JP2008208044A - 日焼け止め化粧料 - Google Patents
日焼け止め化粧料 Download PDFInfo
- Publication number
- JP2008208044A JP2008208044A JP2007044222A JP2007044222A JP2008208044A JP 2008208044 A JP2008208044 A JP 2008208044A JP 2007044222 A JP2007044222 A JP 2007044222A JP 2007044222 A JP2007044222 A JP 2007044222A JP 2008208044 A JP2008208044 A JP 2008208044A
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- JP
- Japan
- Prior art keywords
- water
- oil
- ultraviolet
- sunscreen cosmetic
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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Abstract
【解決手段】紫外線散乱剤としての酸化チタン及び酸化亜鉛をポリエーテル変性シリコーンにて予め湿式方法にてコーティングして前処理粉体とし、更に、揮発性油剤、エラストマーオルガノポリシロキサン、セチルジメチコンを含有することで非常に高い紫外線防御効果(SPF50+ PA+++)を有した紫外線吸収剤を含まない油中水型日焼け止め化粧料を得ることが可能となる。
Description
PA+++)日焼け止め化粧料が存在したとしても、使用時において、「白さが目立つ」や「分散不良などの状態変化」等の問題点を有している。
以下に示す処方に従って、本発明の有機系紫外線吸収剤を含まない油中水型日焼け止め化粧料を作製した。(実施例1〜3)即ち、本発明の紫外線散乱剤としての酸化チタン及び酸化亜鉛を予めポリエーテル変性シリコーンにより湿式方法にてコーティングして前処理粉体とし、更に、揮発性油剤、エラストマーオルガノポリシロキサン、セチルジメチコンの油相成分と混合した後、3本ロールにかけ分散相とし、ディスパーで撹拌しながら水相を徐々に加え、充分均一に混合撹拌して本発明の有機系紫外線吸収剤を含まない油中水型日焼け止め化粧料を得た。また、その比較として従来製法により有機系紫外線吸収剤を含まない油中水型日焼け止め化粧料を作製した。(比較例1〜3)即ち、本発明の紫外線散乱剤としての酸化チタン及び酸化亜鉛をポリエーテル変性シリコーンで予めコーティングする前処理を行なわない方法で作製した。なお、各成分の配合割合は断りのない限り重量部である。
◎:たいへん良い、○:良い、△:普通、×:やや悪い、××:悪い
以下に示す処方に従って、本発明の有機系紫外線吸収剤を含まない油中水型日焼け止め化粧料を作製した。(実施例4〜15)即ち、本発明の紫外線散乱剤としての酸化チタン及び酸化亜鉛をポリエーテル変性シリコーンにより湿式方法にて予めコーティングして前処理粉体とし、更に揮発性油剤、エラストマーオルガノポリシロキサン、セチルジメチコンの油相成分と混合した後、3本ロールにかけ分散相とし、ディスパーで撹拌しながら水相を徐々に加え、充分均一に混合撹拌し、本発明の有機系紫外線吸収剤を含まない油中水型日焼け止め化粧料を得た。また、その比較として従来汎用されていた分散剤を用い、紫外線吸収剤を含まない油中水型日焼け止め化粧料を作製した。(比較例4〜15)なお、各成分の配合割合は断りのない限り重量部である。
◎:たいへん良い、○:良い、△:普通、×:やや悪い、××:悪い
Claims (3)
- ポリエーテル変性シリコーン、酸化チタン及び酸化亜鉛、揮発性油剤、エラストマーオルガノポリシロキサン及びセチルジメチコンを含有することを特徴とする紫外線吸収剤を含まない油中水型日焼け止め化粧料。
- 上記ポリエーテル変性シリコーンが、PEG−9ポリジメチルシロキシエチルジメチコン、ラウリルPEG−9ポリジメチルシロキシエチルジメチコンから選択される1種又は2種以上を含有することを特徴とする請求項1記載の紫外線吸収剤を含まない油中水型日焼け止め化粧料。
- ポリエーテル変性シリコーンの配合量が1〜7重量%、酸化チタンの配合量が7〜15重量%及び酸化亜鉛の配合量が5〜20重量%、揮発性油剤の配合量が20〜40重量%、エラストマーオルガノポリシロキサンの配合量が0.1〜1重量%、セチルジメチコンの配合量が0.05〜0.5重量%であることを特徴とする請求項1乃至請求項2記載の紫外線吸収剤を含まない油中水型日焼け止め化粧料。
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2010195694A (ja) * | 2009-02-24 | 2010-09-09 | Miyoshi Kasei Inc | 粉体分散物とこの粉体分散物を含有する化粧料 |
JP2018027902A (ja) * | 2016-08-16 | 2018-02-22 | 株式会社希松 | 液晶組成物、及び液晶組成物が配合された化粧料 |
WO2021153704A1 (ja) | 2020-01-31 | 2021-08-05 | 花王株式会社 | 油中水型乳化化粧料 |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2001058926A (ja) * | 1999-08-20 | 2001-03-06 | Kose Corp | 粉体組成物及び油中粉体分散物並びにそれらを含有する化粧料 |
WO2003024413A1 (fr) * | 2001-09-14 | 2003-03-27 | Shin-Etsu Chemical Co., Ltd. | Composition et preparation cosmetique contenant ladite composition |
JP2004169015A (ja) * | 2002-11-01 | 2004-06-17 | Shin Etsu Chem Co Ltd | 粉体組成物及び油中粉体分散物.並びにそれらを有する化粧料 |
JP2007001867A (ja) * | 2005-06-21 | 2007-01-11 | Pola Chem Ind Inc | 乳化分散化粧料 |
WO2007017921A1 (ja) * | 2005-08-05 | 2007-02-15 | Shiseido Company, Ltd. | セルフタンニング化粧料 |
-
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Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2001058926A (ja) * | 1999-08-20 | 2001-03-06 | Kose Corp | 粉体組成物及び油中粉体分散物並びにそれらを含有する化粧料 |
WO2003024413A1 (fr) * | 2001-09-14 | 2003-03-27 | Shin-Etsu Chemical Co., Ltd. | Composition et preparation cosmetique contenant ladite composition |
JP2004169015A (ja) * | 2002-11-01 | 2004-06-17 | Shin Etsu Chem Co Ltd | 粉体組成物及び油中粉体分散物.並びにそれらを有する化粧料 |
JP2007001867A (ja) * | 2005-06-21 | 2007-01-11 | Pola Chem Ind Inc | 乳化分散化粧料 |
WO2007017921A1 (ja) * | 2005-08-05 | 2007-02-15 | Shiseido Company, Ltd. | セルフタンニング化粧料 |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2010195694A (ja) * | 2009-02-24 | 2010-09-09 | Miyoshi Kasei Inc | 粉体分散物とこの粉体分散物を含有する化粧料 |
JP2018027902A (ja) * | 2016-08-16 | 2018-02-22 | 株式会社希松 | 液晶組成物、及び液晶組成物が配合された化粧料 |
WO2021153704A1 (ja) | 2020-01-31 | 2021-08-05 | 花王株式会社 | 油中水型乳化化粧料 |
KR20220123042A (ko) | 2020-01-31 | 2022-09-05 | 카오카부시키가이샤 | 유중수형 유화 화장료 |
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