JP2010509446A - コア−シェルゴムを有するベンゾキサジン組成物 - Google Patents
コア−シェルゴムを有するベンゾキサジン組成物 Download PDFInfo
- Publication number
- JP2010509446A JP2010509446A JP2009536340A JP2009536340A JP2010509446A JP 2010509446 A JP2010509446 A JP 2010509446A JP 2009536340 A JP2009536340 A JP 2009536340A JP 2009536340 A JP2009536340 A JP 2009536340A JP 2010509446 A JP2010509446 A JP 2010509446A
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- Prior art keywords
- glass
- thermosetting composition
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- core
- group
- Prior art date
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- 229920001971 elastomer Polymers 0.000 title claims abstract description 60
- 239000005060 rubber Substances 0.000 title claims abstract description 58
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- CMLFRMDBDNHMRA-UHFFFAOYSA-N 2h-1,2-benzoxazine Chemical compound C1=CC=C2C=CNOC2=C1 CMLFRMDBDNHMRA-UHFFFAOYSA-N 0.000 title claims abstract description 38
- 229920001187 thermosetting polymer Polymers 0.000 claims abstract description 49
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- 125000003342 alkenyl group Chemical group 0.000 claims description 8
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- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical compound C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 claims description 8
- KZTYYGOKRVBIMI-UHFFFAOYSA-N diphenyl sulfone Chemical compound C=1C=CC=CC=1S(=O)(=O)C1=CC=CC=C1 KZTYYGOKRVBIMI-UHFFFAOYSA-N 0.000 claims description 8
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 8
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 8
- 239000000377 silicon dioxide Substances 0.000 claims description 8
- 229910052717 sulfur Inorganic materials 0.000 claims description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 6
- 229910052799 carbon Inorganic materials 0.000 claims description 6
- 239000004696 Poly ether ether ketone Substances 0.000 claims description 5
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- 125000003118 aryl group Chemical group 0.000 claims description 5
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- 229910010271 silicon carbide Inorganic materials 0.000 claims description 5
- ICXAPFWGVRTEKV-UHFFFAOYSA-N 2-[4-(1,3-benzoxazol-2-yl)phenyl]-1,3-benzoxazole Chemical compound C1=CC=C2OC(C3=CC=C(C=C3)C=3OC4=CC=CC=C4N=3)=NC2=C1 ICXAPFWGVRTEKV-UHFFFAOYSA-N 0.000 claims description 4
- JJHHIJFTHRNPIK-UHFFFAOYSA-N Diphenyl sulfoxide Chemical compound C=1C=CC=CC=1S(=O)C1=CC=CC=C1 JJHHIJFTHRNPIK-UHFFFAOYSA-N 0.000 claims description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 4
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- 235000010290 biphenyl Nutrition 0.000 claims description 4
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 claims description 4
- LTYMSROWYAPPGB-UHFFFAOYSA-N diphenyl sulfide Chemical compound C=1C=CC=CC=1SC1=CC=CC=C1 LTYMSROWYAPPGB-UHFFFAOYSA-N 0.000 claims description 4
- CZZYITDELCSZES-UHFFFAOYSA-N diphenylmethane Chemical compound C=1C=CC=CC=1CC1=CC=CC=C1 CZZYITDELCSZES-UHFFFAOYSA-N 0.000 claims description 4
- 239000000945 filler Substances 0.000 claims description 4
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- 150000003573 thiols Chemical class 0.000 claims description 4
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 3
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- 239000004744 fabric Substances 0.000 claims description 3
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- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims description 3
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- PXKLMJQFEQBVLD-UHFFFAOYSA-N bisphenol F Chemical compound C1=CC(O)=CC=C1CC1=CC=C(O)C=C1 PXKLMJQFEQBVLD-UHFFFAOYSA-N 0.000 description 6
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- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 4
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- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 4
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- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 3
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/24—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
- C08J5/241—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using inorganic fibres
- C08J5/242—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using inorganic fibres using metal fibres
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/24—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
- C08J5/241—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using inorganic fibres
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/24—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
- C08J5/241—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using inorganic fibres
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- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/24—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
- C08J5/241—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using inorganic fibres
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- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
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- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
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- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
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Abstract
Description
(a)
(b)コア−シェルゴムを用意するステップ;および
(c)前記ベンゾキサジンと前記コア−シェルゴムとを、前記熱硬化性組成物を製造するのに適切な条件下で混合するステップ、
を含む。
Claims (34)
- (a)
(b)コア−シェルゴム
を含む熱硬化性組成物。 - 前記コア−シェルゴムが、ナノサイズのコア−シェル構造を有し、前記コアが主としてポリブタジエン/スチレンブレンドであるゴム粒子を含む、請求項1に記載の熱硬化性組成物。
- さらに、無機充填材成分を含む、請求項1に記載の熱硬化性組成物。
- 前記無機充填材成分がシリカナノ粒子を含む、請求項6に記載の熱硬化性組成物。
- 請求項1に記載の熱硬化性組成物が注入された繊維層を含む、プリプレグ。
- 前記繊維層が一方向繊維および繊維織物からなる群より選択されるものから製造される、請求項8に記載のプリプレグ。
- 前記繊維が、炭素、ガラス、アラミド、ボロン、ポリアルキレン、石英、ポリベンズイミダゾール、ポリエーテルエーテルケトン、ポリフェニレンスルフィド、ポリp−フェニレンベンゾビスオキサゾール、シリコンカーバイド、フェノールホルムアルデヒド、フタル酸およびナフテノエートからなる群より選択される、請求項8に記載のプリプレグ。
- 前記ガラスが、Sガラス、S2ガラス、Eガラス、Rガラス、Aガラス、ARガラス、Cガラス、Dガラス、ECRガラス、ガラスフィラメント、ステープルガラス、Tガラスおよびジルコニウムオキシドガラスからなる群より選択される、請求項10に記載のプリプレグ。
- 請求項8に記載のプリプレグの硬化反応生成物。
- プリプレグを製造する方法であって、以下のステップ、
(a)繊維層を用意するステップ;
(b)請求項1に記載の熱硬化性組成物を用意するステップ;および
(c)前記熱硬化性組成物と前記繊維層を合わせてプリプレグ組立品を形成し、前記繊維層に前記熱硬化性組成物を注入するのに十分に高い温度と圧力条件に、前記得られたプリプレグ組立品を置いてプリプレグを形成するステップ、
を含む方法。 - プリプレグを製造するための方法であって、以下のステップ、
(a)繊維層を用意するステップ;
(b)請求項1に記載の熱硬化性組成物を液体形態で用意するステップ;
(c)前記繊維層を前記液体の熱硬化性組成物の中を通過させて前記繊維層に前記熱硬化性組成物を注入するステップ;および
(d)過剰の前記熱硬化性組成物を前記プリプレグ組立品から除去するステップ、
を含む方法。 - 請求項13に記載の方法により製造されたプリプレグ。
- 請求項14に記載の方法により製造されたプリプレグ。
- 請求項15に記載のプリプレグの硬化反応生成物。
- 請求項16に記載のプリプレグの硬化反応生成物。
- (a)請求項1に記載の熱硬化性組成物が注入された繊維束を含む、トウプレグ。
- 前記繊維が、炭素、ガラス、アラミド、ボロン、ポリアルキレン、石英、ポリベンズイミダゾール、ポリエーテルエーテルケトン、ポリフェニレンスルフィド、ポリp−フェニレンベンゾビスオキサゾール、シリコンカーバイド、フェノールホルムアルデヒド、フタル酸およびナフテノエートからなる群より選択される、請求項19に記載のトウプレグ。
- 前記ガラスが、S2ガラス、Eガラス、Rガラス、Aガラス、ARガラス、Cガラス、Dガラス、ECRガラス、ガラスフィラメント、ステープルガラス、Tガラスおよびジルコニウムオキシドガラスからなる群より選択される、請求項20に記載のトウプレグ。
- 請求項19に記載のトウプレグの硬化反応生成物。
- トウプレグを製造する方法であって、以下のステップ、
(a)繊維束を用意するステップ;
(b)請求項1に記載の熱硬化性組成物を用意するステップ;および
(c)前記熱硬化性組成物と前記繊維束とを合わせてトウプレグ組立品形成し、前記繊維束に前記熱硬化性組成物を含浸させるのに十分に高い温度と圧力条件に、前記得られたトウプレグ組立品を置いてトウプレグを形成するステップ、
を含む方法。 - トウプレグを製造する方法であって、以下のステップ、
(a)繊維束を用意するステップ;
(b)請求項1に記載の熱硬化性組成物を液体形態で用意するステップ;
(c)前記繊維束を前記液体の熱硬化性組成物の中を通過させて前記繊維束に前記熱硬化性組成物を含浸させるステップ;および
(d)過剰の前記熱硬化性組成物を前記トウプレグ組立品から除去することでトウプレグを形成するステップ、を含む方法。 - 請求項23に記載の方法により製造されたトウプレグ。
- 請求項24に記載の方法により製造されたトウプレグ。
- 請求項25に記載のトウプレグの硬化反応生成物。
- 請求項26に記載のトウプレグの硬化反応生成物。
- 請求項1に記載の熱硬化性組成物を含む接着剤組成物。
- さらに、1種以上の接着促進剤、難燃剤、充填材、熱可塑性添加物、反応性または非反応性希釈剤、およびチキソトロープ剤を含む、請求項29に記載の接着剤組成物。
- 請求項30に記載の接着剤組成物の硬化反応生成物。
- 請求項1に記載の熱硬化性組成物を含む接着剤フィルム。
- さらに、ナイロン、ガラス、炭素、ポリエステル、ポリアルキレン、石英、ポリベンズイミダゾール、ポリエーテルエーテルケトン、ポリフェニレンスルフィド、ポリp−フェニレンベンゾビスオキサゾール、シリコンカーバイド、フェノールホルムアルデヒド、フタル酸およびナフテノエートからなる群より選択される支持体を含む、請求項32に記載の接着剤フィルム。
- 請求項32に記載の接着剤フィルムの硬化反応生成物。
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US86546206P | 2006-11-13 | 2006-11-13 | |
US60/865,462 | 2006-11-13 | ||
PCT/US2007/023859 WO2008060545A1 (en) | 2006-11-13 | 2007-11-13 | Benzoxazine compositions with core shell rubbers |
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JP (1) | JP5409373B2 (ja) |
CN (1) | CN101578332B (ja) |
BR (1) | BRPI0721497B1 (ja) |
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JP2013508486A (ja) * | 2009-10-22 | 2013-03-07 | ヘンケル・アクチェンゲゼルシャフト・ウント・コムパニー・コマンディットゲゼルシャフト・アウフ・アクチェン | ベンゾオキサジン化合物および熱活性化触媒としての環状構造を有するスルホン酸エステルを含有する硬化性組成物 |
WO2013046452A1 (ja) * | 2011-09-30 | 2013-04-04 | 富士重工業株式会社 | 繊維強化樹脂複合材及びその製造方法 |
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KR102478108B1 (ko) | 2015-06-12 | 2022-12-15 | 사이텍 인더스트리스 인코포레이티드 | 벤족사진 에폭시 블렌드를 함유하는 경화성 조성물 및 이의 용도 |
Also Published As
Publication number | Publication date |
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CA2669040C (en) | 2014-10-07 |
WO2008060545A1 (en) | 2008-05-22 |
CN101578332B (zh) | 2014-04-16 |
CA2669040A1 (en) | 2008-05-22 |
EP2081988B1 (en) | 2017-01-04 |
ES2621154T3 (es) | 2017-07-03 |
BRPI0721497A2 (pt) | 2014-02-11 |
EP2081988A1 (en) | 2009-07-29 |
BRPI0721497B1 (pt) | 2018-10-30 |
EP2081988A4 (en) | 2014-12-17 |
JP5409373B2 (ja) | 2014-02-05 |
CN101578332A (zh) | 2009-11-11 |
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