JP2008540377A5 - - Google Patents
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- Publication number
- JP2008540377A5 JP2008540377A5 JP2008509435A JP2008509435A JP2008540377A5 JP 2008540377 A5 JP2008540377 A5 JP 2008540377A5 JP 2008509435 A JP2008509435 A JP 2008509435A JP 2008509435 A JP2008509435 A JP 2008509435A JP 2008540377 A5 JP2008540377 A5 JP 2008540377A5
- Authority
- JP
- Japan
- Prior art keywords
- alkyl
- group
- formula
- compound
- phenyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
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- 150000001875 compounds Chemical class 0.000 claims 21
- -1 1-methoxyeth-1-yl Chemical group 0.000 claims 10
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims 9
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims 8
- 229910052739 hydrogen Inorganic materials 0.000 claims 7
- 239000001257 hydrogen Substances 0.000 claims 7
- 229910052751 metal Inorganic materials 0.000 claims 7
- 239000002184 metal Substances 0.000 claims 7
- 229910052740 iodine Inorganic materials 0.000 claims 6
- 239000003446 ligand Substances 0.000 claims 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 5
- 150000001450 anions Chemical class 0.000 claims 5
- 229910052794 bromium Inorganic materials 0.000 claims 5
- 150000004696 coordination complex Chemical class 0.000 claims 5
- 150000002894 organic compounds Chemical class 0.000 claims 5
- 229910052801 chlorine Inorganic materials 0.000 claims 4
- WFDIJRYMOXRFFG-UHFFFAOYSA-N Acetic anhydride Chemical compound CC(=O)OC(C)=O WFDIJRYMOXRFFG-UHFFFAOYSA-N 0.000 claims 3
- 150000002430 hydrocarbons Chemical group 0.000 claims 3
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims 3
- 229910052741 iridium Inorganic materials 0.000 claims 3
- 238000000034 method Methods 0.000 claims 3
- 229910052703 rhodium Inorganic materials 0.000 claims 3
- 239000010948 rhodium Substances 0.000 claims 3
- 125000003808 silyl group Chemical group [H][Si]([H])([H])[*] 0.000 claims 3
- 229910052717 sulfur Inorganic materials 0.000 claims 3
- KWGRBVOPPLSCSI-WPRPVWTQSA-N (-)-ephedrine Chemical compound CN[C@@H](C)[C@H](O)C1=CC=CC=C1 KWGRBVOPPLSCSI-WPRPVWTQSA-N 0.000 claims 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims 2
- 239000002253 acid Substances 0.000 claims 2
- 125000002252 acyl group Chemical group 0.000 claims 2
- 125000001931 aliphatic group Chemical group 0.000 claims 2
- 125000003118 aryl group Chemical group 0.000 claims 2
- 125000004429 atom Chemical group 0.000 claims 2
- 229910052799 carbon Inorganic materials 0.000 claims 2
- CREMABGTGYGIQB-UHFFFAOYSA-N carbon carbon Chemical compound C.C CREMABGTGYGIQB-UHFFFAOYSA-N 0.000 claims 2
- 239000011203 carbon fibre reinforced carbon Substances 0.000 claims 2
- 125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 claims 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims 2
- 229910052731 fluorine Inorganic materials 0.000 claims 2
- 229910052736 halogen Inorganic materials 0.000 claims 2
- 125000001475 halogen functional group Chemical group 0.000 claims 2
- 125000005843 halogen group Chemical group 0.000 claims 2
- 150000002367 halogens Chemical class 0.000 claims 2
- 150000004715 keto acids Chemical class 0.000 claims 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 2
- 230000003647 oxidation Effects 0.000 claims 2
- 238000007254 oxidation reaction Methods 0.000 claims 2
- 229910052707 ruthenium Inorganic materials 0.000 claims 2
- 125000001424 substituent group Chemical group 0.000 claims 2
- 239000011593 sulfur Substances 0.000 claims 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims 2
- 229920002554 vinyl polymer Polymers 0.000 claims 2
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 claims 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims 1
- BWGNESOTFCXPMA-UHFFFAOYSA-N Dihydrogen disulfide Chemical compound SS BWGNESOTFCXPMA-UHFFFAOYSA-N 0.000 claims 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims 1
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 claims 1
- 238000007259 addition reaction Methods 0.000 claims 1
- 150000001336 alkenes Chemical class 0.000 claims 1
- 125000004848 alkoxyethyl group Chemical group 0.000 claims 1
- 125000001118 alkylidene group Chemical group 0.000 claims 1
- IYABWNGZIDDRAK-UHFFFAOYSA-N allene Chemical group C=C=C IYABWNGZIDDRAK-UHFFFAOYSA-N 0.000 claims 1
- 150000001413 amino acids Chemical class 0.000 claims 1
- 150000008064 anhydrides Chemical class 0.000 claims 1
- 125000000051 benzyloxy group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])O* 0.000 claims 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims 1
- 150000001721 carbon Chemical group 0.000 claims 1
- 125000004432 carbon atom Chemical group C* 0.000 claims 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims 1
- 239000003054 catalyst Substances 0.000 claims 1
- 230000003197 catalytic effect Effects 0.000 claims 1
- 239000003153 chemical reaction reagent Substances 0.000 claims 1
- ONCCWDRMOZMNSM-FBCQKBJTSA-N compound Z Chemical compound N1=C2C(=O)NC(N)=NC2=NC=C1C(=O)[C@H]1OP(O)(=O)OC[C@H]1O ONCCWDRMOZMNSM-FBCQKBJTSA-N 0.000 claims 1
- 229910052802 copper Inorganic materials 0.000 claims 1
- 125000004122 cyclic group Chemical group 0.000 claims 1
- KWGRBVOPPLSCSI-UHFFFAOYSA-N d-ephedrine Natural products CNC(C)C(O)C1=CC=CC=C1 KWGRBVOPPLSCSI-UHFFFAOYSA-N 0.000 claims 1
- 150000001993 dienes Chemical class 0.000 claims 1
- 229960002179 ephedrine Drugs 0.000 claims 1
- 125000002541 furyl group Chemical group 0.000 claims 1
- 229910052737 gold Inorganic materials 0.000 claims 1
- 125000005842 heteroatom Chemical group 0.000 claims 1
- 239000002815 homogeneous catalyst Substances 0.000 claims 1
- 230000007062 hydrolysis Effects 0.000 claims 1
- 238000006460 hydrolysis reaction Methods 0.000 claims 1
- 125000000879 imine group Chemical group 0.000 claims 1
- 239000011630 iodine Substances 0.000 claims 1
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 claims 1
- 229910052744 lithium Inorganic materials 0.000 claims 1
- 229910052749 magnesium Inorganic materials 0.000 claims 1
- 239000011777 magnesium Substances 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- 150000002739 metals Chemical class 0.000 claims 1
- 125000006178 methyl benzyl group Chemical group 0.000 claims 1
- 239000000203 mixture Substances 0.000 claims 1
- 125000001624 naphthyl group Chemical group 0.000 claims 1
- 229910052759 nickel Inorganic materials 0.000 claims 1
- 125000004433 nitrogen atom Chemical group N* 0.000 claims 1
- 150000008427 organic disulfides Chemical class 0.000 claims 1
- 238000006053 organic reaction Methods 0.000 claims 1
- 229910052760 oxygen Inorganic materials 0.000 claims 1
- 229910052763 palladium Inorganic materials 0.000 claims 1
- 229910052697 platinum Inorganic materials 0.000 claims 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 claims 1
- 125000006413 ring segment Chemical group 0.000 claims 1
- 125000000467 secondary amino group Chemical group [H]N([*:1])[*:2] 0.000 claims 1
- 229910052709 silver Inorganic materials 0.000 claims 1
- 229910052723 transition metal Inorganic materials 0.000 claims 1
- 150000003624 transition metals Chemical class 0.000 claims 1
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH7762005 | 2005-05-03 | ||
| PCT/EP2006/061973 WO2006117369A1 (de) | 2005-05-03 | 2006-05-02 | Ferrocenylliganden, herstellung und verwendung |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2008540377A JP2008540377A (ja) | 2008-11-20 |
| JP2008540377A5 true JP2008540377A5 (enExample) | 2009-06-25 |
Family
ID=36869223
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2008509435A Withdrawn JP2008540377A (ja) | 2005-05-03 | 2006-05-02 | フェロセニル配位子、製造およびその使用 |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US20090082581A1 (enExample) |
| EP (1) | EP1885733A1 (enExample) |
| JP (1) | JP2008540377A (enExample) |
| CN (1) | CN101171259A (enExample) |
| CA (1) | CA2606654A1 (enExample) |
| IL (1) | IL187006A0 (enExample) |
| WO (1) | WO2006117369A1 (enExample) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2007020221A2 (en) * | 2005-08-12 | 2007-02-22 | Solvias Ag | Amino-phosphinoalkyl-ferrocenes and their use as ligands in catalysts for asymmetric reactions |
| EP1894938A1 (en) * | 2006-08-31 | 2008-03-05 | Evonik Degussa GmbH | New cyclopentadienyl, indenyl or fluorenyl substituted phosphine compounds and their use in catalytic reactions |
| CN101861326B (zh) * | 2007-11-20 | 2014-10-15 | 索尔维亚斯股份公司 | 用于催化不对称加成反应的二齿手性配位体 |
| FR2961813B1 (fr) | 2010-06-29 | 2013-02-22 | Centre Nat Rech Scient | Ligands supportes a haute densite locale d'atomes coordinants |
| US9227901B2 (en) | 2012-07-05 | 2016-01-05 | Abbvie Inc. | Process for preparing bicyclic amine derivatives |
| US9308527B2 (en) * | 2014-03-17 | 2016-04-12 | Eastman Chemical Company | Phosphorous compounds useful as ligands and compositions and methods regarding them |
| CN104974192B (zh) * | 2015-06-04 | 2017-06-13 | 浙江工业大学 | 一种噻吩酰胺取代的手性膦二茂铁催化剂的合成方法及应用 |
| CN107089912B (zh) * | 2017-05-16 | 2020-10-30 | 湖南大学 | 一种茂金属配合物选择性催化合成扁桃酸酯类化合物的方法 |
| CN108083980B (zh) * | 2017-11-27 | 2021-02-02 | 万华化学集团股份有限公司 | 一种制备光学纯l-薄荷醇的方法 |
| CN111018922A (zh) * | 2019-12-31 | 2020-04-17 | 复旦大学 | 基于二茂铁骨架的手性亚磺酰胺单膦配体及其全构型的制备方法 |
| CN113801253A (zh) * | 2020-06-17 | 2021-12-17 | 中化学科学技术研究有限公司 | 一种催化剂组分、固体钛催化剂、乙烯聚合催化剂及其应用和聚乙烯产品 |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0803510B1 (de) * | 1996-04-25 | 2002-09-11 | Hoechst Aktiengesellschaft | 2,2'-Disubstituierte 1,1'-Diphosphino-ferrocene und 1',2-disubstituierte 1-Phosphino-ferrocene, Verfahren zu ihrer Herstellung, ihre Verwendung sowie sie enthaltende Übergangsmetallkomplexe |
| US6620954B1 (en) * | 2002-03-25 | 2003-09-16 | Eastman Chemical Company | Phosphinometallocenylamides as novel ligands for asymmetric catalysis |
| CN1894268A (zh) * | 2003-12-12 | 2007-01-10 | 索尔维亚斯股份公司 | 二茂铁基－1,2－二膦、其制备和其用途 |
| WO2007135179A1 (en) * | 2006-05-23 | 2007-11-29 | Solvias Ag | Chiral ligands used in transition metal catalysts for asymmetric addition reactions especially hydrogenation |
-
2006
- 2006-05-02 JP JP2008509435A patent/JP2008540377A/ja not_active Withdrawn
- 2006-05-02 US US11/919,762 patent/US20090082581A1/en not_active Abandoned
- 2006-05-02 EP EP06743395A patent/EP1885733A1/de not_active Withdrawn
- 2006-05-02 CA CA002606654A patent/CA2606654A1/en not_active Abandoned
- 2006-05-02 WO PCT/EP2006/061973 patent/WO2006117369A1/de not_active Ceased
- 2006-05-02 CN CNA2006800150765A patent/CN101171259A/zh active Pending
-
2007
- 2007-10-29 IL IL187006A patent/IL187006A0/en unknown
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