JP2008530269A5 - - Google Patents
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- Publication number
- JP2008530269A5 JP2008530269A5 JP2007554176A JP2007554176A JP2008530269A5 JP 2008530269 A5 JP2008530269 A5 JP 2008530269A5 JP 2007554176 A JP2007554176 A JP 2007554176A JP 2007554176 A JP2007554176 A JP 2007554176A JP 2008530269 A5 JP2008530269 A5 JP 2008530269A5
- Authority
- JP
- Japan
- Prior art keywords
- group
- sulfonic acid
- acid compound
- inhibitor
- aryl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- -1 sulfonic acid compound Chemical class 0.000 claims description 21
- 125000000217 alkyl group Chemical group 0.000 claims description 20
- 125000003118 aryl group Chemical group 0.000 claims description 15
- 125000000018 nitroso group Chemical group N(=O)* 0.000 claims description 12
- 229910052739 hydrogen Inorganic materials 0.000 claims description 10
- 239000001257 hydrogen Substances 0.000 claims description 10
- 125000002252 acyl group Chemical group 0.000 claims description 9
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 9
- 125000003545 alkoxy group Chemical group 0.000 claims description 6
- 125000000623 heterocyclic group Chemical group 0.000 claims description 6
- 125000000472 sulfonyl group Chemical group *S(*)(=O)=O 0.000 claims description 6
- 125000000753 cycloalkyl group Chemical group 0.000 claims description 5
- 125000004423 acyloxy group Chemical group 0.000 claims description 3
- 229910052736 halogen Inorganic materials 0.000 claims description 3
- 150000002367 halogens Chemical class 0.000 claims description 3
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims description 3
- 239000003112 inhibitor Substances 0.000 claims 12
- 238000000034 method Methods 0.000 claims 12
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 claims 9
- 125000004432 carbon atom Chemical group C* 0.000 claims 7
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 claims 6
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims 6
- 239000000178 monomer Substances 0.000 claims 6
- 150000001412 amines Chemical class 0.000 claims 5
- KOOMFXGDLMRWSN-UHFFFAOYSA-N n-phenylnitrous amide Chemical compound O=NNC1=CC=CC=C1 KOOMFXGDLMRWSN-UHFFFAOYSA-N 0.000 claims 5
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical group C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims 4
- 238000010538 cationic polymerization reaction Methods 0.000 claims 4
- IQUPABOKLQSFBK-UHFFFAOYSA-N 2-nitrophenol Chemical group OC1=CC=CC=C1[N+]([O-])=O IQUPABOKLQSFBK-UHFFFAOYSA-N 0.000 claims 3
- 125000005037 alkyl phenyl group Chemical group 0.000 claims 3
- HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 claims 3
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 claims 3
- IMFACGCPASFAPR-UHFFFAOYSA-N tributylamine Chemical compound CCCCN(CCCC)CCCC IMFACGCPASFAPR-UHFFFAOYSA-N 0.000 claims 3
- OWZPCEFYPSAJFR-UHFFFAOYSA-N 2-(butan-2-yl)-4,6-dinitrophenol Chemical group CCC(C)C1=CC([N+]([O-])=O)=CC([N+]([O-])=O)=C1O OWZPCEFYPSAJFR-UHFFFAOYSA-N 0.000 claims 2
- 238000006243 chemical reaction Methods 0.000 claims 2
- 150000001875 compounds Chemical class 0.000 claims 2
- 238000004519 manufacturing process Methods 0.000 claims 2
- 238000006116 polymerization reaction Methods 0.000 claims 2
- 230000002028 premature Effects 0.000 claims 2
- 238000000746 purification Methods 0.000 claims 2
- 125000001624 naphthyl group Chemical group 0.000 claims 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims 1
- 150000002431 hydrogen Chemical class 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US64956305P | 2005-02-04 | 2005-02-04 | |
| US60/649,563 | 2005-02-04 | ||
| PCT/US2006/003487 WO2006083923A1 (en) | 2005-02-04 | 2006-01-31 | Means for controlling the exothermic reaction of styrenic monomers with sulfonic acids |
| US11/345,194 US8013083B2 (en) | 2005-02-04 | 2006-01-31 | Means for controlling the exothermic reaction of styrenic monomers with sulfonic acids |
| US11/345,194 | 2006-01-31 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2008530269A JP2008530269A (ja) | 2008-08-07 |
| JP2008530269A5 true JP2008530269A5 (enExample) | 2010-06-17 |
| JP4686550B2 JP4686550B2 (ja) | 2011-05-25 |
Family
ID=36592989
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2007554176A Expired - Fee Related JP4686550B2 (ja) | 2005-02-04 | 2006-01-31 | スチレン系単量体とスルホン酸との発熱反応を制御する手段 |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US8013083B2 (enExample) |
| EP (1) | EP1843995B1 (enExample) |
| JP (1) | JP4686550B2 (enExample) |
| KR (1) | KR101276975B1 (enExample) |
| CN (1) | CN101115699B (enExample) |
| BR (1) | BRPI0606801A2 (enExample) |
| CA (1) | CA2593400C (enExample) |
| ES (1) | ES2441429T3 (enExample) |
| MX (1) | MX2007009236A (enExample) |
| RU (1) | RU2393143C2 (enExample) |
| WO (1) | WO2006083923A1 (enExample) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPWO2006051941A1 (ja) * | 2004-11-15 | 2008-05-29 | 伯東株式会社 | ジビニルベンゼンと芳香族ビニル化合物を含む共重合体の重合抑制方法 |
| RU2612507C2 (ru) * | 2011-11-29 | 2017-03-09 | Дорф Кетал Кемикалс (Индия) Прайвит Лимитэд | Композиция добавки на основе амина для контроля и ингибирования полимеризации стирола и способ ее использования |
| ES2547893T3 (es) * | 2011-12-26 | 2015-10-09 | Dorf Ketal Chemicals (India) Private Limited | Composición de aditivo mejorada a base de amina para el control y la inhibición de la polimerización de monómeros aromáticos de vinilo, y procedimiento para su uso |
| CN108341736A (zh) * | 2017-01-23 | 2018-07-31 | 中国石油化工股份有限公司 | 一种复配阻聚剂及其应用 |
| EP3773388A4 (en) | 2018-04-02 | 2022-01-19 | Polygreen Ltd. | LIQUID POLYMER SOLUTION FOR THE TREATMENT OF NON-WOVEN WEBS |
| WO2019195272A1 (en) | 2018-04-02 | 2019-10-10 | Green Polymers Ltd. | Process for the production of biodegradable superabsorbent polymer with high absorbency under load based on styrene maleic acid copolymers and biopolymer |
| US11180578B2 (en) * | 2018-07-13 | 2021-11-23 | Ecolab Usa Inc. | Polymerization inhibitor and retarder compositions with amine stabilizer |
| US12129419B2 (en) | 2018-11-13 | 2024-10-29 | Polygreen Ltd | Polymeric composition for use as soil conditioner with improved water absorbency during watering of the agricultural crops |
Family Cites Families (39)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US665344A (en) * | 1900-04-02 | 1901-01-01 | Anders Andersen Pindstofte | Apparatus for automatically washing bottles. |
| US2046356A (en) | 1933-12-27 | 1936-07-07 | Ici Ltd | Manufacture of diarylamine derivatives |
| US2522680A (en) * | 1949-07-20 | 1950-09-19 | American Cyanamid Co | Polymerizable dioxolane compound, products prepared therefrom, and methods of preparation |
| US2867672A (en) * | 1955-08-29 | 1959-01-06 | Shell Dev | Method of minimizing styrene polymerization during storage |
| NL137479C (enExample) * | 1962-08-14 | |||
| JPS52153817A (en) * | 1976-06-18 | 1977-12-21 | Masatoshi Tsuda | Flux for modification of proeutectic silicon in the high silicon aluminium alloy |
| US4086147A (en) * | 1976-12-10 | 1978-04-25 | Cosden Technology, Inc. | Polymerization inhibitor for vinyl aromatic compounds |
| US4468343A (en) * | 1983-04-11 | 1984-08-28 | Cosden Technology, Inc. | Polymerization co-inhibitors for vinyl aromatic compounds |
| US4670131A (en) * | 1986-01-13 | 1987-06-02 | Exxon Chemical Patents Inc. | Method for controlling fouling of hydrocarbon compositions containing olefinic compounds |
| US4654450A (en) * | 1986-02-24 | 1987-03-31 | Atlantic Richfield Company | Inhibiting polymerization of vinyl aromatic monomers |
| US5023372A (en) | 1989-05-16 | 1991-06-11 | Betz Laboratories, Inc. | Methods and compositions for inhibiting (meth)acrylic acid polymerization |
| US5290888A (en) * | 1990-07-20 | 1994-03-01 | Ciba-Geigy Corporation | Process for stabilizing ethylenically unsaturated compounds and stabilized monomer compositions |
| US5212272A (en) * | 1990-10-31 | 1993-05-18 | Peach State Labs, Inc. | Polyacrylic acid compositions for textile processing |
| US5254760A (en) | 1992-07-29 | 1993-10-19 | Ciba-Geigy Corporation | Inhibiting polymerization of vinyl aromatic monomers |
| JP3545440B2 (ja) * | 1993-12-16 | 2004-07-21 | 伯東株式会社 | 芳香族不飽和化合物の粘度上昇抑制剤およびその方法 |
| US5824829A (en) * | 1993-12-16 | 1998-10-20 | Baker Hughes Incorporated | Hydrocarbon viscosity inhibitor and inhibiting method |
| US5728872A (en) | 1994-06-27 | 1998-03-17 | Lutz Riemenschneider | Stabilized acrylic acid compositions |
| US5446220A (en) * | 1994-08-24 | 1995-08-29 | Betz Laboratories, Inc. | Methods for inhibiting vinyl aromatic monomer polymerization |
| JP3673292B2 (ja) | 1994-07-27 | 2005-07-20 | 伯東株式会社 | ビニル化合物を扱う工程でのファウリング防止方法 |
| US5545786C1 (en) | 1994-11-28 | 2001-10-16 | Ciba Geigy Corp | Method for inhibiting premature polymerization of vinyl aromatic monomers |
| RU2127243C1 (ru) * | 1995-02-03 | 1999-03-10 | Циба Спешиалти Чемикалс Холдинг Инк. | Композиция, предупреждающая преждевременную полимеризацию, и способ ингибирования преждевременной полимеризации |
| US5590232A (en) * | 1995-02-16 | 1996-12-31 | Motorola, Inc. | Optical package and method of making |
| DE19510184A1 (de) * | 1995-03-21 | 1996-09-26 | Basf Ag | 4-Acylaminopiperidin-N-oxyle |
| US5648573A (en) * | 1995-06-12 | 1997-07-15 | Betzdearborn Inc. | Compositions and methods for inhibiting vinyl aromatic monomer polymerization |
| WO1997046504A1 (de) * | 1996-06-05 | 1997-12-11 | Basf Aktiengesellschaft | Mischungen, enthaltend monomere und stabilisatoren |
| DE19651307A1 (de) | 1996-12-10 | 1998-06-18 | Basf Ag | Stoffmischungen, enthaltend vinylgruppenhaltige Verbindungen und Stabilisatoren |
| US5932735A (en) * | 1997-06-13 | 1999-08-03 | Ciba Specialty Chemicals Corporation | Derivatives of 1-oxyl-4-hydroxy-2,2,6,6-tetramethylpiperidine as polymerization inhibitors for (meth)acrylate monomers |
| US6156858A (en) * | 1997-06-25 | 2000-12-05 | Xerox Corporation | Stable free radical polymerization processes |
| US6136951A (en) * | 1999-08-16 | 2000-10-24 | Uniroyal Chemical Company, Inc. | Test method for evaluating insoluble polymer growth |
| KR100715592B1 (ko) | 1999-12-02 | 2007-05-10 | 켐트라 코포레이션 | 불포화 모노머의 중합 억제방법 |
| AR029410A1 (es) * | 1999-12-02 | 2003-06-25 | Crompton Corp | Metodo para inhibir la polimerizacion prematura de monomeros etilenicamente insaturados y composiciones de los mismos |
| US7045647B2 (en) * | 2000-10-16 | 2006-05-16 | Uniroyal Chemical Company, Inc. | Blends of quinone alkide and nitroxyl compounds and polymerization inhibitors |
| US6685823B2 (en) * | 2000-10-16 | 2004-02-03 | Uniroyal Chemical Company, Inc. | C-nitrosoaniline compounds and their blends as polymerization inhibitors |
| JP3788950B2 (ja) * | 2001-04-25 | 2006-06-21 | 伯東株式会社 | 芳香族ビニル化合物の重合抑制方法 |
| JP4223222B2 (ja) * | 2002-03-19 | 2009-02-12 | 伯東株式会社 | 芳香族ビニル化合物の重合抑制方法 |
| JP4165816B2 (ja) | 2003-03-31 | 2008-10-15 | 伯東株式会社 | 芳香族ビニル化合物の重合抑制剤組成物 |
| JP2004300385A (ja) * | 2003-04-01 | 2004-10-28 | Hakuto Co Ltd | 芳香族ビニル化合物の重合抑制方法 |
| US20060069219A1 (en) * | 2004-09-28 | 2006-03-30 | Vilan Kosover | Sulfonated phenols with nitrophenols as polymerization inhibitors |
| JPWO2006051941A1 (ja) * | 2004-11-15 | 2008-05-29 | 伯東株式会社 | ジビニルベンゼンと芳香族ビニル化合物を含む共重合体の重合抑制方法 |
-
2006
- 2006-01-31 CA CA2593400A patent/CA2593400C/en not_active Expired - Fee Related
- 2006-01-31 MX MX2007009236A patent/MX2007009236A/es active IP Right Grant
- 2006-01-31 KR KR1020077017634A patent/KR101276975B1/ko not_active Expired - Fee Related
- 2006-01-31 JP JP2007554176A patent/JP4686550B2/ja not_active Expired - Fee Related
- 2006-01-31 US US11/345,194 patent/US8013083B2/en not_active Expired - Fee Related
- 2006-01-31 BR BRPI0606801-4A patent/BRPI0606801A2/pt not_active Application Discontinuation
- 2006-01-31 EP EP06734143.8A patent/EP1843995B1/en not_active Expired - Lifetime
- 2006-01-31 RU RU2007133105/04A patent/RU2393143C2/ru not_active IP Right Cessation
- 2006-01-31 WO PCT/US2006/003487 patent/WO2006083923A1/en not_active Ceased
- 2006-01-31 ES ES06734143.8T patent/ES2441429T3/es not_active Expired - Lifetime
- 2006-01-31 CN CN2006800040290A patent/CN101115699B/zh not_active Expired - Fee Related
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