JP2008530269A5 - - Google Patents
Download PDFInfo
- Publication number
- JP2008530269A5 JP2008530269A5 JP2007554176A JP2007554176A JP2008530269A5 JP 2008530269 A5 JP2008530269 A5 JP 2008530269A5 JP 2007554176 A JP2007554176 A JP 2007554176A JP 2007554176 A JP2007554176 A JP 2007554176A JP 2008530269 A5 JP2008530269 A5 JP 2008530269A5
- Authority
- JP
- Japan
- Prior art keywords
- group
- sulfonic acid
- acid compound
- inhibitor
- aryl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- -1 sulfonic acid compound Chemical class 0.000 claims description 21
- 125000000217 alkyl group Chemical group 0.000 claims description 20
- 125000003118 aryl group Chemical group 0.000 claims description 15
- 125000000018 nitroso group Chemical group N(=O)* 0.000 claims description 12
- 229910052739 hydrogen Inorganic materials 0.000 claims description 10
- 239000001257 hydrogen Substances 0.000 claims description 10
- 125000002252 acyl group Chemical group 0.000 claims description 9
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 9
- 125000003545 alkoxy group Chemical group 0.000 claims description 6
- 125000000623 heterocyclic group Chemical group 0.000 claims description 6
- 125000000472 sulfonyl group Chemical group *S(*)(=O)=O 0.000 claims description 6
- 125000000753 cycloalkyl group Chemical group 0.000 claims description 5
- 125000004423 acyloxy group Chemical group 0.000 claims description 3
- 229910052736 halogen Inorganic materials 0.000 claims description 3
- 150000002367 halogens Chemical class 0.000 claims description 3
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims description 3
- 239000003112 inhibitor Substances 0.000 claims 12
- 238000000034 method Methods 0.000 claims 12
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 claims 9
- 125000004432 carbon atom Chemical group C* 0.000 claims 7
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 claims 6
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims 6
- 239000000178 monomer Substances 0.000 claims 6
- 150000001412 amines Chemical class 0.000 claims 5
- KOOMFXGDLMRWSN-UHFFFAOYSA-N n-phenylnitrous amide Chemical compound O=NNC1=CC=CC=C1 KOOMFXGDLMRWSN-UHFFFAOYSA-N 0.000 claims 5
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical group C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims 4
- 238000010538 cationic polymerization reaction Methods 0.000 claims 4
- IQUPABOKLQSFBK-UHFFFAOYSA-N 2-nitrophenol Chemical group OC1=CC=CC=C1[N+]([O-])=O IQUPABOKLQSFBK-UHFFFAOYSA-N 0.000 claims 3
- 125000005037 alkyl phenyl group Chemical group 0.000 claims 3
- HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 claims 3
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 claims 3
- IMFACGCPASFAPR-UHFFFAOYSA-N tributylamine Chemical compound CCCCN(CCCC)CCCC IMFACGCPASFAPR-UHFFFAOYSA-N 0.000 claims 3
- OWZPCEFYPSAJFR-UHFFFAOYSA-N 2-(butan-2-yl)-4,6-dinitrophenol Chemical group CCC(C)C1=CC([N+]([O-])=O)=CC([N+]([O-])=O)=C1O OWZPCEFYPSAJFR-UHFFFAOYSA-N 0.000 claims 2
- 238000006243 chemical reaction Methods 0.000 claims 2
- 150000001875 compounds Chemical class 0.000 claims 2
- 238000004519 manufacturing process Methods 0.000 claims 2
- 238000006116 polymerization reaction Methods 0.000 claims 2
- 230000002028 premature Effects 0.000 claims 2
- 238000000746 purification Methods 0.000 claims 2
- 125000001624 naphthyl group Chemical group 0.000 claims 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims 1
- 150000002431 hydrogen Chemical class 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US64956305P | 2005-02-04 | 2005-02-04 | |
| US60/649,563 | 2005-02-04 | ||
| US11/345,194 US8013083B2 (en) | 2005-02-04 | 2006-01-31 | Means for controlling the exothermic reaction of styrenic monomers with sulfonic acids |
| PCT/US2006/003487 WO2006083923A1 (en) | 2005-02-04 | 2006-01-31 | Means for controlling the exothermic reaction of styrenic monomers with sulfonic acids |
| US11/345,194 | 2006-01-31 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2008530269A JP2008530269A (ja) | 2008-08-07 |
| JP2008530269A5 true JP2008530269A5 (enExample) | 2010-06-17 |
| JP4686550B2 JP4686550B2 (ja) | 2011-05-25 |
Family
ID=36592989
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2007554176A Expired - Fee Related JP4686550B2 (ja) | 2005-02-04 | 2006-01-31 | スチレン系単量体とスルホン酸との発熱反応を制御する手段 |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US8013083B2 (enExample) |
| EP (1) | EP1843995B1 (enExample) |
| JP (1) | JP4686550B2 (enExample) |
| KR (1) | KR101276975B1 (enExample) |
| CN (1) | CN101115699B (enExample) |
| BR (1) | BRPI0606801A2 (enExample) |
| CA (1) | CA2593400C (enExample) |
| ES (1) | ES2441429T3 (enExample) |
| MX (1) | MX2007009236A (enExample) |
| RU (1) | RU2393143C2 (enExample) |
| WO (1) | WO2006083923A1 (enExample) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20070084245A (ko) * | 2004-11-15 | 2007-08-24 | 하쿠토 가부시키가이샤 | 디비닐벤젠 및 방향족 비닐 화합물을 포함하는 공중합체의중합 억제 방법 |
| WO2013098846A1 (en) | 2011-11-29 | 2013-07-04 | Dorf Ketal Chemicals (India) Private Limited | Amine based additive composition for control and inhibition of polymerization of styrene, and method of use thereof |
| PL2797864T3 (pl) * | 2011-12-26 | 2015-11-30 | Dorf Ketal Chemicals India Private Ltd | Ulepszona kompozycja dodatków na bazie amin do kontroli i hamowania polimeryzacji aromatycznych monomerów winylowych oraz sposób jej stosowania |
| CN108341736A (zh) * | 2017-01-23 | 2018-07-31 | 中国石油化工股份有限公司 | 一种复配阻聚剂及其应用 |
| JP7384818B2 (ja) | 2018-04-02 | 2023-11-21 | ポリグリーン リミテッド | 不織布処理用の液体ポリマー溶液 |
| EP3775037B1 (en) | 2018-04-02 | 2025-06-25 | Polygreen Ltd. | Process for the production of biodegradable superabsorbent polymer with high absorbency under load based on styrene maleic acid copolymers and biopolymer |
| TW202005938A (zh) * | 2018-07-13 | 2020-02-01 | 美商藝康美國公司 | 具有胺穩定劑之聚合抑制劑及阻滯劑組合物 |
| CN113272406B (zh) | 2018-11-13 | 2023-03-24 | 聚合物绿色有限责任公司 | 在农作物浇水期间吸水性提高的用作土壤改良剂的聚合物组合物 |
Family Cites Families (39)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US665344A (en) * | 1900-04-02 | 1901-01-01 | Anders Andersen Pindstofte | Apparatus for automatically washing bottles. |
| US2046356A (en) | 1933-12-27 | 1936-07-07 | Ici Ltd | Manufacture of diarylamine derivatives |
| US2522680A (en) * | 1949-07-20 | 1950-09-19 | American Cyanamid Co | Polymerizable dioxolane compound, products prepared therefrom, and methods of preparation |
| US2867672A (en) | 1955-08-29 | 1959-01-06 | Shell Dev | Method of minimizing styrene polymerization during storage |
| NL296169A (enExample) | 1962-08-14 | |||
| JPS52153817A (en) | 1976-06-18 | 1977-12-21 | Masatoshi Tsuda | Flux for modification of proeutectic silicon in the high silicon aluminium alloy |
| US4086147A (en) | 1976-12-10 | 1978-04-25 | Cosden Technology, Inc. | Polymerization inhibitor for vinyl aromatic compounds |
| US4468343A (en) | 1983-04-11 | 1984-08-28 | Cosden Technology, Inc. | Polymerization co-inhibitors for vinyl aromatic compounds |
| US4670131A (en) * | 1986-01-13 | 1987-06-02 | Exxon Chemical Patents Inc. | Method for controlling fouling of hydrocarbon compositions containing olefinic compounds |
| US4654450A (en) * | 1986-02-24 | 1987-03-31 | Atlantic Richfield Company | Inhibiting polymerization of vinyl aromatic monomers |
| US5023372A (en) | 1989-05-16 | 1991-06-11 | Betz Laboratories, Inc. | Methods and compositions for inhibiting (meth)acrylic acid polymerization |
| US5290888A (en) | 1990-07-20 | 1994-03-01 | Ciba-Geigy Corporation | Process for stabilizing ethylenically unsaturated compounds and stabilized monomer compositions |
| US5212272A (en) * | 1990-10-31 | 1993-05-18 | Peach State Labs, Inc. | Polyacrylic acid compositions for textile processing |
| US5254760A (en) | 1992-07-29 | 1993-10-19 | Ciba-Geigy Corporation | Inhibiting polymerization of vinyl aromatic monomers |
| JP3545440B2 (ja) * | 1993-12-16 | 2004-07-21 | 伯東株式会社 | 芳香族不飽和化合物の粘度上昇抑制剤およびその方法 |
| US5824829A (en) * | 1993-12-16 | 1998-10-20 | Baker Hughes Incorporated | Hydrocarbon viscosity inhibitor and inhibiting method |
| US5728872A (en) | 1994-06-27 | 1998-03-17 | Lutz Riemenschneider | Stabilized acrylic acid compositions |
| US5446220A (en) * | 1994-08-24 | 1995-08-29 | Betz Laboratories, Inc. | Methods for inhibiting vinyl aromatic monomer polymerization |
| JP3673292B2 (ja) | 1994-07-27 | 2005-07-20 | 伯東株式会社 | ビニル化合物を扱う工程でのファウリング防止方法 |
| US5545786C1 (en) | 1994-11-28 | 2001-10-16 | Ciba Geigy Corp | Method for inhibiting premature polymerization of vinyl aromatic monomers |
| RU2127243C1 (ru) * | 1995-02-03 | 1999-03-10 | Циба Спешиалти Чемикалс Холдинг Инк. | Композиция, предупреждающая преждевременную полимеризацию, и способ ингибирования преждевременной полимеризации |
| US5590232A (en) | 1995-02-16 | 1996-12-31 | Motorola, Inc. | Optical package and method of making |
| DE19510184A1 (de) | 1995-03-21 | 1996-09-26 | Basf Ag | 4-Acylaminopiperidin-N-oxyle |
| US5648573A (en) | 1995-06-12 | 1997-07-15 | Betzdearborn Inc. | Compositions and methods for inhibiting vinyl aromatic monomer polymerization |
| EP0906257B2 (de) | 1996-06-05 | 2010-04-07 | Basf Se | Mischungen, enthaltend monomere und stabilisatoren |
| DE19651307A1 (de) | 1996-12-10 | 1998-06-18 | Basf Ag | Stoffmischungen, enthaltend vinylgruppenhaltige Verbindungen und Stabilisatoren |
| US5932735A (en) | 1997-06-13 | 1999-08-03 | Ciba Specialty Chemicals Corporation | Derivatives of 1-oxyl-4-hydroxy-2,2,6,6-tetramethylpiperidine as polymerization inhibitors for (meth)acrylate monomers |
| US6156858A (en) * | 1997-06-25 | 2000-12-05 | Xerox Corporation | Stable free radical polymerization processes |
| US6136951A (en) | 1999-08-16 | 2000-10-24 | Uniroyal Chemical Company, Inc. | Test method for evaluating insoluble polymer growth |
| DE60023542T2 (de) | 1999-12-02 | 2006-07-20 | Crompton Corp., Middlebury | Polymerisationsinhibierung von ungesättigten monomeren |
| AR029410A1 (es) | 1999-12-02 | 2003-06-25 | Crompton Corp | Metodo para inhibir la polimerizacion prematura de monomeros etilenicamente insaturados y composiciones de los mismos |
| US6685823B2 (en) * | 2000-10-16 | 2004-02-03 | Uniroyal Chemical Company, Inc. | C-nitrosoaniline compounds and their blends as polymerization inhibitors |
| US7045647B2 (en) | 2000-10-16 | 2006-05-16 | Uniroyal Chemical Company, Inc. | Blends of quinone alkide and nitroxyl compounds and polymerization inhibitors |
| JP3788950B2 (ja) | 2001-04-25 | 2006-06-21 | 伯東株式会社 | 芳香族ビニル化合物の重合抑制方法 |
| JP4223222B2 (ja) * | 2002-03-19 | 2009-02-12 | 伯東株式会社 | 芳香族ビニル化合物の重合抑制方法 |
| JP4165816B2 (ja) * | 2003-03-31 | 2008-10-15 | 伯東株式会社 | 芳香族ビニル化合物の重合抑制剤組成物 |
| JP2004300385A (ja) * | 2003-04-01 | 2004-10-28 | Hakuto Co Ltd | 芳香族ビニル化合物の重合抑制方法 |
| US20060069219A1 (en) * | 2004-09-28 | 2006-03-30 | Vilan Kosover | Sulfonated phenols with nitrophenols as polymerization inhibitors |
| KR20070084245A (ko) * | 2004-11-15 | 2007-08-24 | 하쿠토 가부시키가이샤 | 디비닐벤젠 및 방향족 비닐 화합물을 포함하는 공중합체의중합 억제 방법 |
-
2006
- 2006-01-31 KR KR1020077017634A patent/KR101276975B1/ko not_active Expired - Fee Related
- 2006-01-31 US US11/345,194 patent/US8013083B2/en not_active Expired - Fee Related
- 2006-01-31 JP JP2007554176A patent/JP4686550B2/ja not_active Expired - Fee Related
- 2006-01-31 EP EP06734143.8A patent/EP1843995B1/en not_active Expired - Lifetime
- 2006-01-31 RU RU2007133105/04A patent/RU2393143C2/ru not_active IP Right Cessation
- 2006-01-31 WO PCT/US2006/003487 patent/WO2006083923A1/en not_active Ceased
- 2006-01-31 ES ES06734143.8T patent/ES2441429T3/es not_active Expired - Lifetime
- 2006-01-31 CA CA2593400A patent/CA2593400C/en not_active Expired - Fee Related
- 2006-01-31 CN CN2006800040290A patent/CN101115699B/zh not_active Expired - Fee Related
- 2006-01-31 BR BRPI0606801-4A patent/BRPI0606801A2/pt not_active Application Discontinuation
- 2006-01-31 MX MX2007009236A patent/MX2007009236A/es active IP Right Grant