JP2009522413A - ホットメルト接着剤組成物 - Google Patents
ホットメルト接着剤組成物 Download PDFInfo
- Publication number
- JP2009522413A JP2009522413A JP2008548686A JP2008548686A JP2009522413A JP 2009522413 A JP2009522413 A JP 2009522413A JP 2008548686 A JP2008548686 A JP 2008548686A JP 2008548686 A JP2008548686 A JP 2008548686A JP 2009522413 A JP2009522413 A JP 2009522413A
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- JP
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- Prior art keywords
- ethylene
- weight
- copolymer
- hot melt
- composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
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- 239000004831 Hot glue Substances 0.000 title claims abstract description 68
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- 239000005977 Ethylene Substances 0.000 claims abstract description 96
- 229920001577 copolymer Polymers 0.000 claims abstract description 91
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 54
- 238000000034 method Methods 0.000 claims abstract description 31
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims abstract description 25
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims abstract description 22
- 239000002253 acid Substances 0.000 claims abstract description 19
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- 229920001897 terpolymer Polymers 0.000 claims abstract description 18
- 229910002091 carbon monoxide Inorganic materials 0.000 claims abstract description 17
- 239000000178 monomer Substances 0.000 claims abstract description 17
- 229920001038 ethylene copolymer Polymers 0.000 claims abstract description 16
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims abstract description 15
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims abstract description 13
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 claims abstract description 12
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- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 claims abstract description 6
- OFNISBHGPNMTMS-UHFFFAOYSA-N 3-methylideneoxolane-2,5-dione Chemical compound C=C1CC(=O)OC1=O OFNISBHGPNMTMS-UHFFFAOYSA-N 0.000 claims abstract description 6
- IFDVQVHZEKPUSC-UHFFFAOYSA-N cyclohex-3-ene-1,2-dicarboxylic acid Chemical compound OC(=O)C1CCC=CC1C(O)=O IFDVQVHZEKPUSC-UHFFFAOYSA-N 0.000 claims abstract description 6
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- AYKYXWQEBUNJCN-UHFFFAOYSA-N 3-methylfuran-2,5-dione Chemical compound CC1=CC(=O)OC1=O AYKYXWQEBUNJCN-UHFFFAOYSA-N 0.000 claims abstract description 4
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- XLYMOEINVGRTEX-UHFFFAOYSA-N fumaric acid monoethyl ester Natural products CCOC(=O)C=CC(O)=O XLYMOEINVGRTEX-UHFFFAOYSA-N 0.000 claims description 4
- 239000011087 paperboard Substances 0.000 claims description 4
- 239000002759 woven fabric Substances 0.000 claims description 4
- XLYMOEINVGRTEX-ARJAWSKDSA-N Ethyl hydrogen fumarate Chemical compound CCOC(=O)\C=C/C(O)=O XLYMOEINVGRTEX-ARJAWSKDSA-N 0.000 claims description 3
- 239000006057 Non-nutritive feed additive Substances 0.000 claims description 3
- 150000001412 amines Chemical class 0.000 claims description 3
- 239000002216 antistatic agent Substances 0.000 claims description 3
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- 239000000975 dye Substances 0.000 claims description 3
- 239000003063 flame retardant Substances 0.000 claims description 3
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- 238000005304 joining Methods 0.000 claims description 2
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- 239000012779 reinforcing material Substances 0.000 claims description 2
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 43
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 39
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 39
- 239000001993 wax Substances 0.000 description 37
- -1 alkyl methacrylate Chemical compound 0.000 description 23
- 239000000047 product Substances 0.000 description 18
- 238000002844 melting Methods 0.000 description 14
- 230000008018 melting Effects 0.000 description 14
- 239000002131 composite material Substances 0.000 description 11
- 239000003784 tall oil Substances 0.000 description 11
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 10
- 239000005038 ethylene vinyl acetate Substances 0.000 description 10
- 239000012188 paraffin wax Substances 0.000 description 10
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 10
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical group CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 9
- 239000011888 foil Substances 0.000 description 9
- 229920000139 polyethylene terephthalate Polymers 0.000 description 9
- 239000005020 polyethylene terephthalate Substances 0.000 description 9
- 229920002292 Nylon 6 Polymers 0.000 description 8
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 8
- 238000004806 packaging method and process Methods 0.000 description 8
- 235000019809 paraffin wax Nutrition 0.000 description 8
- 235000019271 petrolatum Nutrition 0.000 description 8
- 238000009472 formulation Methods 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 7
- 150000002989 phenols Chemical class 0.000 description 7
- 239000000126 substance Substances 0.000 description 7
- 125000004432 carbon atom Chemical group C* 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
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- 239000004744 fabric Substances 0.000 description 6
- 125000000524 functional group Chemical group 0.000 description 6
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 6
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 6
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- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 5
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- 239000000376 reactant Substances 0.000 description 5
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- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 4
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- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
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- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
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- RSWGJHLUYNHPMX-ONCXSQPRSA-N abietic acid Chemical compound C([C@@H]12)CC(C(C)C)=CC1=CC[C@@H]1[C@]2(C)CCC[C@@]1(C)C(O)=O RSWGJHLUYNHPMX-ONCXSQPRSA-N 0.000 description 3
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- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 3
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J123/00—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
- C09J123/02—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
- C09J123/04—Homopolymers or copolymers of ethene
- C09J123/08—Copolymers of ethene
- C09J123/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
- C09J123/0853—Vinylacetate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J123/00—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
- C09J123/02—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
- C09J123/04—Homopolymers or copolymers of ethene
- C09J123/08—Copolymers of ethene
- C09J123/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
- C09J123/0869—Acids or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
- C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
- C08L2666/04—Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof
- C08L2666/06—Homopolymers or copolymers of unsaturated hydrocarbons; Derivatives thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
Description
(a)(a)と(b)との合わせた総量の約5〜約95重量%の量で存在する、エチレンと、無水マレイン酸、無水シトラコン酸、無水イタコン酸、無水テトラヒドロフタル酸、マレイン酸、シトラコン酸、イタコン酸、フマル酸、テトラヒドロフタル酸、これらの酸の対応する塩、モノエステルおよびジエステル、ならびにこれらの任意の混合物から選択されたコモノマーとの共重合から得られた機能性コポリマーと、
(b)エチレンと極性モノマーとの共重合から得られた少なくとも1つのエチレンコポリマーであって、前記極性コモノマーが8〜40重量%の量でコポリマー中に存在し、(a)と(b)との合わせた総量の約5〜約95重量%の量で、エチレン/酢酸ビニルコポリマー、エチレン/アルキル(メタ)アクリレートコポリマーおよびエチレン/アルキル(メタ)アクリレート/一酸化炭素ターポリマーからなる群から選択される前記エチレンコポリマーとを含み、100グラム/10分以上、好ましくは150グラム/10分以上のメルトインデックスを有する
ホットメルト接着剤組成物を提供する。
(1)約50重量%〜約90重量%の
(a)(a)と(b)との合わせた総量の約5〜約95重量%の量で存在する、エチレンと、無水マレイン酸、無水シトラコン酸、無水イタコン酸、無水テトラヒドロフタル酸、マレイン酸、シトラコン酸、イタコン酸、フマル酸、テトラヒドロフタル酸、これらの酸の対応する塩、モノエステルおよびジエステル、ならびにこれらの任意の混合物から選択されたコモノマーとの共重合から得られた機能性コポリマーと、
(b)エチレンと極性モノマーとの共重合から得られた少なくとも1つのエチレンコポリマーであって、前記極性コモノマーが8〜40重量%の量でコポリマー中に存在し、かつ、(a)と(b)との合わせた総量の約5〜約95重量%の量で、エチレン/酢酸ビニルコポリマー、エチレン/アルキル(メタ)アクリレートコポリマーおよびエチレン/アルキル(メタ)アクリレート/一酸化炭素ターポリマーからなる群から選択される前記エチレンコポリマーと
の組み合わせ、ならびに
(2)組成物の総重量を基準として、約10〜約50重量%の
(c)全組成物の重量を基準として、0〜約50重量%のワックス、
(d)全組成物の重量を基準として、0〜約50重量%の粘着付与剤、および
(e)全組成物の重量を基準として、0〜約15重量%の可塑剤、安定剤、酸化防止剤、紫外線吸収剤、帯電防止剤、染料、顔料、着色剤、無機充填剤、難燃剤、滑剤、強化材、加工助剤、スリップ剤、粘着防止剤、剥離剤およびそれらの混合物からなる群から選択された他の添加剤
を含む。好ましくは(a)、(b)、(c)、(d)および(e)の合計は、ホットメルト接着剤組成物の約100重量%である。
ホットメルト接着剤組成物は、第1成分として(a)エチレンと無水マレイン酸または別の極性の反応性官能基との共重合から得られた機能性コポリマーを含む。本明細書で用いるところでは、用語「機能性コポリマー」は、極性の反応性官能基を有するコモノマー、例えば、無水マレイン酸を含有するコポリマーに対する簡単な表記法として用いられる。いかなる特定の理論によって制限されることなく、反応性官能基は、組成物の他の成分とおよび/または基材と化学相互作用して化学関連部位を形成する。例えば、それらは求核試薬と反応して共有結合を形成してもよく、またはそれらはイオン結合を形成してもよい。無水マレイン酸または他の極性の反応性官能基は、基材への組成物の接着性を高める反応機能性を提供する。他の極性の反応性官能基には、無水シトラコン酸、無水イタコン酸、および無水テトラヒドロフタル酸が含まれる。それらにはまた、マレイン酸、シトラコン酸、イタコン酸、フマル酸、テトラヒドロフタル酸、およびこれらの酸の対応する塩、モノエステルまたはジエステルが含まれる。
本ホットメルト接着剤組成物は、第2成分として(b)エチレンと極性モノマーとの共重合から得られる少なくとも1つのエチレンコポリマー(極性エチレンコポリマー)を含む。エチレンとの共重合に好適な極性モノマーには、酢酸ビニル、アルキル(メタ)アクリレートおよび一酸化炭素(CO)コモノマーが含まれる。かかるコポリマーには、エチレン/酢酸ビニルコポリマー(EVA)およびエチレン/アルキル(メタ)アクリレート/COコポリマーを含む、エチレン/アルキル(メタ)アクリレートコポリマーおよび/またはこれらの任意の混合物が含まれる。それぞれが異なる重量%で同じ極性コモノマーを有する2つ以上の極性エチレンコポリマーの組み合わせが使用されてもよい。異なる極性コモノマーの2つ以上の極性エチレンコポリマーの組み合わせもまた使用されてもよい。
本ホットメルト接着剤組成物は、少なくとも1つのエチレン/酢酸ビニルコポリマー(EVAコポリマー)を含むことができる。用語「エチレン/酢酸ビニルダイポリマー」には、エチレンと酢酸ビニルとの共重合から誘導されるコポリマーが含まれる。
本ホットメルト接着剤組成物は、少なくとも1つのエチレン/アルキル(メタ)アクリレートコポリマーを含んでもよい。用語「エチレン/アルキル(メタ)アクリレートコポリマー」には、エチレンと、アルキル部分が1〜8個の炭素原子を含有するアルキル(メタ)アクリレートとのコポリマーが含まれる。
本ホットメルト接着剤組成物は、アルキル部分が1〜8個の炭素原子を含有するエチレン/アルキル(メタ)アクリレート/一酸化炭素ターポリマーを含んでもよい。
ワックスは場合により、ホットメルト組成物の特性を改質するために使用することができる。ワックスは接着剤の全体粘度を下げ、それによってそれが容易に液化することを可能にする。ワックスはまた、システムの開放時間、硬化速度および熱安定性を調節するかもしれない。ワックスは、存在するとき、好ましくは接着剤組成物の総重量の少なくとも約0.1重量%、少なくとも約2重量%、または少なくとも約5重量%の限られた量で含まれる。また好ましくは、ワックスは、接着剤組成物の総重量を基準として、約10重量%、20重量%、25重量%、30重量%、35重量%、40重量%、または50重量%以下の限られた量で存在する。
場合により、粘着付与剤は、差別化基材への初期接着性を高めるために主として使用されてもよい。粘着性は、加熱された接着剤が硬化する前に物品の適切な接合を可能にするためのホットメルト接着剤組成物において有用である。粘着付与剤は、接着剤におよびまたより低い粘度のものに粘着性を与えるために加えられる。粘着付与剤は、組成物が塗布中の湿潤を改善することによってより接着性であることを可能にする。粘着付与剤の存在は、変形への抵抗性を低くし、それ故に接触時の結合形成を容易にする。
接着剤組成物は、ポリマー技術で普通に使用され、よく知られている少量の任意の物質をさらに含むことができる。かかる任意の添加剤(上記の成分(e))には、可塑剤、粘度安定剤および加水分解安定剤を含む安定剤、一次および二次酸化防止剤、紫外線吸収剤、帯電防止剤、染料、顔料もしくは他の着色剤、無機充填剤、難燃剤、滑剤、ガラス繊維およびフレークなどの強化材、加工助剤、スリップ剤、シリカもしくはタルクなどの粘着防止剤、剥離剤および/またはそれらの混合物が含まれる。これらの添加剤はカーク−オスマー化学技術百科事典(Kirk Othmer Encyclopedia of Chemical Technology)に記載されている。
ナイロン6は、商品名ウルトラアミド(ULTRAMID)B3でバスフ(BASF)から入手可能である。
ポリエチレンテレフタレート(PET)は、商品名クリスター(CRYSTAR)3924でデュポン(DuPont)から入手可能である。
EVA−1は、400のMIのエチレン/酢酸ビニルコポリマー(28重量%VA)である。
EVA−2は、500のMIのエチレン/酢酸ビニルコポリマー(18重量%VA)である。
F−1は、205のMIおよび104℃の融点のエチレン/無水マレイン酸コポリマー(E/MAH85/15重量%)である。
F−2は、30のMIおよび108℃の融点のエチレン/マレイン酸エチルモノエステルコポリマー(E/MAME90.5/9.5重量%)である。
組成物のメルトインデックス(MI)は、2.16kg重量を使用してASTM D1238を用いて測定し、そして190℃で測定した。
4.シールの破壊なしに2つのフィルムを分離することができないときシールは「優れて」いる。
3.2つのフィルムを努力すれば分離することができるときシールは「良好で」ある。
2.2つのフィルムを容易に分離することができるときシールは「不満足で」ある。
1.2つのフィルムはヒートシール処理下にシールしなかった。
Claims (13)
- (a)(a)と(b)との合わせた総量の約5〜約95重量%の量で存在する、エチレンと、無水マレイン酸、無水シトラコン酸、無水イタコン酸、無水テトラヒドロフタル酸、マレイン酸、シトラコン酸、イタコン酸、フマル酸、テトラヒドロフタル酸、これらの酸の対応する塩、モノエステルおよびジエステル、ならびにこれらの任意の混合物から選択されたコモノマーとの共重合から得られた機能性コポリマーと、
(b)エチレンと極性モノマーとの共重合から得られた少なくとも1つのエチレンコポリマーであって、前記極性コモノマーが8〜40重量%の量で前記コポリマー中に存在し、(a)と(b)との合わせた総量の約5〜約95重量%の量で、エチレン/酢酸ビニルコポリマー、エチレン/アルキル(メタ)アクリレートコポリマーおよびエチレン/アルキル(メタ)アクリレート/一酸化炭素ターポリマーからなる群から選択されるエチレンコポリマーとを含み、100グラム/10分以上、好ましくは150グラム/10分以上のメルトインデックスを有するホットメルト接着剤組成物。 - (1)約50重量%〜約90重量%の
(a)(a)と(b)との合わせた総量の約5〜約95重量%の量で存在する、エチレンと、無水マレイン酸、無水シトラコン酸、無水イタコン酸、無水テトラヒドロフタル酸、マレイン酸、シトラコン酸、イタコン酸、フマル酸、テトラヒドロフタル酸、これらの酸の対応する塩、モノエステルおよびジエステル、ならびにこれらの任意の混合物から選択されたコモノマーとの共重合から得られた機能性コポリマーと、
(b)エチレンと極性モノマーとの共重合から得られた少なくとも1つのエチレンコポリマーであって、前記極性コモノマーが8〜40重量%の量で前記コポリマー中に存在し、かつ、(a)と(b)との合わせた総量の約5〜約95重量%の量で、エチレン/酢酸ビニルコポリマー、エチレン/アルキル(メタ)アクリレートコポリマーおよびエチレン/アルキル(メタ)アクリレート/一酸化炭素ターポリマーからなる群から選択されるエチレンコポリマーと
の組み合わせ、ならびに
(2)前記組成物の総重量を基準として、約10〜約50重量%の
(c)前記全組成物の重量を基準として、0〜約50重量%のワックス、
(d)前記全組成物の重量を基準として、0〜約50重量%の粘着付与剤、および
(e)前記全組成物の重量を基準として、0〜約15重量%の可塑剤、安定剤、酸化防止剤、紫外線吸収剤、帯電防止剤、染料、顔料、着色剤、無機充填剤、難燃剤、滑剤、強化材、加工助剤、スリップ剤、粘着防止剤、剥離剤およびそれらの混合物からなる群から選択された他の添加剤
を含む請求項1に記載の組成物。 - (a)、(b)、(c)、(d)および(e)の合計が組成物の100重量%である請求項2に記載の組成物。
- (a)の前記機能性コポリマーがエチレンと無水マレイン酸とのコポリマーである請求項1〜3のいずれか一項に記載の組成物。
- (a)の前記機能性コポリマーが、マレイン酸モノアルキルとしてのマレイン酸エチル水素とのコポリマーを含むマレイン酸モノアルキルである請求項1〜3のいずれか一項に記載の組成物。
- メラミン樹脂、エポキシ樹脂、アミン含有樹脂、金属アルコキシドおよび有機酸の金属塩からなる群から好ましくは選択された、架橋剤をさらに含む請求項1〜5のいずれか一項に記載の組成物。
- 架橋剤を含まない請求項1〜5のいずれか一項に記載の組成物。
- スティックのり、カートン、ケース、トレイ、製本、使い捨て品、パッケージ、バッグ、衣類、シューズ、スポーツ用品、自動車部品、書籍または不織布地を含む、請求項1〜7のいずれか一項に記載のホットメルト接着剤組成物を含むかまたはそれから製造された製品。
- 前記組成物が少なくとも1つの基材に接着され、前記少なくとも1つの基材が織布または不織布、金属、ポリマー、ガラスまたは木材および木材製品、紙、および板紙などのセルロース製品からなる群から選択される請求項8に記載の物品。
- 第1表面および第2表面を含み、第2表面の少なくとも一部がホットメルト接着剤組成物によって第1表面の少なくとも一部に接着される請求項8または9に記載の物品。
- パッケージがホットメルト接着剤組成物を含むか、またはホットメルト接着剤組成物を使用することによって形成されるかもしくはシールされる、包装食品を含む、包装物品をさらに含む請求項8〜10のいずれか一項に記載の物品。
- 第2基材への第1基材の接合方法であって、(i)第1基材に請求項1〜7のいずれか一項に記載の溶融ホットメルト接着剤組成物を塗布する工程と、(ii)第2基材を前記溶融ホットメルト接着剤組成物と接触させる工程と、(iii)前記溶融ホットメルト接着剤組成物を放冷しそして凝固させ、それによって前記基材を一緒に接合させる工程とを含む方法。
- 請求項1〜7のいずれか一項に記載のホットメルト接着剤組成物を塗布してケース、カートン、トレイ、バッグまたは書籍をシールするおよび/または形成する工程を含むケース、カートン、トレイ、バッグまたは書籍のシールまたは形成方法。
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Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
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JP2011521802A (ja) * | 2008-05-01 | 2011-07-28 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | エチレン酸コポリマーおよび官能性エチレンコポリマーを含む組成物 |
KR101108546B1 (ko) * | 2009-10-07 | 2012-01-31 | 한국신발피혁연구소 | 백카운터용 핫멜트 접착제 조성물 |
JP2014522431A (ja) * | 2011-05-24 | 2014-09-04 | アダリス・コーポレーション | 感圧接着開封テープ |
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WO2020190018A1 (ko) * | 2019-03-18 | 2020-09-24 | 효성화학 주식회사 | 폴리케톤 및 폴리올레핀을 포함하는 다층구조의 관 |
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Families Citing this family (32)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7879949B2 (en) * | 2004-10-06 | 2011-02-01 | E.I. Du Pont De Nemours And Company | Blends of ethylene copolymers with high-frequency weldability |
US7767311B2 (en) * | 2004-07-29 | 2010-08-03 | E.I. Du Pont De Nemours And Company | Adhesive compositions derived from highly functionalized ethylene copolymers |
US20070172614A1 (en) * | 2005-12-30 | 2007-07-26 | I-Hwa Lee | Heat shrinkable multilayer film and tube with improved adhesion after orientation |
US20080255303A1 (en) * | 2007-04-13 | 2008-10-16 | Chou Richard T | Blends of polyolefins, polar ethylene copolymers and functionalized ethylene copolymers |
RU2480333C2 (ru) * | 2007-11-14 | 2013-04-27 | Таркетт Сас | Сварочный шнур для напольных покрытий |
US8076407B2 (en) | 2008-02-08 | 2011-12-13 | Henkel Ag & Co. Kgaa | Hot melt adhesive |
FR2927332B1 (fr) * | 2008-02-13 | 2010-04-30 | Arkema France | Liant a base de copolymere ethylene-ester vinylique d'acide carboxylique et de polyolefine contenant un monomere fonctionnel |
KR101021233B1 (ko) * | 2008-07-18 | 2011-03-11 | 주식회사유풍 | 모자, 친환경 챙심지 및 그 제조방법 |
US8080727B2 (en) | 2008-11-24 | 2011-12-20 | E. I. Du Pont De Nemours And Company | Solar cell modules comprising an encapsulant sheet of a blend of ethylene copolymers |
US8084129B2 (en) * | 2008-11-24 | 2011-12-27 | E. I. Du Pont De Nemours And Company | Laminated articles comprising a sheet of a blend of ethylene copolymers |
TWI488746B (zh) * | 2009-02-13 | 2015-06-21 | Toyo Aluminium Kk | 層積體及容器 |
WO2010107697A1 (en) * | 2009-03-16 | 2010-09-23 | Interlock Industries, Inc. | Multi-purpose adhesives and methods of making and using thereof |
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Citations (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6051768A (ja) * | 1983-08-31 | 1985-03-23 | Du Pont Mitsui Polychem Co Ltd | ホツトメルト接着剤組成物 |
JPH03255150A (ja) * | 1990-03-03 | 1991-11-14 | Showa Denko Kk | 樹脂組成物 |
JPH05286037A (ja) * | 1992-04-08 | 1993-11-02 | Showa Denko Kk | 合板及びその製造方法 |
JPH07157734A (ja) * | 1993-07-30 | 1995-06-20 | Taoka Chem Co Ltd | ホットメルト接着剤組成物 |
WO1999035206A1 (fr) * | 1998-01-12 | 1999-07-15 | Sumitomo Electric Industries, Ltd. | Composition de resine adhesive et articles thermoretractables realises avec cette composition |
JPH11199833A (ja) * | 1997-11-13 | 1999-07-27 | Sekisui Chem Co Ltd | ホットメルト接着剤組成物 |
JP2003119444A (ja) * | 2001-08-07 | 2003-04-23 | Yasuhara Chemical Co Ltd | ホットメルト接着剤組成物 |
JP2004525214A (ja) * | 2001-01-19 | 2004-08-19 | エクソンモービル・ケミカル・パテンツ・インク | ホットメルト接着剤 |
JP2005089575A (ja) * | 2003-09-16 | 2005-04-07 | Sekisui Chem Co Ltd | カード又はタグ用接着シート |
JP2005133084A (ja) * | 2003-10-07 | 2005-05-26 | Natl Starch & Chem Investment Holding Corp | ホットメルト接着剤組成物 |
Family Cites Families (30)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL6715002A (ja) | 1966-11-04 | 1968-05-06 | ||
US4813947A (en) * | 1985-12-30 | 1989-03-21 | Personal Products Company | Closure system for resealably attaching a tape tab to a fabric surface |
US5242980A (en) * | 1990-02-06 | 1993-09-07 | Exxon Chemical Patents Inc. | Ethylene-unsaturated alcohol or acid copolymer and epoxy crosslinker |
US5217812A (en) | 1990-06-25 | 1993-06-08 | E. I. Du Pont De Nemours And Company | Extrudable and primerless adhesives and products therefrom |
US5326413A (en) * | 1990-11-19 | 1994-07-05 | Pearle, Inc. | Hot melt adhesive composition that melts at relatively low temperatures |
DE4211125C2 (de) * | 1992-04-03 | 1994-12-08 | Henkel Kgaa | Schmelzklebstoffe, Verfahren zu deren Herstellung und deren Verwendung |
US5401791A (en) | 1992-12-03 | 1995-03-28 | Exxon Chemical Patents Inc. | Bookbinding adhesives; processes for production of bookbinding adhesives; and methods of bookbinding |
US5382615A (en) | 1993-10-01 | 1995-01-17 | Eastman Chemical Company | Modified polyethylene based hot-melt adhesives for use in packaging |
US7222380B2 (en) | 1994-04-19 | 2007-05-29 | Applied Elastomerics, Inc. | Tear resistant gels, composites, and cushion articles |
US6465107B1 (en) | 1996-09-13 | 2002-10-15 | Dupont Canada Inc. | Silicone-containing polyolefin film |
US6211291B1 (en) | 1997-07-01 | 2001-04-03 | E. I. Du Pont De Nemours And Company | Polyolefin compositions |
US6528550B1 (en) | 1999-07-01 | 2003-03-04 | E. I. Du Pont De Nemours And Company | Crosslinked foam of ethylene vinyl acetate copolymer and acid copolymer |
US20030021945A1 (en) | 2001-06-15 | 2003-01-30 | Kelch Robert H. | High-frequency active polymeric compositions and films |
US20030091760A1 (en) * | 2001-11-09 | 2003-05-15 | Cecile Drogou | Adhesive for difficult to bond substrates |
US6756443B2 (en) | 2002-01-25 | 2004-06-29 | E. I. Du Pont De Nemours And Company | Ionomer/polyamide blends with improved flow and impact properties |
FR2836480B1 (fr) * | 2002-02-26 | 2005-04-01 | Atofina | Adhesifs thermofusibles a base de copolymeres greffes a blocs polyamides |
US20060148988A1 (en) | 2004-10-06 | 2006-07-06 | Chou Richard T | Miscible blends of ethylene copolymers with improved temperature resistance |
CA2483196A1 (en) | 2002-05-23 | 2003-12-04 | E. I. Du Pont De Nemours And Company | Toughened thermoplastic polyamide compositions |
US7879949B2 (en) | 2004-10-06 | 2011-02-01 | E.I. Du Pont De Nemours And Company | Blends of ethylene copolymers with high-frequency weldability |
US20090298372A1 (en) | 2003-06-05 | 2009-12-03 | E. I. Du Pont De Nemours And Company | Article comprising ionomer and polyamide |
US20050020762A1 (en) | 2003-06-05 | 2005-01-27 | Chou Richard T. | Scuff resistant compositions comprising ethylene acid copolymers and polyamides |
DE602004016550D1 (de) | 2003-11-25 | 2008-10-23 | Du Pont | Flammwidrige halogenfreie zusammensetzungen |
US20050228145A1 (en) | 2004-01-26 | 2005-10-13 | Christophe Lacroix | Polyamide 1/interlayer/polyamide 2 multilayer structures for decorated articles |
US8455574B2 (en) | 2004-02-19 | 2013-06-04 | E I Du Pont De Nemours And Company | Composite compositions comprising cellulose and polymeric components |
US7767311B2 (en) | 2004-07-29 | 2010-08-03 | E.I. Du Pont De Nemours And Company | Adhesive compositions derived from highly functionalized ethylene copolymers |
EP1786864B1 (en) | 2004-09-08 | 2010-10-20 | E.I. Du Pont De Nemours And Company | Ethylene copolymer modified polypropylene and shaped articles |
US7700692B2 (en) | 2006-04-28 | 2010-04-20 | E.I. Du Pont De Nemours And Company | Process for recycling polyolefin blend composition using an ethylene copolymer compatibilizing agent |
US20080255303A1 (en) | 2007-04-13 | 2008-10-16 | Chou Richard T | Blends of polyolefins, polar ethylene copolymers and functionalized ethylene copolymers |
US20090215928A1 (en) | 2007-12-17 | 2009-08-27 | E. I. Du Pont De Nemours And Company | Ethylene/ester copolymer nanofiller composition |
US20090274856A1 (en) | 2008-05-01 | 2009-11-05 | Chou Richard T | Compositions comprising ethylene acid copolymers and functional ethylene copolymers |
-
2006
- 2006-12-20 US US11/642,107 patent/US7767760B2/en active Active
- 2006-12-27 WO PCT/US2006/049313 patent/WO2007079092A1/en active Application Filing
- 2006-12-27 EP EP06848180A patent/EP1976953B1/en active Active
- 2006-12-27 CN CN2006800500203A patent/CN101351519B/zh active Active
- 2006-12-27 AU AU2006332770A patent/AU2006332770A1/en not_active Abandoned
- 2006-12-27 JP JP2008548686A patent/JP5430941B2/ja active Active
- 2006-12-28 AR ARP060105871A patent/AR059403A1/es unknown
Patent Citations (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6051768A (ja) * | 1983-08-31 | 1985-03-23 | Du Pont Mitsui Polychem Co Ltd | ホツトメルト接着剤組成物 |
JPH03255150A (ja) * | 1990-03-03 | 1991-11-14 | Showa Denko Kk | 樹脂組成物 |
JPH05286037A (ja) * | 1992-04-08 | 1993-11-02 | Showa Denko Kk | 合板及びその製造方法 |
JPH07157734A (ja) * | 1993-07-30 | 1995-06-20 | Taoka Chem Co Ltd | ホットメルト接着剤組成物 |
JPH11199833A (ja) * | 1997-11-13 | 1999-07-27 | Sekisui Chem Co Ltd | ホットメルト接着剤組成物 |
WO1999035206A1 (fr) * | 1998-01-12 | 1999-07-15 | Sumitomo Electric Industries, Ltd. | Composition de resine adhesive et articles thermoretractables realises avec cette composition |
JP2004525214A (ja) * | 2001-01-19 | 2004-08-19 | エクソンモービル・ケミカル・パテンツ・インク | ホットメルト接着剤 |
JP2003119444A (ja) * | 2001-08-07 | 2003-04-23 | Yasuhara Chemical Co Ltd | ホットメルト接着剤組成物 |
JP2005089575A (ja) * | 2003-09-16 | 2005-04-07 | Sekisui Chem Co Ltd | カード又はタグ用接着シート |
JP2005133084A (ja) * | 2003-10-07 | 2005-05-26 | Natl Starch & Chem Investment Holding Corp | ホットメルト接着剤組成物 |
Cited By (13)
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JP2011521802A (ja) * | 2008-05-01 | 2011-07-28 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | エチレン酸コポリマーおよび官能性エチレンコポリマーを含む組成物 |
KR101108546B1 (ko) * | 2009-10-07 | 2012-01-31 | 한국신발피혁연구소 | 백카운터용 핫멜트 접착제 조성물 |
JP2014522431A (ja) * | 2011-05-24 | 2014-09-04 | アダリス・コーポレーション | 感圧接着開封テープ |
US10686226B2 (en) | 2016-03-31 | 2020-06-16 | Dongguan Amperex Technology Limited | Thermal conductive adhesive and secondary battery containing the same |
JP2017186498A (ja) * | 2016-03-31 | 2017-10-12 | 東莞新能源科技有限公司Dongguan Amperex Technology Limited | 熱伝導性接着剤及び該熱伝導性接着剤を含む二次電池 |
WO2018212154A1 (ja) * | 2017-05-17 | 2018-11-22 | ハリマ化成株式会社 | 粘着付与樹脂および粘着剤組成物 |
JPWO2018212154A1 (ja) * | 2017-05-17 | 2020-03-19 | ハリマ化成株式会社 | 粘着付与樹脂および粘着剤組成物 |
JP7044773B2 (ja) | 2017-05-17 | 2022-03-30 | ハリマ化成株式会社 | 粘着付与樹脂および粘着剤組成物 |
KR20200069412A (ko) * | 2018-12-06 | 2020-06-17 | 효성화학 주식회사 | 접착 수지 조성물 및 이를 포함하는 접착 시트 |
KR102156201B1 (ko) * | 2018-12-06 | 2020-09-16 | 효성화학 주식회사 | 접착 수지 조성물 및 이를 포함하는 접착 시트 |
JP2022513788A (ja) * | 2018-12-20 | 2022-02-09 | バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ | カーペット基布用ポリオレフィン組成物 |
JP7196310B2 (ja) | 2018-12-20 | 2022-12-26 | バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ | カーペット基布用ポリオレフィン組成物 |
WO2020190018A1 (ko) * | 2019-03-18 | 2020-09-24 | 효성화학 주식회사 | 폴리케톤 및 폴리올레핀을 포함하는 다층구조의 관 |
Also Published As
Publication number | Publication date |
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CN101351519B (zh) | 2012-05-16 |
EP1976953B1 (en) | 2012-02-29 |
EP1976953A1 (en) | 2008-10-08 |
AR059403A1 (es) | 2008-04-09 |
CN101351519A (zh) | 2009-01-21 |
JP5430941B2 (ja) | 2014-03-05 |
WO2007079092A1 (en) | 2007-07-12 |
US20070155904A1 (en) | 2007-07-05 |
AU2006332770A1 (en) | 2007-07-12 |
US7767760B2 (en) | 2010-08-03 |
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