JP2013232393A - カルボニル末端基の量を減らしたフッ素化イオノマー - Google Patents
カルボニル末端基の量を減らしたフッ素化イオノマー Download PDFInfo
- Publication number
- JP2013232393A JP2013232393A JP2012236308A JP2012236308A JP2013232393A JP 2013232393 A JP2013232393 A JP 2013232393A JP 2012236308 A JP2012236308 A JP 2012236308A JP 2012236308 A JP2012236308 A JP 2012236308A JP 2013232393 A JP2013232393 A JP 2013232393A
- Authority
- JP
- Japan
- Prior art keywords
- fluoropolymer
- group
- groups
- end groups
- fluorinated
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F14/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F14/18—Monomers containing fluorine
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F214/18—Monomers containing fluorine
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F214/18—Monomers containing fluorine
- C08F214/26—Tetrafluoroethene
- C08F214/262—Tetrafluoroethene with fluorinated vinyl ethers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/18—Introducing halogen atoms or halogen-containing groups
- C08F8/20—Halogenation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/20—Manufacture of shaped structures of ion-exchange resins
- C08J5/22—Films, membranes or diaphragms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/20—Manufacture of shaped structures of ion-exchange resins
- C08J5/22—Films, membranes or diaphragms
- C08J5/2206—Films, membranes or diaphragms based on organic and/or inorganic macromolecular compounds
- C08J5/2218—Synthetic macromolecular compounds
- C08J5/2231—Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions involving unsaturated carbon-to-carbon bonds
- C08J5/2243—Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions involving unsaturated carbon-to-carbon bonds obtained by introduction of active groups capable of ion-exchange into compounds of the type C08J5/2231
- C08J5/225—Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions involving unsaturated carbon-to-carbon bonds obtained by introduction of active groups capable of ion-exchange into compounds of the type C08J5/2231 containing fluorine
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M6/00—Primary cells; Manufacture thereof
- H01M6/14—Cells with non-aqueous electrolyte
- H01M6/16—Cells with non-aqueous electrolyte with organic electrolyte
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
- C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
- C08J2327/12—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Electrochemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Conductive Materials (AREA)
- Fuel Cell (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Abstract
【解決手段】−CF2SO3X、−CF2SO2F、又はこれらの組み合わせを末端とする複数のペンダント基(式中、XはH+及び一価カチオンから成る群から選択される)、及び少なくとも1つの−CF2Y末端基(式中、Yは塩素原子、臭素原子、ヨウ素原子、ニトリル基、及び−SO3X基から成る群から選択される)を含むフルオロポリマーを用いる。
【選択図】なし
Description
好ましい実施形態を参照しながら本発明を説明してきたが、本発明の精神および範囲から逸脱しない形態および詳細の変更を行えることが、当業者であれば理解できるであろう。
[1]
−CF 2 SO 3 X、−CF 2 SO 2 F、又はこれらの組み合わせを末端とする複数のペンダント基(式中、XはH + 及びカチオンから成る群から選択される);並びに
少なくとも1つの−CF 2 Y末端基(式中、Yは塩素原子、臭素原子、ヨウ素原子、ニトリル基、及び−SO 3 X基から成る群から選択される)を含むフルオロポリマー。
[2]
Yが、塩素原子又は−SO 3 X基を含む、[1]に記載のフルオロポリマー。
[3]
前記フルオロポリマーが、塩又は擬ハロゲンの不存在下にて生成された類似のフルオロポリマーと比較して、少なくとも約25%少ないカルボニル末端基を有する、[1]に記載のフルオロポリマー。
[4]
過フッ素化主鎖を更に含む、[1]に記載のフルオロポリマー。
[5]
前記ペンダント基が、−O(CF 2 ) 4 SO 2 X、−O(CF 2 ) 4 SO 2 F、−OCF 2 CF(CF 3 )OCF 2 CF 2 SO 2 X、−OCF 2 CF(CF 3 )OCF 2 CF 2 SO 2 F、及びこれらの組み合わせからなる群から選択される、[1]に記載のフルオロポリマー。
[6]
[1]のフルオロポリマーを含む電解質膜。
[7]
前記電解質膜が、架橋している、[6]に記載の電解質膜。
[8]
一部分がフルオロポリマーから構成され、各フルオロポリマーが、−CF 2 SO 3 Xを末端とする複数のペンダント基(式中、XはH + 及びカチオンから成る群から選択される);並びに少なくとも1つの−CF 2 Y末端基(式中、Yは塩素原子及び−SO 3 X基から成る群から選択される)を含む、電解質膜。
[9]
前記フルオロポリマーが、塩又は擬ハロゲンの不存在下にて生成された類似のフルオロポリマーと比較して、少なくとも約25%少ないカルボニル末端基を有する、[8]に記載の電解質膜。
[10]
各フルオロポリマーが、少なくとも1つの−CF 3 末端基を更に含む、[8]に記載の電解質膜。
[11]
[8]に記載の電解質膜を備える、電気化学的デバイス。
[12]
前記フルオロポリマーを製造するために、塩、擬ハロゲン、又は当該塩及び当該擬ハロゲンの組み合わせの存在下で、フッ素化モノマーをラジカル重合させることを含み、ここで、前記フルオロポリマーが、−CF 2 SO 2 Fを末端とする複数のペンダント基及び少なくとも1つの−CF 2 Y末端基を含み、式中、Yが、塩素原子、臭素原子、ヨウ素原子、ニトリル基及び−SO 3 X基から成る群から選択され、式中、Xが、H + 及びカチオンから成る群から選択される、フルオロポリマー製造方法。
[13]
前記フルオロポリマーが、塩又は擬ハロゲンの不存在下にて生成された類似のフルオロポリマーと比較して、少なくとも約25%少ないカルボニル末端基を有する、[12]に記載のフルオロポリマー。
[14]
前記フルオロポリマーを加水分解させることを更に含み、ここで加水分解させることで、−CF 2 SO 2 Fを末端とする前記ペンダント基を−CF 2 SO 3 Xを末端とするペンダント基に実質的に転化させる、[12]に記載の方法。
[15]
フルオロポリマーの後フッ素化処理(post-fluorinating)を更に含み、当該後フッ素化処理が実質的に、−CF 2 Y末端基を−CF 3 末端基に転化させる、[12]に記載の方法。
[16]
前記フルオロポリマーを加水分解させることを更に含み、ここで、加水分解させることで、−CF 2 SO 2 Fを末端とする前記ペンダント基を−CF 2 SO 3 Xを末端とするペンダント基に実質的に転化させる、[15]に記載の方法。
[17]
前記ラジカル重合を、1以上の二亜硫酸塩の存在下で行なう、[12]に記載の方法。
[18]
前記ラジカル重合を、フルオロアルキルスルフィン酸塩、フルオロアルキルスルフィン酸、及びこれらの組み合わせから成る群から選択される1以上の化合物の存在下で行なう、[12]に記載の方法。
[19]
フッ素化モノマーを提供すること(ここで、前記フッ素化モノマーの少なくとも1つが、スルホニルフッ化物モノマーを含む);及び
前記フルオロポリマーを製造するために、塩、擬ハロゲン、又は当該塩及び当該擬ハロゲンの組み合わせの存在下で、フッ素化モノマーをラジカル反応させ、ここで、前記フルオロポリマーが、塩又は擬ハロゲンの不存在下にて生成された類似のフルオロポリマーと比較して、少なくとも約25%少ないカルボニル末端基を有すること、を含む、フルオロポリマーの製造方法。
[20]
フルオロポリマーが、−CF 2 SO 2 Fを末端とする複数のペンダント基を含む、[19]に記載の方法。
[21]
前記フルオロポリマーを加水分解して、当該フルオロポリマーが−CF 2 SO 3 Xを末端とする複数のペンダント基を含むようにすることを更に含み、ここで式中、XがH + 及び一価カチオンから成る群から選択される、[20]に記載の方法。
[22]
フルオロポリマーを後フッ素化処理(post-fluorinating)することを更に含む、[19]に記載の方法。
Claims (2)
- −CF2SO3X、−CF2SO2F、又はこれらの組み合わせを末端とする複数のペンダント基(式中、XはH+及びカチオンから成る群から選択される);並びに
少なくとも1つの−CF2Y末端基(式中、Yは塩素原子、臭素原子、ヨウ素原子、ニトリル基、及び−SO3X基から成る群から選択される)を含み、
塩又は擬ハロゲンの不存在下にて生成された類似のフルオロポリマーと比較して、少なくとも25%少ないカルボニル末端基を有する、フルオロポリマー。 - Yが、塩素原子、臭素原子、ヨウ素原子及びニトリル基から成る群から選択される、請求項1に記載のフルオロポリマー。
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US11/120,822 US7214740B2 (en) | 2005-05-03 | 2005-05-03 | Fluorinated ionomers with reduced amounts of carbonyl end groups |
US11/120,822 | 2005-05-03 |
Related Parent Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2008510114A Division JP5166248B2 (ja) | 2005-05-03 | 2006-05-02 | カルボニル末端基の量を減らしたフッ素化イオノマー |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2015215826A Division JP2016104854A (ja) | 2005-05-03 | 2015-11-02 | カルボニル末端基の量を減らしたフッ素化イオノマー |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2013232393A true JP2013232393A (ja) | 2013-11-14 |
JP5973319B2 JP5973319B2 (ja) | 2016-08-23 |
Family
ID=36808353
Family Applications (3)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2008510114A Expired - Fee Related JP5166248B2 (ja) | 2005-05-03 | 2006-05-02 | カルボニル末端基の量を減らしたフッ素化イオノマー |
JP2012236308A Expired - Fee Related JP5973319B2 (ja) | 2005-05-03 | 2012-10-26 | カルボニル末端基の量を減らしたフッ素化イオノマー |
JP2015215826A Withdrawn JP2016104854A (ja) | 2005-05-03 | 2015-11-02 | カルボニル末端基の量を減らしたフッ素化イオノマー |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2008510114A Expired - Fee Related JP5166248B2 (ja) | 2005-05-03 | 2006-05-02 | カルボニル末端基の量を減らしたフッ素化イオノマー |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2015215826A Withdrawn JP2016104854A (ja) | 2005-05-03 | 2015-11-02 | カルボニル末端基の量を減らしたフッ素化イオノマー |
Country Status (6)
Country | Link |
---|---|
US (2) | US7214740B2 (ja) |
EP (1) | EP1877454B1 (ja) |
JP (3) | JP5166248B2 (ja) |
KR (1) | KR20080003857A (ja) |
CN (1) | CN101171271B (ja) |
WO (1) | WO2006119224A1 (ja) |
Families Citing this family (39)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2010514140A (ja) * | 2006-12-21 | 2010-04-30 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | リチウムイオン電池および電気二重層キャパシタのための電極バインダー組成物および電極 |
US20100068592A1 (en) * | 2007-08-09 | 2010-03-18 | Matsushita Electric Industrial Co., Ltd. | Electrodes for use in hydrocarbon-based membrane electrode assemblies of direct oxidation fuel cells |
KR100978609B1 (ko) * | 2007-11-27 | 2010-08-27 | 한양대학교 산학협력단 | 불소가스를 이용한 직접불소화법에 의해 표면처리된수소이온전도성 고분자막, 이를 포함하는 막-전극 어셈블리및 연료전지 |
US8722809B2 (en) * | 2008-01-21 | 2014-05-13 | The University Of Tokyo | Process for preparing end-modified vinylidene fluoride elastomer |
KR100978553B1 (ko) * | 2008-07-10 | 2010-08-27 | 한양대학교 산학협력단 | 불소계 또는 부분불소계 분산제를 포함하는 불소계 고분자전해질막 및 이를 포함하는 연료전지 |
PL2145917T3 (pl) * | 2008-07-17 | 2012-11-30 | Gore W L & Ass Gmbh | Powłoka polimerowa zawierająca kompleks jonowego fluoropolieteru oraz środka przeciwjonowego |
JP5575885B2 (ja) | 2009-06-12 | 2014-08-20 | ソルヴェイ・スペシャルティ・ポリマーズ・イタリー・エッセ・ピ・ア | 低い表面張力、低い液体粘度および高い固体含量を有するフルオロイオノマー分散体 |
DK2588507T3 (da) * | 2010-07-01 | 2014-09-15 | Solvay Specialty Polymers It | Fremgangsmåde til behandling af sulfonylfluoridpolymerer |
EP2652049A4 (en) * | 2010-12-17 | 2016-01-13 | 3M Innovative Properties Co | FLUORINATED OLIGOMERS HAVING FRACTIONS CONTAINING PENDING BROMINE |
US20130245219A1 (en) * | 2010-12-20 | 2013-09-19 | E I Du Pont De Nemours And Company | Ionomers and ionically conductive compositions |
EP3138875B1 (en) | 2011-08-04 | 2019-11-20 | 3M Innovative Properties Company | Crosslinked fluorinated polymers with manganese or cerium as additives |
CN104798244B (zh) | 2013-10-31 | 2017-07-28 | 株式会社Lg化学 | 锂二次电池 |
EP3256501B1 (en) | 2015-02-12 | 2018-12-12 | 3M Innovative Properties Company | Tetrafluoroethylene/hexafluoropropylene copolymers including perfluoroalkoxyalkyl pendant groups and methods of making and using the same |
WO2016130914A1 (en) | 2015-02-12 | 2016-08-18 | 3M Innovative Properties Company | Tetrafluoroethylene/hexafluoropropylene copolymers including perfluoroalkoxyalkyl pendant groups |
CN107406550A (zh) | 2015-02-12 | 2017-11-28 | 3M创新有限公司 | 具有磺酰基基团的四氟乙烯共聚物 |
CN105037604B (zh) * | 2015-05-25 | 2017-10-10 | 上海交通大学 | 燃料电池用短链全氟磺酰胺阴离子离聚物及其制备和应用 |
WO2017053563A1 (en) | 2015-09-23 | 2017-03-30 | 3M Innovative Properties Company | Method of making a copolymer of tetrafluoroethylene having sulfonyl pendant groups |
CN111094438B (zh) | 2017-09-14 | 2022-11-08 | 3M创新有限公司 | 具有磺酰基侧基的氟化共聚物以及包含其的组合物和制品 |
US11767379B2 (en) | 2018-03-01 | 2023-09-26 | Daikin Industries, Ltd. | Method for manufacturing fluoropolymer |
US11014999B2 (en) * | 2018-04-24 | 2021-05-25 | Inhance Technologies, LLC | Systems and methods for processing fluoropolymer materials and related workpieces |
CN113039213B (zh) | 2018-11-19 | 2023-07-28 | 大金工业株式会社 | 改性聚四氟乙烯的制造方法和组合物 |
CN113039241B (zh) | 2018-11-19 | 2023-11-07 | 大金工业株式会社 | 组合物和拉伸体 |
CN113728014A (zh) | 2019-04-26 | 2021-11-30 | 大金工业株式会社 | 含氟聚合物水性分散液的制造方法、排水的处理方法和含氟聚合物水性分散液 |
CN113710620A (zh) | 2019-04-26 | 2021-11-26 | 大金工业株式会社 | 水的处理方法和组合物 |
CN114364710B (zh) | 2019-09-05 | 2024-02-09 | 大金工业株式会社 | 全氟弹性体的制造方法和组合物 |
WO2021045227A1 (ja) | 2019-09-05 | 2021-03-11 | ダイキン工業株式会社 | 組成物およびその製造方法 |
CN114651018A (zh) | 2019-11-19 | 2022-06-21 | 大金工业株式会社 | 含氟聚合物的制造方法、聚四氟乙烯的制造方法、全氟弹性体的制造方法和组合物 |
KR20220119048A (ko) | 2019-12-20 | 2022-08-26 | 쓰리엠 이노베이티브 프로퍼티즈 컴파니 | 플루오르화 공중합체 및 이를 포함하는 조성물 및 물품 |
CN115398684A (zh) | 2020-04-09 | 2022-11-25 | 3M创新有限公司 | 包含氟化聚合物和盐纳米粒子的复合材料以及包含其的制品 |
WO2022107891A1 (ja) | 2020-11-19 | 2022-05-27 | ダイキン工業株式会社 | 含フッ素エラストマー水性分散液の製造方法および組成物 |
JPWO2022107890A1 (ja) | 2020-11-19 | 2022-05-27 | ||
WO2022107894A1 (ja) | 2020-11-19 | 2022-05-27 | ダイキン工業株式会社 | ポリテトラフルオロエチレンの製造方法およびポリテトラフルオロエチレンを含有する組成物 |
KR20230150868A (ko) | 2021-03-10 | 2023-10-31 | 다이킨 고교 가부시키가이샤 | 도료 조성물, 도포막, 적층체 및 도장 물품 |
WO2022244784A1 (ja) | 2021-05-19 | 2022-11-24 | ダイキン工業株式会社 | フルオロポリマーの製造方法、ポリテトラフルオロエチレンの製造方法および組成物 |
CN117529511A (zh) | 2021-06-11 | 2024-02-06 | 大金工业株式会社 | 含氟弹性体水性分散液的制造方法、组合物和水性分散液 |
CN117500848A (zh) | 2021-06-30 | 2024-02-02 | 大金工业株式会社 | 含氟聚合物组合物的制造方法和含氟聚合物组合物 |
EP4365211A1 (en) | 2021-06-30 | 2024-05-08 | Daikin Industries, Ltd. | Method for producing high-purity fluoropolymer-containing composition, and high-purity fluoropolymer-containing composition |
WO2023057926A1 (en) | 2021-10-07 | 2023-04-13 | 3M Innovative Properties Company | Composite including fluorinated polymer and lithium fluoride nanoparticles and articles including the same |
WO2023165912A1 (en) * | 2022-03-01 | 2023-09-07 | Solvay Specialty Polymers Italy S.P.A. | Method for making fluoropolymers containing ion exchange groups |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS4623245B1 (ja) * | 1968-01-18 | 1971-07-02 | ||
JP2002305023A (ja) * | 2001-01-03 | 2002-10-18 | Ausimont Spa | 電気化学用のパーフルオロポリエーテル添加剤 |
JP2003518170A (ja) * | 1999-12-21 | 2003-06-03 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | フルオロオレフィンの重合における連鎖移動剤 |
JP2003305023A (ja) * | 2002-04-15 | 2003-10-28 | Koga Iryo Kenkyusho:Kk | 呼吸耐力予備指数測定装置 |
WO2005054363A1 (ja) * | 2003-12-01 | 2005-06-16 | Daikin Industries, Ltd. | 含フッ素ポリマー液状組成物及びフッ素系架橋体製造方法 |
Family Cites Families (34)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL251214A (ja) * | 1959-05-05 | |||
US3467636A (en) * | 1967-02-24 | 1969-09-16 | Du Pont | Redox catalyst system for preparing vinylidene fluoride interpolymers |
US4523039A (en) * | 1980-04-11 | 1985-06-11 | The University Of Texas | Method for forming perfluorocarbon ethers |
US4743658A (en) * | 1985-10-21 | 1988-05-10 | E. I. Du Pont De Nemours And Company | Stable tetrafluoroethylene copolymers |
US4742122A (en) * | 1985-10-25 | 1988-05-03 | E. I. Du Pont De Nemours And Company | Melt-processible tetrafluoroethylene/perfluoroolefin copolymers and processes for preparing them |
US4940525A (en) * | 1987-05-08 | 1990-07-10 | The Dow Chemical Company | Low equivalent weight sulfonic fluoropolymers |
IT1235545B (it) * | 1989-07-10 | 1992-09-09 | Ausimont Srl | Fluoroelastomeri dotati di migliore processabilita' e procedimento di preparazione |
US5285002A (en) * | 1993-03-23 | 1994-02-08 | Minnesota Mining And Manufacturing Company | Fluorine-containing polymers and preparation and use thereof |
US5639837A (en) * | 1996-06-04 | 1997-06-17 | E. I. Du Pont De Nemours And Company | Process for making fluoropolymers |
US5936060A (en) * | 1996-11-25 | 1999-08-10 | E. I. Du Pont De Nemours And Company | Perfluoroelastomer composition having improved processability |
US6042959A (en) * | 1997-10-10 | 2000-03-28 | 3M Innovative Properties Company | Membrane electrode assembly and method of its manufacture |
US6090895A (en) * | 1998-05-22 | 2000-07-18 | 3M Innovative Properties Co., | Crosslinked ion conductive membranes |
US6277512B1 (en) * | 1999-06-18 | 2001-08-21 | 3M Innovative Properties Company | Polymer electrolyte membranes from mixed dispersions |
US6423784B1 (en) * | 1999-12-15 | 2002-07-23 | 3M Innovative Properties Company | Acid functional fluoropolymer membranes and method of manufacture |
DE10112585A1 (de) * | 2000-03-15 | 2001-10-31 | Japan Storage Battery Co Ltd | Composit-Katalysator für eine Brennstoffzelle vom festen Polymer-Elektrolyt-Typ und Verfahren zu seiner Herstellung |
WO2001080336A2 (en) * | 2000-04-18 | 2001-10-25 | 3M Innovative Properties Company | Membrane electrode assembly having annealed polymer electrolyte membrane |
IT1318594B1 (it) | 2000-06-23 | 2003-08-27 | Ausimont Spa | Processo di polimerizzazione di monomeri solfonici. |
ITMI20012744A1 (it) | 2001-12-21 | 2003-06-21 | Ausimont Spa | Processo di polimerizzazione di monomeri solfonici |
US6812310B2 (en) * | 2002-06-21 | 2004-11-02 | 3M Innovative Properties Company | Process for producing fluoropolymers having a reduced amount of polar end groups |
US6803435B2 (en) * | 2002-07-18 | 2004-10-12 | 3M Innovative Properties Company | Curable fluoropolymers containing bromine groups having improved compression set |
US7345124B2 (en) * | 2002-07-24 | 2008-03-18 | Daikin Industries, Ltd. | Process for preparing fluorine-containing polymer |
DE60335627D1 (de) * | 2002-07-29 | 2011-02-17 | 3M Innovative Properties Co | Fluorelastomer und verfahren zur dessen herstellung |
US6838545B2 (en) * | 2002-11-08 | 2005-01-04 | E. I. Du Pont De Nemours And Company | Reaction of fluoropolymer melts |
KR20050086728A (ko) * | 2002-11-20 | 2005-08-30 | 쓰리엠 이노베이티브 프로퍼티즈 캄파니 | 니트릴 말단기를 가지는 플루오로중합체의 제조 방법 |
US20040116742A1 (en) * | 2002-12-17 | 2004-06-17 | 3M Innovative Properties Company | Selective reaction of hexafluoropropylene oxide with perfluoroacyl fluorides |
US6624328B1 (en) * | 2002-12-17 | 2003-09-23 | 3M Innovative Properties Company | Preparation of perfluorinated vinyl ethers having a sulfonyl fluoride end-group |
US7348088B2 (en) * | 2002-12-19 | 2008-03-25 | 3M Innovative Properties Company | Polymer electrolyte membrane |
US7071271B2 (en) * | 2003-10-30 | 2006-07-04 | 3M Innovative Properties Company | Aqueous emulsion polymerization of functionalized fluoromonomers |
US7265162B2 (en) * | 2003-11-13 | 2007-09-04 | 3M Innovative Properties Company | Bromine, chlorine or iodine functional polymer electrolytes crosslinked by e-beam |
ATE529451T1 (de) | 2003-11-17 | 2011-11-15 | 3M Innovative Properties Co | Wässrige ptfe-dispersionen mit einem niedrigen gehalt an fluorierten emulgatoren |
US7060738B2 (en) * | 2003-12-11 | 2006-06-13 | 3M Innovative Properties Company | Polymer electrolytes crosslinked by ultraviolet radiation |
US7173067B2 (en) * | 2003-12-17 | 2007-02-06 | 3M Innovative Properties Company | Polymer electrolyte membranes crosslinked by direct fluorination |
EP1634895B1 (en) * | 2004-09-09 | 2008-11-05 | 3M Innovative Properties Company | Fluoropolymer for making a fluoroelastomer |
GB0427913D0 (en) * | 2004-12-21 | 2005-01-19 | 3M Innovative Properties Co | Fluoropolymer for making a fluoroelastomer |
-
2005
- 2005-05-03 US US11/120,822 patent/US7214740B2/en active Active
-
2006
- 2006-05-02 WO PCT/US2006/016696 patent/WO2006119224A1/en active Application Filing
- 2006-05-02 JP JP2008510114A patent/JP5166248B2/ja not_active Expired - Fee Related
- 2006-05-02 KR KR1020077025468A patent/KR20080003857A/ko not_active Application Discontinuation
- 2006-05-02 EP EP06752039.5A patent/EP1877454B1/en not_active Not-in-force
- 2006-05-02 CN CN2006800154198A patent/CN101171271B/zh not_active Expired - Fee Related
-
2007
- 2007-04-03 US US11/695,654 patent/US20070185220A1/en not_active Abandoned
-
2012
- 2012-10-26 JP JP2012236308A patent/JP5973319B2/ja not_active Expired - Fee Related
-
2015
- 2015-11-02 JP JP2015215826A patent/JP2016104854A/ja not_active Withdrawn
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS4623245B1 (ja) * | 1968-01-18 | 1971-07-02 | ||
JP2003518170A (ja) * | 1999-12-21 | 2003-06-03 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | フルオロオレフィンの重合における連鎖移動剤 |
JP2002305023A (ja) * | 2001-01-03 | 2002-10-18 | Ausimont Spa | 電気化学用のパーフルオロポリエーテル添加剤 |
JP2003305023A (ja) * | 2002-04-15 | 2003-10-28 | Koga Iryo Kenkyusho:Kk | 呼吸耐力予備指数測定装置 |
WO2005054363A1 (ja) * | 2003-12-01 | 2005-06-16 | Daikin Industries, Ltd. | 含フッ素ポリマー液状組成物及びフッ素系架橋体製造方法 |
Also Published As
Publication number | Publication date |
---|---|
CN101171271A (zh) | 2008-04-30 |
EP1877454B1 (en) | 2014-01-22 |
JP2016104854A (ja) | 2016-06-09 |
EP1877454A1 (en) | 2008-01-16 |
JP5973319B2 (ja) | 2016-08-23 |
US20070185220A1 (en) | 2007-08-09 |
US7214740B2 (en) | 2007-05-08 |
CN101171271B (zh) | 2011-09-07 |
WO2006119224A1 (en) | 2006-11-09 |
JP5166248B2 (ja) | 2013-03-21 |
JP2008540738A (ja) | 2008-11-20 |
US20060252888A1 (en) | 2006-11-09 |
KR20080003857A (ko) | 2008-01-08 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP5973319B2 (ja) | カルボニル末端基の量を減らしたフッ素化イオノマー | |
EP3353221B1 (en) | Method of making a copolymer of tetrafluoroethylene having sulfonyl pendant groups | |
US7071271B2 (en) | Aqueous emulsion polymerization of functionalized fluoromonomers | |
JP2002088103A (ja) | スルホンモノマーの重合方法 | |
EP3426701B1 (en) | Fluorinated copolymer having sulfonyl pendant groups and method of making an ionomer | |
US20110303868A1 (en) | Cation conductive membranes comprising polysulfonic acid polymers and metal salts having an f-containing anion | |
JP2007513471A (ja) | 強化ポリマー電解質膜 | |
EP1525233B1 (en) | Fluorelastomer and process for making a fluoroelastomer | |
EP2493940B1 (en) | Process for the isolation of sulfonyl fluoride polymers and polymers obtained therefrom | |
JP5978762B2 (ja) | 含フッ素ポリマー水性分散体の製造方法及び精製含フッ素ポリマー水性分散体 | |
WO2018167189A1 (en) | Method for making fluoropolymers | |
JPWO2003106515A1 (ja) | スルホン酸官能基含有フッ素化単量体、それを含有する含フッ素共重合体、およびイオン交換膜 | |
TW202346456A (zh) | 製備官能化聚合物之方法 | |
JPS6258382B2 (ja) | ||
WO2022180547A1 (en) | Process for making a fluoropolymer and fluoropolymer made therefrom | |
WO2023165912A1 (en) | Method for making fluoropolymers containing ion exchange groups |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20140311 |
|
A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20140610 |
|
A602 | Written permission of extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A602 Effective date: 20140613 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20140819 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20150224 |
|
A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20150522 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20150605 |
|
A02 | Decision of refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A02 Effective date: 20150630 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20151102 |
|
A911 | Transfer to examiner for re-examination before appeal (zenchi) |
Free format text: JAPANESE INTERMEDIATE CODE: A911 Effective date: 20151110 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20160112 |
|
A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20160411 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20160614 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20160714 |
|
R150 | Certificate of patent or registration of utility model |
Ref document number: 5973319 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
LAPS | Cancellation because of no payment of annual fees |