JP2010513629A5 - - Google Patents
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- JP2010513629A5 JP2010513629A5 JP2009541985A JP2009541985A JP2010513629A5 JP 2010513629 A5 JP2010513629 A5 JP 2010513629A5 JP 2009541985 A JP2009541985 A JP 2009541985A JP 2009541985 A JP2009541985 A JP 2009541985A JP 2010513629 A5 JP2010513629 A5 JP 2010513629A5
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- JP
- Japan
- Prior art keywords
- catalyst component
- group
- solid catalyst
- amount
- molar
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000010936 titanium Substances 0.000 claims 7
- 239000011949 solid catalyst Substances 0.000 claims 6
- 239000003054 catalyst Substances 0.000 claims 3
- 239000000460 chlorine Substances 0.000 claims 3
- VSCWAEJMTAWNJL-UHFFFAOYSA-K Aluminium chloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 claims 2
- 239000004215 Carbon black (E152) Substances 0.000 claims 2
- 150000001336 alkenes Chemical class 0.000 claims 2
- 229910052782 aluminium Inorganic materials 0.000 claims 2
- -1 aluminum compound Chemical class 0.000 claims 2
- 150000001450 anions Chemical class 0.000 claims 2
- 150000001768 cations Chemical class 0.000 claims 2
- 229910052801 chlorine Inorganic materials 0.000 claims 2
- 150000001875 compounds Chemical class 0.000 claims 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims 2
- 229910052736 halogen Inorganic materials 0.000 claims 2
- 150000002367 halogens Chemical group 0.000 claims 2
- 150000002430 hydrocarbons Chemical group 0.000 claims 2
- 238000006116 polymerization reaction Methods 0.000 claims 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N titanium Chemical group [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims 2
- 229910052719 titanium Inorganic materials 0.000 claims 2
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L MgCl2 Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims 1
- 125000000217 alkyl group Chemical group 0.000 claims 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminum Chemical class [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims 1
- 125000000129 anionic group Chemical group 0.000 claims 1
- 125000003118 aryl group Chemical group 0.000 claims 1
- 125000004429 atoms Chemical group 0.000 claims 1
- 238000006243 chemical reaction Methods 0.000 claims 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims 1
- 125000000753 cycloalkyl group Chemical group 0.000 claims 1
- 150000002148 esters Chemical class 0.000 claims 1
- 238000010438 heat treatment Methods 0.000 claims 1
- 125000005842 heteroatoms Chemical group 0.000 claims 1
- 150000002576 ketones Chemical class 0.000 claims 1
- 229910052749 magnesium Inorganic materials 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 claims 1
- 229910052753 mercury Inorganic materials 0.000 claims 1
- 239000011148 porous material Substances 0.000 claims 1
- 239000000047 product Substances 0.000 claims 1
- 150000003377 silicon compounds Chemical class 0.000 claims 1
- 239000012265 solid product Substances 0.000 claims 1
Claims (7)
- Ｔｉ、Ｍｇ、Ａｌ、Ｃｌ、及び場合によってはＯＲＩ基（式中、ＲＩは、０．５より低いＯＲＩ／Ｔｉのモル比を与えるような量以下の、場合によってはヘテロ原子を含むＣ１〜Ｃ２０炭化水素基である）を含み、チタン原子の実質的に全部が４の原子価状態であり、水銀法によって測定した１μｍ以下の半径を有する孔による多孔度（ＰＦ）が少なくとも０．４ｃｍ３／ｇであり、Ｃｌ／Ｔｉのモル比が２８より低く、Ａｌの量がＴｉの量より少ないことを特徴とする、オレフィン重合用の触媒成分。
- ０．５より高い「ＬＡ」ファクター（ここで、「ＬＡ」ファクターは、固体触媒成分中に存在するアニオンの全モル当量に応じて化合しなかった固体触媒成分中に存在するカチオンの全モル当量に応じて化合するためには不足しているアニオン種のモル当量（ここで、アニオン及びカチオンのモル当量は全てＴｉのモル量に関するものである）である）を有することを更に特徴とする、請求項１に記載の固体触媒成分。
- 式：ＡｌＣｌＬ２（式中、Ｌは、独立して、請求項１に定義したＯＲＩ基、又は塩素であってよい）のアルミニウム化合物からなる群から選択される塩化アルミニウムを含む、請求項１又は２に記載の固体触媒成分。
- 化合物：ＭｇＣｌ２・ｍＲＩＩＯＨ・ｔＨ２Ｏ（式中、０．３≦ｍ≦１．７であり、ｔは０．０１〜０．６であり、ＲＩＩは、１〜１２個の炭素原子を有するアルキル、シクロアルキル、又はアリール基である）を、式：Ｔｉ（ＯＲＩ）ｎＸｙ−ｎ（式中、ｎは０〜０．５の範囲であり、ｙはチタンの原子価であり、Ｘはハロゲンであり、ＲＩは請求項１に定義した通りである）のチタン化合物と、式：ＡｌＬ３（式中、Ｌは、独立して、ＯＲＩ基（式中、ＲＩはＣ１〜Ｃ２０炭化水素基である）、又はハロゲンであってよい）のアルミニウム化合物の存在下において反応させる工程（ａ）を含む、請求項１〜３のいずれかに記載の触媒成分の製造方法。
- 工程（ａ）から回収される固体生成物を、５０℃より高い温度で行う熱処理にかける第２工程（ｂ）を更に含む、請求項４に記載の方法。
- 工程（ａ）又は（ｂ）の後に得られる該固体触媒成分を、エーテル、ケトン、エステル、及びケイ素化合物の中から選択される電子ドナー化合物と接触させることを特徴とする、請求項４又は５に記載の方法。
- 請求項１〜３のいずれかに記載の固体触媒成分とアルキルアルミニウム化合物との反応の生成物を含む触媒系の存在下で行う、オレフィンの重合方法。
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US87673706P | 2006-12-22 | 2006-12-22 | |
| EP06127075.7 | 2006-12-22 | ||
| US60/876,737 | 2006-12-22 | ||
| EP06127075 | 2006-12-22 | ||
| PCT/EP2007/063707 WO2008077770A1 (en) | 2006-12-22 | 2007-12-11 | Catalyst components for the polymerization of olefins and catalysts therefrom obtained |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2010513629A JP2010513629A (ja) | 2010-04-30 |
| JP2010513629A5 true JP2010513629A5 (ja) | 2011-01-27 |
| JP5583973B2 JP5583973B2 (ja) | 2014-09-03 |
Family
ID=39186141
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2009541985A Expired - Fee Related JP5583973B2 (ja) | 2006-12-22 | 2007-12-11 | オレフィン重合用の触媒成分及びそれから得られる触媒 |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US8071499B2 (ja) |
| EP (1) | EP2121773B1 (ja) |
| JP (1) | JP5583973B2 (ja) |
| KR (1) | KR20090101192A (ja) |
| WO (1) | WO2008077770A1 (ja) |
Families Citing this family (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2285840B1 (en) * | 2008-06-13 | 2015-03-18 | Basell Poliolefine Italia S.r.l. | Catalyst system for the polymerization of olefins |
| US8557931B2 (en) * | 2009-02-27 | 2013-10-15 | Basell Polyolefin Gmbh | Multistage process for the polymerization of ethylene |
| WO2010146072A1 (en) | 2009-06-18 | 2010-12-23 | Basell Poliolefine Italia S.R.L. | Catalyst components for the polymerization of olefins and catalysts therefrom obtained |
| US9068028B2 (en) | 2009-06-19 | 2015-06-30 | Basell Poliolefine Italia S.R.L. | Process for the preparation of impact resistant propylene polymer compositions |
| RU2012108226A (ru) * | 2009-08-06 | 2013-09-20 | Базелль Полиолефин Италия С.Р.Л. | Способ получения полимеров этилена с узким молекулярно-массовым распределением |
| JP5890316B2 (ja) * | 2009-12-23 | 2016-03-22 | バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ | 塩化マグネシウム水付加体とそれから得られる触媒成分 |
| RU2012131222A (ru) | 2009-12-23 | 2014-01-27 | Базелль Полиолефин Италия С.Р.Л. | Компоненты катализатора полимеризации олефинов и полученные из них катализаторы |
| US7935651B1 (en) | 2010-02-04 | 2011-05-03 | Equistar Chemicals, L.P. | Method for preparing a Ziegler-Natta catalyst |
| CN103108890B (zh) * | 2010-03-08 | 2015-11-25 | 巴塞尔聚烯烃意大利有限责任公司 | 用于烯烃聚合的催化剂组分 |
| EP2601224B1 (en) * | 2010-08-05 | 2018-09-19 | Basell Poliolefine Italia S.r.l. | Catalyst components for the polymerization of olefins |
| US20130217844A1 (en) * | 2010-10-19 | 2013-08-22 | Basell Poliolefine Italia S.R.L. | Process for the polymerization of olefins |
| KR101872196B1 (ko) * | 2010-12-24 | 2018-06-28 | 바셀 폴리올레핀 이탈리아 에스.알.엘 | 마그네슘 디클로라이드-에탄올 부가물 및 그로부터 수득한 촉매 성분 |
| CN102977233B (zh) * | 2011-09-02 | 2014-08-27 | 中国石油化工股份有限公司 | 一种用于乙烯聚合的催化剂体系 |
| WO2015091978A1 (en) | 2013-12-20 | 2015-06-25 | Saudi Basic Industries Corporation | Catalyst composition for polymerization of olefins |
| WO2015091984A1 (en) | 2013-12-20 | 2015-06-25 | Saudi Basic Industries Corporation | Procatalyst for polymerization of olefins |
| US10647795B2 (en) | 2014-02-07 | 2020-05-12 | Eastman Chemical Company | Adhesive composition comprising amorphous propylene-ethylene copolymer and polyolefins |
| US11267916B2 (en) | 2014-02-07 | 2022-03-08 | Eastman Chemical Company | Adhesive composition comprising amorphous propylene-ethylene copolymer and polyolefins |
| US10308740B2 (en) | 2014-02-07 | 2019-06-04 | Eastman Chemical Company | Amorphous propylene-ethylene copolymers |
| US9382351B2 (en) | 2014-02-07 | 2016-07-05 | Eastman Chemical Company | Amorphous propylene-ethylene copolymers |
| US10696765B2 (en) | 2014-02-07 | 2020-06-30 | Eastman Chemical Company | Adhesive composition comprising amorphous propylene-ethylene copolymer and propylene polymer |
| US10723824B2 (en) | 2014-02-07 | 2020-07-28 | Eastman Chemical Company | Adhesives comprising amorphous propylene-ethylene copolymers |
| EP3802641A1 (en) * | 2018-06-01 | 2021-04-14 | Dow Global Technologies LLC | Ziegler-natta catalyst system having a thermally treated magnesium chloride component |
Family Cites Families (29)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT1096661B (it) | 1978-06-13 | 1985-08-26 | Montedison Spa | Procedimento per la preparazione di prodotti in forma sferoidale solidi a temperatura ambiente |
| IT1098272B (it) | 1978-08-22 | 1985-09-07 | Montedison Spa | Componenti,di catalizzatori e catalizzatori per la polimerizzazione delle alfa-olefine |
| US4347158A (en) * | 1980-05-02 | 1982-08-31 | Dart Industries, Inc. | Supported high efficiency polyolefin catalyst component and methods of making and using the same |
| FI80055C (fi) | 1986-06-09 | 1990-04-10 | Neste Oy | Foerfarande foer framstaellning av katalytkomponenter foer polymerisation av olefiner. |
| IT1227258B (it) | 1988-09-30 | 1991-03-28 | Himont Inc | Componenti e catalizzatori per la polimerizzazione di olefine |
| IT1227260B (it) | 1988-09-30 | 1991-03-28 | Himont Inc | Dieteri utilizzabili nella preparazione di catalizzatori ziegler-natta |
| IT1230134B (it) | 1989-04-28 | 1991-10-14 | Himont Inc | Componenti e catalizzatori per la polimerizzazione di olefine. |
| US5221651A (en) | 1989-04-28 | 1993-06-22 | Himont Incorporated | Component and catalysts for the polymerization of olefins |
| JP2879347B2 (ja) | 1989-10-02 | 1999-04-05 | チッソ株式会社 | オレフィン重合用触媒の製法 |
| US6316546B1 (en) * | 1991-03-06 | 2001-11-13 | Exxonmobil Oil Corporation | Ethylene polymer film resins |
| IT1246614B (it) | 1991-06-03 | 1994-11-24 | Himont Inc | Procedimento per la polimerizzazione in fase gas delle olefine |
| IT1250731B (it) | 1991-07-31 | 1995-04-21 | Himont Inc | Procedimento per la preparazione di polietilene lineare a bassa densita' |
| IT1262934B (it) * | 1992-01-31 | 1996-07-22 | Montecatini Tecnologie Srl | Componenti e catalizzatori per la polimerizzazione di olefine |
| IT1262935B (it) * | 1992-01-31 | 1996-07-22 | Montecatini Tecnologie Srl | Componenti e catalizzatori per la polimerizzazione di olefine |
| IT1254279B (it) | 1992-03-13 | 1995-09-14 | Montecatini Tecnologie Srl | Procedimento per la polimerizzazione in fase gas delle olefine |
| IT1256648B (it) * | 1992-12-11 | 1995-12-12 | Montecatini Tecnologie Srl | Componenti e catalizzatori per la polimerizzazione delle olefine |
| JPH07238108A (ja) * | 1994-02-28 | 1995-09-12 | Idemitsu Petrochem Co Ltd | エチレン重合用固体触媒成分の調製方法および該固体触媒成分を含む触媒を用いるエチレン共重合体の製造方法 |
| IL117114A (en) | 1995-02-21 | 2000-02-17 | Montell North America Inc | Components and catalysts for the polymerization ofolefins |
| IT1275573B (it) | 1995-07-20 | 1997-08-07 | Spherilene Spa | Processo ed apparecchiatura per la pomimerizzazione in fase gas delle alfa-olefine |
| SE9504539D0 (sv) | 1995-12-19 | 1995-12-19 | Borealis As | Procatalyst and process for the preparation of a multimodal ethylene homopolymer and/or ethylene/ 1-olefin copolymer by gas-phase polymerisation |
| JP3455023B2 (ja) * | 1996-07-29 | 2003-10-06 | 東邦チタニウム株式会社 | オレフィン重合体の製造方法 |
| US6407028B1 (en) | 1997-03-29 | 2002-06-18 | Basell Technology Company Bv | Magnesium dichloride-alcohol adducts, process for their preparation and catalyst components obtained therefrom |
| CZ296873B6 (cs) | 1997-03-29 | 2006-07-12 | Montell Technology Company B. V. | Adicní produkty chloridu horecnatého a alkoholu |
| US6323152B1 (en) | 1998-03-30 | 2001-11-27 | Basell Technology Company Bv | Magnesium dichloride-alcohol adducts process for their preparation and catalyst components obtained therefrom |
| IL141358A0 (en) | 1999-06-18 | 2002-03-10 | Basell Technology Co Bv | Catalyst components for the polymerization of olefins and catalysts obtained therefrom |
| DE60139676D1 (de) | 2000-05-12 | 2009-10-08 | Basell Poliolefine Srl | Vorpolymerisierte Katalysatorbestandteile für die Polymerisation von Olefinen |
| EP1518866A1 (en) * | 2003-09-29 | 2005-03-30 | Basell Poliolefine Italia S.P.A. | Process for the preparation of porous ethylene polymers |
| RU2351603C2 (ru) | 2003-09-29 | 2009-04-10 | Базелль Полиолефине Гмбх | Способ изомеризации соединений металлоцена |
| EP2094744A1 (en) | 2006-12-20 | 2009-09-02 | Basell Poliolefine Italia S.R.L. | Catalyst components for the polymerization of olefins and catalysts therefrom obtained |
-
2007
- 2007-12-11 EP EP07857394.6A patent/EP2121773B1/en not_active Not-in-force
- 2007-12-11 JP JP2009541985A patent/JP5583973B2/ja not_active Expired - Fee Related
- 2007-12-11 KR KR1020097012886A patent/KR20090101192A/ko not_active Application Discontinuation
- 2007-12-11 WO PCT/EP2007/063707 patent/WO2008077770A1/en active Application Filing
- 2007-12-11 US US12/448,289 patent/US8071499B2/en not_active Expired - Fee Related
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