JP2010511096A5 - - Google Patents
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- Publication number
- JP2010511096A5 JP2010511096A5 JP2009539303A JP2009539303A JP2010511096A5 JP 2010511096 A5 JP2010511096 A5 JP 2010511096A5 JP 2009539303 A JP2009539303 A JP 2009539303A JP 2009539303 A JP2009539303 A JP 2009539303A JP 2010511096 A5 JP2010511096 A5 JP 2010511096A5
- Authority
- JP
- Japan
- Prior art keywords
- monomer
- reactor
- weight
- group
- tetrafluoroethylene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 239000000178 monomer Substances 0.000 claims description 26
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 claims description 18
- 239000000203 mixture Substances 0.000 claims description 16
- BQCIDUSAKPWEOX-UHFFFAOYSA-N 1,1-Difluoroethene Chemical compound FC(F)=C BQCIDUSAKPWEOX-UHFFFAOYSA-N 0.000 claims description 13
- 229920001973 fluoroelastomer Polymers 0.000 claims description 7
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 6
- 229910052731 fluorine Inorganic materials 0.000 claims description 6
- 239000011737 fluorine Substances 0.000 claims description 6
- 238000006116 polymerization reaction Methods 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 5
- 239000004215 Carbon black (E152) Substances 0.000 claims description 4
- 229930195733 hydrocarbon Natural products 0.000 claims description 4
- -1 hydrocarbon olefins Chemical class 0.000 claims description 4
- 239000004094 surface-active agent Substances 0.000 claims description 4
- 239000006185 dispersion Substances 0.000 claims description 3
- 238000007720 emulsion polymerization reaction Methods 0.000 claims description 3
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 claims description 2
- 150000001336 alkenes Chemical class 0.000 claims description 2
- 125000000217 alkyl group Chemical group 0.000 claims description 2
- 239000003945 anionic surfactant Substances 0.000 claims description 2
- 239000007864 aqueous solution Substances 0.000 claims description 2
- 125000004432 carbon atom Chemical group C* 0.000 claims description 2
- 150000001768 cations Chemical class 0.000 claims description 2
- 150000002430 hydrocarbons Chemical class 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims description 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 2
- 239000012429 reaction media Substances 0.000 claims description 2
- BLTXWCKMNMYXEA-UHFFFAOYSA-N 1,1,2-trifluoro-2-(trifluoromethoxy)ethene Chemical compound FC(F)=C(F)OC(F)(F)F BLTXWCKMNMYXEA-UHFFFAOYSA-N 0.000 description 11
- 238000010556 emulsion polymerization method Methods 0.000 description 5
- HCDGVLDPFQMKDK-UHFFFAOYSA-N hexafluoropropylene Chemical group FC(F)=C(F)C(F)(F)F HCDGVLDPFQMKDK-UHFFFAOYSA-N 0.000 description 5
- OUJSWWHXKJQNMJ-UHFFFAOYSA-N 3,3,4,4-tetrafluoro-4-iodobut-1-ene Chemical compound FC(F)(I)C(F)(F)C=C OUJSWWHXKJQNMJ-UHFFFAOYSA-N 0.000 description 4
- GVCWGFZDSIWLMO-UHFFFAOYSA-N 4-bromo-3,3,4,4-tetrafluorobut-1-ene Chemical compound FC(F)(Br)C(F)(F)C=C GVCWGFZDSIWLMO-UHFFFAOYSA-N 0.000 description 4
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 3
- 239000005977 Ethylene Substances 0.000 description 3
- 229910001870 ammonium persulfate Inorganic materials 0.000 description 2
- 229940052354 dibasic sodium phosphate heptahydrate Drugs 0.000 description 2
- PYLIXCKOHOHGKQ-UHFFFAOYSA-L disodium;hydrogen phosphate;heptahydrate Chemical compound O.O.O.O.O.O.O.[Na+].[Na+].OP([O-])([O-])=O PYLIXCKOHOHGKQ-UHFFFAOYSA-L 0.000 description 2
- 239000003999 initiator Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- QAERDLQYXMEHEB-UHFFFAOYSA-N 1,1,3,3,3-pentafluoroprop-1-ene Chemical compound FC(F)=CC(F)(F)F QAERDLQYXMEHEB-UHFFFAOYSA-N 0.000 description 1
- LYIPDZSLYLDLCU-UHFFFAOYSA-N 2,2,3,3-tetrafluoro-3-[1,1,1,2,3,3-hexafluoro-3-(1,2,2-trifluoroethenoxy)propan-2-yl]oxypropanenitrile Chemical compound FC(F)=C(F)OC(F)(F)C(F)(C(F)(F)F)OC(F)(F)C(F)(F)C#N LYIPDZSLYLDLCU-UHFFFAOYSA-N 0.000 description 1
- GVNVAWHJIKLAGL-UHFFFAOYSA-N 2-(cyclohexen-1-yl)cyclohexan-1-one Chemical compound O=C1CCCCC1C1=CCCCC1 GVNVAWHJIKLAGL-UHFFFAOYSA-N 0.000 description 1
- PIAYITIFQWFJCD-UHFFFAOYSA-N 4-phenoxypent-1-enyl hypofluorite Chemical compound FOC=CCC(C)OC1=CC=CC=C1 PIAYITIFQWFJCD-UHFFFAOYSA-N 0.000 description 1
- 101150065749 Churc1 gene Proteins 0.000 description 1
- 102100038239 Protein Churchill Human genes 0.000 description 1
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 1
- 239000012986 chain transfer agent Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000000701 coagulant Substances 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US86170106P | 2006-11-29 | 2006-11-29 | |
| US60/861,701 | 2006-11-29 | ||
| US11/977,021 | 2007-10-23 | ||
| US11/977,021 US7521513B2 (en) | 2006-11-29 | 2007-10-23 | Semi-batch process for producing fluoroelastomers |
| PCT/US2007/024495 WO2008066839A1 (en) | 2006-11-29 | 2007-11-28 | Semi-batch process for producing fluoroelastomers |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2010511096A JP2010511096A (ja) | 2010-04-08 |
| JP2010511096A5 true JP2010511096A5 (cg-RX-API-DMAC7.html) | 2011-01-20 |
| JP5144676B2 JP5144676B2 (ja) | 2013-02-13 |
Family
ID=39313231
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2009539303A Active JP5144676B2 (ja) | 2006-11-29 | 2007-11-28 | フルオロエラストマーの半回分式製造方法 |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US7521513B2 (cg-RX-API-DMAC7.html) |
| EP (1) | EP2091978B1 (cg-RX-API-DMAC7.html) |
| JP (1) | JP5144676B2 (cg-RX-API-DMAC7.html) |
| CN (1) | CN101541844B (cg-RX-API-DMAC7.html) |
| AT (1) | ATE502061T1 (cg-RX-API-DMAC7.html) |
| DE (1) | DE602007013276D1 (cg-RX-API-DMAC7.html) |
| WO (1) | WO2008066839A1 (cg-RX-API-DMAC7.html) |
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2611840B1 (en) * | 2010-09-01 | 2019-03-27 | Arkema, Inc. | Method of producing fluoropolymers using acid-functionalized monomers |
| JP6201236B2 (ja) | 2010-11-09 | 2017-09-27 | ザ ケマーズ カンパニー エフシー リミテッド ライアビリティ カンパニー | フルオロモノマーの水性重合における核形成 |
| JP6109073B2 (ja) * | 2010-11-09 | 2017-04-05 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニーＥ．Ｉ．Ｄｕ Ｐｏｎｔ Ｄｅ Ｎｅｍｏｕｒｓ Ａｎｄ Ｃｏｍｐａｎｙ | 炭化水素界面活性剤を用いたフルオロモノマーの水性重合 |
| CN103210003B (zh) | 2010-11-09 | 2016-09-07 | 纳幕尔杜邦公司 | 减弱含烃表面活性剂在含氟单体含水分散体聚合反应中的调聚性能 |
| US9175112B2 (en) * | 2012-05-09 | 2015-11-03 | The Chemours Company Fc, Llc | Drying wet fluoropolymer resin and exposing to oxygen source to reduce discoloration |
| JP6622209B2 (ja) | 2013-11-26 | 2019-12-18 | ザ ケマーズ カンパニー エフシー リミテッド ライアビリティ カンパニー | フルオロモノマーの水性重合において核を形成するためのポリアルキレンオキシドの使用 |
| WO2015134435A1 (en) | 2014-03-06 | 2015-09-11 | 3M Innovative Properties Company | Highly fluorinated elastomers |
| EP3059265B1 (en) | 2015-02-23 | 2020-10-07 | 3M Innovative Properties Company | Peroxide curable fluoropolymers obtainable by polymerization with non-fluorinated emulsifiers |
| JP6987740B2 (ja) | 2015-07-13 | 2022-01-05 | スリーエム イノベイティブ プロパティズ カンパニー | フッ素化ブロックコポリマー |
| JP7071258B2 (ja) * | 2015-09-18 | 2022-05-18 | ソルベイ スペシャルティ ポリマーズ イタリー エス．ピー．エー． | フルオロエラストマー組成物 |
| CN109963887A (zh) | 2016-11-09 | 2019-07-02 | 3M创新有限公司 | 可过氧化物固化的部分氟化聚合物 |
| US11261280B2 (en) | 2017-01-18 | 2022-03-01 | 3M Innovative Properties Company | Fluorinated block copolymers |
| JP2020504225A (ja) | 2017-01-18 | 2020-02-06 | スリーエム イノベイティブ プロパティズ カンパニー | ニトリル硬化部位モノマーから誘導されるフッ素化ブロックコポリマー |
| WO2018136332A1 (en) | 2017-01-18 | 2018-07-26 | 3M Innovative Properties Company | Fluorinated block copolymers derived from cure-site monomers |
| US11999681B2 (en) | 2017-03-31 | 2024-06-04 | Daikin Industries, Ltd. | Alkyl sulfate ester or salt of same |
| CN110461883B (zh) | 2017-03-31 | 2021-11-30 | 大金工业株式会社 | 含氟聚合物的制造方法、聚合用表面活性剂和表面活性剂的使用 |
| EP3604349B1 (en) | 2017-03-31 | 2023-09-13 | Daikin Industries, Ltd. | Production method for fluoropolymer, surfactant for polymerization, and use of surfactant |
| WO2019156175A1 (ja) | 2018-02-08 | 2019-08-15 | ダイキン工業株式会社 | フルオロポリマーの製造方法、重合用界面活性剤、界面活性剤の使用及び組成物 |
| CN116234794A (zh) | 2020-10-01 | 2023-06-06 | 科慕埃弗西有限公司 | 含氟聚合物的水性聚合反应中的低反应性烃分散剂 |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4035565A (en) | 1975-03-27 | 1977-07-12 | E. I. Du Pont De Nemours And Company | Fluoropolymer containing a small amount of bromine-containing olefin units |
| US4130523A (en) | 1977-07-18 | 1978-12-19 | Union Carbide Corporation | High solids latexes |
| US4281092A (en) | 1978-11-30 | 1981-07-28 | E. I. Du Pont De Nemours And Company | Vulcanizable fluorinated copolymers |
| US5216065A (en) | 1990-11-29 | 1993-06-01 | The Mead Corporation | Emulsion polymerization with large particle size |
| US5955556A (en) * | 1995-11-06 | 1999-09-21 | Alliedsignal Inc. | Method of manufacturing fluoropolymers |
| JP3702468B2 (ja) * | 1995-12-20 | 2005-10-05 | イー・アイ・デユポン・ドウ・ヌムール・アンド・カンパニー | パーフルオロ重合体の製造における連鎖移動剤としてのヨードニトリル |
| US5753742A (en) | 1996-07-31 | 1998-05-19 | The B.F.Goodrich Company | High-solids, aqueous, polymeric dispersions |
| FR2757865B1 (fr) | 1996-12-26 | 1999-04-02 | Atochem Elf Sa | Procede de polymerisation ou copolymerisation radicalaire controlee de monomeres (meth)acryliques, vinyliques, vinylideniques et dieniques et (co)polymeres obtenus |
| US6774164B2 (en) * | 2000-09-22 | 2004-08-10 | Dupont Dow Elastomers L.L.C. | Process for producing fluoroelastomers with fluorinated anionic surfactants |
| US6512063B2 (en) | 2000-10-04 | 2003-01-28 | Dupont Dow Elastomers L.L.C. | Process for producing fluoroelastomers |
| JP4125561B2 (ja) * | 2002-08-14 | 2008-07-30 | 三菱レイヨン株式会社 | ポリマー粒子の製造方法及びそれにより得られたポリマー粒子 |
-
2007
- 2007-10-23 US US11/977,021 patent/US7521513B2/en active Active
- 2007-11-28 WO PCT/US2007/024495 patent/WO2008066839A1/en not_active Ceased
- 2007-11-28 CN CN2007800438334A patent/CN101541844B/zh active Active
- 2007-11-28 JP JP2009539303A patent/JP5144676B2/ja active Active
- 2007-11-28 DE DE602007013276T patent/DE602007013276D1/de active Active
- 2007-11-28 AT AT07862286T patent/ATE502061T1/de not_active IP Right Cessation
- 2007-11-28 EP EP07862286A patent/EP2091978B1/en active Active
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