JP2008533241A - プロピレンポリマー触媒供与体成分 - Google Patents
プロピレンポリマー触媒供与体成分 Download PDFInfo
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- JP2008533241A JP2008533241A JP2008500794A JP2008500794A JP2008533241A JP 2008533241 A JP2008533241 A JP 2008533241A JP 2008500794 A JP2008500794 A JP 2008500794A JP 2008500794 A JP2008500794 A JP 2008500794A JP 2008533241 A JP2008533241 A JP 2008533241A
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- Prior art keywords
- catalyst component
- carbon atoms
- magnesium
- catalyst
- component according
- Prior art date
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- 239000003054 catalyst Substances 0.000 title claims abstract description 142
- 229920001155 polypropylene Polymers 0.000 title description 21
- 239000011777 magnesium Substances 0.000 claims abstract description 149
- 229910052749 magnesium Inorganic materials 0.000 claims abstract description 100
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims abstract description 82
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 81
- 239000007787 solid Substances 0.000 claims abstract description 56
- 150000001875 compounds Chemical class 0.000 claims abstract description 51
- 239000010936 titanium Substances 0.000 claims abstract description 48
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 36
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 24
- 239000001257 hydrogen Substances 0.000 claims abstract description 21
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 21
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 16
- 150000001336 alkenes Chemical class 0.000 claims abstract description 15
- 125000004122 cyclic group Chemical group 0.000 claims abstract description 12
- 229910052736 halogen Inorganic materials 0.000 claims abstract description 10
- 150000002367 halogens Chemical class 0.000 claims abstract description 10
- 125000001424 substituent group Chemical group 0.000 claims abstract description 10
- 230000000379 polymerizing effect Effects 0.000 claims abstract description 6
- 125000000217 alkyl group Chemical group 0.000 claims description 48
- 239000000203 mixture Substances 0.000 claims description 35
- 238000000034 method Methods 0.000 claims description 33
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 33
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 21
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 21
- 229910052757 nitrogen Inorganic materials 0.000 claims description 18
- 150000002430 hydrocarbons Chemical group 0.000 claims description 17
- 239000004711 α-olefin Substances 0.000 claims description 16
- 125000003710 aryl alkyl group Chemical group 0.000 claims description 11
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 10
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 7
- XTFIVUDBNACUBN-UHFFFAOYSA-N 1,3,5-trinitro-1,3,5-triazinane Chemical compound [O-][N+](=O)N1CN([N+]([O-])=O)CN([N+]([O-])=O)C1 XTFIVUDBNACUBN-UHFFFAOYSA-N 0.000 claims description 6
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 5
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 4
- 239000005977 Ethylene Substances 0.000 claims description 4
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims description 4
- UJHKDJROFCQOBO-UHFFFAOYSA-N (2-ethoxy-2-oxoethyl) 2-phenylacetate Chemical compound CCOC(=O)COC(=O)CC1=CC=CC=C1 UJHKDJROFCQOBO-UHFFFAOYSA-N 0.000 claims description 3
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims description 3
- 125000001183 hydrocarbyl group Chemical group 0.000 abstract description 25
- 239000000126 substance Substances 0.000 abstract description 6
- -1 titanium halide Chemical class 0.000 description 77
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 57
- 238000006116 polymerization reaction Methods 0.000 description 42
- 229920000642 polymer Polymers 0.000 description 37
- 238000007334 copolymerization reaction Methods 0.000 description 36
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 35
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 28
- 239000002245 particle Substances 0.000 description 27
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 26
- 239000000243 solution Substances 0.000 description 25
- 239000007788 liquid Substances 0.000 description 22
- 239000003607 modifier Substances 0.000 description 21
- 239000003085 diluting agent Substances 0.000 description 18
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical group C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 17
- 239000000460 chlorine Substances 0.000 description 17
- 239000000178 monomer Substances 0.000 description 16
- 238000003756 stirring Methods 0.000 description 16
- NNBZCPXTIHJBJL-UHFFFAOYSA-N decalin Chemical compound C1CCCC2CCCCC21 NNBZCPXTIHJBJL-UHFFFAOYSA-N 0.000 description 15
- 239000000463 material Substances 0.000 description 14
- 238000002360 preparation method Methods 0.000 description 14
- YIWUKEYIRIRTPP-UHFFFAOYSA-N 2-ethylhexan-1-ol Chemical compound CCCCC(CC)CO YIWUKEYIRIRTPP-UHFFFAOYSA-N 0.000 description 13
- 239000001569 carbon dioxide Substances 0.000 description 13
- 229910002092 carbon dioxide Inorganic materials 0.000 description 13
- 239000004743 Polypropylene Substances 0.000 description 12
- 125000003118 aryl group Chemical group 0.000 description 12
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 12
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 12
- 239000002002 slurry Substances 0.000 description 12
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 11
- 229930195733 hydrocarbon Natural products 0.000 description 11
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 11
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 11
- 239000004215 Carbon black (E152) Substances 0.000 description 10
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 10
- 150000001298 alcohols Chemical class 0.000 description 10
- 238000006243 chemical reaction Methods 0.000 description 10
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 10
- 229910052723 transition metal Inorganic materials 0.000 description 10
- 150000003624 transition metals Chemical class 0.000 description 10
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 9
- 239000002841 Lewis acid Substances 0.000 description 9
- 125000004429 atom Chemical group 0.000 description 9
- 229920001577 copolymer Polymers 0.000 description 9
- 150000007517 lewis acids Chemical class 0.000 description 9
- 239000000843 powder Substances 0.000 description 9
- 239000011701 zinc Substances 0.000 description 9
- RVDLHGSZWAELAU-UHFFFAOYSA-N 5-tert-butylthiophene-2-carbonyl chloride Chemical compound CC(C)(C)C1=CC=C(C(Cl)=O)S1 RVDLHGSZWAELAU-UHFFFAOYSA-N 0.000 description 8
- 125000005907 alkyl ester group Chemical group 0.000 description 8
- 229910052782 aluminium Inorganic materials 0.000 description 8
- 239000007795 chemical reaction product Substances 0.000 description 8
- 230000000052 comparative effect Effects 0.000 description 8
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical group CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 8
- 239000000047 product Substances 0.000 description 8
- 150000004756 silanes Chemical class 0.000 description 8
- 239000002904 solvent Substances 0.000 description 8
- 150000001491 aromatic compounds Chemical class 0.000 description 7
- 230000000694 effects Effects 0.000 description 7
- 229910052751 metal Inorganic materials 0.000 description 7
- 239000002184 metal Substances 0.000 description 7
- 239000006228 supernatant Substances 0.000 description 7
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 6
- DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 description 6
- 230000015572 biosynthetic process Effects 0.000 description 6
- 238000009835 boiling Methods 0.000 description 6
- 229910052801 chlorine Inorganic materials 0.000 description 6
- 229910001629 magnesium chloride Inorganic materials 0.000 description 6
- 150000007524 organic acids Chemical class 0.000 description 6
- 239000001301 oxygen Substances 0.000 description 6
- 229910052760 oxygen Inorganic materials 0.000 description 6
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 6
- RFFLAFLAYFXFSW-UHFFFAOYSA-N 1,2-dichlorobenzene Chemical compound ClC1=CC=CC=C1Cl RFFLAFLAYFXFSW-UHFFFAOYSA-N 0.000 description 5
- 125000002252 acyl group Chemical group 0.000 description 5
- 125000002877 alkyl aryl group Chemical group 0.000 description 5
- NHYFIJRXGOQNFS-UHFFFAOYSA-N dimethoxy-bis(2-methylpropyl)silane Chemical compound CC(C)C[Si](OC)(CC(C)C)OC NHYFIJRXGOQNFS-UHFFFAOYSA-N 0.000 description 5
- 238000009826 distribution Methods 0.000 description 5
- 239000011521 glass Substances 0.000 description 5
- 150000001282 organosilanes Chemical class 0.000 description 5
- 239000002685 polymerization catalyst Substances 0.000 description 5
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 5
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 5
- 150000003609 titanium compounds Chemical class 0.000 description 5
- 150000003623 transition metal compounds Chemical class 0.000 description 5
- PXXNTAGJWPJAGM-UHFFFAOYSA-N vertaline Natural products C1C2C=3C=C(OC)C(OC)=CC=3OC(C=C3)=CC=C3CCC(=O)OC1CC1N2CCCC1 PXXNTAGJWPJAGM-UHFFFAOYSA-N 0.000 description 5
- UBOXGVDOUJQMTN-UHFFFAOYSA-N 1,1,2-trichloroethane Chemical compound ClCC(Cl)Cl UBOXGVDOUJQMTN-UHFFFAOYSA-N 0.000 description 4
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 4
- 238000001644 13C nuclear magnetic resonance spectroscopy Methods 0.000 description 4
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 4
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 4
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- 150000001408 amides Chemical class 0.000 description 4
- 150000001412 amines Chemical class 0.000 description 4
- 229910052794 bromium Inorganic materials 0.000 description 4
- 150000004292 cyclic ethers Chemical class 0.000 description 4
- DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 4
- 238000010908 decantation Methods 0.000 description 4
- 150000002148 esters Chemical class 0.000 description 4
- 238000001914 filtration Methods 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- 238000012685 gas phase polymerization Methods 0.000 description 4
- 150000004820 halides Chemical class 0.000 description 4
- 229920001519 homopolymer Polymers 0.000 description 4
- 150000002431 hydrogen Chemical class 0.000 description 4
- PHTQWCKDNZKARW-UHFFFAOYSA-N isoamylol Chemical compound CC(C)CCO PHTQWCKDNZKARW-UHFFFAOYSA-N 0.000 description 4
- 150000002681 magnesium compounds Chemical class 0.000 description 4
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 4
- 235000005985 organic acids Nutrition 0.000 description 4
- 150000002894 organic compounds Chemical class 0.000 description 4
- 229910052698 phosphorus Inorganic materials 0.000 description 4
- 239000011574 phosphorus Substances 0.000 description 4
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical class OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 4
- 229910000077 silane Inorganic materials 0.000 description 4
- 229910052710 silicon Inorganic materials 0.000 description 4
- 239000010703 silicon Substances 0.000 description 4
- 239000011949 solid catalyst Substances 0.000 description 4
- RSJKGSCJYJTIGS-UHFFFAOYSA-N undecane Chemical compound CCCCCCCCCCC RSJKGSCJYJTIGS-UHFFFAOYSA-N 0.000 description 4
- 239000008096 xylene Substances 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 3
- AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical compound CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 description 3
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical group OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 3
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 230000002411 adverse Effects 0.000 description 3
- 150000001335 aliphatic alkanes Chemical class 0.000 description 3
- 125000003545 alkoxy group Chemical group 0.000 description 3
- 230000003197 catalytic effect Effects 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 150000002170 ethers Chemical class 0.000 description 3
- 125000005842 heteroatom Chemical group 0.000 description 3
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 3
- HONQAQNYJBKAMA-UHFFFAOYSA-L magnesium;ethyl carbonate Chemical compound [Mg+2].CCOC([O-])=O.CCOC([O-])=O HONQAQNYJBKAMA-UHFFFAOYSA-L 0.000 description 3
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 3
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 description 3
- 239000002574 poison Substances 0.000 description 3
- 231100000614 poison Toxicity 0.000 description 3
- 239000002244 precipitate Substances 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 3
- 239000007858 starting material Substances 0.000 description 3
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 229910001868 water Inorganic materials 0.000 description 3
- 229910052725 zinc Inorganic materials 0.000 description 3
- KVNYFPKFSJIPBJ-UHFFFAOYSA-N 1,2-diethylbenzene Chemical compound CCC1=CC=CC=C1CC KVNYFPKFSJIPBJ-UHFFFAOYSA-N 0.000 description 2
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 2
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 2
- KCXZNSGUUQJJTR-UHFFFAOYSA-N Di-n-hexyl phthalate Chemical compound CCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCC KCXZNSGUUQJJTR-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- FHUODBDRWMIBQP-UHFFFAOYSA-N Ethyl p-anisate Chemical compound CCOC(=O)C1=CC=C(OC)C=C1 FHUODBDRWMIBQP-UHFFFAOYSA-N 0.000 description 2
- UUGLJVMIFJNVFH-UHFFFAOYSA-N Hexyl benzoate Chemical compound CCCCCCOC(=O)C1=CC=CC=C1 UUGLJVMIFJNVFH-UHFFFAOYSA-N 0.000 description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
- 238000005481 NMR spectroscopy Methods 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
- 229910003902 SiCl 4 Inorganic materials 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 description 2
- LCKIEQZJEYYRIY-UHFFFAOYSA-N Titanium ion Chemical compound [Ti+4] LCKIEQZJEYYRIY-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 150000001299 aldehydes Chemical class 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 2
- 239000012298 atmosphere Substances 0.000 description 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 2
- 150000001733 carboxylic acid esters Chemical group 0.000 description 2
- 125000001309 chloro group Chemical group Cl* 0.000 description 2
- IJOOHPMOJXWVHK-UHFFFAOYSA-N chlorotrimethylsilane Chemical compound C[Si](C)(C)Cl IJOOHPMOJXWVHK-UHFFFAOYSA-N 0.000 description 2
- RWGFKTVRMDUZSP-UHFFFAOYSA-N cumene Chemical compound CC(C)C1=CC=CC=C1 RWGFKTVRMDUZSP-UHFFFAOYSA-N 0.000 description 2
- HPXRVTGHNJAIIH-UHFFFAOYSA-N cyclohexanol Chemical compound OC1CCCCC1 HPXRVTGHNJAIIH-UHFFFAOYSA-N 0.000 description 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 2
- MGWAVDBGNNKXQV-UHFFFAOYSA-N diisobutyl phthalate Chemical compound CC(C)COC(=O)C1=CC=CC=C1C(=O)OCC(C)C MGWAVDBGNNKXQV-UHFFFAOYSA-N 0.000 description 2
- MTZQAGJQAFMTAQ-UHFFFAOYSA-N ethyl benzoate Chemical compound CCOC(=O)C1=CC=CC=C1 MTZQAGJQAFMTAQ-UHFFFAOYSA-N 0.000 description 2
- FKRCODPIKNYEAC-UHFFFAOYSA-N ethyl propionate Chemical compound CCOC(=O)CC FKRCODPIKNYEAC-UHFFFAOYSA-N 0.000 description 2
- IIEWJVIFRVWJOD-UHFFFAOYSA-N ethylcyclohexane Chemical compound CCC1CCCCC1 IIEWJVIFRVWJOD-UHFFFAOYSA-N 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 238000000605 extraction Methods 0.000 description 2
- 238000005227 gel permeation chromatography Methods 0.000 description 2
- 125000005843 halogen group Chemical group 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 2
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 2
- 150000002576 ketones Chemical class 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229910001507 metal halide Inorganic materials 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- QPJVMBTYPHYUOC-UHFFFAOYSA-N methyl benzoate Chemical compound COC(=O)C1=CC=CC=C1 QPJVMBTYPHYUOC-UHFFFAOYSA-N 0.000 description 2
- UAEPNZWRGJTJPN-UHFFFAOYSA-N methylcyclohexane Chemical compound CC1CCCCC1 UAEPNZWRGJTJPN-UHFFFAOYSA-N 0.000 description 2
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- ROTONRWJLXYJBD-UHFFFAOYSA-N oxan-2-ylmethanol Chemical compound OCC1CCCCO1 ROTONRWJLXYJBD-UHFFFAOYSA-N 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- WVDDGKGOMKODPV-ZQBYOMGUSA-N phenyl(114C)methanol Chemical compound O[14CH2]C1=CC=CC=C1 WVDDGKGOMKODPV-ZQBYOMGUSA-N 0.000 description 1
- 229940049953 phenylacetate Drugs 0.000 description 1
- WLJVXDMOQOGPHL-UHFFFAOYSA-N phenylacetic acid Chemical compound OC(=O)CC1=CC=CC=C1 WLJVXDMOQOGPHL-UHFFFAOYSA-N 0.000 description 1
- UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 description 1
- 125000005498 phthalate group Chemical class 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- FDNAPBUWERUEDA-UHFFFAOYSA-N silicon tetrachloride Chemical compound Cl[Si](Cl)(Cl)Cl FDNAPBUWERUEDA-UHFFFAOYSA-N 0.000 description 1
- 125000003808 silyl group Chemical group [H][Si]([H])([H])[*] 0.000 description 1
- 230000003381 solubilizing effect Effects 0.000 description 1
- 230000000707 stereoselective effect Effects 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 150000003900 succinic acid esters Chemical class 0.000 description 1
- HXLWJGIPGJFBEZ-UHFFFAOYSA-N tert-butyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C(C)(C)C HXLWJGIPGJFBEZ-UHFFFAOYSA-N 0.000 description 1
- RAOIDOHSFRTOEL-UHFFFAOYSA-N tetrahydrothiophene Chemical compound C1CCSC1 RAOIDOHSFRTOEL-UHFFFAOYSA-N 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- NBXZNTLFQLUFES-UHFFFAOYSA-N triethoxy(propyl)silane Chemical compound CCC[Si](OCC)(OCC)OCC NBXZNTLFQLUFES-UHFFFAOYSA-N 0.000 description 1
- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 1
- XYJRNCYWTVGEEG-UHFFFAOYSA-N trimethoxy(2-methylpropyl)silane Chemical compound CO[Si](OC)(OC)CC(C)C XYJRNCYWTVGEEG-UHFFFAOYSA-N 0.000 description 1
- 239000005051 trimethylchlorosilane Substances 0.000 description 1
- 238000009827 uniform distribution Methods 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
- JBIQAPKSNFTACH-UHFFFAOYSA-K vanadium oxytrichloride Chemical compound Cl[V](Cl)(Cl)=O JBIQAPKSNFTACH-UHFFFAOYSA-K 0.000 description 1
- JTJFQBNJBPPZRI-UHFFFAOYSA-J vanadium tetrachloride Chemical compound Cl[V](Cl)(Cl)Cl JTJFQBNJBPPZRI-UHFFFAOYSA-J 0.000 description 1
- 230000004580 weight loss Effects 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
- DUNKXUFBGCUVQW-UHFFFAOYSA-J zirconium tetrachloride Chemical compound Cl[Zr](Cl)(Cl)Cl DUNKXUFBGCUVQW-UHFFFAOYSA-J 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
Description
基R2とR3、R3とR4、R3とR5、及び基R6とR7は、結合して環式構造を形成してもよい)
の構造を有する電子供与置換基を有する化合物を含む内部電子供与体を更に含む、オレフィンを重合するのに有用な固体で炭化水素不溶性の触媒成分。
基R1とR2、R2とR3、R3とR4、R3とR5、及び基R6とR7は、結合して環式構造を形成してもよい)
の構造を有する電子供与置換基を有する誘導体を含む少なくとも一つの内部電子供与体を含む。
本発明のアルキルジカルボン酸エステルを形成するアルキル基は同一であってよいが、本発明は、異なるアルキル基を有するアルキルジカルボン酸エステルも包含する。
本発明において用いるアルキル基は、また、窒素、リン、ケイ素、及びハロゲンをはじめとするヘテロ原子を有する適合しうる基で置換されていてもよい、而して、本発明において用いる炭化水素基は、アミン基、アミド基、クロロ基、ブロモ基、又はシリル基で置換されていてもよい。供与体化合物中に含ませることのできる環式構造は、窒素、ケイ素、及びリンのようなヘテロ原子を含んでいてもよい。
本発明に包含される構造の例としては、下記のものが挙げられる(水素は示さない)。
のものとして記載することができる。而して、Rはエチルであってよく、R’はt−ブチルであってよい。
のものである。
本発明において記載する供与体化合物の混合物、並びにこれらの供与体化合物と当該技術において公知の他の供与体化合物との混合物を用いることができる。
によって表すことができる。更に、二つの異なる上記のヒドロカルビル基を有するマグネシウムアルコラートを用いることができる。コスト及び入手可能性の観点から、本発明にしたがって用いることが好ましいマグネシウムアルコラートは、式:Mg(OR)2(式中、Rは下記に定義する通りである)のものである。触媒活性及び立体特異性の観点から、最良の結果は、式:Mg(OR’)2(式中、R’は、1〜8個の炭素原子を有するアルキル基、6〜12個の炭素原子を有するアリール基、或いは7〜12個の炭素原子を有するアルカリール又はアラルキル基である)のマグネシウムアルコラートを用いることによって達成される。マグネシウムエトキシドが最も好ましい。
のように二酸化炭素と反応する。
y+n=2の場合には、
マグネシウム含有種を形成するマグネシウム化合物が、式:XMgR(式中、Xはハロゲンであり、Rは1〜20個の炭素原子を有するヒドロカルビル基である)を有するヒドロカルビルマグネシウム化合物である場合には、ヒドロカルビルマグネシウム化合物と二酸化炭素との反応によってマグネシウムカルボキシレートが形成され、これは次式:
ヒドロカルビルマグネシウム化合物が二つのヒドロカルビル基を有する場合には、反応は次式:
のように表される。
本発明において有用なヒドロカルビルマグネシウム化合物は、式:R−Mg−Q(式中、Qは、水素、ハロゲン、又はR’(それぞれのR’は、独立して、1〜20個の炭素原子を有するヒドロカルビル基である)である)の構造を有する。本発明において有用なヒドロカルビルマグネシウム化合物の特定の例としては、Mg(CH3)2、Mg(C2H5)2、Mg(C4H9)2、Mg(C6H5)2、Mg(C6H13)2、Mg(C9H19)2、Mg(C10H7)2、Mg(C12H9)2、Mg(C12H25)2、Mg(C16H33)2、Mg(C20H41)2、Mg(CH3)(C2H5)、Mg(CH3)(C6H13)、Mg(C2H5)(C8H17)、Mg(C6H13)(C20H41)、Mg(C3H7)(C10H7)、Mg(C2H4Cl)2、及びMg(C16H33)(C18H37)、Mg(C2H5)(H)、Mg(C2H5)(Cl)、Mg(C2H5)(Br)等が挙げられる。所望の場合には、ヒドロカルビルマグネシウム化合物の混合物を用いることもできる。コスト及び入手可能性の観点から、本発明において用いるのに好ましいジヒドロカルビルマグネシウム化合物は、式:MgR2(式中、Rは上記に定義した通りである)のものである。触媒活性及び立体特異性の観点から、最良の結果は、式:MgR’Q’(式中、R’は、1〜18個の炭素原子を有するアルキル基、6〜12個の炭素原子を有するアリール基、或いは7〜12個の炭素原子を有するアルカリール又はアラルキル基であり、Q’は塩素又は臭素である)のヒドロカルビルマグネシウムハロゲン化物を用いることによって達成される。
例えば、マグネシウム金属屑を、ヨウ素又は四塩化炭素のような触媒の存在下又は不存在下で、メタノール、エタノール、又は1−プロパノールのような低分子量アルコールと反応させて固体のマグネシウムアルコラートを形成することによって調製されるマグネシウムアルコラートを用いることができる。任意の過剰のアルコールは、濾過、蒸発又はデカテーションによって除去する。この方法で製造されたマグネシウムアルコラートをマグネシウム含有化合物として用いることによって、実質的に低下した粘度を有するマグネシウム含有種の溶液が提供される。
供与体化合物の調製
供与体変性剤化合物の調製を、下記及びTable 1において説明する。
塩化マグネシウム−THF触媒担体の合成
米国特許4,946,816に記載のものと同様の方法で、2−エチル−1−ヘキサノールを含むトルエン溶液中の1当量のマグネシウムエトキシドの溶液(1mLあたり約0.1グラム当量のマグネシウムエトキシドを含む)を、300kPaの二酸化炭素下で迅速に撹拌しながら93℃において3時間、乾燥窒素の雰囲気下で反応させることによって、塩化マグネシウム−THF付加体触媒担体を調製した。得られたマグネシウムヒドロカルビルカーボネート溶液を単離し、トルエン中で四塩化チタン(TiCl4)(0.9当量)と反応させ、固体粒子を沈殿させた。沈殿物を含む混合物を25℃で15分間迅速に撹拌した後、ボンベを通して反応器にマグネシウムヒドロカルビルカーボネート溶液を加え、その後固体粒子を沈殿させた。
触媒調製工程A:
触媒A1:上記に記載の塩化マグネシウム−THF付加体触媒担体(22.5g)を、200mLのヘプタン中に懸濁し、窒素下で、塔頂スターラーを具備する1Lのジャケット付ガラス反応器に移した。デカンテーションによってヘプタンを除去し、固体をトルエンで洗浄し、次にデカンテーションした。更にトルエンを加え、撹拌しながら四塩化チタン(TiCl4)(105mL、Akzo)を加えた。反応器の内容物を90℃に加温し、更に1時間混合した。α−ヒドロキシ酸誘導体供与体変性剤(M1)(2mL)をシリンジによって混合物に加え、得られた混合物を90℃で1時間撹拌し、固体を沈降させて、上澄み液をデカンテーションした。トルエン及び四塩化チタン(105mL)を加え、100℃で撹拌した。更に1mLの同じ変性剤をシリンジによって加え、得られた混合物を100℃で1時間撹拌した。撹拌を停止し、固体を沈降させ、上澄み液を濾過によって除去した。トルエンを加え、スラリーを90℃で0.5時間撹拌した。固体を沈降させ、濾過し、トルエン(125mL)及びTiCl4(105mL)を加え、混合物を90℃で0.5時間撹拌した。次に、得られた固体を、100mLのヘプタンで5回洗浄した。固体をヘプタン(100mL)中でスラリー化し、グローブボックスに移し、焼結ガラスフリット上で濾過し、窒素流で乾燥して、微細な淡緑色の粉末を得た(約12g)。固体は、4.09重量%のTi、20.2重量%のMgを含んでいた(誘導結合プラズマ(ICP)による含量)。粉末は、顕微鏡によって判断して均一な粒子形状、及びMalvern Mastersizerレーザー回折粒径分析器によって測定して均一な分布、d10=12.05、d50=28.82、d90=57.28、及びスパン=1.57を有していた。この触媒A1を実施例4及び5において用いた。
ストリップ担体の調製:上記に記載の塩化マグネシウム−THF付加体触媒担体(22.5g)をヘプタン中に懸濁し、窒素下で、塔頂スターラーを具備した1Lのジャケット付きガラス反応器に移した。デカンテーションによってヘプタンを除去し、撹拌しながらトルエンで1分間洗浄し、固体をデカンテーションによって回収し、撹拌しながら更なるトルエン(125mL)及び四塩化チタン(105mL、Akzo)を加えた。反応器の内容物を95℃に加温し、更に1.25時間混合し、撹拌を停止し、固体を沈降させた。上澄み液をデカンテーションし、残りの固体をトルエン(125mL)中でスラリー化した。撹拌を停止し、固体を沈降させ、上澄み液を濾過によって除去した。固体をヘプタン(100mL)中でスラリー化し、グローブボックスに移し、焼結ガラスフリット上で濾過し、窒素流で乾燥した。明桃色の固体(12.0g)が単離された。固体は、3.2重量%のTi、18.0重量%のMg、及び5.35重量%のTHFを含んでいた。
触媒B3:工程Bを用いたが、第1のTiCl4処理において、変性剤を用いず、混合物を60℃に1時間加熱し、第2のTiCl4処理において、10mgの変性剤M1を用い、混合物を80℃に1時間加熱した。
比較触媒Y2:上記の工程Bを用いたが、TiCl4処理において変性剤ジ−n−ブチルフタレート(M2)(15mg)を用いた。
プロピレン重合
条件A:標準的な2Lのヘプタンスラリー:塔頂スターラー、フラッシュボトムダンプバルブを具備し、温度制御装置が取り付けられた窒素がパージされたジャケット付き2LステンレススチールParr反応器内において、触媒A1を用いて標準的なプロピレンの重合を行った。反応器に、トリエチルアルミニウムの1.25Mヘプタン溶液2.0mL、ジイソブチルジメトキシシランの0.125Mヘプタン溶液2.0mL、触媒20mg、及びヘプタン850mLを加えた。スラリーを38℃において500rpmで撹拌した。水素(9ミリモル)を加え、次に直ちに30gの液体プロピレンを加えた。反応器を加温し、温度が71℃に到達した時点(約15分後)で、プロピレンによって圧力を560kPaに上昇させた。反応器を、71℃、560kPa、及び560rpmにおいて60分保持した。次に、プロピレンの供給を停止し、圧力が約85kPaになるまで反応器を5分間排気した。反応器を窒素によって305kPaに加圧し、次に2回排気して、残留プロピレンを除去した。反応器を窒素によって再び305kPaに加圧し、ボトムダンプバルブを通して反応器スラリーをフィルターソック中に移した。フィルターソック中で得られたヘプタンで濡れた固体をガラス皿に移し、固体を、減圧オーブン中、僅かに窒素をパージさせながら、82℃、0.15barで1時間乾燥して、白色のポリプロピレン粉末を得た。
塔頂スターラーを具備し、温度制御装置が取り付けられた窒素でパージされたジャケット付き300mLステンレススチールParr反応器内において、プロピレンの重合を行った。反応器を約55℃にして、トリエチルアルミニウムの0.75Mヘプタン溶液1.0mL、ジイソブチルジメトキシシランの0.1Mヘプタン溶液1.0mL、触媒B2(7.3mg)、液体プロピレン(約200mL)、及び水素(5.7ミリモル)を仕込んだ。反応器を500rpmで撹拌しながら71℃にした。60分後、温度制御を停止し、プロピレンをゆっくりと排気し、反応器を窒素で2回再充填した。ポリマーを反応器から取り出し、一晩空気乾燥した。白色のポリプロピレン粉末(33g)が得られた。
実施例3:条件Bを用いたが、触媒B1に代えて触媒B3(6mg)を用い、6.5ミリモルの水素を用いて、39gの白色のポリプロピレン粉末を得た。
実施例5:条件Bを用いたが、触媒B1に代えて触媒A1(8.9mg)を用いて、52gの白色のポリプロピレン粉末を得た。
Claims (20)
- Rが1〜8個の炭素原子を有するアルキル基である請求項1に記載の触媒成分。
- R2が1〜8個の炭素原子を有するアルキル基であり、R3が水素である請求項1に記載の触媒成分。
- R2がメチルである請求項3に記載の触媒成分。
- R4が、1〜8個の炭素原子を有するアルキル基又は7〜15個の炭素原子を有するアリールアルキル基である請求項1に記載の触媒成分。
- R4がメチル又はベンジルである請求項5に記載の触媒成分。
- R3とR5が結合して5員環又は6員環を形成している請求項1に記載の触媒成分。
- R5とR6が結合して5又は6員環を形成している請求項1に記載の触媒成分。
- R5とR6が結合して、少なくとも一つの窒素又は酸素ヘテロ原子を含む5又は6員環を形成している請求項1に記載の触媒成分。
- R及びR’が、1〜8個の炭素原子を有するアルキル基である請求項10に記載の触媒成分。
- R及びR’が、異なるアルキル基である請求項11に記載の触媒成分。
- Rが、7〜20個の炭素原子を有するアリールアルキル基である請求項10に記載の触媒成分。
- Rがベンジル基である請求項13に記載の触媒成分。
- R4が−NR2であり、Rが1〜8個の炭素原子を有するアルキル基である請求項15に記載の触媒成分。
- Rがエチル基である請求項16に記載の触媒成分。
- 電子供与体含有化合物がエチル(フェニルアセトキシ)アセテートである請求項1に記載の触媒成分。
- R4が水素でない請求項1に記載の触媒成分。
- 請求項1〜19のいずれかに記載の触媒成分を含む触媒系を用いる、プロピレン、又はプロピレンとエチレン若しくはC4〜C8−α−オレフィンとの混合物を重合する方法。
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WO (1) | WO2006096621A2 (ja) |
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JP2018507304A (ja) * | 2015-03-10 | 2018-03-15 | バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ | オレフイン重合用触媒成分 |
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- 2006-03-06 JP JP2008500794A patent/JP5127696B2/ja active Active
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Cited By (5)
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---|---|---|---|---|
JP2011500901A (ja) * | 2007-10-16 | 2011-01-06 | 中国石化揚子石油化工有限公司 | マグネシウム化合物担持非メタロセン触媒およびその製造 |
US9243081B2 (en) | 2011-09-20 | 2016-01-26 | Toho Titanium Co., Ltd. | Solid catalyst component for polymerization of olefin, catalyst for polymerization of olefin, and method for producing olefin polymer |
JP2016515157A (ja) * | 2013-03-14 | 2016-05-26 | フォルモサ プラスティクス コーポレイション, ユーエスエー | ポリオレフィン触媒のための電子供与体としての非フタル酸エステル化合物 |
JP2018507304A (ja) * | 2015-03-10 | 2018-03-15 | バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ | オレフイン重合用触媒成分 |
US10017590B2 (en) | 2015-03-10 | 2018-07-10 | Basell Poliolefine Italia S.R.L. | Catalyst components for the polymerization of olefins |
Also Published As
Publication number | Publication date |
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WO2006096621A2 (en) | 2006-09-14 |
WO2006096621A3 (en) | 2006-11-09 |
US20070179047A1 (en) | 2007-08-02 |
EP1863855A2 (en) | 2007-12-12 |
JP5127696B2 (ja) | 2013-01-23 |
US7491781B2 (en) | 2009-02-17 |
US20080194782A1 (en) | 2008-08-14 |
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