JP2012515242A - カップリング剤としての疎水性基を有するアクリル櫛型コポリマーを実現する自己結合性顔料粒子を調製する方法、自己結合性顔料粒子およびこの使用 - Google Patents
カップリング剤としての疎水性基を有するアクリル櫛型コポリマーを実現する自己結合性顔料粒子を調製する方法、自己結合性顔料粒子およびこの使用 Download PDFInfo
- Publication number
- JP2012515242A JP2012515242A JP2011545717A JP2011545717A JP2012515242A JP 2012515242 A JP2012515242 A JP 2012515242A JP 2011545717 A JP2011545717 A JP 2011545717A JP 2011545717 A JP2011545717 A JP 2011545717A JP 2012515242 A JP2012515242 A JP 2012515242A
- Authority
- JP
- Japan
- Prior art keywords
- weight
- monomer
- copolymer
- radical
- binders
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229920001577 copolymer Polymers 0.000 title claims abstract description 54
- 238000000034 method Methods 0.000 title claims abstract description 46
- 239000000049 pigment Substances 0.000 title claims abstract description 33
- 239000002245 particle Substances 0.000 title claims abstract description 32
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 title claims abstract description 29
- 239000007822 coupling agent Substances 0.000 title description 41
- 125000001165 hydrophobic group Chemical group 0.000 title 1
- 239000011230 binding agent Substances 0.000 claims abstract description 51
- 239000000178 monomer Substances 0.000 claims abstract description 39
- 239000000725 suspension Substances 0.000 claims abstract description 34
- -1 acrylic ester Chemical class 0.000 claims abstract description 22
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 11
- 230000008569 process Effects 0.000 claims abstract description 11
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 10
- 239000000126 substance Substances 0.000 claims abstract description 10
- 125000000129 anionic group Chemical group 0.000 claims abstract description 9
- 150000001336 alkenes Chemical group 0.000 claims abstract description 6
- 150000001408 amides Chemical class 0.000 claims abstract description 6
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 claims abstract description 5
- 125000002877 alkyl aryl group Chemical group 0.000 claims abstract description 5
- 125000003118 aryl group Chemical group 0.000 claims abstract description 5
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 claims abstract description 5
- 125000005429 oxyalkyl group Chemical group 0.000 claims abstract description 4
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical group NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims abstract description 3
- 239000007864 aqueous solution Substances 0.000 claims abstract description 3
- 125000003710 aryl alkyl group Chemical group 0.000 claims abstract description 3
- 230000002209 hydrophobic effect Effects 0.000 claims abstract description 3
- 238000006116 polymerization reaction Methods 0.000 claims abstract description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 22
- 239000002270 dispersing agent Substances 0.000 claims description 21
- 150000003254 radicals Chemical group 0.000 claims description 21
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 19
- 238000000227 grinding Methods 0.000 claims description 19
- 239000007787 solid Substances 0.000 claims description 18
- 239000000203 mixture Substances 0.000 claims description 16
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 10
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 10
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 9
- 229920000896 Ethulose Polymers 0.000 claims description 6
- 239000001859 Ethyl hydroxyethyl cellulose Substances 0.000 claims description 6
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 claims description 6
- 235000019326 ethyl hydroxyethyl cellulose Nutrition 0.000 claims description 6
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 4
- 229920002678 cellulose Polymers 0.000 claims description 4
- 239000001913 cellulose Substances 0.000 claims description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- 150000002170 ethers Chemical class 0.000 claims description 4
- 230000003472 neutralizing effect Effects 0.000 claims description 4
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 3
- 239000004215 Carbon black (E152) Substances 0.000 claims description 3
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims description 3
- 229920002472 Starch Polymers 0.000 claims description 3
- 239000002174 Styrene-butadiene Substances 0.000 claims description 3
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 claims description 3
- 239000005018 casein Substances 0.000 claims description 3
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 claims description 3
- 235000021240 caseins Nutrition 0.000 claims description 3
- 238000001035 drying Methods 0.000 claims description 3
- 229930195733 hydrocarbon Natural products 0.000 claims description 3
- 238000006386 neutralization reaction Methods 0.000 claims description 3
- 239000011118 polyvinyl acetate Substances 0.000 claims description 3
- 235000018102 proteins Nutrition 0.000 claims description 3
- 102000004169 proteins and genes Human genes 0.000 claims description 3
- 108090000623 proteins and genes Proteins 0.000 claims description 3
- 239000008107 starch Substances 0.000 claims description 3
- 235000019698 starch Nutrition 0.000 claims description 3
- 239000011115 styrene butadiene Substances 0.000 claims description 3
- 229920003048 styrene butadiene rubber Polymers 0.000 claims description 3
- 229920001909 styrene-acrylic polymer Polymers 0.000 claims description 3
- TVFWYUWNQVRQRG-UHFFFAOYSA-N 2,3,4-tris(2-phenylethenyl)phenol Chemical compound C=1C=CC=CC=1C=CC1=C(C=CC=2C=CC=CC=2)C(O)=CC=C1C=CC1=CC=CC=C1 TVFWYUWNQVRQRG-UHFFFAOYSA-N 0.000 claims description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 2
- 239000005995 Aluminium silicate Substances 0.000 claims description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 2
- 235000013162 Cocos nucifera Nutrition 0.000 claims description 2
- 244000060011 Cocos nucifera Species 0.000 claims description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical group C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 2
- 230000002378 acidificating effect Effects 0.000 claims description 2
- 229920005822 acrylic binder Polymers 0.000 claims description 2
- 125000002009 alkene group Chemical group 0.000 claims description 2
- RMRFFCXPLWYOOY-UHFFFAOYSA-N allyl radical Chemical compound [CH2]C=C RMRFFCXPLWYOOY-UHFFFAOYSA-N 0.000 claims description 2
- 235000012211 aluminium silicate Nutrition 0.000 claims description 2
- 238000006243 chemical reaction Methods 0.000 claims description 2
- 239000004927 clay Substances 0.000 claims description 2
- 238000009833 condensation Methods 0.000 claims description 2
- 230000005494 condensation Effects 0.000 claims description 2
- 239000010459 dolomite Substances 0.000 claims description 2
- 229910000514 dolomite Inorganic materials 0.000 claims description 2
- 125000000524 functional group Chemical group 0.000 claims description 2
- 239000010440 gypsum Substances 0.000 claims description 2
- 229910052602 gypsum Inorganic materials 0.000 claims description 2
- 150000002430 hydrocarbons Chemical group 0.000 claims description 2
- 229910052739 hydrogen Inorganic materials 0.000 claims description 2
- 239000001257 hydrogen Substances 0.000 claims description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 2
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims description 2
- 239000011976 maleic acid Substances 0.000 claims description 2
- 229910000000 metal hydroxide Inorganic materials 0.000 claims description 2
- 150000004692 metal hydroxides Chemical class 0.000 claims description 2
- 229910044991 metal oxide Inorganic materials 0.000 claims description 2
- 150000004706 metal oxides Chemical class 0.000 claims description 2
- 239000010445 mica Substances 0.000 claims description 2
- 229910052618 mica group Inorganic materials 0.000 claims description 2
- 239000003973 paint Substances 0.000 claims description 2
- 239000004033 plastic Substances 0.000 claims description 2
- 229920003023 plastic Polymers 0.000 claims description 2
- 239000011591 potassium Substances 0.000 claims description 2
- 229910052700 potassium Inorganic materials 0.000 claims description 2
- OCAAZRFBJBEVPS-UHFFFAOYSA-N prop-2-enyl carbamate Chemical compound NC(=O)OCC=C OCAAZRFBJBEVPS-UHFFFAOYSA-N 0.000 claims description 2
- 239000011734 sodium Substances 0.000 claims description 2
- 229910052708 sodium Inorganic materials 0.000 claims description 2
- 239000000454 talc Substances 0.000 claims description 2
- 229910052623 talc Inorganic materials 0.000 claims description 2
- 239000004408 titanium dioxide Substances 0.000 claims description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 2
- ORGHESHFQPYLAO-UHFFFAOYSA-N vinyl radical Chemical compound C=[CH] ORGHESHFQPYLAO-UHFFFAOYSA-N 0.000 claims description 2
- MXRIRQGCELJRSN-UHFFFAOYSA-N O.O.O.[Al] Chemical compound O.O.O.[Al] MXRIRQGCELJRSN-UHFFFAOYSA-N 0.000 claims 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 claims 1
- DOEXKUOGPAEBAD-UHFFFAOYSA-N ethyl n-(2-methylprop-2-enoyl)carbamate Chemical compound CCOC(=O)NC(=O)C(C)=C DOEXKUOGPAEBAD-UHFFFAOYSA-N 0.000 claims 1
- IPZIVCLZBFDXTA-UHFFFAOYSA-N ethyl n-prop-2-enoylcarbamate Chemical compound CCOC(=O)NC(=O)C=C IPZIVCLZBFDXTA-UHFFFAOYSA-N 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 abstract description 4
- 150000001649 bromium compounds Chemical class 0.000 abstract 1
- 238000012360 testing method Methods 0.000 description 34
- 229910010272 inorganic material Inorganic materials 0.000 description 13
- 239000011147 inorganic material Substances 0.000 description 13
- 239000007900 aqueous suspension Substances 0.000 description 11
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 7
- 229910052799 carbon Inorganic materials 0.000 description 7
- JHPBZFOKBAGZBL-UHFFFAOYSA-N (3-hydroxy-2,2,4-trimethylpentyl) 2-methylprop-2-enoate Chemical group CC(C)C(O)C(C)(C)COC(=O)C(C)=C JHPBZFOKBAGZBL-UHFFFAOYSA-N 0.000 description 6
- 239000006185 dispersion Substances 0.000 description 6
- 239000012065 filter cake Substances 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 239000011324 bead Substances 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 238000001914 filtration Methods 0.000 description 4
- 239000004816 latex Substances 0.000 description 4
- 229920000126 latex Polymers 0.000 description 4
- 238000005259 measurement Methods 0.000 description 4
- 229920000642 polymer Polymers 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- NJVOHKFLBKQLIZ-UHFFFAOYSA-N (2-ethenylphenyl) prop-2-enoate Chemical compound C=CC(=O)OC1=CC=CC=C1C=C NJVOHKFLBKQLIZ-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000008346 aqueous phase Substances 0.000 description 3
- 235000010980 cellulose Nutrition 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 239000000839 emulsion Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 229920005789 ACRONAL® acrylic binder Polymers 0.000 description 2
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 2
- 238000007385 chemical modification Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000000706 filtrate Substances 0.000 description 2
- 229920001519 homopolymer Polymers 0.000 description 2
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 2
- 239000004579 marble Substances 0.000 description 2
- 238000003801 milling Methods 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- 229910001415 sodium ion Inorganic materials 0.000 description 2
- JQEBZBUGQPSANC-UHFFFAOYSA-N 3-methoxy-2-methylprop-2-enoic acid Chemical compound COC=C(C)C(O)=O JQEBZBUGQPSANC-UHFFFAOYSA-N 0.000 description 1
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 description 1
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000011088 calibration curve Methods 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 238000009223 counseling Methods 0.000 description 1
- 238000010494 dissociation reaction Methods 0.000 description 1
- 230000005593 dissociations Effects 0.000 description 1
- 229920006226 ethylene-acrylic acid Polymers 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910001425 magnesium ion Inorganic materials 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- 125000005395 methacrylic acid group Chemical group 0.000 description 1
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical group CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
- 238000010951 particle size reduction Methods 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- IWZKICVEHNUQTL-UHFFFAOYSA-M potassium hydrogen phthalate Chemical compound [K+].OC(=O)C1=CC=CC=C1C([O-])=O IWZKICVEHNUQTL-UHFFFAOYSA-M 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 238000000518 rheometry Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical class [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- GYLZSBPASSUYIS-UHFFFAOYSA-N tert-butyl n-benzyl-n-prop-1-en-2-ylcarbamate Chemical compound CC(C)(C)OC(=O)N(C(=C)C)CC1=CC=CC=C1 GYLZSBPASSUYIS-UHFFFAOYSA-N 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/02—Compounds of alkaline earth metals or magnesium
- C09C1/021—Calcium carbonates
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/36—Compounds of titanium
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/36—Compounds of titanium
- C09C1/3607—Titanium dioxide
- C09C1/3669—Treatment with low-molecular organic compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/36—Compounds of titanium
- C09C1/3607—Titanium dioxide
- C09C1/3676—Treatment with macro-molecular organic compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/40—Compounds of aluminium
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/40—Compounds of aluminium
- C09C1/405—Compounds of aluminium containing combined silica, e.g. mica
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/40—Compounds of aluminium
- C09C1/407—Aluminium oxides or hydroxides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/40—Compounds of aluminium
- C09C1/42—Clays
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/62—Submicrometer sized, i.e. from 0.1-1 micrometer
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/12—Surface area
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/22—Rheological behaviour as dispersion, e.g. viscosity, sedimentation stability
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Paper (AREA)
- Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP09150759A EP2208761B1 (en) | 2009-01-16 | 2009-01-16 | Process to prepare self-binding pigment particles implementing acrylic comb copolymers with hydrophobic groups as coupling agents, self binding pigment particles and uses thereof |
| EP09150759.0 | 2009-01-16 | ||
| US20700409P | 2009-02-06 | 2009-02-06 | |
| US61/207,004 | 2009-02-06 | ||
| PCT/EP2010/050227 WO2010081785A1 (en) | 2009-01-16 | 2010-01-11 | Process to prepare self-binding pigment particles implementing acrylic comb copolymers with hydrophobic groups as coupling agents, self binding pigment particles and uses thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2012515242A true JP2012515242A (ja) | 2012-07-05 |
| JP2012515242A5 JP2012515242A5 (enExample) | 2012-10-18 |
Family
ID=40785602
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2011545717A Pending JP2012515242A (ja) | 2009-01-16 | 2010-01-11 | カップリング剤としての疎水性基を有するアクリル櫛型コポリマーを実現する自己結合性顔料粒子を調製する方法、自己結合性顔料粒子およびこの使用 |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US20120016061A1 (enExample) |
| EP (2) | EP2208761B1 (enExample) |
| JP (1) | JP2012515242A (enExample) |
| KR (1) | KR20110108365A (enExample) |
| CN (1) | CN102282220B (enExample) |
| CA (1) | CA2748915C (enExample) |
| DK (1) | DK2379649T3 (enExample) |
| ES (1) | ES2444966T3 (enExample) |
| HR (1) | HRP20140070T1 (enExample) |
| PT (1) | PT2379649E (enExample) |
| RU (1) | RU2531183C2 (enExample) |
| SI (1) | SI2379649T1 (enExample) |
| TW (1) | TWI516506B (enExample) |
| WO (1) | WO2010081785A1 (enExample) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2014513170A (ja) * | 2011-04-01 | 2014-05-29 | オムヤ インターナショナル アーゲー | 自己結合顔料粒子を調製する方法 |
| JP2014514393A (ja) * | 2011-04-01 | 2014-06-19 | オムヤ インターナショナル アーゲー | 自己結合顔料ハイブリッド |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BR112013009011A2 (pt) | 2010-10-15 | 2019-11-26 | Cerealus Holdings Llc | composição de carga modificada para uso na fabricação de um ou mais produtos finais, respectivo método de fabricação e produto de papel |
| DK2455429T3 (da) * | 2010-11-19 | 2013-11-25 | Omya Int Ag | Fremgangsmåde til at fremstille vandige suspensioner af mineralmaterialer ved at anvende aminer kombineret med vinyl karboxyl polymerer |
| ES2536787T3 (es) | 2011-08-31 | 2015-05-28 | Omya International Ag | Proceso para preparar suspensiones de partículas de pigmentos autoaglutinantes |
| ES2456369T3 (es) | 2011-08-31 | 2014-04-22 | Omya International Ag | Híbrido de pigmentos autoaglutinantes |
| WO2013063199A1 (en) | 2011-10-26 | 2013-05-02 | Lubrizol Advanced Materials, Inc. | Dispersant composition |
| CN103917609B (zh) | 2011-10-26 | 2015-11-25 | 路博润高级材料公司 | 分散剂组合物 |
| ES2547097T3 (es) | 2012-03-23 | 2015-10-01 | Omya International Ag | Preparación de pigmentos |
| US9371435B2 (en) * | 2013-04-22 | 2016-06-21 | Ethox Chemicals, Llc | Additives to resin compositions for improved impact strength and flexibility |
| US10030335B2 (en) * | 2013-12-30 | 2018-07-24 | Kemira Oyj | Filler aggregate composition and its production |
| EP3018175B1 (en) | 2014-11-07 | 2019-02-06 | Omya International AG | A process for the preparation of flocculated filler particles |
| ES2672735T3 (es) | 2014-11-07 | 2018-06-15 | Omya International Ag | Un proceso para la preparación de partículas de carga floculadas |
| CN111648159B (zh) * | 2020-05-29 | 2022-03-11 | 仙鹤股份有限公司 | 一种防霉玻璃间隔纸的制备方法 |
| US20240294793A1 (en) * | 2021-06-02 | 2024-09-05 | Omya International Ag | Aqueous coating composition |
| FR3133610B1 (fr) * | 2022-03-18 | 2025-11-21 | Coatex Sas | Copolymère alkylé épaississant |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5730555A (en) * | 1980-08-01 | 1982-02-18 | Kanzaki Paper Mfg Co Ltd | Wet crushing method for heavy calcium carbonate |
| JPH11116238A (ja) * | 1997-07-18 | 1999-04-27 | Pluss Stauffer Ag | 無機物質の水性懸濁液及びその使用 |
| JP2000313845A (ja) * | 1999-04-27 | 2000-11-14 | Sannopuko Kk | 水系コーティング剤用改質剤 |
| JP2002265813A (ja) * | 2001-03-09 | 2002-09-18 | Toyo Ink Mfg Co Ltd | 顔料組成物および顔料分散体 |
| JP2008506807A (ja) * | 2004-07-13 | 2008-03-06 | オムヤ・デベロツプメント・アー・ゲー | 乾燥品、水性懸濁液または分散液であり、無機物質および結合剤を含有する自己結合性顔料粒子の製造方法 |
| WO2008044118A1 (fr) * | 2006-10-12 | 2008-04-17 | Coatex S.A.S. | Utilisation d'une suspension et/ou d'une dispersion aqueuse de matieres minerales contenant un copolymere hydrosoluble a groupement hydrophobe dans la fabrication d'une feuille de papier |
| WO2008139292A1 (fr) * | 2007-05-11 | 2008-11-20 | Omya Development Ag | Procede de broyage en milieu aqueux de matieres minerales et de liants mettant en oeuvre une emulsion inverse d'un polymere de l'acrylamide avec un monomere acrylique |
| JP2008542563A (ja) * | 2005-05-31 | 2008-11-27 | ビーエーエスエフ ソシエタス・ヨーロピア | 製紙用のポリマー−顔料−ハイブリッド |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2080961C (fr) * | 1991-11-12 | 2002-04-02 | Jean-Bernard Egraz | Agent de broyage et/ou de dispersion a base de polymeres et/ou copolymeres neutralises en partie par du magnesium pour suspensions aqueuses de materiaux mineraux en vue d'applications pigmentaires |
| FR2693203B1 (fr) * | 1992-07-01 | 1994-08-26 | Coatex Sas | Copolymère acrylique partiellement ou totalement hydrosoluble, réticulé ou non et son utilisation. |
| FR2846971B1 (fr) | 2002-11-08 | 2006-09-29 | Omya Ag | Utilisation d'un copolymere disposant d'au moins une fonction greffee alkoxy ou hydroxy polyalkylene glycol, comme agent ameliorant la brillance du papier et produits obtenus |
| FR2846972B1 (fr) | 2002-11-08 | 2005-02-18 | Omya Ag | Suspensions aqueuses de matieres minerales broyees, faiblement chargees ioniquement et leurs utilisations |
| DE10315363A1 (de) * | 2003-04-03 | 2004-10-14 | Basf Ag | Wässrige Anschlämmungen von feinteiligen Füllstoffen, Verfahren zu ihrer Herstellung und ihre Verwendung zur Herstellung füllstoffhaltiger Papiere |
| FR2873047B1 (fr) * | 2004-07-13 | 2007-10-05 | Coatex Soc Par Actions Simplif | Procede de broyage de matieres minerales en presence de liants, suspensions aqueuses obtenues et leurs utilisations |
| FR2913427B1 (fr) | 2007-03-05 | 2011-10-07 | Omya Development Ag | Procede de broyage a sec d'un ou plusieurs materiaux comprenant au moins un carbonate de calcium |
| FR2913420B1 (fr) * | 2007-03-05 | 2009-05-01 | Coatex Soc Par Actions Simplif | Utilisation dans une composition de liant hydraulique,d'un carbonate de calcium broye a sec avec un copolymere de l'acide (meth) acrylique et une fonction alcoxy ou hydroxy polyalkyleneglycol. |
| DE602007007906D1 (de) * | 2007-05-11 | 2010-09-02 | Coatex Sas | Use of a reverse emulsion of an acrylamide polymer with an acrylic monomer as a stabilising agent and foam reducer, in a method for the grinding of mineral materials and binders in an aqueous medium. |
-
2009
- 2009-01-16 EP EP09150759A patent/EP2208761B1/en not_active Not-in-force
- 2009-12-24 TW TW098144637A patent/TWI516506B/zh not_active IP Right Cessation
-
2010
- 2010-01-11 EP EP10700401.2A patent/EP2379649B1/en not_active Not-in-force
- 2010-01-11 CA CA2748915A patent/CA2748915C/en not_active Expired - Fee Related
- 2010-01-11 SI SI201030505T patent/SI2379649T1/sl unknown
- 2010-01-11 WO PCT/EP2010/050227 patent/WO2010081785A1/en not_active Ceased
- 2010-01-11 RU RU2011134295/05A patent/RU2531183C2/ru not_active IP Right Cessation
- 2010-01-11 CN CN201080004578.4A patent/CN102282220B/zh not_active Expired - Fee Related
- 2010-01-11 HR HRP20140070AT patent/HRP20140070T1/hr unknown
- 2010-01-11 JP JP2011545717A patent/JP2012515242A/ja active Pending
- 2010-01-11 DK DK10700401.2T patent/DK2379649T3/da active
- 2010-01-11 PT PT107004012T patent/PT2379649E/pt unknown
- 2010-01-11 ES ES10700401.2T patent/ES2444966T3/es active Active
- 2010-01-11 US US13/138,107 patent/US20120016061A1/en not_active Abandoned
- 2010-01-11 KR KR1020117017145A patent/KR20110108365A/ko not_active Ceased
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5730555A (en) * | 1980-08-01 | 1982-02-18 | Kanzaki Paper Mfg Co Ltd | Wet crushing method for heavy calcium carbonate |
| JPH11116238A (ja) * | 1997-07-18 | 1999-04-27 | Pluss Stauffer Ag | 無機物質の水性懸濁液及びその使用 |
| JP2000313845A (ja) * | 1999-04-27 | 2000-11-14 | Sannopuko Kk | 水系コーティング剤用改質剤 |
| JP2002265813A (ja) * | 2001-03-09 | 2002-09-18 | Toyo Ink Mfg Co Ltd | 顔料組成物および顔料分散体 |
| JP2008506807A (ja) * | 2004-07-13 | 2008-03-06 | オムヤ・デベロツプメント・アー・ゲー | 乾燥品、水性懸濁液または分散液であり、無機物質および結合剤を含有する自己結合性顔料粒子の製造方法 |
| JP2008542563A (ja) * | 2005-05-31 | 2008-11-27 | ビーエーエスエフ ソシエタス・ヨーロピア | 製紙用のポリマー−顔料−ハイブリッド |
| WO2008044118A1 (fr) * | 2006-10-12 | 2008-04-17 | Coatex S.A.S. | Utilisation d'une suspension et/ou d'une dispersion aqueuse de matieres minerales contenant un copolymere hydrosoluble a groupement hydrophobe dans la fabrication d'une feuille de papier |
| JP2010506058A (ja) * | 2006-10-12 | 2010-02-25 | コアテツクス・エス・アー・エス | 紙シート製造のための疎水基水溶性コポリマーを含有する無機質材料の水性懸濁液および／または水性分散液の使用 |
| WO2008139292A1 (fr) * | 2007-05-11 | 2008-11-20 | Omya Development Ag | Procede de broyage en milieu aqueux de matieres minerales et de liants mettant en oeuvre une emulsion inverse d'un polymere de l'acrylamide avec un monomere acrylique |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2014513170A (ja) * | 2011-04-01 | 2014-05-29 | オムヤ インターナショナル アーゲー | 自己結合顔料粒子を調製する方法 |
| JP2014514393A (ja) * | 2011-04-01 | 2014-06-19 | オムヤ インターナショナル アーゲー | 自己結合顔料ハイブリッド |
Also Published As
| Publication number | Publication date |
|---|---|
| CA2748915C (en) | 2017-05-23 |
| ES2444966T3 (es) | 2014-02-27 |
| CN102282220B (zh) | 2014-05-14 |
| TWI516506B (zh) | 2016-01-11 |
| TW201031679A (en) | 2010-09-01 |
| DK2379649T3 (da) | 2014-01-27 |
| PT2379649E (pt) | 2014-01-23 |
| EP2208761B1 (en) | 2012-10-10 |
| CN102282220A (zh) | 2011-12-14 |
| EP2379649A1 (en) | 2011-10-26 |
| EP2208761A1 (en) | 2010-07-21 |
| RU2011134295A (ru) | 2013-02-27 |
| US20120016061A1 (en) | 2012-01-19 |
| HRP20140070T1 (hr) | 2014-02-28 |
| CA2748915A1 (en) | 2010-07-22 |
| SI2379649T1 (sl) | 2014-02-28 |
| RU2531183C2 (ru) | 2014-10-20 |
| WO2010081785A1 (en) | 2010-07-22 |
| EP2379649B1 (en) | 2013-11-13 |
| KR20110108365A (ko) | 2011-10-05 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP2012515242A (ja) | カップリング剤としての疎水性基を有するアクリル櫛型コポリマーを実現する自己結合性顔料粒子を調製する方法、自己結合性顔料粒子およびこの使用 | |
| JP4686192B2 (ja) | 低イオン負荷の粉砕無機物の水性懸濁液およびそれらの使用 | |
| JP5666765B2 (ja) | 乾燥品、水性懸濁液または分散液であり、無機物質および結合剤を含有する自己結合性顔料粒子の製造方法 | |
| TWI502030B (zh) | 顏料之製備 | |
| CN107075272B (zh) | 用于制造包含含碳酸钙材料的悬浮体的方法 | |
| CN102272238A (zh) | 矿物材料的含水悬浮液或干燥的矿物材料的制造方法、获得的产品及其用途 | |
| JP5413840B2 (ja) | 炭酸カルシウムおよびカオリンを含有する水性懸濁物または分散物の製造方法ならびに紙コーティングの製造におけるこの使用 | |
| US8191807B2 (en) | Use of acrylic comb polymers with hydrophobic groups as coupling agents in a method for grinding mineral materials with binders | |
| CN101057036B (zh) | 基于颜料-聚合物混杂物的涂纸浆液 | |
| KR20250133392A (ko) | 광물 분산액을 위한 공분산제로서의 폴리비닐 알코올 | |
| HK1124357B (en) | Process for manufacturing particles based on natural calcium carbonate and salts of acrylic acid-ethylene, suspensions and dry pigments obtained, and uses thereof | |
| MX2008009093A (es) | Proceso de fabricacion de particulasa base de carbonato de calcio natural y de sales de acido etileno acrilico, suspensiones y pigmentos secos obtenidos y sus utilizaciones | |
| HK1124357A1 (en) | Process for manufacturing particles based on natural calcium carbonate and salts of acrylic acid-ethylene, suspensions and dry pigments obtained, and uses thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20120828 |
|
| A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20120828 |
|
| A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20131010 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20131029 |
|
| A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20140120 |
|
| A602 | Written permission of extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A602 Effective date: 20140127 |
|
| A02 | Decision of refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A02 Effective date: 20140701 |