JP2012036233A - マレイミド系重合体 - Google Patents
マレイミド系重合体 Download PDFInfo
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- JP2012036233A JP2012036233A JP2010174774A JP2010174774A JP2012036233A JP 2012036233 A JP2012036233 A JP 2012036233A JP 2010174774 A JP2010174774 A JP 2010174774A JP 2010174774 A JP2010174774 A JP 2010174774A JP 2012036233 A JP2012036233 A JP 2012036233A
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- maleimide
- maleimide polymer
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- 229920000642 polymer Polymers 0.000 title claims abstract description 72
- PEEHTFAAVSWFBL-UHFFFAOYSA-N Maleimide Chemical compound O=C1NC(=O)C=C1 PEEHTFAAVSWFBL-UHFFFAOYSA-N 0.000 title claims abstract description 68
- 125000003118 aryl group Chemical group 0.000 claims abstract description 20
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 15
- 150000001875 compounds Chemical class 0.000 claims description 18
- 238000007334 copolymerization reaction Methods 0.000 claims description 14
- -1 maleimide compound Chemical class 0.000 claims description 11
- 238000005259 measurement Methods 0.000 description 20
- NCSZRNMVUILZEC-UHFFFAOYSA-N 3-methylidene-1,2-dihydroindene Chemical compound C1=CC=C2C(=C)CCC2=C1 NCSZRNMVUILZEC-UHFFFAOYSA-N 0.000 description 16
- 239000007787 solid Substances 0.000 description 13
- 230000009477 glass transition Effects 0.000 description 10
- HIDBROSJWZYGSZ-UHFFFAOYSA-N 1-phenylpyrrole-2,5-dione Chemical compound O=C1C=CC(=O)N1C1=CC=CC=C1 HIDBROSJWZYGSZ-UHFFFAOYSA-N 0.000 description 9
- 238000006243 chemical reaction Methods 0.000 description 9
- 229920001577 copolymer Polymers 0.000 description 9
- 239000011259 mixed solution Substances 0.000 description 8
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 7
- 239000013585 weight reducing agent Substances 0.000 description 7
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- SEEYREPSKCQBBF-UHFFFAOYSA-N n-methylmaleimide Chemical compound CN1C(=O)C=CC1=O SEEYREPSKCQBBF-UHFFFAOYSA-N 0.000 description 6
- 238000005160 1H NMR spectroscopy Methods 0.000 description 5
- 238000001644 13C nuclear magnetic resonance spectroscopy Methods 0.000 description 4
- AUIURIPXSQBMJD-UHFFFAOYSA-N 4-methylidene-2,3-dihydro-1h-naphthalene Chemical compound C1=CC=C2C(=C)CCCC2=C1 AUIURIPXSQBMJD-UHFFFAOYSA-N 0.000 description 4
- 125000004432 carbon atom Chemical group C* 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- SJLLJZNSZJHXQN-UHFFFAOYSA-N 1-dodecylpyrrole-2,5-dione Chemical compound CCCCCCCCCCCCN1C(=O)C=CC1=O SJLLJZNSZJHXQN-UHFFFAOYSA-N 0.000 description 3
- 150000003923 2,5-pyrrolediones Chemical class 0.000 description 3
- 0 C*(C)C(*)(C1)c2c1cccc2 Chemical compound C*(C)C(*)(C1)c2c1cccc2 0.000 description 3
- 125000005439 maleimidyl group Chemical group C1(C=CC(N1*)=O)=O 0.000 description 3
- 239000000178 monomer Substances 0.000 description 3
- 239000007870 radical polymerization initiator Substances 0.000 description 3
- 230000035484 reaction time Effects 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 150000003440 styrenes Chemical class 0.000 description 3
- XHLHPRDBBAGVEG-UHFFFAOYSA-N 1-tetralone Chemical compound C1=CC=C2C(=O)CCCC2=C1 XHLHPRDBBAGVEG-UHFFFAOYSA-N 0.000 description 2
- RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 238000005481 NMR spectroscopy Methods 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 238000007239 Wittig reaction Methods 0.000 description 2
- 238000009529 body temperature measurement Methods 0.000 description 2
- BKRKYEFQSANYGA-UHFFFAOYSA-N bromo-methyl-triphenyl-$l^{5}-phosphane Chemical compound C=1C=CC=CC=1P(Br)(C=1C=CC=CC=1)(C)C1=CC=CC=C1 BKRKYEFQSANYGA-UHFFFAOYSA-N 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- ZQMIGQNCOMNODD-UHFFFAOYSA-N diacetyl peroxide Chemical compound CC(=O)OOC(C)=O ZQMIGQNCOMNODD-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- NFJPEKRRHIYYES-UHFFFAOYSA-N methylidenecyclopentane Chemical compound C=C1CCCC1 NFJPEKRRHIYYES-UHFFFAOYSA-N 0.000 description 2
- 239000005297 pyrex Substances 0.000 description 2
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 2
- 125000006732 (C1-C15) alkyl group Chemical group 0.000 description 1
- 125000003837 (C1-C20) alkyl group Chemical group 0.000 description 1
- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 description 1
- LGJCFVYMIJLQJO-UHFFFAOYSA-N 1-dodecylperoxydodecane Chemical compound CCCCCCCCCCCCOOCCCCCCCCCCCC LGJCFVYMIJLQJO-UHFFFAOYSA-N 0.000 description 1
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 1
- PFHOSZAOXCYAGJ-UHFFFAOYSA-N 2-[(2-cyano-4-methoxy-4-methylpentan-2-yl)diazenyl]-4-methoxy-2,4-dimethylpentanenitrile Chemical compound COC(C)(C)CC(C)(C#N)N=NC(C)(C#N)CC(C)(C)OC PFHOSZAOXCYAGJ-UHFFFAOYSA-N 0.000 description 1
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 description 1
- FXXLVNARLGNNLX-UHFFFAOYSA-N 5-methylidene-6,7,8,9-tetrahydrobenzo[7]annulene Chemical compound C=C1CCCCC2=CC=CC=C12 FXXLVNARLGNNLX-UHFFFAOYSA-N 0.000 description 1
- KWHUHTFXMNQHAA-UHFFFAOYSA-N 6,7,8,9-tetrahydrobenzo[7]annulen-5-one Chemical compound O=C1CCCCC2=CC=CC=C12 KWHUHTFXMNQHAA-UHFFFAOYSA-N 0.000 description 1
- SYNMYUUTAJUSDF-UHFFFAOYSA-N 7-methylidenebicyclo[4.2.0]octa-1,3,5-triene Chemical compound C1=CC=C2C(=C)CC2=C1 SYNMYUUTAJUSDF-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- 239000004342 Benzoyl peroxide Substances 0.000 description 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- KYIKRXIYLAGAKQ-UHFFFAOYSA-N abcn Chemical compound C1CCCCC1(C#N)N=NC1(C#N)CCCCC1 KYIKRXIYLAGAKQ-UHFFFAOYSA-N 0.000 description 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 1
- 125000005250 alkyl acrylate group Chemical group 0.000 description 1
- 125000002178 anthracenyl group Chemical group C1(=CC=CC2=CC3=CC=CC=C3C=C12)* 0.000 description 1
- 235000019400 benzoyl peroxide Nutrition 0.000 description 1
- 125000006267 biphenyl group Chemical group 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000001460 carbon-13 nuclear magnetic resonance spectrum Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- 125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 description 1
- 230000006837 decompression Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 125000003187 heptyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 150000002734 metacrylic acid derivatives Chemical class 0.000 description 1
- 125000005397 methacrylic acid ester group Chemical group 0.000 description 1
- ZQMHJBXHRFJKOT-UHFFFAOYSA-N methyl 2-[(1-methoxy-2-methyl-1-oxopropan-2-yl)diazenyl]-2-methylpropanoate Chemical compound COC(=O)C(C)(C)N=NC(C)(C)C(=O)OC ZQMHJBXHRFJKOT-UHFFFAOYSA-N 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- QYZFTMMPKCOTAN-UHFFFAOYSA-N n-[2-(2-hydroxyethylamino)ethyl]-2-[[1-[2-(2-hydroxyethylamino)ethylamino]-2-methyl-1-oxopropan-2-yl]diazenyl]-2-methylpropanamide Chemical compound OCCNCCNC(=O)C(C)(C)N=NC(C)(C)C(=O)NCCNCCO QYZFTMMPKCOTAN-UHFFFAOYSA-N 0.000 description 1
- 125000001624 naphthyl group Chemical group 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000000655 nuclear magnetic resonance spectrum Methods 0.000 description 1
- SRSFOMHQIATOFV-UHFFFAOYSA-N octanoyl octaneperoxoate Chemical compound CCCCCCCC(=O)OOC(=O)CCCCCCC SRSFOMHQIATOFV-UHFFFAOYSA-N 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 150000001451 organic peroxides Chemical class 0.000 description 1
- 125000001147 pentyl group Chemical group C(CCCC)* 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000000425 proton nuclear magnetic resonance spectrum Methods 0.000 description 1
- 125000001725 pyrenyl group Chemical group 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 229930195734 saturated hydrocarbon Natural products 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 238000009751 slip forming Methods 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- SWAXTRYEYUTSAP-UHFFFAOYSA-N tert-butyl ethaneperoxoate Chemical compound CC(=O)OOC(C)(C)C SWAXTRYEYUTSAP-UHFFFAOYSA-N 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- 125000003944 tolyl group Chemical group 0.000 description 1
- 125000002889 tridecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000002948 undecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 230000004580 weight loss Effects 0.000 description 1
- 125000005023 xylyl group Chemical group 0.000 description 1
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- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
Description
[式中、R1はアルキル基又はアリール基を示す。]
[式中、mは0〜3の整数を示す。]
本実施形態に係るマレイミド系重合体は、例えば、式(5)で表されるマレイミド化合物と式(6)で表されるエキソメチレン化合物とを、ラジカル共重合する共重合工程を備える製造方法により製造することができる。
(1)重量平均分子量Mw、数平均分子量Mn
重量平均分子量Mwと数平均分子量Mnは、標準ポリスチレン換算GPC装置CCPDRE−8020(東ソー(株)製)を用いて測定し、流出溶媒にはTHFを用いた。
(2)分子量分布
上記(1)により得られた重量平均分子量Mwと数平均分子量Mnの比Mw/Mnを、分子量分布を示す値とした。
(3)ガラス転移温度測定(DSC)
ガラス転移温度(Tg)は、DSC6200(セイコー電子工業(株)製)を用いて測定した。
(4)熱分解温度測定(TG/DTA)
TG/DTA6200(セイコー電子工業(株)製)を用いて、昇温・降温速度を10℃/分、窒素雰囲気で測定し、5%重量減少温度T95を求めた。
(5)核磁気共鳴分光法(NMR)
BRUKER製AV300(300MHz)を用い、ケミカルシフトはCDCl3(1H:7.26ppm、13C:77.0ppm)を基準として、NMRスペクトルを求めた。
10mL用のメスフラスコに、N−メチルマレイミド222mg(東京化成工業(株)製、2.0mmol)、1−メチレンインダン260mg(2.0mmol)、アゾジイソブチロニトリル16.4mg(東京化成工業(株)製、0.1mmol)を加えた後に、1,2−ジクロロエタン(和光純薬(株)製)を加えることで全量を10mLとした。
13C−NMR:δ 179.5−177.8(マレイミド骨格中のC=O)、143.8−123.3(メチレンインダンの芳香環)、69.2、54.7−53.8、42.7−40.4、31.0−24.4(主鎖及びメチレンインダンの飽和炭化水素)、24.4(N−CH3)
N−メチルマレイミドに替えて、N−フェニルマレイミド346mg(2.0mmol)を用いたこと以外は、実施例1と同様の方法により、白色固体としてマレイミド系重合体(81mg)を得た。その対理論収率は9%であった。
1H−NMR:δ 7.9−6.4(メチレンインダンの芳香環、N上の芳香環)、4.2−1.4(主鎖及びメチレンインダンの飽和炭化水素)
N−メチルマレイミドに替えて、N−フェニルマレイミド346mg(2.0mmol)を用い、反応温度を80℃、反応時間を3時間に変更したこと以外は、実施例1と同様の方法により、白色固体としてマレイミド系重合体(153mg)を得た。その対理論収率は25%であった。
N−フェニルマレイミドに替えて、N−ドデシルマレイミド531mg(2.0mmol)を用いたこと以外は、実施例3と同様の方法により、白色固体としてマレイミド系重合体(206mg)を得た。その対理論収率は26%であった。
1−メチレンインダンに替えて、1−メチレンテトラリン268mg(2.0mmol)を用いたこと以外は、実施例3と同様の方法により、白色固体としてマレイミド系重合体(23mg)を得た。その対理論収率は3%であった。
1−メチレンインダンに替えて、1−メチレンシクロペンタン1.64g(20mmol)を用いたこと以外は、実施例1と同様の方法により、白色固体としてマレイミド系重合体(1.72g)を得た。その対理論収率は91%であった。
Claims (4)
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR20210010376A (ko) | 2019-07-19 | 2021-01-27 | 신에쓰 가가꾸 고교 가부시끼가이샤 | 방향족 비스말레이미드 화합물 및 그의 제조 방법, 그리고 해당 화합물을 포함하는 열경화성 환상 이미드 수지 조성물 |
WO2021205806A1 (ja) * | 2020-04-06 | 2021-10-14 | Dic株式会社 | 硬化性樹脂、硬化性樹脂組成物、及び、硬化物 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2003295441A (ja) * | 2002-04-01 | 2003-10-15 | Shin Etsu Chem Co Ltd | ポジ型レジスト材料及びこれを用いたパターン形成方法 |
JP2004149754A (ja) * | 2002-09-03 | 2004-05-27 | Shin Etsu Chem Co Ltd | 高分子化合物及びポジ型レジスト材料並びにこれを用いたパターン形成方法 |
JP2011168673A (ja) * | 2010-02-17 | 2011-09-01 | Tokyo Institute Of Technology | 1−メチレンインダン重合体及びその製造方法、ブロック共重合体及びその製造方法、並びに、光学フィルム。 |
JP2011168674A (ja) * | 2010-02-17 | 2011-09-01 | Tokyo Institute Of Technology | 1−メチレンテトラリン重合体及びその製造方法 |
-
2010
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Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2003295441A (ja) * | 2002-04-01 | 2003-10-15 | Shin Etsu Chem Co Ltd | ポジ型レジスト材料及びこれを用いたパターン形成方法 |
JP2004149754A (ja) * | 2002-09-03 | 2004-05-27 | Shin Etsu Chem Co Ltd | 高分子化合物及びポジ型レジスト材料並びにこれを用いたパターン形成方法 |
JP2011168673A (ja) * | 2010-02-17 | 2011-09-01 | Tokyo Institute Of Technology | 1−メチレンインダン重合体及びその製造方法、ブロック共重合体及びその製造方法、並びに、光学フィルム。 |
JP2011168674A (ja) * | 2010-02-17 | 2011-09-01 | Tokyo Institute Of Technology | 1−メチレンテトラリン重合体及びその製造方法 |
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CN115348977A (zh) * | 2020-04-06 | 2022-11-15 | Dic株式会社 | 硬化性树脂、硬化性树脂组合物及硬化物 |
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