JP2010138062A - 水素ガスの生成方法 - Google Patents
水素ガスの生成方法 Download PDFInfo
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- JP2010138062A JP2010138062A JP2009253864A JP2009253864A JP2010138062A JP 2010138062 A JP2010138062 A JP 2010138062A JP 2009253864 A JP2009253864 A JP 2009253864A JP 2009253864 A JP2009253864 A JP 2009253864A JP 2010138062 A JP2010138062 A JP 2010138062A
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/06—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
- C01B3/065—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents from a hydride
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/06—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Combustion & Propulsion (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Sustainable Development (AREA)
- Sustainable Energy (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Fuel Cell (AREA)
- Catalysts (AREA)
Abstract
【解決手段】遷移金属触媒の存在下で、水素化ホウ素化合物および塩基を含む固体組成物と水と一緒にすることによる、低減された発泡の水素生成方法。
【選択図】なし
Description
Claims (10)
- 5重量%〜40重量%の少なくとも1種の塩基および60重量%〜95重量%の少なくとも1種の水素化ホウ素化合物を含む固体組成物に、水を含む液体を添加することを含み;
前記固体組成物および前記液体の少なくとも一方が、少なくとも1種の第8、9および10族からの遷移金属塩を含み;前記液体が5重量%未満しか酸を含まない;
水素の生成方法。 - 前記少なくとも1種の水素化ホウ素化合物が少なくとも1種の水素化ホウ素アルカリ金属であり、かつ前記少なくとも1種の塩基が水酸化ナトリウム、水酸化リチウム、水酸化カリウム、ナトリウムメトキシド、カリウムメトキシド、またはこれらの組み合わせである、請求項1に記載の方法。
- 固体組成物が5重量%〜25重量%の前記少なくとも1種の塩基、70重量%〜85重量%の前記少なくとも1種の水素化ホウ素化合物、および2重量%〜15重量%の前記少なくとも1種の第8、9および10族からの遷移金属塩を含む、請求項2に記載の方法。
- 前記少なくとも1種の水素化ホウ素アルカリ金属が水素化ホウ素ナトリウム、水素化ホウ素カリウムまたはこれらの組み合わせである、請求項3に記載の方法。
- 液体が2重量%以下の前記少なくとも1種の第8、9および10族からの遷移金属塩を含む、請求項4に記載の方法。
- 固体組成物が、6重量%〜22重量%の前記少なくとも1種の塩基、70重量%〜85重量%の前記少なくとも1種の水素化ホウ素化合物、および4重量%〜14重量%の前記少なくとも1種の第8、9および10族からの遷移金属塩を含み;液体が0.5重量%以下の前記少なくとも1種の第8、9および10族からの遷移金属塩を含む、請求項5に記載の方法。
- 固体組成物が、8重量%〜30重量%の前記少なくとも1種の塩基、70重量%〜92重量%の前記少なくとも1種の水素化ホウ素化合物を含む、請求項2に記載の方法。
- 前記少なくとも1種の第8、9および10族からの遷移金属塩が3重量%〜15重量%の量で液体中に存在する、請求項7に記載の方法。
- 前記少なくとも1種の水素化ホウ素アルカリ金属が水素化ホウ素ナトリウム、水素化ホウ素カリウムまたはこれらの組み合わせである、請求項8に記載の方法。
- 固体組成物が、0.5重量%以下の前記少なくとも1種の第8、9および10族からの遷移金属塩を含み;液体が1重量%未満しか酸を含まず;液体が5重量%〜15重量%の量で前記少なくとも1種の遷移金属塩を含む、請求項9に記載の方法。
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US20139008P | 2008-12-10 | 2008-12-10 | |
US61/201,390 | 2008-12-10 |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2010138062A true JP2010138062A (ja) | 2010-06-24 |
JP5150604B2 JP5150604B2 (ja) | 2013-02-20 |
Family
ID=41786345
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2009253864A Expired - Fee Related JP5150604B2 (ja) | 2008-12-10 | 2009-11-05 | 水素ガスの生成方法 |
Country Status (6)
Country | Link |
---|---|
US (1) | US20100143240A1 (ja) |
EP (1) | EP2196433A1 (ja) |
JP (1) | JP5150604B2 (ja) |
KR (1) | KR101132678B1 (ja) |
CN (1) | CN101746722A (ja) |
CA (1) | CA2684857C (ja) |
Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR101386238B1 (ko) * | 2010-07-22 | 2014-04-17 | 한국전자통신연구원 | 배열 안테나를 이용한 도래각 측정 장치, 이를 이용한 무선 통신 rf 수신단 및 도래각 측정 방법 |
RU2473460C2 (ru) * | 2011-04-26 | 2013-01-27 | Федеральное государственное образовательное учреждение высшего профессионального образования "Национальный исследовательский ядерный университет "МИФИ" (НИЯУ МИФИ) | Гидрореакционная композиция для получения водорода химическим разложением минерализованной и сточной воды |
WO2013052093A1 (en) * | 2011-10-03 | 2013-04-11 | David Randolph Smith | Method and apparatus to increase recovery of hydrocarbons |
GB2507466B (en) * | 2012-07-16 | 2015-04-08 | Prometheus Wireless Ltd | Fuel cell apparatus |
WO2014014649A1 (en) | 2012-07-17 | 2014-01-23 | Rohm And Haas Company | Method for generation of hydrogen gas |
US20140154171A1 (en) | 2012-12-04 | 2014-06-05 | Eveready Battery Company, Inc. | Hydrogen Generation from Stabilized Alane |
WO2016016720A1 (en) * | 2014-07-29 | 2016-02-04 | Intelligent Energy Limited | Performance balancing elastomeric hydrogen reactor |
BR112017012854B1 (pt) * | 2014-12-15 | 2022-07-26 | Hidrogas Ltda | Processo para obtenção de hidrogênio e composto iônico alcalino não corrosivo, solução eletrolítica alcalina, composto iônico alcalino não corrosivo, e uso do composto iônico alcalino não corrosivo |
NL2016374B1 (en) | 2015-11-06 | 2017-05-29 | H2Fuel Cascade B V | Method for Producing Metal borohydride and Molecular Hydrogen. |
NL2016379B1 (en) * | 2015-11-06 | 2017-05-29 | H2Fuel-Systems B V | Method and Apparatus for Obtaining a Mixture for Producing H2, Corresponding Mixture, and Method and Apparatus for Producing H2. |
EA039795B1 (ru) * | 2016-03-07 | 2022-03-15 | Эйч2ФЬЮЭЛ-СИСТЕМЗ Б.В. | Способ получения смеси для получения н2 и соответствующая смесь для получения н2 |
CN108862192A (zh) * | 2018-09-06 | 2018-11-23 | 四川大学 | 一种用于水解制氢的复合制氢剂以及利用其制备氢气的方法 |
Citations (9)
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JP2004002115A (ja) * | 2002-05-31 | 2004-01-08 | Seijiro Suda | 水素ガス発生方法 |
US20050238573A1 (en) * | 2004-04-14 | 2005-10-27 | Qinglin Zhang | Systems and methods for hydrogen generation from solid hydrides |
JP2006056753A (ja) * | 2004-08-20 | 2006-03-02 | Materials & Energy Research Institute Tokyo Ltd | 水素発生方法、水素発生装置及び燃料電池システム |
JP2007502248A (ja) * | 2003-08-14 | 2007-02-08 | ザ ジレット カンパニー | 水素発生器 |
WO2007044452A1 (en) * | 2005-10-06 | 2007-04-19 | Millennium Cell, Inc. | Solid fuel packging system and method of hydrogen generation |
JP2007525400A (ja) * | 2004-02-26 | 2007-09-06 | ゼネラル・モーターズ・コーポレーション | 水素貯蔵系材料および水素化物と水酸化物を含む方法 |
JP2007238431A (ja) * | 2006-02-16 | 2007-09-20 | Rohm & Haas Co | 水素化ホウ素からの水素ガスの発生方法 |
CA2631097A1 (en) * | 2007-06-05 | 2008-12-05 | Rohm And Haas Company | Composition for hydrogen generation |
US20090324452A1 (en) * | 2003-05-14 | 2009-12-31 | Carlos Salinas | Hydrogen generator |
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US4358753A (en) * | 1981-03-16 | 1982-11-09 | Rockwell International Corporation | High resolution shaft position encoder |
EP0841538B1 (en) * | 1996-05-24 | 2003-02-19 | Seiko Epson Corporation | Position detector, encoder board, position detecting method, timer and electronic device |
JP3328518B2 (ja) * | 1996-11-06 | 2002-09-24 | セイコークロック株式会社 | 時計機械体 |
TW558677B (en) * | 2002-08-02 | 2003-10-21 | Chih-Hao Yiu | Device for detecting angular position |
US20060269470A1 (en) * | 2004-04-14 | 2006-11-30 | Qinglin Zhang | Methods and devices for hydrogen generation from solid hydrides |
US20060196112A1 (en) * | 2005-03-02 | 2006-09-07 | Grant Berry | Borohydride fuel compositions and methods |
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2009
- 2009-11-05 JP JP2009253864A patent/JP5150604B2/ja not_active Expired - Fee Related
- 2009-11-09 CA CA2684857A patent/CA2684857C/en not_active Expired - Fee Related
- 2009-11-17 EP EP09176249A patent/EP2196433A1/en not_active Ceased
- 2009-11-25 KR KR1020090114364A patent/KR101132678B1/ko not_active IP Right Cessation
- 2009-12-03 US US12/592,824 patent/US20100143240A1/en not_active Abandoned
- 2009-12-09 CN CN200910258540A patent/CN101746722A/zh active Pending
Patent Citations (10)
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JP2004002115A (ja) * | 2002-05-31 | 2004-01-08 | Seijiro Suda | 水素ガス発生方法 |
US20090324452A1 (en) * | 2003-05-14 | 2009-12-31 | Carlos Salinas | Hydrogen generator |
JP2007502248A (ja) * | 2003-08-14 | 2007-02-08 | ザ ジレット カンパニー | 水素発生器 |
JP2007525400A (ja) * | 2004-02-26 | 2007-09-06 | ゼネラル・モーターズ・コーポレーション | 水素貯蔵系材料および水素化物と水酸化物を含む方法 |
US20050238573A1 (en) * | 2004-04-14 | 2005-10-27 | Qinglin Zhang | Systems and methods for hydrogen generation from solid hydrides |
WO2005102914A2 (en) * | 2004-04-14 | 2005-11-03 | Millennium, Cell, Inc. | Systems and methods for hydrogen generation from solid hydrides |
JP2006056753A (ja) * | 2004-08-20 | 2006-03-02 | Materials & Energy Research Institute Tokyo Ltd | 水素発生方法、水素発生装置及び燃料電池システム |
WO2007044452A1 (en) * | 2005-10-06 | 2007-04-19 | Millennium Cell, Inc. | Solid fuel packging system and method of hydrogen generation |
JP2007238431A (ja) * | 2006-02-16 | 2007-09-20 | Rohm & Haas Co | 水素化ホウ素からの水素ガスの発生方法 |
CA2631097A1 (en) * | 2007-06-05 | 2008-12-05 | Rohm And Haas Company | Composition for hydrogen generation |
Non-Patent Citations (1)
Title |
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JPN6012040467; H.I. SCHLESINGER et al.: Journal of the American Chemical Society 5 January 1953, Vol.75, pp.215-219 * |
Also Published As
Publication number | Publication date |
---|---|
JP5150604B2 (ja) | 2013-02-20 |
CA2684857A1 (en) | 2010-06-10 |
CA2684857C (en) | 2012-10-30 |
EP2196433A1 (en) | 2010-06-16 |
KR101132678B1 (ko) | 2012-04-03 |
US20100143240A1 (en) | 2010-06-10 |
CN101746722A (zh) | 2010-06-23 |
KR20100067042A (ko) | 2010-06-18 |
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