JP2012515242A5 - - Google Patents
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- JP2012515242A5 JP2012515242A5 JP2011545717A JP2011545717A JP2012515242A5 JP 2012515242 A5 JP2012515242 A5 JP 2012515242A5 JP 2011545717 A JP2011545717 A JP 2011545717A JP 2011545717 A JP2011545717 A JP 2011545717A JP 2012515242 A5 JP2012515242 A5 JP 2012515242A5
- Authority
- JP
- Japan
- Prior art keywords
- weight
- radical
- binders
- monomer
- copolymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000000034 method Methods 0.000 claims 21
- 239000000178 monomer Substances 0.000 claims 12
- 150000003254 radicals Chemical group 0.000 claims 11
- 239000011230 binding agent Substances 0.000 claims 10
- -1 acrylic ester Chemical class 0.000 claims 8
- 229920001577 copolymer Polymers 0.000 claims 7
- 239000000203 mixture Substances 0.000 claims 7
- 239000000725 suspension Substances 0.000 claims 6
- 239000000126 substance Substances 0.000 claims 5
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims 4
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 claims 3
- 125000000217 alkyl group Chemical group 0.000 claims 3
- 125000000129 anionic group Chemical group 0.000 claims 3
- 125000004432 carbon atom Chemical group C* 0.000 claims 3
- 239000003795 chemical substances by application Substances 0.000 claims 3
- 239000002245 particle Substances 0.000 claims 3
- 239000000049 pigment Substances 0.000 claims 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims 2
- 229920000896 Ethulose Polymers 0.000 claims 2
- 239000001859 Ethyl hydroxyethyl cellulose Substances 0.000 claims 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims 2
- 150000001336 alkenes Chemical group 0.000 claims 2
- 125000002877 alkyl aryl group Chemical group 0.000 claims 2
- 150000001408 amides Chemical class 0.000 claims 2
- 125000003118 aryl group Chemical group 0.000 claims 2
- 239000002270 dispersing agent Substances 0.000 claims 2
- 150000002170 ethers Chemical class 0.000 claims 2
- 235000019326 ethyl hydroxyethyl cellulose Nutrition 0.000 claims 2
- 230000003472 neutralizing effect Effects 0.000 claims 2
- TVFWYUWNQVRQRG-UHFFFAOYSA-N 2,3,4-tris(2-phenylethenyl)phenol Chemical compound C=1C=CC=CC=1C=CC1=C(C=CC=2C=CC=CC=2)C(O)=CC=C1C=CC1=CC=CC=C1 TVFWYUWNQVRQRG-UHFFFAOYSA-N 0.000 claims 1
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical group NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims 1
- 239000005995 Aluminium silicate Substances 0.000 claims 1
- 239000004215 Carbon black (E152) Substances 0.000 claims 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims 1
- 102000011632 Caseins Human genes 0.000 claims 1
- 108010076119 Caseins Proteins 0.000 claims 1
- 235000013162 Cocos nucifera Nutrition 0.000 claims 1
- 244000060011 Cocos nucifera Species 0.000 claims 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical group CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 claims 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical group C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims 1
- MXRIRQGCELJRSN-UHFFFAOYSA-N O.O.O.[Al] Chemical compound O.O.O.[Al] MXRIRQGCELJRSN-UHFFFAOYSA-N 0.000 claims 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims 1
- 229920002472 Starch Polymers 0.000 claims 1
- 239000002174 Styrene-butadiene Substances 0.000 claims 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 claims 1
- 230000002378 acidificating effect Effects 0.000 claims 1
- 229920005822 acrylic binder Polymers 0.000 claims 1
- 125000002009 alkene group Chemical group 0.000 claims 1
- RMRFFCXPLWYOOY-UHFFFAOYSA-N allyl radical Chemical compound [CH2]C=C RMRFFCXPLWYOOY-UHFFFAOYSA-N 0.000 claims 1
- 235000012211 aluminium silicate Nutrition 0.000 claims 1
- 239000007864 aqueous solution Substances 0.000 claims 1
- 125000003710 aryl alkyl group Chemical group 0.000 claims 1
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 claims 1
- 229910000019 calcium carbonate Inorganic materials 0.000 claims 1
- 239000005018 casein Substances 0.000 claims 1
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 claims 1
- 235000021240 caseins Nutrition 0.000 claims 1
- 229920002678 cellulose Polymers 0.000 claims 1
- 239000001913 cellulose Substances 0.000 claims 1
- 238000006243 chemical reaction Methods 0.000 claims 1
- 239000004927 clay Substances 0.000 claims 1
- 238000009833 condensation Methods 0.000 claims 1
- 230000005494 condensation Effects 0.000 claims 1
- 239000010459 dolomite Substances 0.000 claims 1
- 229910000514 dolomite Inorganic materials 0.000 claims 1
- 238000001035 drying Methods 0.000 claims 1
- DOEXKUOGPAEBAD-UHFFFAOYSA-N ethyl n-(2-methylprop-2-enoyl)carbamate Chemical compound CCOC(=O)NC(=O)C(C)=C DOEXKUOGPAEBAD-UHFFFAOYSA-N 0.000 claims 1
- IPZIVCLZBFDXTA-UHFFFAOYSA-N ethyl n-prop-2-enoylcarbamate Chemical compound CCOC(=O)NC(=O)C=C IPZIVCLZBFDXTA-UHFFFAOYSA-N 0.000 claims 1
- 125000000524 functional group Chemical group 0.000 claims 1
- 239000010440 gypsum Substances 0.000 claims 1
- 229910052602 gypsum Inorganic materials 0.000 claims 1
- 229930195733 hydrocarbon Natural products 0.000 claims 1
- 150000002430 hydrocarbons Chemical group 0.000 claims 1
- 229910052739 hydrogen Inorganic materials 0.000 claims 1
- 239000001257 hydrogen Substances 0.000 claims 1
- 230000002209 hydrophobic effect Effects 0.000 claims 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims 1
- 239000011976 maleic acid Substances 0.000 claims 1
- 229910000000 metal hydroxide Inorganic materials 0.000 claims 1
- 150000004692 metal hydroxides Chemical class 0.000 claims 1
- 229910044991 metal oxide Inorganic materials 0.000 claims 1
- 150000004706 metal oxides Chemical class 0.000 claims 1
- 239000010445 mica Substances 0.000 claims 1
- 229910052618 mica group Inorganic materials 0.000 claims 1
- 238000006386 neutralization reaction Methods 0.000 claims 1
- 125000005429 oxyalkyl group Chemical group 0.000 claims 1
- 239000003973 paint Substances 0.000 claims 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 claims 1
- 239000004033 plastic Substances 0.000 claims 1
- 229920003023 plastic Polymers 0.000 claims 1
- 238000006116 polymerization reaction Methods 0.000 claims 1
- 239000011118 polyvinyl acetate Substances 0.000 claims 1
- 239000011591 potassium Substances 0.000 claims 1
- 229910052700 potassium Inorganic materials 0.000 claims 1
- OCAAZRFBJBEVPS-UHFFFAOYSA-N prop-2-enyl carbamate Chemical compound NC(=O)OCC=C OCAAZRFBJBEVPS-UHFFFAOYSA-N 0.000 claims 1
- 235000018102 proteins Nutrition 0.000 claims 1
- 102000004169 proteins and genes Human genes 0.000 claims 1
- 108090000623 proteins and genes Proteins 0.000 claims 1
- 239000011734 sodium Substances 0.000 claims 1
- 229910052708 sodium Inorganic materials 0.000 claims 1
- 239000007787 solid Substances 0.000 claims 1
- 235000019698 starch Nutrition 0.000 claims 1
- 239000011115 styrene butadiene Substances 0.000 claims 1
- 229920003048 styrene butadiene rubber Polymers 0.000 claims 1
- 229920001909 styrene-acrylic polymer Polymers 0.000 claims 1
- 239000000454 talc Substances 0.000 claims 1
- 229910052623 talc Inorganic materials 0.000 claims 1
- 239000004408 titanium dioxide Substances 0.000 claims 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims 1
- ORGHESHFQPYLAO-UHFFFAOYSA-N vinyl radical Chemical compound C=[CH] ORGHESHFQPYLAO-UHFFFAOYSA-N 0.000 claims 1
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP09150759A EP2208761B1 (en) | 2009-01-16 | 2009-01-16 | Process to prepare self-binding pigment particles implementing acrylic comb copolymers with hydrophobic groups as coupling agents, self binding pigment particles and uses thereof |
| EP09150759.0 | 2009-01-16 | ||
| US20700409P | 2009-02-06 | 2009-02-06 | |
| US61/207,004 | 2009-02-06 | ||
| PCT/EP2010/050227 WO2010081785A1 (en) | 2009-01-16 | 2010-01-11 | Process to prepare self-binding pigment particles implementing acrylic comb copolymers with hydrophobic groups as coupling agents, self binding pigment particles and uses thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2012515242A JP2012515242A (ja) | 2012-07-05 |
| JP2012515242A5 true JP2012515242A5 (enExample) | 2012-10-18 |
Family
ID=40785602
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2011545717A Pending JP2012515242A (ja) | 2009-01-16 | 2010-01-11 | カップリング剤としての疎水性基を有するアクリル櫛型コポリマーを実現する自己結合性顔料粒子を調製する方法、自己結合性顔料粒子およびこの使用 |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US20120016061A1 (enExample) |
| EP (2) | EP2208761B1 (enExample) |
| JP (1) | JP2012515242A (enExample) |
| KR (1) | KR20110108365A (enExample) |
| CN (1) | CN102282220B (enExample) |
| CA (1) | CA2748915C (enExample) |
| DK (1) | DK2379649T3 (enExample) |
| ES (1) | ES2444966T3 (enExample) |
| HR (1) | HRP20140070T1 (enExample) |
| PT (1) | PT2379649E (enExample) |
| RU (1) | RU2531183C2 (enExample) |
| SI (1) | SI2379649T1 (enExample) |
| TW (1) | TWI516506B (enExample) |
| WO (1) | WO2010081785A1 (enExample) |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BR112013009011A2 (pt) | 2010-10-15 | 2019-11-26 | Cerealus Holdings Llc | composição de carga modificada para uso na fabricação de um ou mais produtos finais, respectivo método de fabricação e produto de papel |
| DK2455429T3 (da) * | 2010-11-19 | 2013-11-25 | Omya Int Ag | Fremgangsmåde til at fremstille vandige suspensioner af mineralmaterialer ved at anvende aminer kombineret med vinyl karboxyl polymerer |
| ES2444952T3 (es) | 2011-04-01 | 2014-02-27 | Omya International Ag | Procedimiento para preparar partículas de pigmento autoaglutinantes |
| ES2487639T3 (es) * | 2011-04-01 | 2014-08-22 | Omya International Ag | Híbrido de pigmentos autoaglutinantes |
| ES2536787T3 (es) | 2011-08-31 | 2015-05-28 | Omya International Ag | Proceso para preparar suspensiones de partículas de pigmentos autoaglutinantes |
| ES2456369T3 (es) | 2011-08-31 | 2014-04-22 | Omya International Ag | Híbrido de pigmentos autoaglutinantes |
| WO2013063199A1 (en) | 2011-10-26 | 2013-05-02 | Lubrizol Advanced Materials, Inc. | Dispersant composition |
| CN103917609B (zh) | 2011-10-26 | 2015-11-25 | 路博润高级材料公司 | 分散剂组合物 |
| ES2547097T3 (es) | 2012-03-23 | 2015-10-01 | Omya International Ag | Preparación de pigmentos |
| US9371435B2 (en) * | 2013-04-22 | 2016-06-21 | Ethox Chemicals, Llc | Additives to resin compositions for improved impact strength and flexibility |
| US10030335B2 (en) * | 2013-12-30 | 2018-07-24 | Kemira Oyj | Filler aggregate composition and its production |
| EP3018175B1 (en) | 2014-11-07 | 2019-02-06 | Omya International AG | A process for the preparation of flocculated filler particles |
| ES2672735T3 (es) | 2014-11-07 | 2018-06-15 | Omya International Ag | Un proceso para la preparación de partículas de carga floculadas |
| CN111648159B (zh) * | 2020-05-29 | 2022-03-11 | 仙鹤股份有限公司 | 一种防霉玻璃间隔纸的制备方法 |
| US20240294793A1 (en) * | 2021-06-02 | 2024-09-05 | Omya International Ag | Aqueous coating composition |
| FR3133610B1 (fr) * | 2022-03-18 | 2025-11-21 | Coatex Sas | Copolymère alkylé épaississant |
Family Cites Families (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5730555A (en) * | 1980-08-01 | 1982-02-18 | Kanzaki Paper Mfg Co Ltd | Wet crushing method for heavy calcium carbonate |
| CA2080961C (fr) * | 1991-11-12 | 2002-04-02 | Jean-Bernard Egraz | Agent de broyage et/ou de dispersion a base de polymeres et/ou copolymeres neutralises en partie par du magnesium pour suspensions aqueuses de materiaux mineraux en vue d'applications pigmentaires |
| FR2693203B1 (fr) * | 1992-07-01 | 1994-08-26 | Coatex Sas | Copolymère acrylique partiellement ou totalement hydrosoluble, réticulé ou non et son utilisation. |
| FR2766107B1 (fr) * | 1997-07-18 | 1999-08-20 | Pluss Stauffer Ag | Suspensions aqueuses de matieres minerales et leurs utilisations |
| JP4378446B2 (ja) * | 1999-04-27 | 2009-12-09 | サンノプコ株式会社 | 水系コーティング剤用改質剤 |
| JP2002265813A (ja) * | 2001-03-09 | 2002-09-18 | Toyo Ink Mfg Co Ltd | 顔料組成物および顔料分散体 |
| FR2846971B1 (fr) | 2002-11-08 | 2006-09-29 | Omya Ag | Utilisation d'un copolymere disposant d'au moins une fonction greffee alkoxy ou hydroxy polyalkylene glycol, comme agent ameliorant la brillance du papier et produits obtenus |
| FR2846972B1 (fr) | 2002-11-08 | 2005-02-18 | Omya Ag | Suspensions aqueuses de matieres minerales broyees, faiblement chargees ioniquement et leurs utilisations |
| DE10315363A1 (de) * | 2003-04-03 | 2004-10-14 | Basf Ag | Wässrige Anschlämmungen von feinteiligen Füllstoffen, Verfahren zu ihrer Herstellung und ihre Verwendung zur Herstellung füllstoffhaltiger Papiere |
| FR2873047B1 (fr) * | 2004-07-13 | 2007-10-05 | Coatex Soc Par Actions Simplif | Procede de broyage de matieres minerales en presence de liants, suspensions aqueuses obtenues et leurs utilisations |
| FR2873127B1 (fr) | 2004-07-13 | 2008-08-29 | Omya Development Ag | Procede de fabrication de particules pigmentaires autoliantes, seches ou en suspension ou dispersion aqueuses, contenant des matieres inorganiques et des liants |
| DE102005025374A1 (de) | 2005-05-31 | 2006-12-07 | Basf Ag | Polymer-Pigment-Hybride für die Papierherstellung |
| FR2907127B1 (fr) * | 2006-10-12 | 2011-07-29 | Coatex Sas | Utilisation d'une suspension et/ou d'une dispersion aqueuse de matieres minerales contenant un copolymere hydrosoluble a groupement hydrophobe dans la fabrication d'une feuille de papier. |
| FR2913427B1 (fr) | 2007-03-05 | 2011-10-07 | Omya Development Ag | Procede de broyage a sec d'un ou plusieurs materiaux comprenant au moins un carbonate de calcium |
| FR2913420B1 (fr) * | 2007-03-05 | 2009-05-01 | Coatex Soc Par Actions Simplif | Utilisation dans une composition de liant hydraulique,d'un carbonate de calcium broye a sec avec un copolymere de l'acide (meth) acrylique et une fonction alcoxy ou hydroxy polyalkyleneglycol. |
| DE602007007906D1 (de) * | 2007-05-11 | 2010-09-02 | Coatex Sas | Use of a reverse emulsion of an acrylamide polymer with an acrylic monomer as a stabilising agent and foam reducer, in a method for the grinding of mineral materials and binders in an aqueous medium. |
| EP1990376B1 (fr) * | 2007-05-11 | 2011-04-20 | Omya Development Ag | Procédé de broyage en millieu aqueux de matières minérales et de liants mettant en oeuvre une émulsion inverse d'un polymère de l'acrylamide avec un monomère acrylique |
-
2009
- 2009-01-16 EP EP09150759A patent/EP2208761B1/en not_active Not-in-force
- 2009-12-24 TW TW098144637A patent/TWI516506B/zh not_active IP Right Cessation
-
2010
- 2010-01-11 EP EP10700401.2A patent/EP2379649B1/en not_active Not-in-force
- 2010-01-11 CA CA2748915A patent/CA2748915C/en not_active Expired - Fee Related
- 2010-01-11 SI SI201030505T patent/SI2379649T1/sl unknown
- 2010-01-11 WO PCT/EP2010/050227 patent/WO2010081785A1/en not_active Ceased
- 2010-01-11 RU RU2011134295/05A patent/RU2531183C2/ru not_active IP Right Cessation
- 2010-01-11 CN CN201080004578.4A patent/CN102282220B/zh not_active Expired - Fee Related
- 2010-01-11 HR HRP20140070AT patent/HRP20140070T1/hr unknown
- 2010-01-11 JP JP2011545717A patent/JP2012515242A/ja active Pending
- 2010-01-11 DK DK10700401.2T patent/DK2379649T3/da active
- 2010-01-11 PT PT107004012T patent/PT2379649E/pt unknown
- 2010-01-11 ES ES10700401.2T patent/ES2444966T3/es active Active
- 2010-01-11 US US13/138,107 patent/US20120016061A1/en not_active Abandoned
- 2010-01-11 KR KR1020117017145A patent/KR20110108365A/ko not_active Ceased
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