JP2010511036A5 - - Google Patents
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- JP2010511036A5 JP2010511036A5 JP2009538817A JP2009538817A JP2010511036A5 JP 2010511036 A5 JP2010511036 A5 JP 2010511036A5 JP 2009538817 A JP2009538817 A JP 2009538817A JP 2009538817 A JP2009538817 A JP 2009538817A JP 2010511036 A5 JP2010511036 A5 JP 2010511036A5
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- JP
- Japan
- Prior art keywords
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- formula
- atom
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 16
- 239000003446 ligand Substances 0.000 claims description 14
- 229910052799 carbon Inorganic materials 0.000 claims description 13
- 125000004432 carbon atom Chemical group C* 0.000 claims description 13
- 125000003118 aryl group Chemical group 0.000 claims description 11
- 125000003342 alkenyl group Chemical group 0.000 claims description 10
- 229920006395 saturated elastomer Polymers 0.000 claims description 9
- 125000004429 atom Chemical group 0.000 claims description 7
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 6
- UFWIBTONFRDIAS-UHFFFAOYSA-N naphthalene-acid Natural products C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 claims description 6
- 125000004437 phosphorous atom Chemical group 0.000 claims description 6
- 125000003277 amino group Chemical group 0.000 claims description 5
- 125000004122 cyclic group Chemical group 0.000 claims description 5
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 claims description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 4
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 4
- 150000001875 compounds Chemical class 0.000 claims description 3
- 150000002790 naphthalenes Chemical group 0.000 claims description 3
- 229910052698 phosphorus Inorganic materials 0.000 claims description 3
- 125000002924 primary amino group Chemical class [H]N([H])* 0.000 claims description 3
- 125000000008 (C1-C10) alkyl group Chemical group 0.000 claims description 2
- 125000004209 (C1-C8) alkyl group Chemical group 0.000 claims description 2
- 125000000623 heterocyclic group Chemical group 0.000 claims description 2
- 229910052757 nitrogen Inorganic materials 0.000 claims description 2
- 125000004433 nitrogen atom Chemical group N* 0.000 claims description 2
- 125000004430 oxygen atom Chemical group O* 0.000 claims description 2
- 238000000034 method Methods 0.000 claims 12
- 239000003054 catalyst Substances 0.000 claims 4
- 150000001340 alkali metals Chemical class 0.000 claims 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 2
- 229910052783 alkali metal Inorganic materials 0.000 claims 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims 2
- 125000000217 alkyl group Chemical group 0.000 claims 2
- 239000002585 base Substances 0.000 claims 2
- 229910052739 hydrogen Inorganic materials 0.000 claims 2
- 239000001257 hydrogen Substances 0.000 claims 2
- 238000005984 hydrogenation reaction Methods 0.000 claims 2
- 230000007935 neutral effect Effects 0.000 claims 2
- -1 phosphino groups Chemical group 0.000 claims 2
- 239000002243 precursor Substances 0.000 claims 2
- 125000004191 (C1-C6) alkoxy group Chemical group 0.000 claims 1
- 125000006704 (C5-C6) cycloalkyl group Chemical group 0.000 claims 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 1
- 229910000272 alkali metal oxide Inorganic materials 0.000 claims 1
- 229910001860 alkaline earth metal hydroxide Inorganic materials 0.000 claims 1
- 150000001342 alkaline earth metals Chemical class 0.000 claims 1
- 229940059260 amidate Drugs 0.000 claims 1
- 125000003710 aryl alkyl group Chemical group 0.000 claims 1
- 125000002843 carboxylic acid group Chemical group 0.000 claims 1
- 150000002009 diols Chemical class 0.000 claims 1
- 150000002148 esters Chemical group 0.000 claims 1
- NPUKDXXFDDZOKR-LLVKDONJSA-N etomidate Chemical compound CCOC(=O)C1=CN=CN1[C@H](C)C1=CC=CC=C1 NPUKDXXFDDZOKR-LLVKDONJSA-N 0.000 claims 1
- 125000003827 glycol group Chemical group 0.000 claims 1
- 229910052736 halogen Inorganic materials 0.000 claims 1
- 125000005843 halogen group Chemical group 0.000 claims 1
- 150000002367 halogens Chemical class 0.000 claims 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims 1
- 125000000686 lactone group Chemical group 0.000 claims 1
- GKTNLYAAZKKMTQ-UHFFFAOYSA-N n-[bis(dimethylamino)phosphinimyl]-n-methylmethanamine Chemical compound CN(C)P(=N)(N(C)C)N(C)C GKTNLYAAZKKMTQ-UHFFFAOYSA-N 0.000 claims 1
- 125000001624 naphthyl group Chemical group 0.000 claims 1
- 229920001515 polyalkylene glycol Polymers 0.000 claims 1
- 239000000758 substrate Substances 0.000 claims 1
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical group C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 1
- 229910021386 carbon form Inorganic materials 0.000 description 1
- RWRDLPDLKQPQOW-UHFFFAOYSA-N tetrahydropyrrole Substances C1CCNC1 RWRDLPDLKQPQOW-UHFFFAOYSA-N 0.000 description 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IB2006054449 | 2006-11-27 | ||
| IBPCT/IB2006/054449 | 2006-11-27 | ||
| PCT/IB2007/054746 WO2008065588A1 (en) | 2006-11-27 | 2007-11-22 | Hydrogenation of esters with ru/bidentate ligands complexes |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2010511036A JP2010511036A (ja) | 2010-04-08 |
| JP2010511036A5 true JP2010511036A5 (enExample) | 2013-04-25 |
| JP5460328B2 JP5460328B2 (ja) | 2014-04-02 |
Family
ID=39247814
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2009538817A Active JP5460328B2 (ja) | 2006-11-27 | 2007-11-22 | Ｒｕ／二座配位子錯体によるエステルの水素化 |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US8198488B2 (enExample) |
| EP (1) | EP2089345B1 (enExample) |
| JP (1) | JP5460328B2 (enExample) |
| CN (1) | CN101541716B (enExample) |
| AT (1) | ATE458712T1 (enExample) |
| DE (1) | DE602007005027D1 (enExample) |
| ES (1) | ES2339073T3 (enExample) |
| WO (1) | WO2008065588A1 (enExample) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1970360B1 (en) * | 2007-03-16 | 2016-08-31 | Takasago International Corporation | Method for producing alcohols |
| JP5283931B2 (ja) * | 2007-03-16 | 2013-09-04 | 高砂香料工業株式会社 | アルコール類の製造方法 |
| JP5451209B2 (ja) * | 2008-07-08 | 2014-03-26 | 国立大学法人東京工業大学 | エステル類およびラクトン類の実用的な還元方法 |
| JP5477557B2 (ja) | 2008-09-09 | 2014-04-23 | 高砂香料工業株式会社 | エステル又はラクトン類の水素還元によるアルコール類の製造方法 |
| EP2344276A1 (en) * | 2008-10-02 | 2011-07-20 | Firmenich S.A. | Hydrogenation of esters or carbonyl groups with phosphino-oxide based ruthenium complexes |
| CN102227261A (zh) | 2008-11-28 | 2011-10-26 | 弗门尼舍有限公司 | 用具有二胺和磷-氮二齿配体的钌络合物进行的酯、酮或醛基的氢化 |
| KR20110133491A (ko) * | 2009-03-31 | 2011-12-12 | 스미또모 가가꾸 가부시키가이샤 | 알코올 화합물의 제조 방법 및 이의 촉매 |
| CN103261133B (zh) * | 2010-12-21 | 2015-04-15 | 弗门尼舍有限公司 | 使用基于四齿氨基/亚氨基-硫醚的钌络合物对酯或羰基的氢化 |
| WO2013010275A1 (en) | 2011-07-18 | 2013-01-24 | The Governors Of The University Of Alberta | Catalysts and processes for the hydrogenation of amides |
| CN103857468B (zh) * | 2011-10-06 | 2016-04-13 | 弗门尼舍有限公司 | 用ru/双齿配体络合物对醛的选择性氢化 |
| GB201208589D0 (en) * | 2012-05-16 | 2012-06-27 | Givaudan Sa | Improvements in or relating to organic compounds |
| GB202017456D0 (en) * | 2020-11-04 | 2020-12-16 | Johnson Matthey Plc | Process |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1087278C (zh) * | 1996-04-26 | 2002-07-10 | 巴斯福股份公司 | 在原处生成的钌催化剂存在下进行有机化合物反应的方法 |
| JP3720235B2 (ja) * | 2000-03-14 | 2005-11-24 | 高砂香料工業株式会社 | 光学活性ルテニウムホスフィン錯体の製造方法及び該錯体を用いた光学活性アルコールの製造方法 |
| AU2001270892A1 (en) * | 2000-07-24 | 2002-02-05 | Chirotech Technology Limited | Ruthenium complexes and their use in asymmetric hydrogenation |
| JP4919562B2 (ja) * | 2001-09-28 | 2012-04-18 | 日本曹達株式会社 | ルテニウムヒドリド錯体、アルコール化合物の製造方法およびラセミ体カルボニル化合物の分割方法 |
| JP3566955B2 (ja) * | 2001-12-28 | 2004-09-15 | 関東化学株式会社 | 新規ルテニウム錯体およびこれを触媒として用いるアルコール化合物の製造方法 |
| US7378560B2 (en) * | 2004-10-25 | 2008-05-27 | Kanto Kangaku Kabushiki Kaisha | Ruthenium complex and process for producing tert-alkyl alcohol therewith |
| US7989665B2 (en) * | 2005-04-05 | 2011-08-02 | Firmenich Sa | Hydrogenation of esters with Ru/tetradentate ligands complexes |
| WO2006106483A1 (en) | 2005-04-05 | 2006-10-12 | Firmenich Sa | Hydrogenation of esters with ru/bidentate ligands complexes |
| EP1868965B1 (en) * | 2005-04-05 | 2013-08-28 | Firmenich Sa | Hydrogenation of esters with ru/tetradentate ligands complexes |
-
2007
- 2007-11-22 JP JP2009538817A patent/JP5460328B2/ja active Active
- 2007-11-22 EP EP07849220A patent/EP2089345B1/en active Active
- 2007-11-22 ES ES07849220T patent/ES2339073T3/es active Active
- 2007-11-22 WO PCT/IB2007/054746 patent/WO2008065588A1/en not_active Ceased
- 2007-11-22 DE DE602007005027T patent/DE602007005027D1/de active Active
- 2007-11-22 US US12/515,934 patent/US8198488B2/en active Active
- 2007-11-22 CN CN2007800430667A patent/CN101541716B/zh active Active
- 2007-11-22 AT AT07849220T patent/ATE458712T1/de not_active IP Right Cessation
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