JP2012104273A - 金属空気電池 - Google Patents
金属空気電池 Download PDFInfo
- Publication number
- JP2012104273A JP2012104273A JP2010249938A JP2010249938A JP2012104273A JP 2012104273 A JP2012104273 A JP 2012104273A JP 2010249938 A JP2010249938 A JP 2010249938A JP 2010249938 A JP2010249938 A JP 2010249938A JP 2012104273 A JP2012104273 A JP 2012104273A
- Authority
- JP
- Japan
- Prior art keywords
- positive electrode
- metal
- layer
- air battery
- electrolyte
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 49
- 239000002184 metal Substances 0.000 title claims abstract description 49
- 239000003792 electrolyte Substances 0.000 claims abstract description 97
- 239000003054 catalyst Substances 0.000 claims abstract description 72
- 239000007788 liquid Substances 0.000 claims abstract description 43
- 239000005871 repellent Substances 0.000 claims abstract description 39
- 230000002940 repellent Effects 0.000 claims abstract description 34
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 28
- 239000001301 oxygen Substances 0.000 claims abstract description 28
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 18
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 14
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 14
- 229910021645 metal ion Inorganic materials 0.000 claims abstract description 14
- -1 oxygen ion Chemical class 0.000 claims abstract description 13
- 238000006722 reduction reaction Methods 0.000 claims abstract description 9
- 239000008151 electrolyte solution Substances 0.000 claims description 47
- 239000000463 material Substances 0.000 claims description 13
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 abstract description 12
- 238000007599 discharging Methods 0.000 abstract description 9
- 230000001737 promoting effect Effects 0.000 abstract description 4
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- 238000005192 partition Methods 0.000 description 30
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 11
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 10
- 239000010408 film Substances 0.000 description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 8
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 description 6
- 239000001569 carbon dioxide Substances 0.000 description 5
- 229910002092 carbon dioxide Inorganic materials 0.000 description 5
- 210000001787 dendrite Anatomy 0.000 description 5
- 239000010419 fine particle Substances 0.000 description 5
- 239000007784 solid electrolyte Substances 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 239000010409 thin film Substances 0.000 description 5
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 4
- 239000004020 conductor Substances 0.000 description 4
- 229910052744 lithium Inorganic materials 0.000 description 4
- 229910044991 metal oxide Inorganic materials 0.000 description 4
- 150000004706 metal oxides Chemical class 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 239000000377 silicon dioxide Substances 0.000 description 4
- 239000011701 zinc Substances 0.000 description 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 3
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 3
- 239000000919 ceramic Substances 0.000 description 3
- 238000005229 chemical vapour deposition Methods 0.000 description 3
- 238000001125 extrusion Methods 0.000 description 3
- 238000001027 hydrothermal synthesis Methods 0.000 description 3
- 229910052746 lanthanum Inorganic materials 0.000 description 3
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 3
- 229910000000 metal hydroxide Inorganic materials 0.000 description 3
- 150000004692 metal hydroxides Chemical class 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 230000000149 penetrating effect Effects 0.000 description 3
- 238000005240 physical vapour deposition Methods 0.000 description 3
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 3
- 238000011084 recovery Methods 0.000 description 3
- 238000007581 slurry coating method Methods 0.000 description 3
- 229910052725 zinc Inorganic materials 0.000 description 3
- 229910004298 SiO 2 Inorganic materials 0.000 description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 125000005103 alkyl silyl group Chemical group 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- 229910010293 ceramic material Inorganic materials 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 2
- 238000010304 firing Methods 0.000 description 2
- 125000003709 fluoroalkyl group Chemical group 0.000 description 2
- 125000000524 functional group Chemical group 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 229910010272 inorganic material Inorganic materials 0.000 description 2
- 239000011147 inorganic material Substances 0.000 description 2
- 239000012212 insulator Substances 0.000 description 2
- 229910002075 lanthanum strontium manganite Inorganic materials 0.000 description 2
- XGZVUEUWXADBQD-UHFFFAOYSA-L lithium carbonate Chemical compound [Li+].[Li+].[O-]C([O-])=O XGZVUEUWXADBQD-UHFFFAOYSA-L 0.000 description 2
- 239000011572 manganese Substances 0.000 description 2
- 229910000510 noble metal Inorganic materials 0.000 description 2
- 239000011255 nonaqueous electrolyte Substances 0.000 description 2
- 239000011368 organic material Substances 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 239000010948 rhodium Substances 0.000 description 2
- 235000012239 silicon dioxide Nutrition 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 description 2
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- 229910018921 CoO 3 Inorganic materials 0.000 description 1
- 101000622430 Homo sapiens Vang-like protein 2 Proteins 0.000 description 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 1
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 1
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 239000004809 Teflon Substances 0.000 description 1
- 229920006362 Teflon® Polymers 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 102100023520 Vang-like protein 2 Human genes 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- PTFCDOFLOPIGGS-UHFFFAOYSA-N Zinc dication Chemical compound [Zn+2] PTFCDOFLOPIGGS-UHFFFAOYSA-N 0.000 description 1
- 229910001297 Zn alloy Inorganic materials 0.000 description 1
- FVROQKXVYSIMQV-UHFFFAOYSA-N [Sr+2].[La+3].[O-][Mn]([O-])=O Chemical compound [Sr+2].[La+3].[O-][Mn]([O-])=O FVROQKXVYSIMQV-UHFFFAOYSA-N 0.000 description 1
- PACGUUNWTMTWCF-UHFFFAOYSA-N [Sr].[La] Chemical compound [Sr].[La] PACGUUNWTMTWCF-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 239000003575 carbonaceous material Substances 0.000 description 1
- 210000004027 cell Anatomy 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 229910052963 cobaltite Inorganic materials 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 239000002241 glass-ceramic Substances 0.000 description 1
- 229910052809 inorganic oxide Inorganic materials 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 239000002608 ionic liquid Substances 0.000 description 1
- 239000011344 liquid material Substances 0.000 description 1
- 229910052808 lithium carbonate Inorganic materials 0.000 description 1
- 229910001416 lithium ion Inorganic materials 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000007773 negative electrode material Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910052574 oxide ceramic Inorganic materials 0.000 description 1
- 239000011224 oxide ceramic Substances 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000007774 positive electrode material Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- JBQYATWDVHIOAR-UHFFFAOYSA-N tellanylidenegermanium Chemical compound [Te]=[Ge] JBQYATWDVHIOAR-UHFFFAOYSA-N 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Images
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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- Inert Electrodes (AREA)
- Hybrid Cells (AREA)
Priority Applications (6)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2010249938A JP2012104273A (ja) | 2010-11-08 | 2010-11-08 | 金属空気電池 |
| PCT/JP2011/062616 WO2011152464A1 (ja) | 2010-06-04 | 2011-06-01 | 金属空気電池 |
| KR1020127031693A KR20130112697A (ko) | 2010-06-04 | 2011-06-01 | 금속공기전지 |
| US13/700,253 US20130078535A1 (en) | 2010-06-04 | 2011-06-01 | Metal-air battery |
| CN2011800274665A CN102934280A (zh) | 2010-06-04 | 2011-06-01 | 金属空气电池 |
| US13/934,510 US20130295472A1 (en) | 2010-06-04 | 2013-07-03 | Metal-air battery |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2010249938A JP2012104273A (ja) | 2010-11-08 | 2010-11-08 | 金属空気電池 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2012104273A true JP2012104273A (ja) | 2012-05-31 |
| JP2012104273A5 JP2012104273A5 (enExample) | 2013-08-29 |
Family
ID=46394453
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2010249938A Pending JP2012104273A (ja) | 2010-06-04 | 2010-11-08 | 金属空気電池 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2012104273A (enExample) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2014194897A (ja) * | 2013-03-29 | 2014-10-09 | Hitachi Zosen Corp | セパレータ、二次電池およびセパレータの製造方法 |
| JP2014194898A (ja) * | 2013-03-29 | 2014-10-09 | Hitachi Zosen Corp | 電極および二次電池 |
| KR20160037136A (ko) * | 2013-06-05 | 2016-04-05 | 자프 에너지 시스템즈, 인코포레이티드. | 페로브스카이트를 포함하는 공기 전극 |
| JP2017208197A (ja) * | 2016-05-17 | 2017-11-24 | 日立造船株式会社 | 金属空気二次電池 |
| KR20220040505A (ko) | 2019-09-12 | 2022-03-30 | 학교법인 도시샤 | 금속 음극 및 상기 금속 음극의 제작 방법 그리고 상기 금속 음극을 구비하는 이차 전지 |
| WO2023063260A1 (ja) | 2021-10-12 | 2023-04-20 | 学校法人同志社 | 二次電池用負極構造体及び該構造体を備えた二次電池 |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0417259A (ja) * | 1990-05-10 | 1992-01-22 | Matsushita Electric Ind Co Ltd | 電池 |
| JPH07282862A (ja) * | 1994-04-06 | 1995-10-27 | Agency Of Ind Science & Technol | ガス拡散電極を備えた電池並びにその充電及び放電方法 |
| JPH0950828A (ja) * | 1995-08-04 | 1997-02-18 | Matsushita Electric Ind Co Ltd | 角形空気電池 |
| JP2003109606A (ja) * | 2001-09-28 | 2003-04-11 | Matsushita Electric Ind Co Ltd | 高分子電解質型燃料電池とその製造方法 |
| JP2008112724A (ja) * | 2006-10-06 | 2008-05-15 | Toyota Central R&D Labs Inc | 正極用触媒及びリチウム空気二次電池 |
| JP2010238547A (ja) * | 2009-03-31 | 2010-10-21 | Equos Research Co Ltd | 燃料電池用触媒担体、燃料電池用触媒及び燃料電池用電極 |
| JP2012099266A (ja) * | 2010-10-29 | 2012-05-24 | Kyoto Univ | 金属空気電池用空気極、並びに当該空気極を備える金属空気電池用膜・空気極接合体及び金属空気電池 |
-
2010
- 2010-11-08 JP JP2010249938A patent/JP2012104273A/ja active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0417259A (ja) * | 1990-05-10 | 1992-01-22 | Matsushita Electric Ind Co Ltd | 電池 |
| JPH07282862A (ja) * | 1994-04-06 | 1995-10-27 | Agency Of Ind Science & Technol | ガス拡散電極を備えた電池並びにその充電及び放電方法 |
| JPH0950828A (ja) * | 1995-08-04 | 1997-02-18 | Matsushita Electric Ind Co Ltd | 角形空気電池 |
| JP2003109606A (ja) * | 2001-09-28 | 2003-04-11 | Matsushita Electric Ind Co Ltd | 高分子電解質型燃料電池とその製造方法 |
| JP2008112724A (ja) * | 2006-10-06 | 2008-05-15 | Toyota Central R&D Labs Inc | 正極用触媒及びリチウム空気二次電池 |
| JP2010238547A (ja) * | 2009-03-31 | 2010-10-21 | Equos Research Co Ltd | 燃料電池用触媒担体、燃料電池用触媒及び燃料電池用電極 |
| JP2012099266A (ja) * | 2010-10-29 | 2012-05-24 | Kyoto Univ | 金属空気電池用空気極、並びに当該空気極を備える金属空気電池用膜・空気極接合体及び金属空気電池 |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2014194897A (ja) * | 2013-03-29 | 2014-10-09 | Hitachi Zosen Corp | セパレータ、二次電池およびセパレータの製造方法 |
| JP2014194898A (ja) * | 2013-03-29 | 2014-10-09 | Hitachi Zosen Corp | 電極および二次電池 |
| KR20160037136A (ko) * | 2013-06-05 | 2016-04-05 | 자프 에너지 시스템즈, 인코포레이티드. | 페로브스카이트를 포함하는 공기 전극 |
| KR102221363B1 (ko) * | 2013-06-05 | 2021-03-03 | 자프 에너지 시스템즈, 인코포레이티드. | 페로브스카이트를 포함하는 공기 전극 |
| JP2017208197A (ja) * | 2016-05-17 | 2017-11-24 | 日立造船株式会社 | 金属空気二次電池 |
| KR20220040505A (ko) | 2019-09-12 | 2022-03-30 | 학교법인 도시샤 | 금속 음극 및 상기 금속 음극의 제작 방법 그리고 상기 금속 음극을 구비하는 이차 전지 |
| US11652204B2 (en) | 2019-09-12 | 2023-05-16 | The Doshisha | Metal negative electrode, method for fabricating the same and secondary battery including the same |
| WO2023063260A1 (ja) | 2021-10-12 | 2023-04-20 | 学校法人同志社 | 二次電池用負極構造体及び該構造体を備えた二次電池 |
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Free format text: JAPANESE INTERMEDIATE CODE: A02 Effective date: 20141225 |