JP2012526894A - ウレタン系感圧接着剤 - Google Patents

ウレタン系感圧接着剤 Download PDF

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Publication number
JP2012526894A
JP2012526894A JP2012510816A JP2012510816A JP2012526894A JP 2012526894 A JP2012526894 A JP 2012526894A JP 2012510816 A JP2012510816 A JP 2012510816A JP 2012510816 A JP2012510816 A JP 2012510816A JP 2012526894 A JP2012526894 A JP 2012526894A
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Japan
Prior art keywords
adhesive
film
group
pressure sensitive
urethane
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Withdrawn
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JP2012510816A
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English (en)
Japanese (ja)
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JP2012526894A5 (enExample
Inventor
エー.シャーマン オードリー
エム.タピオ スコット
ピー.ディジオ ジェイムズ
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3M Innovative Properties Co
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3M Innovative Properties Co
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Publication of JP2012526894A publication Critical patent/JP2012526894A/ja
Publication of JP2012526894A5 publication Critical patent/JP2012526894A5/ja
Withdrawn legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J151/00Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
    • C09J151/08Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G71/00Macromolecular compounds obtained by reactions forming a ureide or urethane link, otherwise, than from isocyanate radicals in the main chain of the macromolecule
    • C08G71/02Polyureas
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J175/00Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
    • C09J175/04Polyurethanes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G71/00Macromolecular compounds obtained by reactions forming a ureide or urethane link, otherwise, than from isocyanate radicals in the main chain of the macromolecule
    • C08G71/04Polyurethanes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J123/00Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
    • C09J123/02Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
    • C09J123/04Homopolymers or copolymers of ethene
    • C09J123/08Copolymers of ethene
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J175/00Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
    • C09J175/04Polyurethanes
    • C09J175/14Polyurethanes having carbon-to-carbon unsaturated bonds
    • C09J175/16Polyurethanes having carbon-to-carbon unsaturated bonds having terminal carbon-to-carbon unsaturated bonds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00Adhesives in the form of films or foils
    • C09J7/20Adhesives in the form of films or foils characterised by their carriers
    • C09J7/22Plastics; Metallised plastics
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00Adhesives in the form of films or foils
    • C09J7/30Adhesives in the form of films or foils characterised by the adhesive composition
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00Adhesives in the form of films or foils
    • C09J7/30Adhesives in the form of films or foils characterised by the adhesive composition
    • C09J7/38Pressure-sensitive adhesives [PSA]
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2170/00Compositions for adhesives
    • C08G2170/40Compositions for pressure-sensitive adhesives
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2203/00Applications of adhesives in processes or use of adhesives in the form of films or foils
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2203/00Applications of adhesives in processes or use of adhesives in the form of films or foils
    • C09J2203/322Applications of adhesives in processes or use of adhesives in the form of films or foils for the production of solar panels
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00Additional features of adhesives in the form of films or foils
    • C09J2301/30Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier
    • C09J2301/302Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier the adhesive being pressure-sensitive, i.e. tacky at temperatures inferior to 30°C
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00Additional features of adhesives in the form of films or foils
    • C09J2301/40Additional features of adhesives in the form of films or foils characterized by the presence of essential components
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2451/00Presence of graft polymer
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2475/00Presence of polyurethane
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/14Layer or component removable to expose adhesive
    • Y10T428/1476Release layer
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/28Web or sheet containing structurally defined element or component and having an adhesive outermost layer
    • Y10T428/2852Adhesive compositions
    • Y10T428/2878Adhesive compositions including addition polymer from unsaturated monomer
    • Y10T428/2887Adhesive compositions including addition polymer from unsaturated monomer including nitrogen containing polymer [e.g., polyacrylonitrile, polymethacrylonitrile, etc.]

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Adhesive Tapes (AREA)
  • Macromonomer-Based Addition Polymer (AREA)
  • Laminated Bodies (AREA)
JP2012510816A 2009-05-15 2010-04-20 ウレタン系感圧接着剤 Withdrawn JP2012526894A (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US17851409P 2009-05-15 2009-05-15
US61/178,514 2009-05-15
PCT/US2010/031689 WO2010132176A2 (en) 2009-05-15 2010-04-20 Urethane-based pressure sensitive adhesives

Related Child Applications (1)

Application Number Title Priority Date Filing Date
JP2015126463A Division JP2015232133A (ja) 2009-05-15 2015-06-24 ウレタン系感圧接着剤

Publications (2)

Publication Number Publication Date
JP2012526894A true JP2012526894A (ja) 2012-11-01
JP2012526894A5 JP2012526894A5 (enExample) 2013-06-06

Family

ID=43085500

Family Applications (2)

Application Number Title Priority Date Filing Date
JP2012510816A Withdrawn JP2012526894A (ja) 2009-05-15 2010-04-20 ウレタン系感圧接着剤
JP2015126463A Pending JP2015232133A (ja) 2009-05-15 2015-06-24 ウレタン系感圧接着剤

Family Applications After (1)

Application Number Title Priority Date Filing Date
JP2015126463A Pending JP2015232133A (ja) 2009-05-15 2015-06-24 ウレタン系感圧接着剤

Country Status (6)

Country Link
US (2) US9296933B2 (enExample)
EP (1) EP2430108A4 (enExample)
JP (2) JP2012526894A (enExample)
KR (1) KR101747980B1 (enExample)
CN (1) CN102459490B (enExample)
WO (1) WO2010132176A2 (enExample)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2014500348A (ja) * 2010-11-05 2014-01-09 スリーエム イノベイティブ プロパティズ カンパニー 抗滑り特性を有するシリコーン変性接着剤
JP2018155909A (ja) * 2017-03-17 2018-10-04 大日本印刷株式会社
WO2020039892A1 (ja) * 2018-08-23 2020-02-27 東レ株式会社 樹脂フィルム、積層体及び積層体の製造方法
WO2020162195A1 (ja) * 2019-02-06 2020-08-13 日東電工株式会社 粘着剤層付き反射防止フィルム、自発光型表示装置およびその製造方法

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EP2231804B1 (en) 2007-12-27 2016-09-07 3M Innovative Properties Company Urea-based pressure sensitive adhesives
KR20110041507A (ko) 2008-07-10 2011-04-21 쓰리엠 이노베이티브 프로퍼티즈 컴파니 점탄성 도광체
WO2010017087A1 (en) 2008-08-08 2010-02-11 3M Innovative Properties Company Lightguide having a viscoelastic layer for managing light
KR101747980B1 (ko) 2009-05-15 2017-06-15 쓰리엠 이노베이티브 프로퍼티즈 컴파니 우레탄계 감압 접착제
KR20130086206A (ko) 2010-06-29 2013-07-31 쓰리엠 이노베이티브 프로퍼티즈 컴파니 윈도우 필름의 적용 방법
US9079383B2 (en) 2010-11-29 2015-07-14 3M Innovative Properties Company Method of applying optical film to large format display panel
US9841534B2 (en) 2010-12-16 2017-12-12 3M Innovative Properties Company Methods for preparing optically clear adhesives and coatings
EP2678736B1 (en) 2011-02-25 2015-01-21 3M Innovative Properties Company Variable index light extraction layer for use in a front-lit reflective display device
WO2012116199A1 (en) 2011-02-25 2012-08-30 3M Innovative Properties Company Variable index light extraction layer and method of illuminating with same
WO2012116215A1 (en) 2011-02-25 2012-08-30 3M Innovative Properties Company Illumination article and device for front-lighting reflective scattering element
WO2012158414A1 (en) 2011-05-13 2012-11-22 3M Innovative Properties Company Back-lit transmissive display having variable index light extraction layer
CN103597379B (zh) 2011-05-25 2016-10-05 3M创新有限公司 光控膜
TWI564364B (zh) * 2011-10-24 2017-01-01 3M新設資產公司 微結構化光學透明黏著劑
JP6545097B2 (ja) * 2012-03-30 2019-07-17 スリーエム イノベイティブ プロパティズ カンパニー 尿素系及びウレタン系の感圧性接着剤ブレンド
EP2855144B1 (de) 2012-06-01 2017-06-21 Covestro Deutschland AG Mehrschichtaufbau als reflektor
EP2877883B1 (en) 2012-07-26 2017-08-23 3M Innovative Properties Company Heat de-bondable optical articles
CN104812859B (zh) 2012-07-26 2018-03-02 3M创新有限公司 可热脱粘的粘合剂制品
KR20150046204A (ko) 2012-08-24 2015-04-29 쓰리엠 이노베이티브 프로퍼티즈 컴파니 가변 굴절률 광 추출 층 및 그의 제조 방법
KR101596725B1 (ko) * 2013-05-22 2016-02-24 삼성디스플레이 주식회사 충전 필름 및 이를 이용한 유기 발광 디스플레이 장치의 제조 방법
JP2016524006A (ja) 2013-06-06 2016-08-12 スリーエム イノベイティブ プロパティズ カンパニー 構造化接着剤物品の調製方法
KR102251049B1 (ko) * 2013-06-06 2021-05-13 쓰리엠 이노베이티브 프로퍼티즈 컴파니 구조화된 적층 접착용품의 제조 방법
KR20160018654A (ko) 2013-06-06 2016-02-17 쓰리엠 이노베이티브 프로퍼티즈 캄파니 구조화된 접착 용품의 제조 방법
CN105377553B (zh) 2013-06-24 2018-05-04 3M创新有限公司 自润湿粘合剂组合物
JP2016527342A (ja) 2013-06-24 2016-09-08 スリーエム イノベイティブ プロパティズ カンパニー 自己浸潤型接着剤組成物
US10185058B2 (en) 2013-07-01 2019-01-22 3M Innovative Properties Company Protection film suitable for illuminated display devices
US10315399B2 (en) 2013-12-31 2019-06-11 Entrotech, Inc. Methods for application of polymeric film and related assemblies
WO2015120212A1 (en) 2014-02-07 2015-08-13 3M Innovative Properties Company Paint color evaluation system that facilitates examination of color at multiple angles and locations on a vehicle
SG11201606936RA (en) 2014-02-20 2016-09-29 3M Innovative Properties Co Multi-layer cover tape constructions with graphite coatings
US9823395B2 (en) 2014-10-17 2017-11-21 3M Innovative Properties Company Multilayer optical film having overlapping harmonics
WO2016099937A1 (en) 2014-12-16 2016-06-23 3M Innovative Properties Company Polyurethane pressure-sensitive adhesives
US10307985B2 (en) 2014-12-19 2019-06-04 3M Innovative Properties Company Adhesives to replace ink step bezels in electronic devices
AU2016214792B2 (en) 2015-02-02 2019-11-21 Coloplast A/S Ostomy device
GB201501965D0 (en) * 2015-02-05 2015-03-25 Lumina Adhesives Ab Polyurethane based switchable adhesives
DK3280368T3 (da) 2015-04-10 2019-09-23 Coloplast As Stomianordning
US20160311182A1 (en) 2015-04-21 2016-10-27 3M Innovative Properties Company Use of optically clear adhesives as skins to deliver flowable hot melt liquid optically clear adhesives
JP6800202B2 (ja) 2015-07-08 2020-12-16 スリーエム イノベイティブ プロパティズ カンパニー ポリオキソメタレートを含有するフォトクロミック物品並びに該物品の製造、及び使用方法
EP3120998A1 (en) * 2015-07-22 2017-01-25 Vampire Optical Coatings, Inc. Multilayer stack of polymer films
US10731045B2 (en) 2015-09-25 2020-08-04 3M Innovative Properties Company Curable infrared light absorbing printing ink and articles prepared with it
US10282583B2 (en) 2015-12-22 2019-05-07 Gemalto Sa Fingerprint imaging systems comprising self-wetting adhesive, films and methods
JP7163287B2 (ja) 2016-11-17 2022-10-31 コベストロ、ドイチュラント、アクチエンゲゼルシャフト 熱管理用ポリカーボネートの不透明多層体
WO2018091556A1 (de) 2016-11-17 2018-05-24 Covestro Deutschland Ag Transparenter mehrschichtkörper zum wärmemanagement
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US11054558B2 (en) 2016-12-02 2021-07-06 3M Innovative Properties Company Photochromic articles containing a porous material with a photochromic dye and fluid, methods of making and using
KR102458776B1 (ko) 2016-12-21 2022-10-25 쓰리엠 이노베이티브 프로퍼티즈 캄파니 전도성 입자, 물품 및 방법
WO2018118767A1 (en) 2016-12-22 2018-06-28 Avery Dennison Corporation Convertible pressure sensitive adhesives comprising urethane (meth) acrylate oligomers
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WO2019191509A1 (en) * 2018-03-28 2019-10-03 Benjamin Lund Thiol-acrylate polymers, methods of synthesis thereof and use in additive manufacturing technologies
US11739177B2 (en) 2018-04-20 2023-08-29 Adaptive 3D Technologies Sealed isocyanates
WO2019204770A1 (en) 2018-04-20 2019-10-24 Lund Benjamin R Sealed isocyanates
US11911956B2 (en) 2018-11-21 2024-02-27 Adaptive 3D Technologies Using occluding fluids to augment additive manufacturing processes
CN113646822B (zh) * 2019-02-02 2023-08-18 艾利丹尼森公司 哑光阻燃标签
KR102808712B1 (ko) * 2019-02-05 2025-05-15 에이지씨 가부시키가이샤 중합체, 경화성 조성물, 경화물, 점착 시트, 적층체 및 플렉시블 디스플레이
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US20160177149A1 (en) 2016-06-23
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