JP2012242824A - スピロジラクタムポリカーボナート中間体転写部材 - Google Patents
スピロジラクタムポリカーボナート中間体転写部材 Download PDFInfo
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- JP2012242824A JP2012242824A JP2012097462A JP2012097462A JP2012242824A JP 2012242824 A JP2012242824 A JP 2012242824A JP 2012097462 A JP2012097462 A JP 2012097462A JP 2012097462 A JP2012097462 A JP 2012097462A JP 2012242824 A JP2012242824 A JP 2012242824A
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- intermediate transfer
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- polycarbonate
- spirodilactam
- copolymer
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- Y10T428/31663—As siloxane, silicone or silane
-
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Abstract
【解決手段】単層中間転写ベルトとして、スピロジラクタムポリカーボナート3、またはスピロジラクタムポリカーボナート3とポリカーボナート4との混合物又はスピロジラクタムポリカーボナート3と必要に応じてシロキサンポリマー5と電気抵抗を調整する導伝性フィラー6との混合物から構成される。さらに離型層を設けて多層構成とすることもできる。
【選択図】図1
Description
コーティング組成物を、Degussa Chemicalsから入手したspecial carbon black 4、PYRE‐M.L.(登録商標)RC‐5019としてIndustrial Summit Technologyから入手可能なピロメリト酸二無水物/4,4′‐オキシジアニリンのポリアミック酸のポリイミド、及びBYK(登録商標)333としてBYK Chemicalから入手可能なポリエステル改変ポリジメチルシロキサンの混合物を、約13重量固体のN‐メチル‐2‐ピロリドン(NMP)中、混合物初期供給量に対して14/85.95/0.05の比で撹拌することによって、製造した。得られた中間体転写部材分散物を、0.5ミリメートル厚のステンレス鋼基板上に被覆し、次いで、この混合物を125℃で30分間、190℃で30分間、及び320℃で60分間の加熱によって硬化した。上記の比で上記の構成要素からなる得られた中間体転写部材は、ステンレス鋼基板から離脱せず、むしろ基板上に付着していた。得られた中間体転写部材フィルムは、水中に3ヶ月間浸漬した後、遂に基板から離脱した。
中間体転写部材を、ピロメリト酸二無水物/4,4′‐オキシジアニリンのポリアミック酸のポリイミドを三菱ガス化学株式会社から入手可能なポリカーボナートであるPCZ‐400[ポリ(4,4′‐ジヒドロキシ‐ジフェニル‐1‐1‐シクロヘキサン、Mw=40,000)]と置き換えたことを除いて比較例1のプロセスを繰り返すことによって製造し、表面抵抗が幾分か類似している結果を得た。
Degussa Chemicalsから入手したspecial carbon black 4、Shell Development Company,Houston Texasから入手した以下の式/構造のスピロジラクタムポリカーボナートとポリカーボナートとのコポリマーA、及び主に表面の平滑性のためにBYK Chemicalから入手したポリエステルとポリジメチルシロキサンとのコポリマーであるBYK(登録商標)333を、約25重量固体のN‐メチル‐2‐ピロリドン中への初期供給量に対してスピロジラクタムコポリマー/カーボンブラック/シロキサンコポリマーの比85/14.95/0.05で含有するコーティング組成物を撹拌及び粉砕で混合することによって製造した。
中間体転写部材を、xが10、20又は30モル%、yが90、80又は70モル%であり、そして重量平均分子量Mwがそれぞれ150,000、200,000又は250,000である上記の式/構造のコポリマーを選択した以外は、実施例1のプロセスを繰り返すことによって製造した。
上記の実施例1並びに比較例1及び比較例2の中間体転写部材を、ヤング係数について公知のASTM D882‐97プロセスに従って測定した。各中間体転写部材のサンプル(0.5インチ×12インチ)を、Instron Tensile Tester測定機中に置き、次いで、このサンプルを、一定の引っ張り速度で破断するまで伸長した。この間、得られた負荷対サンプル伸長を記録した。このヤング係数を、記録した曲線結果の初期直線部分に対し正接する任意の点を取り、対応する引っ張りで引っ張り応力を除算することによって計算した。引っ張り応力を、負荷を各試験サンプルの平均断面積で除算することによって計算した。結果を、下の表に示す。
Claims (10)
- スピロジラクタムポリカーボナートを含有するポリマー層からなる、中間体転写部材。
- 前記スピロジラクタムポリカーボナートは、ゲル透過クロマトグラフィー分析によって測定して約50,000〜約300,000までの重量平均分子量を有する、請求項1に記載の中間体転写部材。
- 前記ポリマー層は、前記スピロジラクタムポリカーボナート、ポリシロキサン、及び必要に応じて導伝性フィラー構成要素からなる成分の混合物からなり、前記スピロジラクタムポリカーボナートは、スピロジラクタムポリカーボナートとポリカーボナートとのコポリマーからなる、請求項1に記載の中間体転写部材。
- 前記ポリマー層と接触する離型層をさらに含み、前記離型層は、フッ化エチレンプロピレンコポリマー、ポリテトラフルオロエチレン、ポリフルオロアルコキシポリテトラフルオロエチレン、フルオロシリコーン、ビニリデンフルオリドとヘキサフルオロプロピレンとテトラフルオロエチレンとのターポリマー及びこれらの混合物からなる群から選択される少なくとも1種の成分からなる、請求項3に記載の中間体転写部材。
- 前記ポリシロキサンは、ポリエーテルとポリジメチルシロキサンとのコポリマー、ポリエステルとポリジメチルシロキサンとのコポリマー、ポリアクリラートとポリジメチルシロキサンとのコポリマー、又はポリエステルポリエーテルとポリジメチルシロキサンとのコポリマーである、請求項3に記載の中間体転写部材。
- 前記混合物の成分それぞれについて、前記スピロジラクタムポリカーボナートコポリマーは、前記成分の総量を約100重量%とした場合、約60〜約95重量%までの量で存在し、前記ポリシロキサンは、約0.05〜約1重量%までの量で存在し、前記導伝性フィラー構成要素は、約1〜約40重量%までの量で存在する、請求項3に記載の中間体転写部材。
- スピロジラクタムポリカーボナートとポリカーボナートとのコポリマー、ポリシロキサン及び導伝性フィラー構成要素の混合物からなる中間体転写部材であって、前記部材は、約3,000〜約5,500メガパスカルまでの係数を有し、前記混合物は、金属基板から容易に離脱可能である、中間体転写部材。
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US13/114,674 | 2011-05-24 | ||
US13/114,674 US8361624B2 (en) | 2011-05-24 | 2011-05-24 | Spirodilactam polycarbonate intermediate transfer members |
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JP2012242824A true JP2012242824A (ja) | 2012-12-10 |
JP2012242824A5 JP2012242824A5 (ja) | 2015-06-11 |
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DE102012208331B4 (de) | 2018-06-28 |
US20120301725A1 (en) | 2012-11-29 |
JP5805004B2 (ja) | 2015-11-04 |
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