JP2011256382A - 特定のハンセン溶解度パラメータを有する溶媒を含む銀ナノ粒子組成物 - Google Patents
特定のハンセン溶解度パラメータを有する溶媒を含む銀ナノ粒子組成物 Download PDFInfo
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- JP2011256382A JP2011256382A JP2011118204A JP2011118204A JP2011256382A JP 2011256382 A JP2011256382 A JP 2011256382A JP 2011118204 A JP2011118204 A JP 2011118204A JP 2011118204 A JP2011118204 A JP 2011118204A JP 2011256382 A JP2011256382 A JP 2011256382A
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- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/24—Electrically-conducting paints
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Abstract
【解決手段】金属ナノ粒子組成物は、有機物で安定化された金属ナノ粒子と溶媒とを含み、この溶媒は以下のハンセン溶解度パラメータ:分散パラメータが約16MPa0.5以上、極性パラメータと水素結合パラメータの合計が約8.0MPa0.5以下を有する。金属ナノ粒子組成物は、種々の基板表面に、均一でなめらかで狭い導電性の線を印刷するのに適している。金属ナノ粒子組成物は、コーヒーリング効果の比率が約1.2〜約0.8、表面粗さが約15以下、線の幅が約200マイクロメートル以下の印刷した導電性の部品を作ることができる。
【選択図】なし
Description
(a)絶縁層と;
(b)ゲート電極と;
(c)半導体層と;
(d)ソース電極と;
(e)ドレイン電極とを備える薄膜トランジスタが得られ、
絶縁層、ゲート電極、半導体層、ソース電極、ドレイン電極は、ゲート電極と半導体層が両方とも絶縁層と接触し、ソース電極とドレイン電極が両方とも半導体層に接触している限り、任意の順序であり、
ソース電極、ドレイン電極、ゲート電極のうち、少なくとも1つが、有機アミン化合物によって安定化された金属ナノ粒子を含む溶液を与えることと、有機アミンで安定化された組成物を基板表面に析出させることと、この基板表面にある有機アミンで安定化された組成物を、約70℃〜約200℃の温度まで加熱し、基板表面に導電性の部品を形成させることとによって作られてもよい。
米国特許出願第12/369,861号にすでに開示されている方法を用い、3つの異なるバッチで製造した銀ナノ粒子を用い、組成物を製造した。銀ナノ粒子の3つのバッチであるバッチ1、バッチ2、バッチ3を、比較例1〜3および実施例1〜3の調製でそれぞれ用いた。銀ナノ粒子粉末の3つのバッチを同じ様式で合成し、再現性を評価した。3バッチすべての銀ナノ粒子には、銀がほぼ85重量%含まれていた。
銀ナノ粒子粉末と、ISOPAR Gおよびテルピネオールを比率2:1で混合した溶媒混合物とを混合することによって、組成物を調製した。銀ナノ粒子は、銀配合物の50重量%であった。銀ナノ粒子を溶媒に混合した後、組成物を1μmシリンジフィルタで濾過した。10pLカートリッジを取り付けたDMP−2800インクジェットプリンタを用い、組成物を印刷した。印刷し、熱によってアニーリングした後、線の形状を表面形状測定装置を用いて特性決定した。
比較例と同じバッチから製造した銀ナノ粒子粉末を混合することによって、組成物を調製した。しかし、組成物の調製は、以下に記載しているように異なっていた。使用した溶媒は、デカヒドロナフタレンであった。デカヒドロナフタレンは、以下のハンセン溶解度パラメータを有している。Hansen Solubility Parameters:A User’s Handbook referenceからわかるように、分散パラメータは18.0MPa0.5であり、極性パラメータは0.0MPa0.5であり、水素結合パラメータは0.0MPa0.5である。銀ナノ粒子は、40重量%保持されていた。銀ナノ粒子を溶媒内で混合した後、組成物を1μmシリンジフィルタで濾過した。10pLカートリッジを取り付けたDMP−2800インクジェットプリンタを用い、組成物を印刷した。印刷し、熱によってアニーリングした後、線の形状を表面形状測定装置を用いて特性決定した。
Claims (3)
- 有機物で安定化された金属ナノ粒子と、溶媒とを含み、この溶媒が、以下のハンセン溶解度パラメータ:分散パラメータが約16MPa0.5以上、極性パラメータと水素結合パラメータの合計が約8.0MPa0.5以下を有する、組成物。
- 有機物で安定化された金属ナノ粒子と、溶媒とを含み、この溶媒が、以下のハンセン溶解度パラメータ:分散パラメータが約18MPa0.5以上、極性パラメータが約1.0MPa0.5〜約0.0MPa0.5、水素結合パラメータが約1.0MPa0.5〜約0.0MPa0.5を有する、組成物。
- 基板表面に導電性の部品を作成する方法であって、
有機物で安定化された金属ナノ粒子と以下のハンセン溶解度パラメータ:分散パラメータが約16MPa0.5以上、極性パラメータと水素結合パラメータとの合計が約5.5MPa0.5以下を有する溶媒とを含む液体組成物を与えることと、
前記基板表面に前記液体組成物を析出させ、析出した部品を作成することと、
基板表面に析出した前記部品を約70℃〜約200℃の温度まで加熱し、前記基板表面に導電性の部品を作成することとを含む、方法。
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US12/797,251 US8765025B2 (en) | 2010-06-09 | 2010-06-09 | Silver nanoparticle composition comprising solvents with specific hansen solubility parameters |
US12/797,251 | 2010-06-09 |
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- 2011-06-02 CA CA2742009A patent/CA2742009C/en not_active Expired - Fee Related
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WO2012111480A1 (ja) * | 2011-02-16 | 2012-08-23 | 株式会社 村田製作所 | 導電性ペースト及び太陽電池 |
JP2012184407A (ja) * | 2011-03-07 | 2012-09-27 | Xerox Corp | 銀ナノ粒子を含む溶媒系インク |
JP2013221058A (ja) * | 2012-04-16 | 2013-10-28 | Daiso Co Ltd | 導電性インク組成物 |
JP2015523680A (ja) * | 2012-05-18 | 2015-08-13 | ユニピクセル ディスプレイズ,インコーポレーテッド | 金属のナノ粒子とナノワイヤを含むインクを用いた導電パターンの形成 |
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JP2017019969A (ja) * | 2015-07-14 | 2017-01-26 | 理想科学工業株式会社 | 着色樹脂粒子分散体、その製造方法及びインクジェットインク |
JP2017107979A (ja) * | 2015-12-09 | 2017-06-15 | トヨタ自動車株式会社 | 熱電変換材料 |
WO2019116978A1 (ja) * | 2017-12-14 | 2019-06-20 | ナガセケムテックス株式会社 | 金属インク、金属インクの製造方法、および金属パターンを備える基材の製造方法 |
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JP7248592B2 (ja) | 2017-12-14 | 2023-03-29 | ナガセケムテックス株式会社 | 金属インク、金属インクの製造方法、および金属パターンを備える基材の製造方法 |
WO2021107107A1 (ja) * | 2019-11-30 | 2021-06-03 | 日鉄ケミカル&マテリアル株式会社 | ニッケルナノ粒子組成物及び積層体 |
WO2022070330A1 (ja) * | 2020-09-30 | 2022-04-07 | 国立大学法人東北大学 | 金属ナノ粒子分散液 |
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Also Published As
Publication number | Publication date |
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DE102011076749A1 (de) | 2011-12-15 |
US8765025B2 (en) | 2014-07-01 |
JP5650054B2 (ja) | 2015-01-07 |
CA2742009C (en) | 2015-04-28 |
US20110305821A1 (en) | 2011-12-15 |
CA2742009A1 (en) | 2011-12-09 |
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