JP2013129841A - デュアル硬化接着剤配合物 - Google Patents
デュアル硬化接着剤配合物 Download PDFInfo
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- JP2013129841A JP2013129841A JP2013024816A JP2013024816A JP2013129841A JP 2013129841 A JP2013129841 A JP 2013129841A JP 2013024816 A JP2013024816 A JP 2013024816A JP 2013024816 A JP2013024816 A JP 2013024816A JP 2013129841 A JP2013129841 A JP 2013129841A
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- Prior art keywords
- reactive adhesive
- adhesive
- adhesive according
- photoinitiator
- exposed
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J5/00—Adhesive processes in general; Adhesive processes not provided for elsewhere, e.g. relating to primers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/46—Polymerisation initiated by wave energy or particle radiation
- C08F2/48—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light
- C08F2/50—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light with sensitising agents
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
- C08F20/10—Esters
- C08F20/12—Esters of monohydric alcohols or phenols
- C08F20/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F20/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/40—Redox systems
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/04—Homopolymers or copolymers of esters
- C09J133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09J133/10—Homopolymers or copolymers of methacrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J5/00—Adhesive processes in general; Adhesive processes not provided for elsewhere, e.g. relating to primers
- C09J5/10—Joining materials by welding overlapping edges with an insertion of plastic material
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C35/00—Heating, cooling or curing, e.g. crosslinking or vulcanising; Apparatus therefor
- B29C35/02—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould
- B29C35/08—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould by wave energy or particle radiation
- B29C35/0805—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould by wave energy or particle radiation using electromagnetic radiation
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Abstract
【解決手段】遊離ラジカル重合可能なモノマー、還元剤、および光開始剤を含む第1の部分と、周囲温度で還元剤と反応することによって遊離ラジカル重合を開始および伝播することが可能である遊離ラジカルを生成する酸化剤およびエポキシ化合物を含む第2の部分とを含む2つの部分からなる反応性接着剤。
【選択図】なし
Description
本出願は、名称「デュアル硬化接着剤配合物」として2006年7月28日に出願した米国仮出願第60/820,680号、および名称「デュアル硬化接着剤配合物」として2006年12月15日に出願した米国仮出願第60/870,143号の利益を主張し、それらを参照により組み込むものである。
R3およびR4は、それぞれ独立に、水素、および直鎖または分枝で飽和または不飽和のC1〜C10アルキルからなる群から選択され;
Xはハロゲンである]。
a)重合可能な成分と、周囲温度ラジカル触媒系と、光開始剤とを含む接着剤に基材を接触させるステップと、
b)結合ライン中の過剰の接着剤が空気に曝露されるようになるまで基材を一緒に加圧することによって基材を接合するステップと、
c)周囲温度ラジカル触媒系によって接着剤が部分的なまたは全部の強度を発達させることが可能になるステップと、
d)空気曝露接着剤を活性化電磁エネルギーにさらすことによって接着剤の曝露部分を硬化させるステップと、を含む方法が提供される。
a)接着剤が、双方の基材を接触させ、基材間の領域を少なくとも部分的に充填し、少なくとも部分的に空気に曝露されるように、重合可能な成分と、周囲温度ラジカル触媒系と、光開始剤とを含む接着剤を2つの基材間に施用するステップと、
b)接着剤が、周囲温度ラジカル触媒系を介して少なくとも部分的に硬化することが可能になるステップと、
c)空気に曝露した接着剤部分を活性化電磁エネルギーで照射することによって光開始剤を介して接着剤の曝露部分を硬化させるステップと、を含む方法が提供される。
(a)第二のパネルのエッジが、第一のパネルのエッジを超えて延在するように、第二のパネルに隣接させるが接触はさせないように第一のパネルを配置するステップと、
(b)重合可能な成分と、周囲温度ラジカル触媒系と、光開始剤とを含む接着剤を2つのパネルの重なる部分の間に供給するステップと、
(c)第二のパネルの重なっていない部分を第一のパネルのエッジ上に折りたたむステップと、
(d)所定の距離だけ離れたままである点までパネルが相互に移動し、接着剤の少なくとも一部分が、第一および第二パネル間のギャップに滞留し、接着剤の一部分が大気に曝露されるように、パネルの重なる部分に圧力をかけるステップと、
(e)周囲温度での硬化が行われることが可能になるステップと、
(f)接着剤の曝露部分を電磁エネルギーにさらすことによって接着剤の曝露部分を硬化させるステップと、を含む方法が提供される。
本発明の一実施形態によれば、好ましい遊離ラジカル重合可能なモノマーは、−C=C−基の存在を特徴とするオレフィンモノマーを含む。代表的なオレフィンモノマーとして、メタクリル酸メチル、メタクリル酸エチル、メタクリル酸ブチル、アクリル酸メチル、アクリル酸ブチル、アクリル酸シクロヘキシル、アクリル酸ヘキシル、アクリル酸2−エチルヘキシル、アクリル酸ラウリル、アクリル酸エチル、ジエチレングリコールジメタクリレート、メタクリル酸ジシクロペンタジエニルオキシエチル、メタクリル酸シクロヘキシル、メタクリル酸ラウリル、メタクリル酸グリシジル、およびメタクリル酸テトラヒドロフルフリルなどの(メト)アクリル酸エステル;メタクリル酸;アクリル酸;イタコン酸、アクリロニトリル、メタクリロニトリル、アクリルアミド、およびメタクリルアミドなどの置換(メト)アクリル酸;スチレン;ビニルスチレン、クロロスチレン、メチルスチレン、およびn−ブチルスチレンなどの置換スチレン;酢酸ビニル;塩化ビニリデン;ならびに2,3−ジクロロ−1,3−ブタジエンおよび2−クロロ−1,3−ブタジエンなどのブタジエンが挙げられる。他のオレフィンモノマーとして、マレイン酸エステル;フマル酸エステル;スチレン、クロロスチレン、メチルスチレン、ブチルスチレン、およびビニルスチレンなどのスチレン化合物が挙げられる。
一実施形態では、接着剤は、周囲温度反応性レドックス開始剤または触媒系を含有する。周囲温度反応性触媒系は、よく知られたレドックスカップル系であるので、本明細書では深く詳細まで議論する必要はないが、それらは、少なくとも1つの酸化剤と、少なくとも1つの還元剤とを含み、それらは、周囲温度で共反応することによって付加重合反応を開始させ、接着剤を硬化させるのに有効な遊離ラジカルを生成する。適切なレドックス(酸化−還元)開始剤として、限定されないが、メタ亜硫酸水素ナトリウムおよび亜硫酸水素ナトリウムなどの還元剤と過硫酸塩開始剤の組合せ;有機過酸化物および第三級アミン(例えば、過酸化ベンゾイル+ジメチルアニリン)をベースとする系;および有機ヒドロペルオキシドおよび遷移金属、例えば、クメンヒドロペルオキシド+ナフテン酸コバルトをベースとする系が挙げられる。
光増感剤または光開始剤は、オレフィン性不飽和種の反応性をさらに促進することができる。光開始剤活性化ラジカル硬化系として用いられる有用な光開始剤は、当技術分野で周知である。適切な例として、ベンジルジメチルケタールおよび1−ヒドロキシシクロヘキシルフェニルケトンなどのアセトフェノン、2−メチル−2−ヒドロキシプロピオフェノンなどの置換α−ケトール、ベンゾインメチルエーテル、ベンゾインイソプロピルエーテルなどのベンゾインエーテル、アニソインメチルエーテルなどの置換ベンゾインエーテル、塩化芳香族スルホニル、光活性オキシム、2−イソプロピルチオキサントンと4−イソプロピルチオキサントンのブレンドなどチオキサントンベースの光開始剤、ならびに2,4,6−トリメチルベンゾイルジフェニルホスフィンオキシドなどのホスフィンオキシド光開始剤が挙げられる。本発明の一実施形態では、好ましい光開始剤は、α−ヒドロキシケトン開始剤を含む。
任意選択で、強化剤ポリマーは、主成分の約0から80重量%、より好ましくは、2〜50重量%で使用することができる。一例としての低分子量強化剤は、約18,000未満の重量平均分子量(Mw)、または約10,000未満の数平均分子量(Mn)を有する。強化剤ポリマー材料は、それ自体で重合可能かまたは少なくとも1つの上記の遊離ラジカル重合可能なモノマーと共重合可能であるオレフィン性不飽和構造を含んでも含まなくてもよい。重合材料は、例えば、多様な固体および液体エラストマー重合材料、特に、その全体の開示が参照により本明細書に組み込まれている特許文献7、特許文献8、特許文献9、特許文献3、および特許文献4に記載の液体オレフィン末端エラストマー;ならびに、その全体の開示が参照により本明細書に組み込まれている特許文献7、特許文献8、特許文献10、および特許文献9に記載のイソシアネート官能性プレポリマーとヒドロキシ官能性モノマーのオレフィンウレタン反応生成物であり得る。
本発明のさらなる実施形態は、接着促進剤をさらに含む。本発明の一実施形態による接着促進剤は、当業者にとってアクリル接着剤の接着を促進するのに有用であることが周知である任意の接着促進剤を含む。本発明の一実施形態による好ましい接着促進剤は、金属接着を向上させ、少なくとも1つのP−OH基、およびオレフィン基が存在することを特徴とする好ましくは末端に位置する少なくとも1つの有機部分を有するホスフィン酸、ホスホン酸、またはリン酸の任意の誘導体であってもよいリン含有化合物である。かかるリン化合物のリストは、特許文献7に見られる。
本発明のさらなる実施形態では、組成物は、エポキシ成分を任意選択で含む。本発明の一実施形態では、エポキシ成分は、分子当り統計的に1を超えるオキシラン環を有する硬化可能なエポキシ官能性化合物(液体樹脂)を含む(ポリエポキシド)。好ましいエポキシ官能性材料は、分子当り2つのエポキシ基を含有する。モノ官能性エポキシ化合物はまた、反応性希釈剤として働く粘度調整剤としてのポリエポキシド成分と合わせることができる。本発明で使用するのに適したエポキシ樹脂として、多価アルコールのポリグリシジルエーテル、およびポリカルボン酸のポリグリシジルエステルが挙げられる。ポリグリシジルエステルは、エピクロロヒドリンまたはエピブロモヒドリンなどのエピハロヒドリンをシュウ酸、コハク酸、グルタル酸、テレフタル酸、2,6−ナフタレンジカルボン酸、および二量体化リノール酸などの脂肪族または芳香族ポリカルボン酸と反応させることによって得ることができる。芳香族ポリオールのポリグリシダールエーテルが好ましく、アルカリの存在下でエピハロヒドリンをポリヒドロキシフェノール化合物と反応させることによって調製される。適切な出発ポリヒドロキシフェノールとして、レゾルシノール、カテコール、ヒドロキノン、ビスフェノールAとも呼ばれるビス(4−ヒドロキシフェニル)−2,2−プロパン、ビス(4−ヒドロキシフェニル)−1,1−イソブタン、4,4−ジヒドロキシベンゾフェノン、ビス(4−ヒドロキシフェノール)−1,1−エタン、ビス(2−ヒドロキシフェニル)−メタン、および1,5−ヒドロキシナフタレン、ならびにビスフェノールAのジグリシジルエーテルが挙げられる。
本発明の多様な実施形態の接着剤は、多数のパッケージ形態をとることができるが、その1つは、一方のパッケージまたは部分が重合可能なまたは反応性の成分と還元剤とを含有し、第二のパッケージまたは部分が酸化剤を含有する複数パックまたは2つの部分からなる接着剤系である。光開始剤は、いずれのパッケージと一緒に含まれてもよいが、本発明の好ましい実施形態では、光開始剤は、還元剤と一緒に含まれる。2つの部分からなる接着剤系は、当技術分野で周知であるのと同様のレオロジー調整剤、ワックス、安定剤、および充填剤を任意選択で含むことができる。
(1)結合活性化剤の全重量に対して約0.5から約50重量%の、レドックスカップル触媒系の酸化剤として機能し得る少なくとも1つの酸化剤と、
(2)結合活性化剤の全重量に対して約30から約99.5重量%の担体ビヒクルと、
を含む。
(I)以下のものを含む第一のパッケージと、
(a)(メト)アクリル酸;(メト)アクリル酸のエステル、アミド、またはニトリル;マレイン酸エステル;フマル酸エステル;ビニルエステル;共役ジエン;イタコン酸;スチレン化合物;およびハロゲン化ビニリデンからなる群から選択される、10〜90、好ましくは、20〜70重量%のオレフィンモノマー、
(b)酸化剤と相互作用をすることによって遊離ラジカル重合反応を開始および伝播することが可能である遊離ラジカルを生成する、0.05〜10、好ましくは、0.1〜6重量%の少なくとも1つの還元剤、
(c)全モノマー100部当り0.001から約10.0、好ましくは、0.01から約5.0重量部の光開始剤、
(d)10〜80、好ましくは、20〜50重量%の主強化剤、
(e)任意選択で1〜15、好ましくは、1〜10重量%の補助強化剤、
(f)任意選択で0.01〜20、好ましくは、2〜10重量%の、1つまたは複数のオレフィン基を有するリン含有化合物、
(II)周囲温度活性レドックスカップル触媒系の酸化剤であって、第一および第二のパッケージを混合することによって遊離ラジカル重合を開始および伝播させることが可能である遊離ラジカルを生成する場合、剤(b)と周囲温度で反応し、その量が剤(b)と相互作用するのに十分である酸化剤を含有する結合活性化剤を含む第二のパッケージと、
を含み、
重量%は、主成分の全量に対するものとする。
接着剤系を使用することによって鋼、アルミニウム、および銅などの金属表面を、金属、プラスチック、および他のポリマーを含めての多様な基材、強化プラスチック、ファイバ、ガラス、セラミックス、木材などに結合させることができる。本発明の一実施形態の特徴は、本明細書記載の接着剤組成物を用いることによって、鋼、アルミニウム、および銅などの金属基材を結合させることができ、接着剤の施用に先立つ金属表面の予備処理はたとえあったとしてもわずかであることである。さらには、本発明の一実施形態の接着剤系は、周囲温度での有効な結合を提供し、したがって、基材に接着剤系を施用するためにも、硬化させるためにも熱を必要としない。
以下のマスターバッチを調製した。
A側に添加された1%の光開始剤Bを含む上記のマスターバッチのビーズを基材に施用し、周囲温度で24時間硬化させた。表面に未硬化接着剤の薄膜を有する硬化接着剤を600mj/cm2のUV放射に曝露した。表面を粘着性なしにした。次いで、試料を塗装した。塗料が完全に硬化した後、ASTM F 1842−02に従って、クロスハッチ接着試験を実施したが、結果として得られた接着は優れていた。
以下の光開始剤を上記マスターバッチのA側に2および4重量%で加え、完全に混合した。
1.光開始剤なし
2.光開始剤C(2−イソプロピルおよび4−イソプロピルチオキサントンのブレンド)
3.光開始剤D(2,4,6−トリメチルベンゾイルジフェニルホスフィンオキシド)
これらの材料それぞれを体積比4:1で、上記マスターバッチのB側と一緒に混合し、幅0.25”のビーズになるように分配し、周囲温度で60分間硬化させた。硬化後、試料全ての表面は粘着性であった。次いで、試料全てを強度2000mJ/cm2でUV光に曝露した。双方の試料#2および#3の表面は、粘着性がなく、#1の表面は、粘着性のままであった。
代替のレドックス開始剤系を含む以下の配合物を調製した。
以下のマスターバッチを、実施例1と同様に、調製し、混合し、次いで施用し、硬化させた。結果は以下の通りである。
以下のマスターバッチを実施例1と同様にワックス成分の添加によって調製し、混合し、施用した。
Claims (31)
- (a)以下の成分を含む第一の部分と、
(i)少なくとも1つの遊離ラジカル重合可能なモノマー、
(ii)少なくとも1つの還元剤、および
(iii)光開始剤、
(b)周囲温度で還元剤と反応することによって遊離ラジカル重合を開始および伝播することが可能である遊離ラジカルを生成する酸化剤と、エポキシ化合物とを含む第二の部分と、
を含むことを特徴とする2つの部分からなる反応性接着剤。 - 光開始剤は、ホスフィンオキシド光開始剤を含むことを特徴とする請求項1に記載の反応性接着剤。
- 前記ホスフィンオキシド光開始剤は、2,4,6−トリメチルベンゾイルジフェニルホスフィンオキシドを含むことを特徴とする請求項2に記載の反応性接着剤。
- 前記エポキシ化合物は、ポリエポキシドを含むことを特徴とする請求項1に記載の反応性接着剤。
- 前記エポキシ化合物は、多価アルコールのポリグリシジルエーテル、およびポリカルボン酸のポリグリシジルエステルからなる群から選択されることを特徴とする請求項1に記載の反応性接着剤。
- 光開始剤は、α−ヒドロキシケトンを含むことを特徴とする請求項1に記載の反応性接着剤。
- 光開始剤は、2−ヒドロキシ−2−メチル−1−フェニル−1−プロパノンを含むことを特徴とする請求項1に記載の反応性接着剤。
- モノマーは、オレフィンモノマーを含むことを特徴とする請求項1に記載の反応性接着剤。
- モノマーは、メタクリル酸テトラヒドロフルフリル、メタクリル酸、およびメタクリル酸メチルのうちの少なくとも1つを含むことを特徴とする請求項1に記載の反応性接着剤。
- モノマーは、成分(a)、(b)、および(c)の全量に対して20〜70重量%の量で存在することを特徴とする請求項1に記載の反応性接着剤。
- 還元剤は、第三級アミンを含むことを特徴とする請求項1に記載の反応性接着剤。
- 還元剤は、N,N−ジイソプロパノール−p−クロロアニリン、N,N−ジイソプロパノール−p−ブロモアニリン、N,N−ジイソプロパノール−p−ブロモ−m−メチルアニリン、N,N−ジメチル−p−クロロアニリン、N,N−ジメチル−p−ブロモアニリン、N,N−ジエチル−p−クロロアニリン、およびN,N−ジエチル−p−ブロモアニリンから選択されることを特徴とする請求項1に記載の反応性接着剤。
- 酸化剤は、有機過酸化物を含むことを特徴とする請求項1に記載の反応性接着剤。
- 接着促進剤をさらに含むことを特徴とする請求項1に記載の反応性接着剤。
- 接着促進剤は、リン含有接着促進剤を含むことを特徴とする請求項1に記載の反応性接着剤。
- 接着促進剤は、主成分の全重量に対して0.01から20重量%を占めることを特徴とする16に記載の反応性接着剤。
- 強化剤をさらに含むことを特徴とする請求項1に記載の反応性接着剤。
- 強化剤は、ヒドロキシル末端ポリアルカジエンから製造されるオレフィン末端液体エラストマ−を含むことを特徴とする請求項18に記載の反応性接着剤。
- 強化剤は、A−B−Aブロックコポリマーを含み、Aブロックは、スチレン、環アルキル化スチレン、またはそれらの混合物から選択され、Bブロックは、共役ジエンまたはエチレン−プロピレンから選択されたTgが低いエラストマーセグメントであることを特徴とする請求項18に記載の反応性接着剤。
- 強化剤は、約1から10重量%の量で存在することを特徴とする請求項18に記載の反応性接着剤。
- 主成分の全重量に対して約1から約15重量%の量で存在する補助強化剤をさらに含むことを特徴とする請求項18に記載の反応性接着剤。
- (a)は、約18,000超のMwまたは約10,000超のMnを有する高分子量補助強化剤をさらに含むことを特徴とする請求項1に記載の反応性接着剤。
- (a)は、0.1から20重量%の、1つまたは複数のオレフィン基を有するリン含有化合物をさらに含むことを特徴とする請求項1に記載の反応性接着剤。
- 基材を一緒に結合させることによってアセンブリを形成する方法であって、
a)前記請求項1から24のいずれか一項に記載の反応性接着剤に基材を接触させるステップと、
b)結合ライン中の過剰の反応性接着剤が空気に曝露されるようになるまで基材を一緒に加圧することによって基材を接合するステップと、
c)反応性接着剤が部分的なまたは全部の強度を発達させることが可能になるステップと、
d)空気曝露反応性接着剤を活性化電磁エネルギーにさらすことによって反応性接着剤の曝露部分を硬化させるステップと、
を含むことを特徴とする方法。 - 基材を一緒に結合させることによってアセンブリを形成するための方法であって、
a)反応性接着剤が、双方の基材を接触させ、基材間の領域を少なくとも部分的に充填し、少なくとも部分的に空気に曝露されるように、前記請求項1から24のいずれか一項に記載の反応性接着剤を2つの基材間に施用するステップと、
b)反応性接着剤が、周囲温度ラジカル触媒系を介して少なくとも部分的に硬化することが可能になるステップと、
c)空気に曝露した反応性接着剤部分を活性化電磁エネルギーで照射することによって光開始剤を介して反応性接着剤の曝露部分を硬化させるステップと、
を含むことを特徴とする方法。 - ヘムフランジアセンブリを形成する方法であって、
(a)第二のパネルのエッジが、第一のパネルのエッジを超えて延在するように、第二のパネルに隣接させるが接触はさせないように第一のパネルを配置するステップと、
(b)前記請求項1から24のいずれか一項に記載の反応性接着剤を2つのパネルの重なる部分の間に供給するステップと、
(c)第二のパネルの重ならない部分を第一のパネルのエッジ上に折りたたむステップと、
(d)所定の距離だけ離れたままである点までパネルが相互に移動し、反応性接着剤の少なくとも一部分が、第一および第二パネル間のギャップに滞留し、反応性接着剤の一部分が大気に曝露されるように、パネルの重なる部分に圧力をかけるステップと、
(e)周囲温度での硬化が行われることが可能になるステップと、
(f)反応性接着剤の曝露部分を電磁エネルギーにさらすことによって反応性接着剤の曝露部分を硬化させるステップと、
を含むことを特徴とする方法。 - 接着剤の曝露部分を電磁エネルギーにさらす前は、反応性接着剤の曝露表面が粘着性であることを特徴とする請求項27に記載の方法。
- 反応性接着剤の曝露部分を電磁エネルギーにさらした後、表面が非粘着性であることを特徴とする請求項27に記載の方法。
- 電磁エネルギー源を備えるロボットアームによって、反応性接着剤が電磁エネルギーに曝露されることを特徴とする請求項27に記載の方法。
- 反応性接着剤が、制御可能なロボットアーム上に取り付けられたアプリケータチップを介して分配されることを特徴とする請求項27に記載の方法。
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US20080023131A1 (en) | 2008-01-31 |
CN101495293B (zh) | 2013-12-04 |
RU2458955C2 (ru) | 2012-08-20 |
KR20090040260A (ko) | 2009-04-23 |
US20120145312A1 (en) | 2012-06-14 |
CN101495293A (zh) | 2009-07-29 |
EP2046559B1 (en) | 2019-01-09 |
BRPI0714584A2 (pt) | 2013-04-30 |
CA2657991C (en) | 2015-04-07 |
WO2008014466A2 (en) | 2008-01-31 |
EP2046559A2 (en) | 2009-04-15 |
JP2010513573A (ja) | 2010-04-30 |
US8382929B2 (en) | 2013-02-26 |
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WO2008014466A3 (en) | 2008-03-13 |
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