JP2008156235A - エアゾル殺虫剤 - Google Patents
エアゾル殺虫剤 Download PDFInfo
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- JP2008156235A JP2008156235A JP2006343204A JP2006343204A JP2008156235A JP 2008156235 A JP2008156235 A JP 2008156235A JP 2006343204 A JP2006343204 A JP 2006343204A JP 2006343204 A JP2006343204 A JP 2006343204A JP 2008156235 A JP2008156235 A JP 2008156235A
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- 239000000443 aerosol Substances 0.000 title claims abstract description 39
- 239000002917 insecticide Substances 0.000 title claims abstract description 31
- 239000007788 liquid Substances 0.000 claims abstract description 53
- 239000002245 particle Substances 0.000 claims abstract description 34
- 230000000749 insecticidal effect Effects 0.000 claims abstract description 29
- 239000003380 propellant Substances 0.000 claims abstract description 18
- 239000004480 active ingredient Substances 0.000 claims abstract description 17
- 230000005484 gravity Effects 0.000 claims abstract description 13
- 239000002904 solvent Substances 0.000 claims abstract description 9
- 241000257303 Hymenoptera Species 0.000 claims description 11
- 239000010419 fine particle Substances 0.000 claims description 8
- 241000239290 Araneae Species 0.000 claims description 3
- 241000320508 Pentatomidae Species 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 2
- 241000256856 Vespidae Species 0.000 abstract description 7
- 241000238631 Hexapoda Species 0.000 abstract description 4
- 230000000694 effects Effects 0.000 abstract description 3
- 239000004615 ingredient Substances 0.000 abstract description 2
- 238000003197 gene knockdown Methods 0.000 abstract 1
- 238000005507 spraying Methods 0.000 description 9
- 238000002347 injection Methods 0.000 description 8
- 239000007924 injection Substances 0.000 description 8
- 239000007921 spray Substances 0.000 description 8
- 239000007789 gas Substances 0.000 description 7
- -1 empentrin Chemical compound 0.000 description 5
- RGSFGYAAUTVSQA-UHFFFAOYSA-N Cyclopentane Chemical compound C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 4
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 4
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 4
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 4
- QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 description 4
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- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
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- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 150000001298 alcohols Chemical class 0.000 description 3
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 239000002728 pyrethroid Substances 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 239000000073 carbamate insecticide Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- RWRIWBAIICGTTQ-UHFFFAOYSA-N difluoromethane Chemical compound FCF RWRIWBAIICGTTQ-UHFFFAOYSA-N 0.000 description 2
- AFABGHUZZDYHJO-UHFFFAOYSA-N dimethyl butane Natural products CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 description 2
- 150000002170 ethers Chemical class 0.000 description 2
- DMEGYFMYUHOHGS-UHFFFAOYSA-N heptamethylene Natural products C1CCCCCC1 DMEGYFMYUHOHGS-UHFFFAOYSA-N 0.000 description 2
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 2
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- 239000003915 liquefied petroleum gas Substances 0.000 description 2
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- 239000000575 pesticide Substances 0.000 description 2
- DDVNRFNDOPPVQJ-HQJQHLMTSA-N transfluthrin Chemical compound CC1(C)[C@H](C=C(Cl)Cl)[C@H]1C(=O)OCC1=C(F)C(F)=CC(F)=C1F DDVNRFNDOPPVQJ-HQJQHLMTSA-N 0.000 description 2
- ZCVAOQKBXKSDMS-AQYZNVCMSA-N (+)-trans-allethrin Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OC1C(C)=C(CC=C)C(=O)C1 ZCVAOQKBXKSDMS-AQYZNVCMSA-N 0.000 description 1
- SBNFWQZLDJGRLK-RTWAWAEBSA-N (1R)-trans-phenothrin Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OCC1=CC=CC(OC=2C=CC=CC=2)=C1 SBNFWQZLDJGRLK-RTWAWAEBSA-N 0.000 description 1
- ZFHGXWPMULPQSE-SZGBIDFHSA-N (Z)-(1S)-cis-tefluthrin Chemical compound FC1=C(F)C(C)=C(F)C(F)=C1COC(=O)[C@@H]1C(C)(C)[C@@H]1\C=C(/Cl)C(F)(F)F ZFHGXWPMULPQSE-SZGBIDFHSA-N 0.000 description 1
- LNJXZKBHJZAIKQ-UHFFFAOYSA-N 1,1,1,2-tetrachloro-3-(2,3,3,3-tetrachloropropoxy)propane Chemical compound ClC(Cl)(Cl)C(Cl)COCC(Cl)C(Cl)(Cl)Cl LNJXZKBHJZAIKQ-UHFFFAOYSA-N 0.000 description 1
- LVGUZGTVOIAKKC-UHFFFAOYSA-N 1,1,1,2-tetrafluoroethane Chemical compound FCC(F)(F)F LVGUZGTVOIAKKC-UHFFFAOYSA-N 0.000 description 1
- UJPMYEOUBPIPHQ-UHFFFAOYSA-N 1,1,1-trifluoroethane Chemical compound CC(F)(F)F UJPMYEOUBPIPHQ-UHFFFAOYSA-N 0.000 description 1
- GNEPLYVYORHREW-UHFFFAOYSA-N 1,1,3,3,6-pentamethyl-7-nitro-2h-inden-5-amine Chemical compound CC1=C(N)C=C2C(C)(C)CC(C)(C)C2=C1[N+]([O-])=O GNEPLYVYORHREW-UHFFFAOYSA-N 0.000 description 1
- NPNPZTNLOVBDOC-UHFFFAOYSA-N 1,1-difluoroethane Chemical compound CC(F)F NPNPZTNLOVBDOC-UHFFFAOYSA-N 0.000 description 1
- FMTFEIJHMMQUJI-NJAFHUGGSA-N 102130-98-3 Natural products CC=CCC1=C(C)[C@H](CC1=O)OC(=O)[C@@H]1[C@@H](C=C(C)C)C1(C)C FMTFEIJHMMQUJI-NJAFHUGGSA-N 0.000 description 1
- OAYXUHPQHDHDDZ-UHFFFAOYSA-N 2-(2-butoxyethoxy)ethanol Chemical compound CCCCOCCOCCO OAYXUHPQHDHDDZ-UHFFFAOYSA-N 0.000 description 1
- MDDVEUPIZIKAJU-UHFFFAOYSA-N 3-methyl-4-pent-2-enylpyrrolidine-2,5-dione Chemical compound CCC=CCC1C(C)C(=O)NC1=O MDDVEUPIZIKAJU-UHFFFAOYSA-N 0.000 description 1
- HIQIXEFWDLTDED-UHFFFAOYSA-N 4-hydroxy-1-piperidin-4-ylpyrrolidin-2-one Chemical compound O=C1CC(O)CN1C1CCNCC1 HIQIXEFWDLTDED-UHFFFAOYSA-N 0.000 description 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
- FIPWRIJSWJWJAI-UHFFFAOYSA-N Butyl carbitol 6-propylpiperonyl ether Chemical compound C1=C(CCC)C(COCCOCCOCCCC)=CC2=C1OCO2 FIPWRIJSWJWJAI-UHFFFAOYSA-N 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 239000005944 Chlorpyrifos Substances 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical class CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 241000258937 Hemiptera Species 0.000 description 1
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 239000005939 Tefluthrin Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 229940024113 allethrin Drugs 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 230000006399 behavior Effects 0.000 description 1
- FYZBOYWSHKHDMT-UHFFFAOYSA-N benfuracarb Chemical compound CCOC(=O)CCN(C(C)C)SN(C)C(=O)OC1=CC=CC2=C1OC(C)(C)C2 FYZBOYWSHKHDMT-UHFFFAOYSA-N 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- 235000012216 bentonite Nutrition 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 229960005286 carbaryl Drugs 0.000 description 1
- CVXBEEMKQHEXEN-UHFFFAOYSA-N carbaryl Chemical compound C1=CC=C2C(OC(=O)NC)=CC=CC2=C1 CVXBEEMKQHEXEN-UHFFFAOYSA-N 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- KYKAJFCTULSVSH-UHFFFAOYSA-N chloro(fluoro)methane Chemical compound F[C]Cl KYKAJFCTULSVSH-UHFFFAOYSA-N 0.000 description 1
- SBPBAQFWLVIOKP-UHFFFAOYSA-N chlorpyrifos Chemical compound CCOP(=S)(OCC)OC1=NC(Cl)=C(Cl)C=C1Cl SBPBAQFWLVIOKP-UHFFFAOYSA-N 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 235000012343 cottonseed oil Nutrition 0.000 description 1
- 239000002385 cottonseed oil Substances 0.000 description 1
- OEBRKCOSUFCWJD-UHFFFAOYSA-N dichlorvos Chemical compound COP(=O)(OC)OC=C(Cl)Cl OEBRKCOSUFCWJD-UHFFFAOYSA-N 0.000 description 1
- 229950001327 dichlorvos Drugs 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- KWKXNDCHNDYVRT-UHFFFAOYSA-N dodecylbenzene Chemical compound CCCCCCCCCCCCC1=CC=CC=C1 KWKXNDCHNDYVRT-UHFFFAOYSA-N 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- ZNOLGFHPUIJIMJ-UHFFFAOYSA-N fenitrothion Chemical compound COP(=S)(OC)OC1=CC=C([N+]([O-])=O)C(C)=C1 ZNOLGFHPUIJIMJ-UHFFFAOYSA-N 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000001863 hydroxypropyl cellulose Substances 0.000 description 1
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 description 1
- VPRAQYXPZIFIOH-UHFFFAOYSA-N imiprothrin Chemical compound CC1(C)C(C=C(C)C)C1C(=O)OCN1C(=O)N(CC#C)CC1=O VPRAQYXPZIFIOH-UHFFFAOYSA-N 0.000 description 1
- 239000001282 iso-butane Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000012046 mixed solvent Substances 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- GTLACDSXYULKMZ-UHFFFAOYSA-N pentafluoroethane Chemical compound FC(F)C(F)(F)F GTLACDSXYULKMZ-UHFFFAOYSA-N 0.000 description 1
- 229960000490 permethrin Drugs 0.000 description 1
- RLLPVAHGXHCWKJ-UHFFFAOYSA-N permethrin Chemical compound CC1(C)C(C=C(Cl)Cl)C1C(=O)OCC1=CC=CC(OC=2C=CC=CC=2)=C1 RLLPVAHGXHCWKJ-UHFFFAOYSA-N 0.000 description 1
- 229960003536 phenothrin Drugs 0.000 description 1
- 229960005235 piperonyl butoxide Drugs 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 229940108410 resmethrin Drugs 0.000 description 1
- VEMKTZHHVJILDY-FIWHBWSRSA-N resmethrin Chemical compound CC1(C)[C@H](C=C(C)C)C1C(=O)OCC1=COC(CC=2C=CC=CC=2)=C1 VEMKTZHHVJILDY-FIWHBWSRSA-N 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 230000000391 smoking effect Effects 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 239000011550 stock solution Substances 0.000 description 1
- 229960005199 tetramethrin Drugs 0.000 description 1
- CXBMCYHAMVGWJQ-UHFFFAOYSA-N tetramethrin Chemical compound CC1(C)C(C=C(C)C)C1C(=O)OCN1C(=O)C(CCCC2)=C2C1=O CXBMCYHAMVGWJQ-UHFFFAOYSA-N 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- YWSCPYYRJXKUDB-KAKFPZCNSA-N tralomethrin Chemical compound CC1(C)[C@@H](C(Br)C(Br)(Br)Br)[C@H]1C(=O)O[C@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 YWSCPYYRJXKUDB-KAKFPZCNSA-N 0.000 description 1
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- 239000008158 vegetable oil Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
【解決手段】 殺虫有効成分およびその溶剤と噴射剤とを含有する液体を弁付き容器に封入してなり、前記噴射剤の圧力によって液体を弁からエアゾル状態に放出可能なエアゾル殺虫剤において、前記液体が、粘度(20℃)が0.002〜0.004Pasであり、比重(20℃)0.76〜0.80であり、かつ引火点が70℃以上に調整された液体を採用したエアゾル殺虫剤とする。5mを越える安全な距離から殺虫成分を噴霧して、いわゆるノックダウンと称されるスズメバチに対する1分以内の即効性が得られる。
【選択図】なし
Description
特に、近年、生息環境の変化により人との接触機会が増えて被害が多発しているハチ類、特にスズメバチに対する駆除をエアゾル殺虫剤で行なうには、このようなハチの攻撃行動について、ヒトが巣の周囲5m以内に近づくと起こるという知見から、噴霧有効距離が5m以上であることが安全のために必要であるにも拘らず、そのようなハチの行動に対処できるエアゾル殺虫剤が存在しなかった。
ピレスロイド系殺虫剤としては、フラメトリン、シフェノトリン、フェノトリン、ペルメトリン、レスメトリン、アレスリン、フタルスリン、トラロメトリン、エムペントリン、テフルスリン、プラレトリン、イミプロトリン、トランスフルスリン(ベンフルスリン)等が挙げられる。
有機リン系殺虫剤としては、フェニトロチオン、クロルピリホス、マラソン、ジクロルボス、ピリダフェンチオン、トリクロルホン等が挙げられる。
カーバメイト系殺虫剤としては、カルバリル、ベンフラカルブ、プロポキスル等を挙げることができる。
そして、上記ピレスロイド系化合物の殺虫効力を増強する化合物(共力剤)としては、例えばピペロニルブトキサイド、オクタクロロジプロピルエーテル、N−(2− エチルヘキシル)−1−イソプロピル−4−メチルビシクロ〔2,2,2〕オクト−5−エン−2,3−ジカルボキシイミド、イソボルニルチオシアノアセテートおよびN−(2−エチニル)−ビシクロ〔2,2,1〕−ヘプタ−5−エン−2,3−ジカルボキシイミドなどが挙げられる。
有効成分としては、実施例1〜3、比較例1、2においてプラレトリン0.2重量%を配合し、実施例4、5および比較例3、4では、プラレトリン0.1重量%およびフタルスリン0.1重量%を配合した。
得られたエアゾル殺虫剤の性能について、試験を行ないその結果を表中に併記した。
Claims (4)
- 殺虫有効成分およびその溶剤と噴射剤とを含有する液体を弁付き容器に封入してなり、前記噴射剤の圧力によって液体を弁からエアゾル状態に放出可能なエアゾル殺虫剤において、
前記液体が、粘度(20℃)0.002〜0.004Pasであり、かつ比重(20℃)0.76〜0.80の液体であることを特徴とするエアゾル殺虫剤。 - 液体が、引火点70℃以上に調整された液体である請求項1に記載のエアゾル殺虫剤。
- エアゾル殺虫剤が、噴射された液体微粒子の飛距離20cmにおける平均粒子径が21〜29μmであるように調整された液体を弁付き容器に封入したものである請求項1または2に記載のエアゾル殺虫剤。
- 液体が、ハチ類、クモ類またはカメムシ類駆除用の殺虫有効成分を含有する液体である請求項1〜3のいずれかに記載のエアゾル殺虫剤。
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JP2006343204A JP5194219B2 (ja) | 2006-12-20 | 2006-12-20 | エアゾル殺虫剤 |
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2011106765A (ja) * | 2009-11-19 | 2011-06-02 | Nippon Koki Co Ltd | 噴射物及びその製造方法 |
WO2014042166A1 (ja) * | 2012-09-13 | 2014-03-20 | 住友化学株式会社 | 液状殺虫組成物 |
JP2015013814A (ja) * | 2013-07-03 | 2015-01-22 | 大日本除蟲菊株式会社 | ハチ防除用塗布型エアゾール剤、及びこれを用いたハチの営巣行動防止方法 |
JP2018177686A (ja) * | 2017-04-12 | 2018-11-15 | フマキラー株式会社 | 飛翔害虫の駆除剤及び駆除方法 |
JPWO2021157271A1 (ja) * | 2020-02-05 | 2021-08-12 |
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2006
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JPS5495733A (en) * | 1977-12-10 | 1979-07-28 | Nippon Nohyaku Co Ltd | Aerosol pesticide composition |
JPS5764601A (en) * | 1980-10-07 | 1982-04-19 | Mikasa Kagaku Kogyo Kk | Animal atrracting and repellent aerosol composition |
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JPWO2014042166A1 (ja) * | 2012-09-13 | 2016-08-18 | 住友化学株式会社 | 液状殺虫組成物 |
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