JP2009096096A - 積層フィルム - Google Patents
積層フィルム Download PDFInfo
- Publication number
- JP2009096096A JP2009096096A JP2007270762A JP2007270762A JP2009096096A JP 2009096096 A JP2009096096 A JP 2009096096A JP 2007270762 A JP2007270762 A JP 2007270762A JP 2007270762 A JP2007270762 A JP 2007270762A JP 2009096096 A JP2009096096 A JP 2009096096A
- Authority
- JP
- Japan
- Prior art keywords
- aliphatic
- acid
- laminated film
- component
- acid component
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- 229920003232 aliphatic polyester Polymers 0.000 claims abstract description 65
- 239000010410 layer Substances 0.000 claims abstract description 56
- 229920000728 polyester Polymers 0.000 claims abstract description 40
- 239000002344 surface layer Substances 0.000 claims abstract description 33
- 239000000203 mixture Substances 0.000 claims abstract description 27
- 229920002451 polyvinyl alcohol Polymers 0.000 claims abstract description 27
- 229920000747 poly(lactic acid) Polymers 0.000 claims abstract description 26
- 239000004626 polylactic acid Substances 0.000 claims abstract description 24
- 238000002844 melting Methods 0.000 claims abstract description 23
- 230000008018 melting Effects 0.000 claims abstract description 23
- 229920000642 polymer Polymers 0.000 claims abstract description 22
- 239000004372 Polyvinyl alcohol Substances 0.000 claims abstract description 16
- 125000001931 aliphatic group Chemical group 0.000 claims description 104
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 52
- 125000002723 alicyclic group Chemical group 0.000 claims description 48
- 125000003118 aryl group Chemical group 0.000 claims description 41
- 150000001875 compounds Chemical class 0.000 claims description 37
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 claims description 18
- 230000001588 bifunctional effect Effects 0.000 claims description 16
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 claims description 15
- 238000000034 method Methods 0.000 claims description 12
- 239000005022 packaging material Substances 0.000 claims description 10
- 239000004310 lactic acid Substances 0.000 claims description 9
- 235000014655 lactic acid Nutrition 0.000 claims description 9
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- 238000002425 crystallisation Methods 0.000 claims description 8
- 230000008025 crystallization Effects 0.000 claims description 8
- 239000002253 acid Substances 0.000 claims description 7
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- 239000002361 compost Substances 0.000 abstract description 6
- 238000012545 processing Methods 0.000 abstract description 4
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- 125000004432 carbon atom Chemical group C* 0.000 description 23
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 20
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 18
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- 235000019422 polyvinyl alcohol Nutrition 0.000 description 15
- JVTAAEKCZFNVCJ-UWTATZPHSA-N D-lactic acid Chemical compound C[C@@H](O)C(O)=O JVTAAEKCZFNVCJ-UWTATZPHSA-N 0.000 description 14
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 14
- 229940022769 d- lactic acid Drugs 0.000 description 14
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 13
- 229930182843 D-Lactic acid Natural products 0.000 description 11
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 9
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 8
- 238000002156 mixing Methods 0.000 description 8
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- 239000001361 adipic acid Substances 0.000 description 7
- 235000011037 adipic acid Nutrition 0.000 description 7
- 238000009264 composting Methods 0.000 description 7
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 description 6
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- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 6
- 239000000126 substance Substances 0.000 description 5
- DNIAPMSPPWPWGF-VKHMYHEASA-N (+)-propylene glycol Chemical compound C[C@H](O)CO DNIAPMSPPWPWGF-VKHMYHEASA-N 0.000 description 4
- YPFDHNVEDLHUCE-UHFFFAOYSA-N 1,3-propanediol Substances OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 description 4
- 229940035437 1,3-propanediol Drugs 0.000 description 4
- OZJPLYNZGCXSJM-UHFFFAOYSA-N 5-valerolactone Chemical compound O=C1CCCCO1 OZJPLYNZGCXSJM-UHFFFAOYSA-N 0.000 description 4
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- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 4
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 4
- 229920001577 copolymer Polymers 0.000 description 4
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 4
- BDJRBEYXGGNYIS-UHFFFAOYSA-N nonanedioic acid Chemical compound OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 description 4
- WLJVNTCWHIRURA-UHFFFAOYSA-N pimelic acid Chemical compound OC(=O)CCCCCC(O)=O WLJVNTCWHIRURA-UHFFFAOYSA-N 0.000 description 4
- 229920000166 polytrimethylene carbonate Polymers 0.000 description 4
- 238000007127 saponification reaction Methods 0.000 description 4
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 4
- TYFQFVWCELRYAO-UHFFFAOYSA-N suberic acid Chemical compound OC(=O)CCCCCCC(O)=O TYFQFVWCELRYAO-UHFFFAOYSA-N 0.000 description 4
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 4
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 4
- WHBMMWSBFZVSSR-UHFFFAOYSA-N 3-hydroxybutyric acid Chemical compound CC(O)CC(O)=O WHBMMWSBFZVSSR-UHFFFAOYSA-N 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
- 239000002202 Polyethylene glycol Substances 0.000 description 3
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 230000007062 hydrolysis Effects 0.000 description 3
- 238000006460 hydrolysis reaction Methods 0.000 description 3
- 150000002596 lactones Chemical class 0.000 description 3
- OJURWUUOVGOHJZ-UHFFFAOYSA-N methyl 2-[(2-acetyloxyphenyl)methyl-[2-[(2-acetyloxyphenyl)methyl-(2-methoxy-2-oxoethyl)amino]ethyl]amino]acetate Chemical compound C=1C=CC=C(OC(C)=O)C=1CN(CC(=O)OC)CCN(CC(=O)OC)CC1=CC=CC=C1OC(C)=O OJURWUUOVGOHJZ-UHFFFAOYSA-N 0.000 description 3
- 229920001432 poly(L-lactide) Polymers 0.000 description 3
- 238000012643 polycondensation polymerization Methods 0.000 description 3
- 229920001223 polyethylene glycol Polymers 0.000 description 3
- 238000006116 polymerization reaction Methods 0.000 description 3
- 239000000377 silicon dioxide Substances 0.000 description 3
- 239000001384 succinic acid Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- PAPBSGBWRJIAAV-UHFFFAOYSA-N ε-Caprolactone Chemical compound O=C1CCCCCO1 PAPBSGBWRJIAAV-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 2
- PXGZQGDTEZPERC-UHFFFAOYSA-N 1,4-cyclohexanedicarboxylic acid Chemical compound OC(=O)C1CCC(C(O)=O)CC1 PXGZQGDTEZPERC-UHFFFAOYSA-N 0.000 description 2
- RTBFRGCFXZNCOE-UHFFFAOYSA-N 1-methylsulfonylpiperidin-4-one Chemical compound CS(=O)(=O)N1CCC(=O)CC1 RTBFRGCFXZNCOE-UHFFFAOYSA-N 0.000 description 2
- FQXGHZNSUOHCLO-UHFFFAOYSA-N 2,2,4,4-tetramethyl-1,3-cyclobutanediol Chemical compound CC1(C)C(O)C(C)(C)C1O FQXGHZNSUOHCLO-UHFFFAOYSA-N 0.000 description 2
- GZZLQUBMUXEOBE-UHFFFAOYSA-N 2,2,4-trimethylhexane-1,6-diol Chemical compound OCCC(C)CC(C)(C)CO GZZLQUBMUXEOBE-UHFFFAOYSA-N 0.000 description 2
- BTUDGPVTCYNYLK-UHFFFAOYSA-N 2,2-dimethylglutaric acid Chemical compound OC(=O)C(C)(C)CCC(O)=O BTUDGPVTCYNYLK-UHFFFAOYSA-N 0.000 description 2
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- DSKYSDCYIODJPC-UHFFFAOYSA-N 2-butyl-2-ethylpropane-1,3-diol Chemical compound CCCCC(CC)(CO)CO DSKYSDCYIODJPC-UHFFFAOYSA-N 0.000 description 2
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- QNKRHLZUPSSIPN-UHFFFAOYSA-N 2-ethyl-2-(2-methylpropyl)propane-1,3-diol Chemical compound CCC(CO)(CO)CC(C)C QNKRHLZUPSSIPN-UHFFFAOYSA-N 0.000 description 2
- NGEWQZIDQIYUNV-UHFFFAOYSA-N 2-hydroxy-3-methylbutyric acid Chemical compound CC(C)C(O)C(O)=O NGEWQZIDQIYUNV-UHFFFAOYSA-N 0.000 description 2
- BWLBGMIXKSTLSX-UHFFFAOYSA-N 2-hydroxyisobutyric acid Chemical compound CC(C)(O)C(O)=O BWLBGMIXKSTLSX-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- QEVGZEDELICMKH-UHFFFAOYSA-N Diglycolic acid Chemical compound OC(=O)COCC(O)=O QEVGZEDELICMKH-UHFFFAOYSA-N 0.000 description 2
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- LUSFFPXRDZKBMF-UHFFFAOYSA-N [3-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1CCCC(CO)C1 LUSFFPXRDZKBMF-UHFFFAOYSA-N 0.000 description 2
- YIMQCDZDWXUDCA-UHFFFAOYSA-N [4-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1CCC(CO)CC1 YIMQCDZDWXUDCA-UHFFFAOYSA-N 0.000 description 2
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- JFCQEDHGNNZCLN-UHFFFAOYSA-N anhydrous glutaric acid Natural products OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 description 2
- HDLHSQWNJQGDLM-UHFFFAOYSA-N bicyclo[2.2.1]heptane-2,5-dicarboxylic acid Chemical compound C1C2C(C(=O)O)CC1C(C(O)=O)C2 HDLHSQWNJQGDLM-UHFFFAOYSA-N 0.000 description 2
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- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 238000002834 transmittance Methods 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W90/00—Enabling technologies or technologies with a potential or indirect contribution to greenhouse gas [GHG] emissions mitigation
- Y02W90/10—Bio-packaging, e.g. packing containers made from renewable resources or bio-plastics
Landscapes
- Laminated Bodies (AREA)
- Wrappers (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2007270762A JP2009096096A (ja) | 2007-10-18 | 2007-10-18 | 積層フィルム |
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| JP2007270762A JP2009096096A (ja) | 2007-10-18 | 2007-10-18 | 積層フィルム |
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| Publication Number | Publication Date |
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| JP2009096096A true JP2009096096A (ja) | 2009-05-07 |
| JP2009096096A5 JP2009096096A5 (OSRAM) | 2010-10-28 |
Family
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| Application Number | Title | Priority Date | Filing Date |
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| JP2007270762A Pending JP2009096096A (ja) | 2007-10-18 | 2007-10-18 | 積層フィルム |
Country Status (1)
| Country | Link |
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| JP (1) | JP2009096096A (OSRAM) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2015507653A (ja) * | 2011-12-15 | 2015-03-12 | ティパ コーポレイション リミティド | 生分解性シート |
| JP2020044717A (ja) * | 2018-09-19 | 2020-03-26 | 株式会社平和化学工業所 | 樹脂成形品及びその製造方法 |
| WO2021049637A1 (ja) * | 2019-09-13 | 2021-03-18 | 三菱ケミカル株式会社 | 生分解性積層シート、容器形成用シート及び生分解性容器 |
| CN112709083A (zh) * | 2021-02-08 | 2021-04-27 | 魔力薇薇(上海)服饰科技有限公司 | 一种改性水溶性高弹聚氨酯印花涂层材料及其制备方法和应用 |
Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0584876A (ja) * | 1991-09-27 | 1993-04-06 | Toppan Printing Co Ltd | 生分解性樹脂積層体 |
| JPH06263954A (ja) * | 1993-03-15 | 1994-09-20 | Kuraray Co Ltd | 組成物および積層体 |
| JPH106445A (ja) * | 1996-06-19 | 1998-01-13 | Dainippon Printing Co Ltd | 生分解性を有する積層体 |
| JP2000238194A (ja) * | 1999-02-22 | 2000-09-05 | Daicel Chem Ind Ltd | 生分解性積層フィルム及び農業用生分解性フィルム |
| JP2003145693A (ja) * | 2001-07-12 | 2003-05-20 | Nippon Synthetic Chem Ind Co Ltd:The | 水溶性防水フィルム |
| JP2003181992A (ja) * | 2001-12-21 | 2003-07-03 | Keiwa Inc | 防水シート及びこれを用いた汚物処理袋 |
| JP2005330332A (ja) * | 2004-05-18 | 2005-12-02 | Tohcello Co Ltd | 脂肪族ポリエステル組成物、それからなるフィルム及び積層フィルム。 |
| JP2007069538A (ja) * | 2005-09-08 | 2007-03-22 | Tohcello Co Ltd | 生分解性脂肪族ポリエステルからなる積層フィルム。 |
| JP2007176143A (ja) * | 2005-12-01 | 2007-07-12 | Tohcello Co Ltd | 生分解性多層フィルム |
-
2007
- 2007-10-18 JP JP2007270762A patent/JP2009096096A/ja active Pending
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0584876A (ja) * | 1991-09-27 | 1993-04-06 | Toppan Printing Co Ltd | 生分解性樹脂積層体 |
| JPH06263954A (ja) * | 1993-03-15 | 1994-09-20 | Kuraray Co Ltd | 組成物および積層体 |
| JPH106445A (ja) * | 1996-06-19 | 1998-01-13 | Dainippon Printing Co Ltd | 生分解性を有する積層体 |
| JP2000238194A (ja) * | 1999-02-22 | 2000-09-05 | Daicel Chem Ind Ltd | 生分解性積層フィルム及び農業用生分解性フィルム |
| JP2003145693A (ja) * | 2001-07-12 | 2003-05-20 | Nippon Synthetic Chem Ind Co Ltd:The | 水溶性防水フィルム |
| JP2003181992A (ja) * | 2001-12-21 | 2003-07-03 | Keiwa Inc | 防水シート及びこれを用いた汚物処理袋 |
| JP2005330332A (ja) * | 2004-05-18 | 2005-12-02 | Tohcello Co Ltd | 脂肪族ポリエステル組成物、それからなるフィルム及び積層フィルム。 |
| JP2007069538A (ja) * | 2005-09-08 | 2007-03-22 | Tohcello Co Ltd | 生分解性脂肪族ポリエステルからなる積層フィルム。 |
| JP2007176143A (ja) * | 2005-12-01 | 2007-07-12 | Tohcello Co Ltd | 生分解性多層フィルム |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2015507653A (ja) * | 2011-12-15 | 2015-03-12 | ティパ コーポレイション リミティド | 生分解性シート |
| JP2020044717A (ja) * | 2018-09-19 | 2020-03-26 | 株式会社平和化学工業所 | 樹脂成形品及びその製造方法 |
| WO2020059793A1 (ja) * | 2018-09-19 | 2020-03-26 | 株式会社平和化学工業所 | 樹脂成形品及びその製造方法 |
| WO2021049637A1 (ja) * | 2019-09-13 | 2021-03-18 | 三菱ケミカル株式会社 | 生分解性積層シート、容器形成用シート及び生分解性容器 |
| JPWO2021049637A1 (OSRAM) * | 2019-09-13 | 2021-03-18 | ||
| CN112709083A (zh) * | 2021-02-08 | 2021-04-27 | 魔力薇薇(上海)服饰科技有限公司 | 一种改性水溶性高弹聚氨酯印花涂层材料及其制备方法和应用 |
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