JP2011508802A - 低色ポリビニルアルコールの作成方法 - Google Patents
低色ポリビニルアルコールの作成方法 Download PDFInfo
- Publication number
- JP2011508802A JP2011508802A JP2010539502A JP2010539502A JP2011508802A JP 2011508802 A JP2011508802 A JP 2011508802A JP 2010539502 A JP2010539502 A JP 2010539502A JP 2010539502 A JP2010539502 A JP 2010539502A JP 2011508802 A JP2011508802 A JP 2011508802A
- Authority
- JP
- Japan
- Prior art keywords
- polyvinyl alcohol
- less
- ppm
- vinyl acetate
- color
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000004372 Polyvinyl alcohol Substances 0.000 title claims abstract description 57
- 229920002451 polyvinyl alcohol Polymers 0.000 title claims abstract description 57
- 239000003112 inhibitor Substances 0.000 claims abstract description 28
- 241001550224 Apha Species 0.000 claims abstract description 17
- 229920002689 polyvinyl acetate Polymers 0.000 claims abstract description 16
- 239000011118 polyvinyl acetate Substances 0.000 claims abstract description 16
- 238000004519 manufacturing process Methods 0.000 claims abstract description 14
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 claims description 26
- 238000000034 method Methods 0.000 claims description 20
- 239000005340 laminated glass Substances 0.000 claims description 7
- 239000000178 monomer Substances 0.000 claims description 3
- 239000011521 glass Substances 0.000 claims 3
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical group CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 abstract description 49
- 230000000379 polymerizing effect Effects 0.000 abstract description 3
- 230000003301 hydrolyzing effect Effects 0.000 abstract description 2
- 239000000047 product Substances 0.000 description 23
- 239000012535 impurity Substances 0.000 description 20
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 18
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 9
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 7
- 229920002554 vinyl polymer Polymers 0.000 description 7
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 238000006116 polymerization reaction Methods 0.000 description 6
- 230000008569 process Effects 0.000 description 6
- 239000002994 raw material Substances 0.000 description 6
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 5
- 238000011084 recovery Methods 0.000 description 5
- IKHGUXGNUITLKF-UHFFFAOYSA-N Acetaldehyde Chemical compound CC=O IKHGUXGNUITLKF-UHFFFAOYSA-N 0.000 description 4
- LOUPRKONTZGTKE-WZBLMQSHSA-N Quinine Chemical compound C([C@H]([C@H](C1)C=C)C2)C[N@@]1[C@@H]2[C@H](O)C1=CC=NC2=CC=C(OC)C=C21 LOUPRKONTZGTKE-WZBLMQSHSA-N 0.000 description 4
- 238000009835 boiling Methods 0.000 description 4
- 239000006227 byproduct Substances 0.000 description 4
- 239000011229 interlayer Substances 0.000 description 4
- 239000010410 layer Substances 0.000 description 4
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 description 4
- 229920000642 polymer Polymers 0.000 description 4
- 238000007127 saponification reaction Methods 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 3
- CLBRCZAHAHECKY-UHFFFAOYSA-N [Co].[Pt] Chemical compound [Co].[Pt] CLBRCZAHAHECKY-UHFFFAOYSA-N 0.000 description 3
- KXKVLQRXCPHEJC-UHFFFAOYSA-N acetic acid trimethyl ester Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 239000003086 colorant Substances 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 235000001258 Cinchona calisaya Nutrition 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- IKHGUXGNUITLKF-XPULMUKRSA-N acetaldehyde Chemical compound [14CH]([14CH3])=O IKHGUXGNUITLKF-XPULMUKRSA-N 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- LOUPRKONTZGTKE-UHFFFAOYSA-N cinchonine Natural products C1C(C(C2)C=C)CCN2C1C(O)C1=CC=NC2=CC=C(OC)C=C21 LOUPRKONTZGTKE-UHFFFAOYSA-N 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 239000013068 control sample Substances 0.000 description 2
- MLUCVPSAIODCQM-NSCUHMNNSA-N crotonaldehyde Chemical compound C\C=C\C=O MLUCVPSAIODCQM-NSCUHMNNSA-N 0.000 description 2
- MLUCVPSAIODCQM-UHFFFAOYSA-N crotonaldehyde Natural products CC=CC=O MLUCVPSAIODCQM-UHFFFAOYSA-N 0.000 description 2
- 230000001419 dependent effect Effects 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 238000004821 distillation Methods 0.000 description 2
- 230000007062 hydrolysis Effects 0.000 description 2
- 238000006460 hydrolysis reaction Methods 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 230000001939 inductive effect Effects 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 229960000948 quinine Drugs 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- DHKHKXVYLBGOIT-UHFFFAOYSA-N 1,1-Diethoxyethane Chemical compound CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 description 1
- AZQWKYJCGOJGHM-UHFFFAOYSA-N 1,4-benzoquinone Chemical compound O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 description 1
- BBTGUNMUUYNPLH-UHFFFAOYSA-N 5-[4-[(1,3-dioxo-2-benzofuran-5-yl)oxy]phenoxy]-2-benzofuran-1,3-dione Chemical compound C1=C2C(=O)OC(=O)C2=CC(OC2=CC=C(C=C2)OC=2C=C3C(=O)OC(C3=CC=2)=O)=C1 BBTGUNMUUYNPLH-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000011354 acetal resin Substances 0.000 description 1
- 150000001242 acetic acid derivatives Chemical class 0.000 description 1
- LZKPUVULVAMJGR-UHFFFAOYSA-N acetic acid;benzene-1,4-diol Chemical compound CC(O)=O.OC1=CC=C(O)C=C1 LZKPUVULVAMJGR-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 238000005882 aldol condensation reaction Methods 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 239000008346 aqueous phase Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 238000010533 azeotropic distillation Methods 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 125000004185 ester group Chemical group 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000004817 gas chromatography Methods 0.000 description 1
- -1 heavy ends Substances 0.000 description 1
- HBMCQTHGYMTCOF-UHFFFAOYSA-N hydroquinone monoacetate Natural products CC(=O)OC1=CC=C(O)C=C1 HBMCQTHGYMTCOF-UHFFFAOYSA-N 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000003456 ion exchange resin Substances 0.000 description 1
- 229920003303 ion-exchange polymer Polymers 0.000 description 1
- 239000004973 liquid crystal related substance Substances 0.000 description 1
- NWVVVBRKAWDGAB-UHFFFAOYSA-N p-methoxyphenol Chemical compound COC1=CC=C(O)C=C1 NWVVVBRKAWDGAB-UHFFFAOYSA-N 0.000 description 1
- 239000000123 paper Substances 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920006324 polyoxymethylene Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 238000004886 process control Methods 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 238000012552 review Methods 0.000 description 1
- 239000005336 safety glass Substances 0.000 description 1
- 239000000523 sample Substances 0.000 description 1
- 238000004513 sizing Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000011550 stock solution Substances 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 238000001429 visible spectrum Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
- B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
- B32B17/1055—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
- B32B17/10761—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer containing vinyl acetal
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/12—Hydrolysis
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/48—Isomerisation; Cyclisation
Landscapes
- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Joining Of Glass To Other Materials (AREA)
- Polymerisation Methods In General (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US879107P | 2007-12-21 | 2007-12-21 | |
| PCT/US2008/013929 WO2009142616A1 (en) | 2007-12-21 | 2008-12-19 | Process for making low color polyvinyl alcohol |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2011508802A true JP2011508802A (ja) | 2011-03-17 |
| JP2011508802A5 JP2011508802A5 (enExample) | 2012-02-02 |
Family
ID=40789403
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2010539502A Withdrawn JP2011508802A (ja) | 2007-12-21 | 2008-12-19 | 低色ポリビニルアルコールの作成方法 |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US20090163658A1 (enExample) |
| EP (1) | EP2222461A1 (enExample) |
| JP (1) | JP2011508802A (enExample) |
| CN (1) | CN101903171A (enExample) |
| WO (1) | WO2009142616A1 (enExample) |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5420804B1 (ja) * | 2013-08-07 | 2014-02-19 | 株式会社クラレ | ポリビニルアセタールを含有するフィルム |
| JP5420805B1 (ja) * | 2013-08-07 | 2014-02-19 | 株式会社クラレ | ポリビニルアセタールおよびそれを含有する合わせガラス用中間膜 |
| JP5420806B1 (ja) * | 2013-08-07 | 2014-02-19 | 株式会社クラレ | ポリビニルアセタール及びそれを含有する合わせガラス用中間膜 |
| JP5420808B1 (ja) * | 2013-08-07 | 2014-02-19 | 株式会社クラレ | ポリビニルアセタールを含有するフィルム |
| JP5469286B1 (ja) * | 2013-10-25 | 2014-04-16 | 株式会社クラレ | 複層フィルム及びそれからなる合わせガラス用中間膜 |
| JP5469287B1 (ja) * | 2013-10-25 | 2014-04-16 | 株式会社クラレ | 複層フィルム及びそれからなる合わせガラス用中間膜 |
| JP5469289B1 (ja) * | 2013-10-25 | 2014-04-16 | 株式会社クラレ | 複層フィルム及びそれからなる合わせガラス用中間膜 |
| JP5469288B1 (ja) * | 2013-10-25 | 2014-04-16 | 株式会社クラレ | 複層フィルム及びそれからなる合わせガラス用中間膜 |
| WO2015122514A1 (ja) * | 2014-02-17 | 2015-08-20 | 株式会社クラレ | セラミック成形用又は導電ペースト用のバインダー、及びそれらの用途 |
| JP2015203088A (ja) * | 2014-04-16 | 2015-11-16 | 株式会社クラレ | ポリビニルアルコール樹脂の製造方法 |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102731696A (zh) * | 2012-06-13 | 2012-10-17 | 安徽皖维集团有限责任公司 | 一种低灰分聚乙烯醇的制备方法 |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2642420A (en) * | 1948-07-02 | 1953-06-16 | Eastman Kodak Co | Preparation of polyvinyl alcohol |
| US2844563A (en) * | 1956-03-30 | 1958-07-22 | Du Pont | Decolorization of polyvinyl alcohol |
| US3052610A (en) * | 1960-05-19 | 1962-09-04 | Kurashiki Rayon Co | Concentration of acetic acid |
| US3303174A (en) * | 1960-08-04 | 1967-02-07 | Shawiningan Chemicals Ltd | Radiation polymerization process and products thereof |
| US3179641A (en) * | 1961-05-22 | 1965-04-20 | Armour & Co | Vinyl aryl stearates and polymers thereof |
| US3318948A (en) * | 1964-03-12 | 1967-05-09 | Air Reduction | Process for increasing polymerization activity of vinyl acetate |
| US3838019A (en) * | 1968-11-08 | 1974-09-24 | Bayer Ag | Inhibition of polymer formation during distillation of crude vinyl acetate |
| US3697495A (en) * | 1970-08-05 | 1972-10-10 | Du Pont | Preparation of polyvinyl alcohol having improved color properties by treating the polyvinyl ester with ozone |
| ES419805A1 (es) * | 1972-10-25 | 1976-07-16 | Hoechst Ag | Procedimiento para la separacion por destilacion extractivade acetato de vinilo y metanol. |
| US4487959A (en) | 1980-10-27 | 1984-12-11 | Ecolochem, Inc. | Vinyl acetate purification process |
| JPH08310979A (ja) * | 1995-05-19 | 1996-11-26 | Bridgestone Corp | ビニル系モノマーの精製法 |
| US6046272A (en) * | 1998-01-29 | 2000-04-04 | Air Products And Chemicals, Inc. | Non yellowing, thermally stable polyvinyl alcohol |
| US7388069B2 (en) * | 2005-12-16 | 2008-06-17 | Celanese International Corporation | Method to purify poly(vinyl alcohol) |
-
2008
- 2008-12-19 WO PCT/US2008/013929 patent/WO2009142616A1/en not_active Ceased
- 2008-12-19 EP EP08874424A patent/EP2222461A1/en not_active Withdrawn
- 2008-12-19 JP JP2010539502A patent/JP2011508802A/ja not_active Withdrawn
- 2008-12-19 US US12/317,114 patent/US20090163658A1/en not_active Abandoned
- 2008-12-19 CN CN2008801221019A patent/CN101903171A/zh active Pending
Cited By (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2015019452A1 (ja) * | 2013-08-07 | 2015-02-12 | 株式会社クラレ | ポリビニルアセタールを含有するフィルム |
| JP5420805B1 (ja) * | 2013-08-07 | 2014-02-19 | 株式会社クラレ | ポリビニルアセタールおよびそれを含有する合わせガラス用中間膜 |
| JP5420806B1 (ja) * | 2013-08-07 | 2014-02-19 | 株式会社クラレ | ポリビニルアセタール及びそれを含有する合わせガラス用中間膜 |
| JP5420808B1 (ja) * | 2013-08-07 | 2014-02-19 | 株式会社クラレ | ポリビニルアセタールを含有するフィルム |
| WO2015019438A1 (ja) * | 2013-08-07 | 2015-02-12 | 株式会社クラレ | ポリビニルアセタール及びそれを含有する合わせガラス用中間膜 |
| JP5420804B1 (ja) * | 2013-08-07 | 2014-02-19 | 株式会社クラレ | ポリビニルアセタールを含有するフィルム |
| WO2015019441A1 (ja) * | 2013-08-07 | 2015-02-12 | 株式会社クラレ | ポリビニルアセタールおよびそれを含有する合わせガラス用中間膜 |
| WO2015019445A1 (ja) * | 2013-08-07 | 2015-02-12 | 株式会社クラレ | ポリビニルアセタールを含有するフィルム |
| JP5469287B1 (ja) * | 2013-10-25 | 2014-04-16 | 株式会社クラレ | 複層フィルム及びそれからなる合わせガラス用中間膜 |
| JP5469288B1 (ja) * | 2013-10-25 | 2014-04-16 | 株式会社クラレ | 複層フィルム及びそれからなる合わせガラス用中間膜 |
| JP5469289B1 (ja) * | 2013-10-25 | 2014-04-16 | 株式会社クラレ | 複層フィルム及びそれからなる合わせガラス用中間膜 |
| JP5469286B1 (ja) * | 2013-10-25 | 2014-04-16 | 株式会社クラレ | 複層フィルム及びそれからなる合わせガラス用中間膜 |
| WO2015059830A1 (ja) * | 2013-10-25 | 2015-04-30 | 株式会社クラレ | 複層フィルム及びそれからなる合わせガラス用中間膜 |
| WO2015059828A1 (ja) * | 2013-10-25 | 2015-04-30 | 株式会社クラレ | 複層フィルム及びそれからなる合わせガラス用中間膜 |
| WO2015059829A1 (ja) * | 2013-10-25 | 2015-04-30 | 株式会社クラレ | 複層フィルム及びそれからなる合わせガラス用中間膜 |
| WO2015059831A1 (ja) * | 2013-10-25 | 2015-04-30 | 株式会社クラレ | 複層フィルム及びそれからなる合わせガラス用中間膜 |
| US10016959B2 (en) | 2013-10-25 | 2018-07-10 | Kuraray Co., Ltd. | Multilayer film and interlayer film for laminated glass therefrom |
| WO2015122514A1 (ja) * | 2014-02-17 | 2015-08-20 | 株式会社クラレ | セラミック成形用又は導電ペースト用のバインダー、及びそれらの用途 |
| JPWO2015122514A1 (ja) * | 2014-02-17 | 2017-03-30 | 株式会社クラレ | セラミック成形用又は導電ペースト用のバインダー、及びそれらの用途 |
| JP2015203088A (ja) * | 2014-04-16 | 2015-11-16 | 株式会社クラレ | ポリビニルアルコール樹脂の製造方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101903171A (zh) | 2010-12-01 |
| WO2009142616A1 (en) | 2009-11-26 |
| US20090163658A1 (en) | 2009-06-25 |
| EP2222461A1 (en) | 2010-09-01 |
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