-03 |
JP2016041270A (ja) | 2016-03-31 |
US20130291488A1 (en) | 2013-11-07 |
WO2011027288A3 (en) | 2011-08-04 |
US8617466B2 (en) | 2013-12-31 |
WO2011027288A2 (en) | 2011-03-10 |
CN102481014B (zh) | 2013-12-25 |
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