JP2008136841A - 塩基性悪臭用消臭剤 - Google Patents
塩基性悪臭用消臭剤 Download PDFInfo
- Publication number
- JP2008136841A JP2008136841A JP2007159680A JP2007159680A JP2008136841A JP 2008136841 A JP2008136841 A JP 2008136841A JP 2007159680 A JP2007159680 A JP 2007159680A JP 2007159680 A JP2007159680 A JP 2007159680A JP 2008136841 A JP2008136841 A JP 2008136841A
- Authority
- JP
- Japan
- Prior art keywords
- hexenyl
- cis
- deodorizing
- deodorant
- odor
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 230000001877 deodorizing effect Effects 0.000 title claims abstract description 47
- 239000000126 substance Substances 0.000 claims abstract description 20
- 239000002904 solvent Substances 0.000 claims abstract description 18
- 239000000284 extract Substances 0.000 claims abstract description 14
- 241000196324 Embryophyta Species 0.000 claims abstract description 12
- UHEPJGULSIKKTP-UHFFFAOYSA-N sulcatone Chemical compound CC(C)=CCCC(C)=O UHEPJGULSIKKTP-UHFFFAOYSA-N 0.000 claims abstract description 11
- 238000000034 method Methods 0.000 claims abstract description 10
- WTOYNNBCKUYIKC-JMSVASOKSA-N (+)-nootkatone Chemical compound C1C[C@@H](C(C)=C)C[C@@]2(C)[C@H](C)CC(=O)C=C21 WTOYNNBCKUYIKC-JMSVASOKSA-N 0.000 claims abstract description 9
- UQURIQWAEZGLAC-UHFFFAOYSA-N 2-cyclohexylpropanal Chemical compound O=CC(C)C1CCCCC1 UQURIQWAEZGLAC-UHFFFAOYSA-N 0.000 claims abstract description 9
- WTOYNNBCKUYIKC-UHFFFAOYSA-N dl-nootkatone Natural products C1CC(C(C)=C)CC2(C)C(C)CC(=O)C=C21 WTOYNNBCKUYIKC-UHFFFAOYSA-N 0.000 claims abstract description 9
- SDQFDHOLCGWZPU-UHFFFAOYSA-N lilial Chemical compound O=CC(C)CC1=CC=C(C(C)(C)C)C=C1 SDQFDHOLCGWZPU-UHFFFAOYSA-N 0.000 claims abstract description 9
- ZPVFWPFBNIEHGJ-UHFFFAOYSA-N 2-octanone Chemical compound CCCCCCC(C)=O ZPVFWPFBNIEHGJ-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000001709 1,2-dimethylcyclohex-3-ene-1-carbaldehyde Substances 0.000 claims abstract description 7
- VPXWZHXOBQZDNM-UHFFFAOYSA-N 4,4-dimethylcyclohex-2-ene-1-carbaldehyde Chemical compound CC1(CCC(C=O)C=C1)C VPXWZHXOBQZDNM-UHFFFAOYSA-N 0.000 claims abstract description 7
- XMLSXPIVAXONDL-PLNGDYQASA-N Jasmone Chemical compound CC\C=C/CC1=C(C)CCC1=O XMLSXPIVAXONDL-PLNGDYQASA-N 0.000 claims abstract description 5
- HMKKIXGYKWDQSV-KAMYIIQDSA-N alpha-Amylcinnamaldehyde Chemical compound CCCCC\C(C=O)=C\C1=CC=CC=C1 HMKKIXGYKWDQSV-KAMYIIQDSA-N 0.000 claims abstract description 5
- YBUIAJZFOGJGLJ-SWRJLBSHSA-N 1-cedr-8-en-9-ylethanone Chemical compound C1[C@]23[C@H](C)CC[C@H]3C(C)(C)[C@@H]1C(C)=C(C(C)=O)C2 YBUIAJZFOGJGLJ-SWRJLBSHSA-N 0.000 claims abstract description 4
- 241000123611 Dipterocarpaceae Species 0.000 claims abstract description 4
- 241000208150 Geraniaceae Species 0.000 claims abstract 2
- 239000002781 deodorant agent Substances 0.000 claims description 56
- 239000003205 fragrance Substances 0.000 claims description 19
- GLZPCOQZEFWAFX-UHFFFAOYSA-N Geraniol Chemical compound CC(C)=CCCC(C)=CCO GLZPCOQZEFWAFX-UHFFFAOYSA-N 0.000 claims description 10
- 239000000796 flavoring agent Substances 0.000 claims description 10
- 235000019634 flavors Nutrition 0.000 claims description 10
- 241000251468 Actinopterygii Species 0.000 claims description 8
- 235000002637 Nicotiana tabacum Nutrition 0.000 claims description 8
- DSFNTAVCWZDPEB-VOTSOKGWSA-N [(e)-hex-2-enyl] 2-methylpropanoate Chemical compound CCC\C=C\COC(=O)C(C)C DSFNTAVCWZDPEB-VOTSOKGWSA-N 0.000 claims description 7
- HNZUNIKWNYHEJJ-FMIVXFBMSA-N geranyl acetone Chemical compound CC(C)=CCC\C(C)=C\CCC(C)=O HNZUNIKWNYHEJJ-FMIVXFBMSA-N 0.000 claims description 7
- HNZUNIKWNYHEJJ-UHFFFAOYSA-N geranyl acetone Natural products CC(C)=CCCC(C)=CCCC(C)=O HNZUNIKWNYHEJJ-UHFFFAOYSA-N 0.000 claims description 7
- 238000011084 recovery Methods 0.000 claims description 7
- 210000002700 urine Anatomy 0.000 claims description 7
- QEBNYNLSCGVZOH-NFAWXSAZSA-N (+)-valencene Chemical compound C1C[C@@H](C(C)=C)C[C@@]2(C)[C@H](C)CCC=C21 QEBNYNLSCGVZOH-NFAWXSAZSA-N 0.000 claims description 6
- 239000001890 (2R)-8,8,8a-trimethyl-2-prop-1-en-2-yl-1,2,3,4,6,7-hexahydronaphthalene Substances 0.000 claims description 6
- XFXOLBNQYFRSLQ-UHFFFAOYSA-N 3-amino-2-naphthoic acid Chemical compound C1=CC=C2C=C(C(O)=O)C(N)=CC2=C1 XFXOLBNQYFRSLQ-UHFFFAOYSA-N 0.000 claims description 6
- RFDUMBPGZUIKOG-UHFFFAOYSA-N Heptyl 2-methylpropanoate Chemical compound CCCCCCCOC(=O)C(C)C RFDUMBPGZUIKOG-UHFFFAOYSA-N 0.000 claims description 6
- KBBLMMCEHYHHIW-VURMDHGXSA-N [(z)-hex-3-enyl] heptanoate Chemical compound CCCCCCC(=O)OCC\C=C/CC KBBLMMCEHYHHIW-VURMDHGXSA-N 0.000 claims description 6
- QUKGYYKBILRGFE-UHFFFAOYSA-N benzyl acetate Chemical compound CC(=O)OCC1=CC=CC=C1 QUKGYYKBILRGFE-UHFFFAOYSA-N 0.000 claims description 6
- WCTNXGFHEZQHDR-UHFFFAOYSA-N valencene Natural products C1CC(C)(C)C2(C)CC(C(=C)C)CCC2=C1 WCTNXGFHEZQHDR-UHFFFAOYSA-N 0.000 claims description 6
- 239000005792 Geraniol Substances 0.000 claims description 5
- GLZPCOQZEFWAFX-YFHOEESVSA-N Geraniol Natural products CC(C)=CCC\C(C)=C/CO GLZPCOQZEFWAFX-YFHOEESVSA-N 0.000 claims description 5
- JKKGTSUICJWEKB-SREVYHEPSA-N cis-3-Hexenyl 2-methylbutanoate Chemical compound CC\C=C/CCOC(=O)C(C)CC JKKGTSUICJWEKB-SREVYHEPSA-N 0.000 claims description 5
- RGACQXBDYBCJCY-ALCCZGGFSA-N cis-3-Hexenyl hexanoate Chemical compound CCCCCC(=O)OCC\C=C/CC RGACQXBDYBCJCY-ALCCZGGFSA-N 0.000 claims description 5
- RGACQXBDYBCJCY-UHFFFAOYSA-N cis-3-Hexenyl-n-caproat Natural products CCCCCC(=O)OCCC=CCC RGACQXBDYBCJCY-UHFFFAOYSA-N 0.000 claims description 5
- 229940113087 geraniol Drugs 0.000 claims description 5
- 239000004615 ingredient Substances 0.000 claims description 5
- OHEFFKYYKJVVOX-UHFFFAOYSA-N sulcatol Natural products CC(O)CCC=C(C)C OHEFFKYYKJVVOX-UHFFFAOYSA-N 0.000 claims description 5
- FJEBKWNPJIZWKJ-UHFFFAOYSA-N 3-methylbut-3-enyl 2,2-dimethylpropanoate Chemical compound CC(=C)CCOC(=O)C(C)(C)C FJEBKWNPJIZWKJ-UHFFFAOYSA-N 0.000 claims description 4
- RMCHMXPTUMFFBZ-UHFFFAOYSA-N 5-bromo-1-methylindazole Chemical compound BrC1=CC=C2N(C)N=CC2=C1 RMCHMXPTUMFFBZ-UHFFFAOYSA-N 0.000 claims description 4
- KBEBGUQPQBELIU-CMDGGOBGSA-N Ethyl cinnamate Chemical compound CCOC(=O)\C=C\C1=CC=CC=C1 KBEBGUQPQBELIU-CMDGGOBGSA-N 0.000 claims description 4
- KBEBGUQPQBELIU-UHFFFAOYSA-N cinnamic acid ethyl ester Natural products CCOC(=O)C=CC1=CC=CC=C1 KBEBGUQPQBELIU-UHFFFAOYSA-N 0.000 claims description 4
- ZCHOPXVYTWUHDS-UHFFFAOYSA-N cis-3-hexenyl n-butyrate Natural products CCCC(=O)OCCC=CCC ZCHOPXVYTWUHDS-UHFFFAOYSA-N 0.000 claims description 4
- 241000233855 Orchidaceae Species 0.000 claims description 3
- 229940007550 benzyl acetate Drugs 0.000 claims description 3
- NNLLMULULOBXBY-PLNGDYQASA-N cis-3-Hexenyl lactate Chemical compound CC\C=C/CCOC(=O)C(C)O NNLLMULULOBXBY-PLNGDYQASA-N 0.000 claims description 3
- UFLHIIWVXFIJGU-ARJAWSKDSA-N (Z)-hex-3-en-1-ol Chemical compound CC\C=C/CCO UFLHIIWVXFIJGU-ARJAWSKDSA-N 0.000 claims 1
- 241000208125 Nicotiana Species 0.000 claims 1
- UFLHIIWVXFIJGU-UHFFFAOYSA-N hex-3-en-1-ol Natural products CCC=CCCO UFLHIIWVXFIJGU-UHFFFAOYSA-N 0.000 claims 1
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 abstract description 17
- 239000003795 chemical substances by application Substances 0.000 abstract description 9
- 239000002304 perfume Substances 0.000 abstract description 5
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 abstract description 4
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 abstract description 4
- 239000004310 lactic acid Substances 0.000 abstract description 3
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 abstract description 2
- 235000019253 formic acid Nutrition 0.000 abstract description 2
- 235000014655 lactic acid Nutrition 0.000 abstract description 2
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Chemical compound CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 abstract 2
- WBYWAXJHAXSJNI-VOTSOKGWSA-M .beta-Phenylacrylic acid Natural products [O-]C(=O)\C=C\C1=CC=CC=C1 WBYWAXJHAXSJNI-VOTSOKGWSA-M 0.000 abstract 1
- 241000208229 Burseraceae Species 0.000 abstract 1
- 241000984092 Cistaceae Species 0.000 abstract 1
- 229930016911 cinnamic acid Natural products 0.000 abstract 1
- 235000013985 cinnamic acid Nutrition 0.000 abstract 1
- IVLCENBZDYVJPA-ARJAWSKDSA-N cis-Jasmone Natural products C\C=C/CC1=C(C)CCC1=O IVLCENBZDYVJPA-ARJAWSKDSA-N 0.000 abstract 1
- WBYWAXJHAXSJNI-UHFFFAOYSA-N methyl p-hydroxycinnamate Natural products OC(=O)C=CC1=CC=CC=C1 WBYWAXJHAXSJNI-UHFFFAOYSA-N 0.000 abstract 1
- XMLSXPIVAXONDL-UHFFFAOYSA-N trans-jasmone Natural products CCC=CCC1=C(C)CCC1=O XMLSXPIVAXONDL-UHFFFAOYSA-N 0.000 abstract 1
- 235000019645 odor Nutrition 0.000 description 39
- 239000000203 mixture Substances 0.000 description 38
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 22
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 20
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 18
- 238000004332 deodorization Methods 0.000 description 18
- 239000000463 material Substances 0.000 description 11
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 9
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 9
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 9
- -1 pyrazine Chemical class 0.000 description 9
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 9
- 238000004140 cleaning Methods 0.000 description 8
- 150000001875 compounds Chemical class 0.000 description 8
- 230000000694 effects Effects 0.000 description 8
- ZFRKQXVRDFCRJG-UHFFFAOYSA-N skatole Chemical compound C1=CC=C2C(C)=CNC2=C1 ZFRKQXVRDFCRJG-UHFFFAOYSA-N 0.000 description 8
- 244000061176 Nicotiana tabacum Species 0.000 description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 7
- 239000003915 liquefied petroleum gas Substances 0.000 description 7
- 239000007921 spray Substances 0.000 description 7
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 239000000443 aerosol Substances 0.000 description 6
- 238000005259 measurement Methods 0.000 description 6
- 229920000642 polymer Polymers 0.000 description 6
- 239000007864 aqueous solution Substances 0.000 description 5
- 239000011521 glass Substances 0.000 description 5
- 239000003921 oil Substances 0.000 description 5
- 235000019198 oils Nutrition 0.000 description 5
- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- 241000208152 Geranium Species 0.000 description 4
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 4
- 150000001412 amines Chemical class 0.000 description 4
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 4
- NEHNMFOYXAPHSD-UHFFFAOYSA-N citronellal Chemical compound O=CCC(C)CCC=C(C)C NEHNMFOYXAPHSD-UHFFFAOYSA-N 0.000 description 4
- KVWWIYGFBYDJQC-UHFFFAOYSA-N methyl dihydrojasmonate Chemical compound CCCCCC1C(CC(=O)OC)CCC1=O KVWWIYGFBYDJQC-UHFFFAOYSA-N 0.000 description 4
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 4
- 239000000419 plant extract Substances 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 239000011347 resin Substances 0.000 description 4
- 229920005989 resin Polymers 0.000 description 4
- 229940074386 skatole Drugs 0.000 description 4
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 4
- UFLHIIWVXFIJGU-ONEGZZNKSA-N (E)-hex-3-en-1-ol Chemical compound CC\C=C\CCO UFLHIIWVXFIJGU-ONEGZZNKSA-N 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 240000008772 Cistus ladanifer Species 0.000 description 3
- 235000005241 Cistus ladanifer Nutrition 0.000 description 3
- 229920000858 Cyclodextrin Polymers 0.000 description 3
- 239000004869 Labdanum Substances 0.000 description 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- 150000003973 alkyl amines Chemical class 0.000 description 3
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 3
- 150000001728 carbonyl compounds Chemical class 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 238000000605 extraction Methods 0.000 description 3
- 239000010985 leather Substances 0.000 description 3
- 239000008601 oleoresin Substances 0.000 description 3
- 150000003216 pyrazines Chemical class 0.000 description 3
- 150000003222 pyridines Chemical class 0.000 description 3
- 239000000377 silicon dioxide Substances 0.000 description 3
- 239000000758 substrate Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 239000002023 wood Substances 0.000 description 3
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 2
- 235000007173 Abies balsamea Nutrition 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
- 239000004857 Balsam Substances 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 229920001661 Chitosan Polymers 0.000 description 2
- QUSNBJAOOMFDIB-UHFFFAOYSA-N Ethylamine Chemical compound CCN QUSNBJAOOMFDIB-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 244000018716 Impatiens biflora Species 0.000 description 2
- SIKJAQJRHWYJAI-UHFFFAOYSA-N Indole Chemical compound C1=CC=C2NC=CC2=C1 SIKJAQJRHWYJAI-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 2
- BAVYZALUXZFZLV-UHFFFAOYSA-N Methylamine Chemical compound NC BAVYZALUXZFZLV-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- PVNIIMVLHYAWGP-UHFFFAOYSA-N Niacin Chemical compound OC(=O)C1=CC=CN=C1 PVNIIMVLHYAWGP-UHFFFAOYSA-N 0.000 description 2
- KYQCOXFCLRTKLS-UHFFFAOYSA-N Pyrazine Chemical compound C1=CN=CC=N1 KYQCOXFCLRTKLS-UHFFFAOYSA-N 0.000 description 2
- 229920002125 Sokalan® Polymers 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 229910021536 Zeolite Inorganic materials 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 150000001299 aldehydes Chemical class 0.000 description 2
- 239000001273 butane Substances 0.000 description 2
- ULDHMXUKGWMISQ-UHFFFAOYSA-N carvone Chemical compound CC(=C)C1CC=C(C)C(=O)C1 ULDHMXUKGWMISQ-UHFFFAOYSA-N 0.000 description 2
- 235000019504 cigarettes Nutrition 0.000 description 2
- 239000010630 cinnamon oil Substances 0.000 description 2
- 239000010632 citronella oil Substances 0.000 description 2
- 235000000983 citronellal Nutrition 0.000 description 2
- 229930003633 citronellal Natural products 0.000 description 2
- 239000003599 detergent Substances 0.000 description 2
- FLKPEMZONWLCSK-UHFFFAOYSA-N diethyl phthalate Chemical compound CCOC(=O)C1=CC=CC=C1C(=O)OCC FLKPEMZONWLCSK-UHFFFAOYSA-N 0.000 description 2
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 2
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 150000002170 ethers Chemical class 0.000 description 2
- 235000011389 fruit/vegetable juice Nutrition 0.000 description 2
- 238000004817 gas chromatography Methods 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 239000011976 maleic acid Substances 0.000 description 2
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- NDVLTYZPCACLMA-UHFFFAOYSA-N silver oxide Chemical compound [O-2].[Ag+].[Ag+] NDVLTYZPCACLMA-UHFFFAOYSA-N 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000000052 vinegar Substances 0.000 description 2
- 235000021419 vinegar Nutrition 0.000 description 2
- 239000000341 volatile oil Substances 0.000 description 2
- 239000010457 zeolite Substances 0.000 description 2
- PFTAWBLQPZVEMU-DZGCQCFKSA-N (+)-catechin Chemical compound C1([C@H]2OC3=CC(O)=CC(O)=C3C[C@@H]2O)=CC=C(O)C(O)=C1 PFTAWBLQPZVEMU-DZGCQCFKSA-N 0.000 description 1
- KJPRLNWUNMBNBZ-QPJJXVBHSA-N (E)-cinnamaldehyde Chemical compound O=C\C=C\C1=CC=CC=C1 KJPRLNWUNMBNBZ-QPJJXVBHSA-N 0.000 description 1
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 1
- IVORCBKUUYGUOL-UHFFFAOYSA-N 1-ethynyl-2,4-dimethoxybenzene Chemical compound COC1=CC=C(C#C)C(OC)=C1 IVORCBKUUYGUOL-UHFFFAOYSA-N 0.000 description 1
- RTBFRGCFXZNCOE-UHFFFAOYSA-N 1-methylsulfonylpiperidin-4-one Chemical compound CS(=O)(=O)N1CCC(=O)CC1 RTBFRGCFXZNCOE-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- NRGGMCIBEHEAIL-UHFFFAOYSA-N 2-ethylpyridine Chemical compound CCC1=CC=CC=N1 NRGGMCIBEHEAIL-UHFFFAOYSA-N 0.000 description 1
- WLAMNBDJUVNPJU-UHFFFAOYSA-N 2-methylbutyric acid Chemical compound CCC(C)C(O)=O WLAMNBDJUVNPJU-UHFFFAOYSA-N 0.000 description 1
- KGIGUEBEKRSTEW-UHFFFAOYSA-N 2-vinylpyridine Chemical compound C=CC1=CC=CC=N1 KGIGUEBEKRSTEW-UHFFFAOYSA-N 0.000 description 1
- CWVRJTMFETXNAD-FWCWNIRPSA-N 3-O-Caffeoylquinic acid Natural products O[C@H]1[C@@H](O)C[C@@](O)(C(O)=O)C[C@H]1OC(=O)\C=C\C1=CC=C(O)C(O)=C1 CWVRJTMFETXNAD-FWCWNIRPSA-N 0.000 description 1
- 125000006041 3-hexenyl group Chemical group 0.000 description 1
- 229920001450 Alpha-Cyclodextrin Polymers 0.000 description 1
- 241000228212 Aspergillus Species 0.000 description 1
- 241000208838 Asteraceae Species 0.000 description 1
- 235000017166 Bambusa arundinacea Nutrition 0.000 description 1
- 235000017491 Bambusa tulda Nutrition 0.000 description 1
- 239000005711 Benzoic acid Substances 0.000 description 1
- 235000018062 Boswellia Nutrition 0.000 description 1
- 240000007551 Boswellia serrata Species 0.000 description 1
- PZIRUHCJZBGLDY-UHFFFAOYSA-N Caffeoylquinic acid Natural products CC(CCC(=O)C(C)C1C(=O)CC2C3CC(O)C4CC(O)CCC4(C)C3CCC12C)C(=O)O PZIRUHCJZBGLDY-UHFFFAOYSA-N 0.000 description 1
- 241000644798 Canarium <sea snail> Species 0.000 description 1
- 240000005209 Canarium indicum Species 0.000 description 1
- 239000005973 Carvone Substances 0.000 description 1
- 244000223760 Cinnamomum zeylanicum Species 0.000 description 1
- WTEVQBCEXWBHNA-UHFFFAOYSA-N Citral Natural products CC(C)=CCCC(C)=CC=O WTEVQBCEXWBHNA-UHFFFAOYSA-N 0.000 description 1
- 240000000560 Citrus x paradisi Species 0.000 description 1
- 241000159188 Commiphora habessinica Species 0.000 description 1
- 241001329106 Commiphora kataf Species 0.000 description 1
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 1
- 241000668724 Dipterocarpus turbinatus Species 0.000 description 1
- 241000207923 Lamiaceae Species 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- CWVRJTMFETXNAD-KLZCAUPSSA-N Neochlorogenin-saeure Natural products O[C@H]1C[C@@](O)(C[C@@H](OC(=O)C=Cc2ccc(O)c(O)c2)[C@@H]1O)C(=O)O CWVRJTMFETXNAD-KLZCAUPSSA-N 0.000 description 1
- 244000270673 Pelargonium graveolens Species 0.000 description 1
- 235000017927 Pelargonium graveolens Nutrition 0.000 description 1
- PCNDJXKNXGMECE-UHFFFAOYSA-N Phenazine Natural products C1=CC=CC2=NC3=CC=CC=C3N=C21 PCNDJXKNXGMECE-UHFFFAOYSA-N 0.000 description 1
- 244000082204 Phyllostachys viridis Species 0.000 description 1
- 235000015334 Phyllostachys viridis Nutrition 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 244000178231 Rosmarinus officinalis Species 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
- 244000269722 Thea sinensis Species 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- DOOTYTYQINUNNV-UHFFFAOYSA-N Triethyl citrate Chemical compound CCOC(=O)CC(O)(C(=O)OCC)CC(=O)OCC DOOTYTYQINUNNV-UHFFFAOYSA-N 0.000 description 1
- 238000007259 addition reaction Methods 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 238000004378 air conditioning Methods 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- HBYWSTUEWLEPMS-UHFFFAOYSA-N aldehydic form of ligstroside aglycone Natural products COC(=O)C1=COC(C)C(C=O)C1CC(=O)OCCC1=CC=C(O)C=C1 HBYWSTUEWLEPMS-UHFFFAOYSA-N 0.000 description 1
- HFHDHCJBZVLPGP-RWMJIURBSA-N alpha-cyclodextrin Chemical compound OC[C@H]([C@H]([C@@H]([C@H]1O)O)O[C@H]2O[C@@H]([C@@H](O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O3)[C@H](O)[C@H]2O)CO)O[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@@H]3O[C@@H]1CO HFHDHCJBZVLPGP-RWMJIURBSA-N 0.000 description 1
- 229940043377 alpha-cyclodextrin Drugs 0.000 description 1
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- JFCQEDHGNNZCLN-UHFFFAOYSA-N anhydrous glutaric acid Natural products OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 235000006708 antioxidants Nutrition 0.000 description 1
- 229940072107 ascorbate Drugs 0.000 description 1
- 235000010323 ascorbic acid Nutrition 0.000 description 1
- 239000011668 ascorbic acid Substances 0.000 description 1
- 239000011425 bamboo Substances 0.000 description 1
- 235000010233 benzoic acid Nutrition 0.000 description 1
- 235000019445 benzyl alcohol Nutrition 0.000 description 1
- WHGYBXFWUBPSRW-FOUAGVGXSA-N beta-cyclodextrin Chemical compound OC[C@H]([C@H]([C@@H]([C@H]1O)O)O[C@H]2O[C@@H]([C@@H](O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O3)[C@H](O)[C@H]2O)CO)O[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@@H]3O[C@@H]1CO WHGYBXFWUBPSRW-FOUAGVGXSA-N 0.000 description 1
- 229960004853 betadex Drugs 0.000 description 1
- 238000010170 biological method Methods 0.000 description 1
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
- 229910052918 calcium silicate Inorganic materials 0.000 description 1
- 239000000378 calcium silicate Substances 0.000 description 1
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- ADRVNXBAWSRFAJ-UHFFFAOYSA-N catechin Natural products OC1Cc2cc(O)cc(O)c2OC1c3ccc(O)c(O)c3 ADRVNXBAWSRFAJ-UHFFFAOYSA-N 0.000 description 1
- 235000005487 catechin Nutrition 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- CWVRJTMFETXNAD-JUHZACGLSA-N chlorogenic acid Chemical compound O[C@@H]1[C@H](O)C[C@@](O)(C(O)=O)C[C@H]1OC(=O)\C=C\C1=CC=C(O)C(O)=C1 CWVRJTMFETXNAD-JUHZACGLSA-N 0.000 description 1
- 229940074393 chlorogenic acid Drugs 0.000 description 1
- FFQSDFBBSXGVKF-KHSQJDLVSA-N chlorogenic acid Natural products O[C@@H]1C[C@](O)(C[C@@H](CC(=O)C=Cc2ccc(O)c(O)c2)[C@@H]1O)C(=O)O FFQSDFBBSXGVKF-KHSQJDLVSA-N 0.000 description 1
- 235000001368 chlorogenic acid Nutrition 0.000 description 1
- 229950001002 cianidanol Drugs 0.000 description 1
- 229940117916 cinnamic aldehyde Drugs 0.000 description 1
- KJPRLNWUNMBNBZ-UHFFFAOYSA-N cinnamic aldehyde Natural products O=CC=CC1=CC=CC=C1 KJPRLNWUNMBNBZ-UHFFFAOYSA-N 0.000 description 1
- 235000017803 cinnamon Nutrition 0.000 description 1
- BMRSEYFENKXDIS-KLZCAUPSSA-N cis-3-O-p-coumaroylquinic acid Natural products O[C@H]1C[C@@](O)(C[C@@H](OC(=O)C=Cc2ccc(O)cc2)[C@@H]1O)C(=O)O BMRSEYFENKXDIS-KLZCAUPSSA-N 0.000 description 1
- 229940043350 citral Drugs 0.000 description 1
- 235000020971 citrus fruits Nutrition 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000010411 cooking Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000002552 dosage form Substances 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 239000004862 elemi Substances 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 239000005038 ethylene vinyl acetate Substances 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 230000002550 fecal effect Effects 0.000 description 1
- 210000003608 fece Anatomy 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 235000011087 fumaric acid Nutrition 0.000 description 1
- 239000002316 fumigant Substances 0.000 description 1
- GDSRMADSINPKSL-HSEONFRVSA-N gamma-cyclodextrin Chemical compound OC[C@H]([C@H]([C@@H]([C@H]1O)O)O[C@H]2O[C@@H]([C@@H](O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O3)[C@H](O)[C@H]2O)CO)O[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@@H]3O[C@@H]1CO GDSRMADSINPKSL-HSEONFRVSA-N 0.000 description 1
- 229940080345 gamma-cyclodextrin Drugs 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- WTEVQBCEXWBHNA-JXMROGBWSA-N geranial Chemical compound CC(C)=CCC\C(C)=C\C=O WTEVQBCEXWBHNA-JXMROGBWSA-N 0.000 description 1
- 125000002791 glucosyl group Chemical group C1([C@H](O)[C@@H](O)[C@H](O)[C@H](O1)CO)* 0.000 description 1
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical class C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 238000011534 incubation Methods 0.000 description 1
- PZOUSPYUWWUPPK-UHFFFAOYSA-N indole Natural products CC1=CC=CC2=C1C=CN2 PZOUSPYUWWUPPK-UHFFFAOYSA-N 0.000 description 1
- RKJUIXBNRJVNHR-UHFFFAOYSA-N indolenine Natural products C1=CC=C2CC=NC2=C1 RKJUIXBNRJVNHR-UHFFFAOYSA-N 0.000 description 1
- 150000002475 indoles Chemical class 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 239000002198 insoluble material Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229940057995 liquid paraffin Drugs 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000001630 malic acid Substances 0.000 description 1
- 235000011090 malic acid Nutrition 0.000 description 1
- 230000000873 masking effect Effects 0.000 description 1
- 235000013372 meat Nutrition 0.000 description 1
- 239000001525 mentha piperita l. herb oil Substances 0.000 description 1
- 125000005397 methacrylic acid ester group Chemical group 0.000 description 1
- 125000002496 methyl group Chemical class [H]C([H])([H])* 0.000 description 1
- JPTOCTSNXXKSSN-UHFFFAOYSA-N methylheptenone Chemical compound CCCC=CC(=O)CC JPTOCTSNXXKSSN-UHFFFAOYSA-N 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 229930014626 natural product Natural products 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 239000011664 nicotinic acid Substances 0.000 description 1
- 229960003512 nicotinic acid Drugs 0.000 description 1
- 235000001968 nicotinic acid Nutrition 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000000123 paper Substances 0.000 description 1
- 235000019477 peppermint oil Nutrition 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical class N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 1
- 238000000053 physical method Methods 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 239000003380 propellant Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- HFHDHCJBZVLPGP-UHFFFAOYSA-N schardinger α-dextrin Chemical compound O1C(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(O)C2O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC2C(O)C(O)C1OC2CO HFHDHCJBZVLPGP-UHFFFAOYSA-N 0.000 description 1
- 230000028327 secretion Effects 0.000 description 1
- 230000001953 sensory effect Effects 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 229910001923 silver oxide Inorganic materials 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 238000000638 solvent extraction Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000001256 steam distillation Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000011550 stock solution Substances 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 235000013616 tea Nutrition 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- UAXOELSVPTZZQG-UHFFFAOYSA-N tiglic acid Natural products CC(C)=C(C)C(O)=O UAXOELSVPTZZQG-UHFFFAOYSA-N 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 230000005068 transpiration Effects 0.000 description 1
- 239000001069 triethyl citrate Substances 0.000 description 1
- VMYFZRTXGLUXMZ-UHFFFAOYSA-N triethyl citrate Natural products CCOC(=O)C(O)(C(=O)OCC)C(=O)OCC VMYFZRTXGLUXMZ-UHFFFAOYSA-N 0.000 description 1
- 235000013769 triethyl citrate Nutrition 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- 229910000166 zirconium phosphate Inorganic materials 0.000 description 1
- LEHFSLREWWMLPU-UHFFFAOYSA-B zirconium(4+);tetraphosphate Chemical compound [Zr+4].[Zr+4].[Zr+4].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LEHFSLREWWMLPU-UHFFFAOYSA-B 0.000 description 1
Landscapes
- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
Abstract
【解決手段】(a):アミルシンナミックアルデヒド、桂皮酸エチル、ヌートカトン、シス−ジャスモン、アセチルセドレン、2-メチル-3-(4-tert-ブチルフェニル)-プロパナール、2-シクロヘキシルプロパナール、ジメチルテトラヒドロベンズアルデヒド、ゲラニルアセトン、6-メチル-5-ヘプテン-2-オン、メチルヘキシルケトン、蟻酸シス-3-ヘキセニル、酪酸シス-3-ヘキセニル、乳酸シス-3-ヘキセニル等から選ばれる1種以上の香料物質、又は(b):カンラン科、ハンニチバナ科、フウロソウ科及びフタバガキ科から選ばれる1種以上の植物の溶剤抽出物からなる塩基性悪臭用消臭剤、及びこれを用いる消臭方法。
【選択図】なし
Description
成分(b); カンラン科、ハンニチバナ科、フウロソウ科及びフタバガキ科から選ばれる1種以上の植物の溶剤抽出物
(a1) α,β-不飽和カルボニル化合物:アミルシンナミックアルデヒド、桂皮酸エチル、ヌートカトン、シス−ジャスモン、アセチルセドレン。
(a2) ケトン又はアルデヒド〔(a1)を除く〕:2-メチル-3-(4-tert-ブチルフェニル)-プロパナール、2-シクロヘキシルプロパナール、ジメチルテトラヒドロベンズアルデヒド、ゲラニルアセトン、6-メチル-5-ヘプテン-2-オン、メチルヘキシルケトン。
(a3) エステル類〔(a1)、(a2)を除く〕:蟻酸シス-3-ヘキセニル、酪酸シス-3-ヘキセニル、乳酸シス-3-ヘキセニル、ヘキサン酸シス-3-ヘキセニル、ヘプタン酸シス-3-ヘキセニル、2-メチル酪酸シス-3-ヘキセニル、イソ酪酸トランス-2-ヘキセニル、イソ酪酸ヘプチル、酢酸ベンジル、2,2-ジメチルプロピオン酸3-メチル-3-ブテニル。
(a4) アルコール類又はエーテル類:トランス-3-ヘキセノール、ゲラニオール。
(a5) 炭化水素類:バレンセン。
(a6) 回収フレーバー:オレンジ回収フレーバー。ここで回収フレーバーとは、果汁を濃縮して濃縮果汁を作る際に水分とともに蒸発する香気成分を含む留出水(柑橘類の場合には油層のオイル分)から水蒸気蒸留や溶剤抽出などによってさらに濃縮したものである。
植物の抽出に使用する溶剤としては、エタノール、アセトン、ブタン、ヘキサンや、プロピレングリコール、ジプロピレングリコール等の多価アルコール、二酸化炭素等があり、水との混合物を使用することもできる。
(中和反応)酢酸、塩酸、木酢液、竹酢液、クエン酸、マロン酸、コハク酸、グルタル酸、フマル酸、リンゴ酸、酒石酸、マレイン酸、アクリル酸、乳酸、アジピン酸、フタル酸、安息香酸、ニコチン酸及びそれらの塩、ベタイン化合物等
(サイクロデキストリン)α-、β-又はγ-サイクロデキストリン、そのメチル誘導体、ヒドロキシプロピル誘導体、グルコシル誘導体、マルトシル誘導体等
〔トリメチルアミンに対する消臭効果の測定〕
50mL容のガラスびん内に、30質量%トリメチルアミン水溶液の0.3質量%水溶液3.2μL及び消臭剤50μLを滴下して混合し、密栓する。30分静置後、アミン用検知管にてトリメチルアミン濃度を測定する。ブランクは消臭剤なしとし、ブランクからの差分から消臭率を求め(悪臭が0ppmの場合、消臭率100%)、下記基準に従ってランク分けした。この結果を表1に示す。
×:50%未満の効果
△:50%以上の効果
○:70%以上の効果
◎:90%以上の効果
グループ1(α,β-不飽和カルボニル構造を有する化合物)
グループ2(その他のカルボニル基を有する化合物)
グループ3(グループ1,2以外のエステル系化合物)
グループ4(グループ1,2以外のアルコール系、エーテル系化合物)
グループ5(炭化水素)
グループ6(回収フレーバー、植物精油)
グループ7(植物の溶剤抽出物)
〔ピリジンに対する消臭効果の測定〕
50mL容のガラスびん内に、ピリジンの0.5質量%水溶液2.5μL及び消臭剤30μLを滴下して混合し、密栓する。30分静置後、ピリジン用検知管にてピリジン濃度を測定する。ブランクは消臭剤なしとし、ブランクからの差分から消臭率を求め(悪臭が0ppmの場合、消臭率100%)、試験例1と同様の基準でランク分けした。この結果を表2に示す。
〔スカトールに対する消臭効果の測定〕
20mL容バイアルびん内に、スカトールの50質量%アセトン溶液10μLを滴下して1時間放置後、消臭剤10μLを滴下混合し、密栓する。軽く振って攪拌した後、HS-GC分析を行った。消臭率は、ブランクの悪臭物質揮散量(GCアバンダンス)に対する、消臭剤存在下での悪臭物質揮散量から求め、試験例1と同様の基準でランク分けした。この結果を表3に示す。
HS-オートサンプラー;PERKIN ELMER製 HS40XL
バイアル保温時間;60℃30分保温後、加圧2分、注入0.3分
GC;HEWLETT PACKARD5890
カラム液相;(5%フェニル)メチルポリシロキサン 無極性
カラム長さ;30m、内径;0.32mm、膜厚;0.25μm
昇温条件;40℃(8℃/分)−60℃(4℃/分)−200℃
消臭率(%)は下記式により求めた。
〔乾燥尿に対する消臭効果の測定〕
50mL容のガラスびん内に、乾燥尿(3人分を混合し、シャーレに入れ、天日で乾燥させたもの)0.06g及び消臭剤100μLを滴下して混合し、密栓する。30分静置後、混合液に1Mの水酸化ナトリウム水溶液を30μL滴下してアルカリ性に調整した後、発生した尿臭をアミン用検知管にて測定する。ブランクは消臭剤なしとし、ブランクからの差分から消臭率を求める(悪臭が0ppmの場合、消臭率100%)。この結果を表4に示す。
〔魚臭に対する消臭効果の測定〕
50mL容のガラスびん内に、焼き魚の廃油(イオン交換水で5質量倍に希釈)100μL、5M水酸化ナトリウム水溶液30μLを入れたプラスチック製の2mL容の小カップ、及び消臭剤50μLの3つを入れ、密栓する。30分静置後、発生した魚臭をアミン用検知管にて測定する。ブランクは消臭剤なしとしブランクからの差分から消臭率を求める(悪臭が0ppmの場合、消臭率100%)。この結果を表5に示す。
〔タバコ臭に対する消臭効果の測定〕
50mL容のガラスびん内に、消臭剤50μLと、1Lセパラフラスコの中で燃焼させたタバコ(マイルドセブンオリジナル先端1cm分)の煙15mL分を注入し、密栓する。30分静置後、タバコ臭をピリジン用検知管にて測定する。ブランクは消臭剤なしとしブランクからの差分から消臭率を求める(ピリジン濃度が0ppmの場合、消臭率100%)。この結果を表6に示す。
表7に示す組成(質量%)の本発明に係る消臭剤を配合した柔軟剤組成物(pH4)を調製した。
表8に示す組成(質量%)の本発明に係る消臭剤を配合した消臭剤組成物を調製し、トリガースプレー容器に入れ、スプレー型消臭剤組成物を調製した。
表9に示す組成(質量%)の原液と液化石油ガス(LPG)を6:4の割合でエアゾール缶に充填し、エアゾールスプレーとした。
表10に示す組成(質量%)の本発明に係る消臭剤を配合した食器用洗浄剤組成物を調製した。
表11に示す組成(質量%)の本発明に係る消臭剤を配合したキッチン用洗浄剤組成物(pH10)を調製した。
表12に示す組成(質量%)の本発明に係る消臭剤を配合したトイレ用洗浄剤組成物をトリガー付き容器に入れ、トイレ用スプレー洗浄剤組成物を調製した。
表13に示す組成(質量%)の本発明に係る消臭剤を配合した配合液を調製し、不織布シートに対して2.5倍量(質量)含浸させ、トイレ用のウェットシートとした。
Claims (3)
- 成分(a)又は(b)からなる塩基性悪臭用消臭剤。
成分(a):アミルシンナミックアルデヒド、桂皮酸エチル、ヌートカトン、シス−ジャスモン、アセチルセドレン、2-メチル-3-(4-tert-ブチルフェニル)-プロパナール、2-シクロヘキシルプロパナール、ジメチルテトラヒドロベンズアルデヒド、ゲラニルアセトン、6-メチル-5-ヘプテン-2-オン、メチルヘキシルケトン、蟻酸シス-3-ヘキセニル、酪酸シス-3-ヘキセニル、乳酸シス-3-ヘキセニル、ヘキサン酸シス-3-ヘキセニル、ヘプタン酸シス-3-ヘキセニル、2-メチル酪酸シス-3-ヘキセニル、イソ酪酸トランス-2-ヘキセニル、イソ酪酸ヘプチル、酢酸ベンジル、2,2-ジメチルプロピオン酸 3-メチル-3-ブテニル、トランス-3-ヘキセノール、ゲラニオール、バレンセン及びオレンジ回収フレーバーから選ばれる1種以上の香料物質
成分(b):カンラン科、ハンニチバナ科、フウロソウ科及びフタバガキ科から選ばれる1種以上の植物の溶剤抽出物 - 請求項1記載の成分(a)又は(b)を用いて塩基性悪臭を消臭する方法。
- 塩基性悪臭が、尿臭、魚臭又はタバコ臭である請求項2記載の方法。
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2007159680A JP5695288B2 (ja) | 2006-11-06 | 2007-06-18 | 塩基性悪臭用消臭剤 |
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2006299844 | 2006-11-06 | ||
JP2006299844 | 2006-11-06 | ||
JP2007159680A JP5695288B2 (ja) | 2006-11-06 | 2007-06-18 | 塩基性悪臭用消臭剤 |
Publications (3)
Publication Number | Publication Date |
---|---|
JP2008136841A true JP2008136841A (ja) | 2008-06-19 |
JP2008136841A5 JP2008136841A5 (ja) | 2011-06-02 |
JP5695288B2 JP5695288B2 (ja) | 2015-04-01 |
Family
ID=39598894
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2007159680A Active JP5695288B2 (ja) | 2006-11-06 | 2007-06-18 | 塩基性悪臭用消臭剤 |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP5695288B2 (ja) |
Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2012169644A1 (en) | 2011-06-06 | 2012-12-13 | Kao Corporation | Method for identifying a malodor inhibitor |
JP2012250958A (ja) * | 2011-06-06 | 2012-12-20 | Kao Corp | 悪臭抑制剤 |
JP2014117676A (ja) * | 2012-12-18 | 2014-06-30 | Kanichi Adachi | 吸収性物品用処理剤および該処理剤を用いた吸収性物品の処理方法 |
JP2015081237A (ja) * | 2013-10-22 | 2015-04-27 | 花王株式会社 | ソトロンによるにおいの抑制剤 |
JP2015193643A (ja) * | 2015-07-09 | 2015-11-05 | 花王株式会社 | 悪臭抑制剤 |
WO2017090518A1 (ja) * | 2015-11-24 | 2017-06-01 | 花王株式会社 | 尿臭抑制剤 |
JP2017101224A (ja) * | 2015-11-24 | 2017-06-08 | 花王株式会社 | 尿臭抑制剤 |
JP2019151574A (ja) * | 2018-03-01 | 2019-09-12 | クラシエホームプロダクツ株式会社 | 悪臭化合物の低減方法。 |
KR102100382B1 (ko) * | 2018-10-31 | 2020-04-13 | 송화섭 | 골프그립 탈취 세정제 제조방법 |
CN113663463A (zh) * | 2021-08-26 | 2021-11-19 | 日东生物科技(浙江)有限公司 | 一种异味抑制剂 |
EP3944855A2 (en) | 2020-07-28 | 2022-02-02 | Takasago International Corporation | Method for screening of unpleasant odor masking agents |
JP2022115911A (ja) * | 2018-03-01 | 2022-08-09 | クラシエホームプロダクツ株式会社 | 悪臭化合物を低減するための組成物 |
Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2001303090A (ja) * | 2000-04-20 | 2001-10-31 | Haarmann & Reimer Kk | 化学的消臭香料組成物 |
JP2002275495A (ja) * | 2001-03-16 | 2002-09-25 | Takasago Internatl Corp | 煙草臭消臭性香料組成物 |
JP2002336337A (ja) * | 2001-05-14 | 2002-11-26 | Lion Corp | 消臭防汚剤 |
JP2003113392A (ja) * | 2001-10-04 | 2003-04-18 | Kiyomitsu Kawasaki | 芳香・消臭組成物および該芳香・消臭組成物を含有する人体用芳香・消臭剤 |
JP2003190264A (ja) * | 2001-12-25 | 2003-07-08 | Kiyomitsu Kawasaki | 環境用芳香消臭組成物及び該環境用芳香消臭組成物を含有する環境用芳香消臭剤 |
JP2004160216A (ja) * | 2002-10-24 | 2004-06-10 | Hiromi Imanaka | 液状消臭剤およびその製造方法 |
JP2005177174A (ja) * | 2003-12-19 | 2005-07-07 | Lion Corp | 放香器及び芳香・消臭剤製品 |
JP2006207112A (ja) * | 2006-04-21 | 2006-08-10 | Lion Corp | 液体柔軟剤組成物 |
-
2007
- 2007-06-18 JP JP2007159680A patent/JP5695288B2/ja active Active
Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2001303090A (ja) * | 2000-04-20 | 2001-10-31 | Haarmann & Reimer Kk | 化学的消臭香料組成物 |
JP2002275495A (ja) * | 2001-03-16 | 2002-09-25 | Takasago Internatl Corp | 煙草臭消臭性香料組成物 |
JP2002336337A (ja) * | 2001-05-14 | 2002-11-26 | Lion Corp | 消臭防汚剤 |
JP2003113392A (ja) * | 2001-10-04 | 2003-04-18 | Kiyomitsu Kawasaki | 芳香・消臭組成物および該芳香・消臭組成物を含有する人体用芳香・消臭剤 |
JP2003190264A (ja) * | 2001-12-25 | 2003-07-08 | Kiyomitsu Kawasaki | 環境用芳香消臭組成物及び該環境用芳香消臭組成物を含有する環境用芳香消臭剤 |
JP2004160216A (ja) * | 2002-10-24 | 2004-06-10 | Hiromi Imanaka | 液状消臭剤およびその製造方法 |
JP2005177174A (ja) * | 2003-12-19 | 2005-07-07 | Lion Corp | 放香器及び芳香・消臭剤製品 |
JP2006207112A (ja) * | 2006-04-21 | 2006-08-10 | Lion Corp | 液体柔軟剤組成物 |
Non-Patent Citations (1)
Title |
---|
特許庁公報 周知・慣用技術集(香料) 第I部 香料一般, vol. 230−250, JPN6012065557, 29 January 1999 (1999-01-29), ISSN: 0002409755 * |
Cited By (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2012169644A1 (en) | 2011-06-06 | 2012-12-13 | Kao Corporation | Method for identifying a malodor inhibitor |
JP2012250958A (ja) * | 2011-06-06 | 2012-12-20 | Kao Corp | 悪臭抑制剤 |
US9249453B2 (en) | 2011-06-06 | 2016-02-02 | Kao Corporation | Method for identifying a malodor inhibitor |
JP2014117676A (ja) * | 2012-12-18 | 2014-06-30 | Kanichi Adachi | 吸収性物品用処理剤および該処理剤を用いた吸収性物品の処理方法 |
JP2015081237A (ja) * | 2013-10-22 | 2015-04-27 | 花王株式会社 | ソトロンによるにおいの抑制剤 |
JP2015193643A (ja) * | 2015-07-09 | 2015-11-05 | 花王株式会社 | 悪臭抑制剤 |
WO2017090518A1 (ja) * | 2015-11-24 | 2017-06-01 | 花王株式会社 | 尿臭抑制剤 |
JP2017101224A (ja) * | 2015-11-24 | 2017-06-08 | 花王株式会社 | 尿臭抑制剤 |
CN108289973A (zh) * | 2015-11-24 | 2018-07-17 | 花王株式会社 | 尿臭抑制剂 |
JP2019151574A (ja) * | 2018-03-01 | 2019-09-12 | クラシエホームプロダクツ株式会社 | 悪臭化合物の低減方法。 |
JP2022115911A (ja) * | 2018-03-01 | 2022-08-09 | クラシエホームプロダクツ株式会社 | 悪臭化合物を低減するための組成物 |
KR102100382B1 (ko) * | 2018-10-31 | 2020-04-13 | 송화섭 | 골프그립 탈취 세정제 제조방법 |
EP3944855A2 (en) | 2020-07-28 | 2022-02-02 | Takasago International Corporation | Method for screening of unpleasant odor masking agents |
CN113663463A (zh) * | 2021-08-26 | 2021-11-19 | 日东生物科技(浙江)有限公司 | 一种异味抑制剂 |
CN113663463B (zh) * | 2021-08-26 | 2022-08-02 | 日东生物科技(浙江)有限公司 | 一种异味抑制剂 |
Also Published As
Publication number | Publication date |
---|---|
JP5695288B2 (ja) | 2015-04-01 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP5695288B2 (ja) | 塩基性悪臭用消臭剤 | |
US7332462B2 (en) | Malodor counteractant compounds | |
US6610648B2 (en) | Malodor counteractant compositions | |
EP2110118B1 (en) | Malodour reducing composition and uses thereof | |
CN111432851B (zh) | 挥发性成分限制或消除对恶臭的感知的用途 | |
KR20180111856A (ko) | 전구 향료 조성물 | |
US11168283B2 (en) | Malodor counteracting ingredients | |
JP6829207B2 (ja) | エアゾール型芳香剤 | |
JP5905070B2 (ja) | 悪臭中和組成物 | |
JP5405621B2 (ja) | 香料組成物 | |
KR101781657B1 (ko) | 식물 유래 정유를 유효성분으로 포함하는 소취제 조성물 | |
CN106999619B (zh) | 作为恶臭抵消成分的大环酮 | |
JP4782478B2 (ja) | 香料組成物 | |
JP2007031605A (ja) | 香料組成物 | |
JP4914595B2 (ja) | 香料組成物 | |
JPH0479961A (ja) | 消臭脱臭剤 | |
JP2001314493A (ja) | 消臭剤組成物 | |
JP7260246B2 (ja) | 消臭剤 | |
JP2019501686A (ja) | アンモニアおよび第一級または第二級アミンに対する臭気中和剤 | |
US20230159853A1 (en) | Spiro compounds as malodor counteracting ingredients | |
JP5570856B2 (ja) | 芳香剤組成物 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20100405 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20110415 |
|
A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20110525 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20121218 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20130218 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20130507 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20130705 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20130806 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20131003 |
|
A02 | Decision of refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A02 Effective date: 20131029 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20140124 |
|
A911 | Transfer to examiner for re-examination before appeal (zenchi) |
Free format text: JAPANESE INTERMEDIATE CODE: A911 Effective date: 20140203 |
|
A912 | Re-examination (zenchi) completed and case transferred to appeal board |
Free format text: JAPANESE INTERMEDIATE CODE: A912 Effective date: 20140221 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20141222 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20150206 |
|
R151 | Written notification of patent or utility model registration |
Ref document number: 5695288 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R151 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |