JP2010537031A5 - - Google Patents
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- Publication number
- JP2010537031A5 JP2010537031A5 JP2010522334A JP2010522334A JP2010537031A5 JP 2010537031 A5 JP2010537031 A5 JP 2010537031A5 JP 2010522334 A JP2010522334 A JP 2010522334A JP 2010522334 A JP2010522334 A JP 2010522334A JP 2010537031 A5 JP2010537031 A5 JP 2010537031A5
- Authority
- JP
- Japan
- Prior art keywords
- gas phase
- monomer
- volume
- monomer solution
- oxygen
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000007789 gas Substances 0.000 claims description 11
- 239000000178 monomer Substances 0.000 claims description 11
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 7
- 239000001301 oxygen Substances 0.000 claims description 7
- 229910052760 oxygen Inorganic materials 0.000 claims description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 3
- 239000003999 initiator Substances 0.000 claims description 3
- 238000000034 method Methods 0.000 claims 11
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims 2
- 239000003431 cross linking reagent Substances 0.000 claims 2
- 238000004519 manufacturing process Methods 0.000 claims 1
- 229910052757 nitrogen Inorganic materials 0.000 claims 1
- 239000002245 particle Substances 0.000 claims 1
- 229920000642 polymer Polymers 0.000 claims 1
- 230000000379 polymerizing effect Effects 0.000 claims 1
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 239000000243 solution Substances 0.000 description 6
- 239000000203 mixture Substances 0.000 description 4
- 229910052783 alkali metal Inorganic materials 0.000 description 3
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- -1 alkali metal hydrogen carbonates Chemical class 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000003112 inhibitor Substances 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Chemical compound [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 description 2
- PQUXFUBNSYCQAL-UHFFFAOYSA-N 1-(2,3-difluorophenyl)ethanone Chemical compound CC(=O)C1=CC=CC(F)=C1F PQUXFUBNSYCQAL-UHFFFAOYSA-N 0.000 description 1
- PUGOMSLRUSTQGV-UHFFFAOYSA-N 2,3-di(prop-2-enoyloxy)propyl prop-2-enoate Chemical class C=CC(=O)OCC(OC(=O)C=C)COC(=O)C=C PUGOMSLRUSTQGV-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 208000034874 Product colour issue Diseases 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 229910000288 alkali metal carbonate Inorganic materials 0.000 description 1
- 150000008041 alkali metal carbonates Chemical class 0.000 description 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 1
- 229910000272 alkali metal oxide Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 239000012223 aqueous fraction Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- LBSPZZSGTIBOFG-UHFFFAOYSA-N bis[2-(4,5-dihydro-1h-imidazol-2-yl)propan-2-yl]diazene;dihydrochloride Chemical compound Cl.Cl.N=1CCNC=1C(C)(C)N=NC(C)(C)C1=NCCN1 LBSPZZSGTIBOFG-UHFFFAOYSA-N 0.000 description 1
- 239000013590 bulk material Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229940047670 sodium acrylate Drugs 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP07115291.2 | 2007-08-30 | ||
| EP07115291 | 2007-08-30 | ||
| PCT/EP2008/061054 WO2009027356A1 (de) | 2007-08-30 | 2008-08-25 | Verfahren zur herstellung wasserabsorbierender polymerpartikel durch polymerisation von tropfen einer monomerlösung |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2010537031A JP2010537031A (ja) | 2010-12-02 |
| JP2010537031A5 true JP2010537031A5 (OSRAM) | 2011-10-13 |
| JP5436427B2 JP5436427B2 (ja) | 2014-03-05 |
Family
ID=39938233
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2010522334A Active JP5436427B2 (ja) | 2007-08-30 | 2008-08-25 | モノマー溶液の液滴の重合による吸水性ポリマー粒子の製造方法 |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US8044158B2 (OSRAM) |
| EP (1) | EP2187978B1 (OSRAM) |
| JP (1) | JP5436427B2 (OSRAM) |
| CN (1) | CN101790390B (OSRAM) |
| AT (1) | ATE499954T1 (OSRAM) |
| BR (1) | BRPI0815765B1 (OSRAM) |
| DE (1) | DE502008002757D1 (OSRAM) |
| MY (1) | MY151277A (OSRAM) |
| RU (1) | RU2484100C2 (OSRAM) |
| WO (1) | WO2009027356A1 (OSRAM) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2125047B1 (de) * | 2006-12-22 | 2015-09-16 | Basf Se | Verfahren zur herstellung mechanisch stabiler wasserabsorbierender polymerpartikel |
| JP5615365B2 (ja) | 2009-08-28 | 2014-10-29 | ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ | トリクロサン被覆超吸収材の製造方法 |
| CN102597082A (zh) | 2009-09-16 | 2012-07-18 | 巴斯夫欧洲公司 | 颜色稳定的超吸收剂 |
| JP2013505313A (ja) | 2009-09-17 | 2013-02-14 | ビーエーエスエフ ソシエタス・ヨーロピア | 色安定性の超吸収剤 |
| WO2011117215A1 (de) * | 2010-03-24 | 2011-09-29 | Basf Se | Verfahren zur entfernung von restmonomeren aus wasserabsorbierenden polymerpartikeln |
| WO2013144026A1 (de) | 2012-03-30 | 2013-10-03 | Basf Se | Farbstabiler superabsorber |
| WO2013144027A1 (de) | 2012-03-30 | 2013-10-03 | Basf Se | Farbstabiler superabsorber |
| KR102301326B1 (ko) | 2013-12-20 | 2021-09-14 | 가부시키가이샤 닛폰 쇼쿠바이 | 폴리아크릴산(염)계 흡수제 및 그의 제조 방법 |
| CN111278551B (zh) | 2017-11-10 | 2023-09-29 | 巴斯夫欧洲公司 | 超吸收剂 |
| KR102677635B1 (ko) | 2018-04-10 | 2024-06-21 | 바스프 에스이 | 투과성 초흡수제 및 이의 생산 방법 |
| DE102019216910A1 (de) | 2018-11-12 | 2020-05-14 | Basf Se | Verfahren zur Oberflächennachvernetzung von Superabsorbern |
| WO2021013639A1 (en) | 2019-07-24 | 2021-01-28 | Basf Se | Permeable superabsorbent and process for production thereof |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SU1481236A1 (ru) * | 1987-07-27 | 1989-05-23 | Институт Высокомолекулярных Соединений Ан Ссср | Способ получени сополимеров с влагоудерживающей и загущающей способностью |
| RU2089561C1 (ru) * | 1994-07-21 | 1997-09-10 | Акционерное общество закрытого типа Научно-внедренческая фирма "АСПА" | Способ получения сополимеров с высокой влагоудерживающей способностью |
| JP2002370025A (ja) * | 2001-03-29 | 2002-12-24 | Mitsubishi Chemicals Corp | 吸水性複合体及びその製造方法 |
| TW200633770A (en) * | 2005-01-28 | 2006-10-01 | Basf Ag | Production of water-absorbing polymeric particles by dropletization polymerization in the gas phase |
| EP1844080B1 (de) * | 2005-01-28 | 2014-10-29 | Basf Se | Verfahren zur herstellung wasserabsorbierender polymerpartikel durch vertropfungspolymerisation in der gasphase |
| JP2007056122A (ja) * | 2005-08-24 | 2007-03-08 | Mitsubishi Chemicals Corp | 液滴重合反応用ノズル、それを用いた重合方法および吸液性複合体の製造方法 |
| WO2007093531A1 (de) * | 2006-02-17 | 2007-08-23 | Basf Se | Verfahren zur herstellung wasserabsorbierender polymerpartikel durch polymerisation von tropfen einer monomerlösung |
| CN101522720B (zh) * | 2006-10-05 | 2012-05-30 | 巴斯夫欧洲公司 | 通过聚合单体溶液液滴而制备吸水性聚合物珠粒的方法 |
| MY148330A (en) * | 2006-10-31 | 2013-03-29 | Basf Se | Regulation of a process for producing water-absorbing polymer particles in a heated gas phase |
| JP5328675B2 (ja) * | 2007-02-06 | 2013-10-30 | ビーエーエスエフ ソシエタス・ヨーロピア | モノマー溶液の液滴の重合による吸水性ポリマー粒子の製造法 |
| JP5419712B2 (ja) * | 2007-02-06 | 2014-02-19 | ビーエーエスエフ ソシエタス・ヨーロピア | モノマー溶液の液滴の重合による吸水性ポリマー粒子を製造する方法 |
| EP2121772B1 (de) * | 2007-02-06 | 2012-11-21 | Basf Se | Verfahren zur herstellung von polymerpartikeln durch polymerisation von flüssigkeitstropfen in einer gasphase |
-
2008
- 2008-08-25 RU RU2010111836/04A patent/RU2484100C2/ru active
- 2008-08-25 US US12/674,143 patent/US8044158B2/en active Active
- 2008-08-25 AT AT08803174T patent/ATE499954T1/de active
- 2008-08-25 WO PCT/EP2008/061054 patent/WO2009027356A1/de not_active Ceased
- 2008-08-25 MY MYPI20100802 patent/MY151277A/en unknown
- 2008-08-25 EP EP08803174A patent/EP2187978B1/de active Active
- 2008-08-25 CN CN200880104850.9A patent/CN101790390B/zh active Active
- 2008-08-25 JP JP2010522334A patent/JP5436427B2/ja active Active
- 2008-08-25 DE DE502008002757T patent/DE502008002757D1/de active Active
- 2008-08-25 BR BRPI0815765A patent/BRPI0815765B1/pt active IP Right Grant
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