JP2010539267A5 - - Google Patents
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- Publication number
- JP2010539267A5 JP2010539267A5 JP2010524458A JP2010524458A JP2010539267A5 JP 2010539267 A5 JP2010539267 A5 JP 2010539267A5 JP 2010524458 A JP2010524458 A JP 2010524458A JP 2010524458 A JP2010524458 A JP 2010524458A JP 2010539267 A5 JP2010539267 A5 JP 2010539267A5
- Authority
- JP
- Japan
- Prior art keywords
- copolymer
- block
- weight
- block copolymer
- vinyl aromatic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229920001400 block copolymer Polymers 0.000 claims description 82
- 239000000203 mixture Substances 0.000 claims description 52
- 229920001577 copolymer Polymers 0.000 claims description 49
- 239000000178 monomer Substances 0.000 claims description 37
- 239000004793 Polystyrene Substances 0.000 claims description 36
- 229920002223 polystyrene Polymers 0.000 claims description 36
- 229920002554 vinyl polymer Polymers 0.000 claims description 32
- 150000001993 dienes Chemical class 0.000 claims description 26
- 230000009477 glass transition Effects 0.000 claims description 20
- 239000004014 plasticizer Substances 0.000 claims description 7
- 239000005022 packaging material Substances 0.000 claims description 6
- 238000009826 distribution Methods 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 18
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 17
- 229920003048 styrene butadiene rubber Polymers 0.000 description 8
- 239000003921 oil Substances 0.000 description 7
- 235000019198 oils Nutrition 0.000 description 7
- 238000002156 mixing Methods 0.000 description 5
- 239000002245 particle Substances 0.000 description 5
- 229920000642 polymer Polymers 0.000 description 5
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 4
- 239000003999 initiator Substances 0.000 description 4
- 238000010539 anionic addition polymerization reaction Methods 0.000 description 3
- 238000005452 bending Methods 0.000 description 3
- 239000011888 foil Substances 0.000 description 3
- 229920005669 high impact polystyrene Polymers 0.000 description 3
- 239000004797 high-impact polystyrene Substances 0.000 description 3
- 239000011159 matrix material Substances 0.000 description 3
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 3
- 229920005604 random copolymer Polymers 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- 239000002174 Styrene-butadiene Substances 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 2
- 239000007822 coupling agent Substances 0.000 description 2
- 238000000113 differential scanning calorimetry Methods 0.000 description 2
- 238000004455 differential thermal analysis Methods 0.000 description 2
- 229920001971 elastomer Polymers 0.000 description 2
- 235000021388 linseed oil Nutrition 0.000 description 2
- 239000000944 linseed oil Substances 0.000 description 2
- WGOPGODQLGJZGL-UHFFFAOYSA-N lithium;butane Chemical compound [Li+].CC[CH-]C WGOPGODQLGJZGL-UHFFFAOYSA-N 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- ZRLVQFQTCMUIRM-UHFFFAOYSA-N potassium;2-methylbutan-2-olate Chemical compound [K+].CCC(C)(C)[O-] ZRLVQFQTCMUIRM-UHFFFAOYSA-N 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000011115 styrene butadiene Substances 0.000 description 2
- 125000003011 styrenyl group Chemical group [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 2
- 229920002633 Kraton (polymer) Polymers 0.000 description 1
- MZRVEZGGRBJDDB-UHFFFAOYSA-N N-Butyllithium Chemical compound [Li]CCCC MZRVEZGGRBJDDB-UHFFFAOYSA-N 0.000 description 1
- STLLXWLDRUVCHL-UHFFFAOYSA-N [2-[1-[2-hydroxy-3,5-bis(2-methylbutan-2-yl)phenyl]ethyl]-4,6-bis(2-methylbutan-2-yl)phenyl] prop-2-enoate Chemical compound CCC(C)(C)C1=CC(C(C)(C)CC)=CC(C(C)C=2C(=C(C=C(C=2)C(C)(C)CC)C(C)(C)CC)OC(=O)C=C)=C1O STLLXWLDRUVCHL-UHFFFAOYSA-N 0.000 description 1
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- ZFMQKOWCDKKBIF-UHFFFAOYSA-N bis(3,5-difluorophenyl)phosphane Chemical compound FC1=CC(F)=CC(PC=2C=C(F)C=C(F)C=2)=C1 ZFMQKOWCDKKBIF-UHFFFAOYSA-N 0.000 description 1
- 238000004581 coalescence Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 125000002897 diene group Chemical group 0.000 description 1
- 238000001938 differential scanning calorimetry curve Methods 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 238000010526 radical polymerization reaction Methods 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000009864 tensile test Methods 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 238000002834 transmittance Methods 0.000 description 1
- 238000001291 vacuum drying Methods 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP07116456 | 2007-09-14 | ||
| EP07116456.0 | 2007-09-14 | ||
| PCT/EP2008/061635 WO2009037115A1 (de) | 2007-09-14 | 2008-09-03 | Transparente und zähsteife formmassen auf basis von styrol-butadien-blockcopolymermischungen |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2010539267A JP2010539267A (ja) | 2010-12-16 |
| JP2010539267A5 true JP2010539267A5 (OSRAM) | 2013-10-03 |
| JP5653754B2 JP5653754B2 (ja) | 2015-01-14 |
Family
ID=40138032
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2010524458A Expired - Fee Related JP5653754B2 (ja) | 2007-09-14 | 2008-09-03 | スチレン−ブタジエンブロック共重合体混合物に基づく透明で強靭で剛性のある成形組成物 |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US8575269B2 (OSRAM) |
| EP (1) | EP2190922B1 (OSRAM) |
| JP (1) | JP5653754B2 (OSRAM) |
| KR (1) | KR20100081319A (OSRAM) |
| CN (1) | CN101855291B (OSRAM) |
| AT (1) | ATE513876T1 (OSRAM) |
| WO (1) | WO2009037115A1 (OSRAM) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8759445B2 (en) | 2008-06-27 | 2014-06-24 | Styrolution GmbH | Styrene butadiene block copolymer mixtures for shrink-wrap films |
| WO2010072596A1 (de) | 2008-12-23 | 2010-07-01 | Basf Se | Phasenseparierende block- oder pfropfcopolymere aus unverträglichen hartblöcken und formmassen mit hoher steifigkeit |
| JP6785065B2 (ja) * | 2016-05-27 | 2020-11-18 | デンカ株式会社 | 成形体 |
| US11041070B2 (en) * | 2016-12-23 | 2021-06-22 | Ineos Styroluction Group Gmbh | Polymer compositions for shrink-wrap films |
| CN114786742B (zh) * | 2019-10-14 | 2025-08-26 | 英力士苯领集团股份公司 | 适于医疗器械的苯乙烯丁二烯嵌段共聚物组合物 |
Family Cites Families (39)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3639517A (en) | 1969-09-22 | 1972-02-01 | Phillips Petroleum Co | Resinous branched block copolymers |
| US3693517A (en) * | 1969-12-23 | 1972-09-26 | Xerox Corp | Printing apparatus |
| GB1482921A (en) | 1973-07-31 | 1977-08-17 | Glaxo Lab Ltd | Polymers |
| DE2550227C2 (de) | 1975-11-08 | 1984-12-20 | Basf Ag, 6700 Ludwigshafen | Verzweigte Blockcopolymerisate und Verfahren zu ihrer Herstellung |
| DE2829625A1 (de) | 1978-07-06 | 1980-01-24 | Basf Ag | Staubfreie aussenschmierung fuer polyamid |
| JPS5575441A (en) * | 1978-12-04 | 1980-06-06 | Asahi Chem Ind Co Ltd | Styrene resin composition having excellent impact resistance |
| DE2927572A1 (de) | 1979-07-07 | 1981-01-22 | Basf Ag | Themoplastische formmassen |
| DE4011162A1 (de) | 1990-04-06 | 1991-10-10 | Basf Ag | Thermoplastische formmasse |
| JP3431944B2 (ja) | 1992-03-19 | 2003-07-28 | 東ソー株式会社 | 難燃性ポリオレフィン系樹脂組成物 |
| US5658987A (en) * | 1993-03-30 | 1997-08-19 | Nippon Zeon Co., Ltd. | Rubber composition |
| CA2134026C (en) | 1993-11-15 | 1998-06-09 | William J. Trepka | Tapered block copolymers of monovinylarenes and conjugated dienes |
| DE4420952A1 (de) | 1994-06-17 | 1995-12-21 | Basf Ag | Thermoplastisches Elastomer |
| US5942561A (en) | 1995-03-03 | 1999-08-24 | Tosoh Corporation | Fire-retardant polymer composition |
| ES2147880T3 (es) * | 1995-10-02 | 2000-10-01 | Basf Ag | Masas de moldeo termoplasticas. |
| DE19810141A1 (de) * | 1998-03-10 | 1999-09-16 | Basf Ag | Polymermischungen aus Styrolpolymeren |
| DE19858141A1 (de) | 1998-12-16 | 2000-06-21 | Basf Ag | Thermoplasische Formmassen |
| DE19914075A1 (de) | 1999-03-27 | 2000-09-28 | Basf Ag | Glasklares, schlagzähes Polystyrol auf Basis von Styrol-Butadien-Blockcopolymeren |
| US6593430B1 (en) | 1999-03-27 | 2003-07-15 | Basf Aktiengesellschaft | Transparent, impact-resistant polystyrene on a styrene-butadiene block copolymer basis |
| DE10037280A1 (de) | 2000-07-28 | 2002-02-07 | Basf Ag | Verfahren zur Agglomeration dispergierter Kautschuke |
| EP1368425A2 (en) * | 2000-09-15 | 2003-12-10 | Dow Global Technologies Inc. | Styrenic polymer compositions with improved clarity |
| MXPA03004116A (es) * | 2000-11-10 | 2003-08-19 | Denki Kagaku Kogyo Kk | Copolimero de bloque, composicion del mismo, y pelicula obtenida del mismo. |
| FR2824347B1 (fr) | 2001-05-04 | 2003-08-08 | Filclair Sa | Dispositif de couverture reversible de toiture de batiments de type serre par une bache |
| DE10158500A1 (de) * | 2001-11-28 | 2003-06-12 | Basf Ag | Transparente Styrol-Butadien-Blockcopolymermischungen |
| IL146821A0 (en) | 2001-11-29 | 2002-07-25 | Bromine Compounds Ltd | Fire retarded polymer composition |
| WO2003091303A1 (fr) * | 2002-04-25 | 2003-11-06 | Asahi Kasei Chemicals Corporation | Copolymere sequence et sa composition |
| IL161592A0 (en) | 2004-04-22 | 2004-09-27 | Bromine Compounds Ltd | Fire retarded styrene polymer compositions |
| AT500875A1 (de) | 2004-07-23 | 2006-04-15 | Intumex Gmbh | Intumeszierende klippprofile für brandschutzeinrichtungen |
| DE102004045172A1 (de) * | 2004-09-17 | 2006-03-23 | Basf Ag | Verfahren zur Herstellung von ein- oder mehrfach gestrichenen Substraten mit einer ein Bindemittel vor Haftung umfassenden Streichfarbenzusammensetzung |
| DE102004058584A1 (de) | 2004-12-03 | 2006-06-08 | Basf Ag | Strahlungshärtbare Beschichtungsmassen |
| DE102004059783A1 (de) * | 2004-12-10 | 2006-06-14 | Basf Ag | Transparente Mischungen linearer Styrol-Butadien-Blockcopolymerer |
| DE102005001637A1 (de) * | 2005-01-12 | 2006-07-20 | Basf Ag | Styrol-Butadien-Blockcopolymermischungen für Schrumpffolien |
| WO2006075665A1 (ja) * | 2005-01-13 | 2006-07-20 | Denki Kagaku Kogyo Kabushiki Kaisha | ブロック共重合体混合物及びそれを用いた熱収縮性フィルム |
| DE102005006137B4 (de) | 2005-02-10 | 2007-09-13 | Wacker Chemie Ag | Verfahren zum Engergieeintrag durch Heizdampf mittels einer Vorrichtung zur Wärmeübertragung |
| JP4681382B2 (ja) | 2005-07-28 | 2011-05-11 | 帝人化成株式会社 | 熱可塑性樹脂組成物 |
| MX2008015870A (es) | 2006-06-27 | 2009-01-13 | Basf Se | Mezclas de copolimero de bloque de estireno-butadieno altamente transparentes y duras-rigidas. |
| US8545953B2 (en) | 2007-02-28 | 2013-10-01 | Styrolution GmbH | Hollow polystyrene body obtained by injection stretch blow moulding |
| EP2152770B1 (de) | 2007-05-23 | 2010-10-13 | Basf Se | Isotaktisches polystyrol mit reaktiven gruppen |
| WO2009007358A1 (en) | 2007-07-10 | 2009-01-15 | Basf Se | Flame retardant thermoplastic molding compositions |
| DE102008056975A1 (de) * | 2008-11-13 | 2010-05-20 | Lanxess Deutschland Gmbh | Lagerstabile, hydroxylmodifizierte Mikrogellatices |
-
2008
- 2008-09-03 EP EP08803606A patent/EP2190922B1/de not_active Not-in-force
- 2008-09-03 WO PCT/EP2008/061635 patent/WO2009037115A1/de not_active Ceased
- 2008-09-03 US US12/677,960 patent/US8575269B2/en not_active Expired - Fee Related
- 2008-09-03 CN CN2008801069399A patent/CN101855291B/zh not_active Expired - Fee Related
- 2008-09-03 JP JP2010524458A patent/JP5653754B2/ja not_active Expired - Fee Related
- 2008-09-03 AT AT08803606T patent/ATE513876T1/de active
- 2008-09-03 KR KR1020107007979A patent/KR20100081319A/ko not_active Abandoned
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