JP2007526868A5 - - Google Patents
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- Publication number
- JP2007526868A5 JP2007526868A5 JP2006551484A JP2006551484A JP2007526868A5 JP 2007526868 A5 JP2007526868 A5 JP 2007526868A5 JP 2006551484 A JP2006551484 A JP 2006551484A JP 2006551484 A JP2006551484 A JP 2006551484A JP 2007526868 A5 JP2007526868 A5 JP 2007526868A5
- Authority
- JP
- Japan
- Prior art keywords
- isotopically enriched
- alkyl
- enriched
- metal
- metal salt
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 claims 31
- 229910052751 metal Inorganic materials 0.000 claims 30
- 239000002184 metal Substances 0.000 claims 30
- 150000003839 salts Chemical class 0.000 claims 13
- -1 borate ester Chemical class 0.000 claims 12
- 125000000217 alkyl group Chemical group 0.000 claims 11
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims 11
- 239000004327 boric acid Substances 0.000 claims 11
- 150000001875 compounds Chemical class 0.000 claims 11
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims 10
- 230000015572 biosynthetic process Effects 0.000 claims 9
- 239000003446 ligand Substances 0.000 claims 8
- 125000003342 alkenyl group Chemical group 0.000 claims 7
- 125000003710 aryl alkyl group Chemical group 0.000 claims 7
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 claims 6
- 125000001153 fluoro group Chemical group F* 0.000 claims 6
- 239000000203 mixture Substances 0.000 claims 6
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical compound [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 claims 5
- 239000002904 solvent Substances 0.000 claims 5
- 125000003545 alkoxy group Chemical group 0.000 claims 4
- 125000003118 aryl group Chemical group 0.000 claims 4
- 230000032050 esterification Effects 0.000 claims 4
- 238000005886 esterification reaction Methods 0.000 claims 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims 3
- 150000008055 alkyl aryl sulfonates Chemical group 0.000 claims 3
- 150000005215 alkyl ethers Chemical class 0.000 claims 3
- 150000008052 alkyl sulfonates Chemical group 0.000 claims 3
- 150000001412 amines Chemical class 0.000 claims 3
- 125000001246 bromo group Chemical group Br* 0.000 claims 3
- 125000001309 chloro group Chemical group Cl* 0.000 claims 3
- 125000001316 cycloalkyl alkyl group Chemical group 0.000 claims 3
- 125000000753 cycloalkyl group Chemical group 0.000 claims 3
- 125000001033 ether group Chemical group 0.000 claims 3
- 125000001188 haloalkyl group Chemical group 0.000 claims 3
- 239000007800 oxidant agent Substances 0.000 claims 3
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 claims 3
- 125000006552 (C3-C8) cycloalkyl group Chemical group 0.000 claims 2
- 239000004215 Carbon black (E152) Substances 0.000 claims 2
- BZLVMXJERCGZMT-UHFFFAOYSA-N Methyl tert-butyl ether Chemical compound COC(C)(C)C BZLVMXJERCGZMT-UHFFFAOYSA-N 0.000 claims 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims 2
- UORVGPXVDQYIDP-UHFFFAOYSA-N borane Chemical compound B UORVGPXVDQYIDP-UHFFFAOYSA-N 0.000 claims 2
- 229930195733 hydrocarbon Natural products 0.000 claims 2
- 150000002430 hydrocarbons Chemical class 0.000 claims 2
- 229910052739 hydrogen Inorganic materials 0.000 claims 2
- 239000001257 hydrogen Substances 0.000 claims 2
- 238000004519 manufacturing process Methods 0.000 claims 2
- UAEPNZWRGJTJPN-UHFFFAOYSA-N methylcyclohexane Chemical compound CC1CCCCC1 UAEPNZWRGJTJPN-UHFFFAOYSA-N 0.000 claims 2
- 230000003647 oxidation Effects 0.000 claims 2
- 238000007254 oxidation reaction Methods 0.000 claims 2
- VDFVNEFVBPFDSB-UHFFFAOYSA-N 1,3-dioxane Chemical compound C1COCOC1 VDFVNEFVBPFDSB-UHFFFAOYSA-N 0.000 claims 1
- WNXJIVFYUVYPPR-UHFFFAOYSA-N 1,3-dioxolane Chemical compound C1COCO1 WNXJIVFYUVYPPR-UHFFFAOYSA-N 0.000 claims 1
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 claims 1
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 claims 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims 1
- 125000006374 C2-C10 alkenyl group Chemical group 0.000 claims 1
- 229910020366 ClO 4 Inorganic materials 0.000 claims 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 claims 1
- XTHFKEDIFFGKHM-UHFFFAOYSA-N Dimethoxyethane Chemical compound COCCOC XTHFKEDIFFGKHM-UHFFFAOYSA-N 0.000 claims 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims 1
- DGEZNRSVGBDHLK-UHFFFAOYSA-N [1,10]phenanthroline Chemical compound C1=CN=C2C3=NC=CC=C3C=CC2=C1 DGEZNRSVGBDHLK-UHFFFAOYSA-N 0.000 claims 1
- 150000001335 aliphatic alkanes Chemical class 0.000 claims 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims 1
- 229910000085 borane Inorganic materials 0.000 claims 1
- 229910052796 boron Inorganic materials 0.000 claims 1
- SBZXBUIDTXKZTM-UHFFFAOYSA-N diglyme Chemical compound COCCOCCOC SBZXBUIDTXKZTM-UHFFFAOYSA-N 0.000 claims 1
- 150000002431 hydrogen Chemical class 0.000 claims 1
- QWPPOHNGKGFGJK-UHFFFAOYSA-N hypochlorous acid Chemical compound ClO QWPPOHNGKGFGJK-UHFFFAOYSA-N 0.000 claims 1
- GYNNXHKOJHMOHS-UHFFFAOYSA-N methyl-cycloheptane Natural products CC1CCCCCC1 GYNNXHKOJHMOHS-UHFFFAOYSA-N 0.000 claims 1
- 230000001590 oxidative effect Effects 0.000 claims 1
- 239000003208 petroleum Substances 0.000 claims 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims 1
- 239000011541 reaction mixture Substances 0.000 claims 1
- 230000002194 synthesizing effect Effects 0.000 claims 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 1
- 239000008096 xylene Substances 0.000 claims 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US54093404P | 2004-01-30 | 2004-01-30 | |
| US60/540,934 | 2004-01-30 | ||
| PCT/US2005/002629 WO2005074531A2 (en) | 2004-01-30 | 2005-01-28 | Methods of synthesis of isotopically enriched borohydride and methods of synthesis of isotopically enriched boranes |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2007526868A JP2007526868A (ja) | 2007-09-20 |
| JP2007526868A5 true JP2007526868A5 (enExample) | 2008-03-13 |
| JP4869947B2 JP4869947B2 (ja) | 2012-02-08 |
Family
ID=34837444
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2006551484A Expired - Fee Related JP4869947B2 (ja) | 2004-01-30 | 2005-01-28 | 同位体濃縮の水素化ホウ素の合成方法及び同位体濃縮のボラン類の合成方法 |
Country Status (6)
| Country | Link |
|---|---|
| US (2) | US7641879B2 (enExample) |
| JP (1) | JP4869947B2 (enExample) |
| KR (1) | KR101169515B1 (enExample) |
| CN (1) | CN101001829B (enExample) |
| TW (1) | TWI372725B (enExample) |
| WO (1) | WO2005074531A2 (enExample) |
Families Citing this family (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TWI372725B (en) * | 2004-01-30 | 2012-09-21 | Semequip Inc | Methods of synthesis of isotopically enriched borohydride and methods of synthesis of isotopically enriched boranes |
| KR101297917B1 (ko) * | 2005-08-30 | 2013-08-27 | 어드밴스드 테크놀러지 머티리얼즈, 인코포레이티드 | 대안적인 불화 붕소 전구체를 이용한 붕소 이온 주입 방법,및 주입을 위한 대형 수소화붕소의 형성 방법 |
| US20070178678A1 (en) * | 2006-01-28 | 2007-08-02 | Varian Semiconductor Equipment Associates, Inc. | Methods of implanting ions and ion sources used for same |
| DE102008004530A1 (de) * | 2008-01-15 | 2009-07-16 | Bergische Universität Wuppertal | Verfahren zur Herstellung von closo-Boranaten |
| US8598022B2 (en) | 2009-10-27 | 2013-12-03 | Advanced Technology Materials, Inc. | Isotopically-enriched boron-containing compounds, and methods of making and using same |
| US8062965B2 (en) * | 2009-10-27 | 2011-11-22 | Advanced Technology Materials, Inc. | Isotopically-enriched boron-containing compounds, and methods of making and using same |
| EP3062330A3 (en) | 2009-10-27 | 2016-11-16 | Entegris, Inc. | Ion implantation system and method |
| TWI585042B (zh) | 2010-02-26 | 2017-06-01 | 恩特葛瑞斯股份有限公司 | 用以增進離子植入系統中之離子源的壽命及性能之方法與設備 |
| US8779383B2 (en) | 2010-02-26 | 2014-07-15 | Advanced Technology Materials, Inc. | Enriched silicon precursor compositions and apparatus and processes for utilizing same |
| US9205392B2 (en) | 2010-08-30 | 2015-12-08 | Entegris, Inc. | Apparatus and method for preparation of compounds or intermediates thereof from a solid material, and using such compounds and intermediates |
| TWI583442B (zh) | 2011-10-10 | 2017-05-21 | 恩特葛瑞斯股份有限公司 | Ｂ２ｆ４之製造程序 |
| KR102225854B1 (ko) | 2013-03-15 | 2021-03-12 | 세라딘, 인크. | 다면체 수소화붕소 또는 카르보란 음이온을 포함하는 원자로 및 원자로의 냉각 방법 |
| EP3033765A4 (en) | 2013-08-16 | 2017-08-16 | Entegris, Inc. | Silicon implantation in substrates and provision of silicon precursor compositions therefor |
| US10059599B2 (en) | 2014-02-03 | 2018-08-28 | The Curators Of The University Of Missouri | Synthesis of borane compounds |
| EP3102586B1 (en) | 2014-02-03 | 2020-09-02 | The Curators Of The University Of Missouri | Synthesis of amine boranes and polyhedral boranes |
| JP6904900B2 (ja) | 2014-04-25 | 2021-07-21 | セラダイン，インコーポレイティド | 多面体水素化ホウ素アニオン又はカルボランアニオンの水溶液を含むプール及びその使用方法 |
| CN118388347A (zh) | 2017-11-01 | 2024-07-26 | 梅琳塔治疗公司 | 化合物、由其形成的硼酸酯衍生物及其制备方法 |
| JP7138482B2 (ja) * | 2018-05-30 | 2022-09-16 | 株式会社トクヤマ | 六方晶窒化ホウ素粉末及びその製造方法 |
Family Cites Families (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2461661A (en) * | 1945-01-09 | 1949-02-15 | Hermann I Schlesinger | Preparation of alkali metal compounds |
| US2642453A (en) | 1947-09-26 | 1953-06-16 | Standard Oil Dev Co | Preparation of borates of tertiary alcohols |
| US2939762A (en) * | 1955-06-09 | 1960-06-07 | Callery Chemical Co | Sodium borohydride from sodium hydride and excess trimethyl borate |
| US3063791A (en) | 1957-10-17 | 1962-11-13 | Metal Hydrides Inc | Preparation of alkali and alkaline earth metal borohydrides |
| US4115521A (en) | 1976-03-22 | 1978-09-19 | Union Carbide Corporation | Process for the synthesis of decaborane(14) |
| US4115520A (en) | 1977-05-20 | 1978-09-19 | Union Carbide Corporation | Process for the synthesis of tetradecahydroundecaborate compounds |
| US4153672A (en) | 1978-07-21 | 1979-05-08 | Union Carbide Corporation | Synthesis of tetradecahydroundecaborate (-1) from borohydride ion |
| US4209510A (en) * | 1978-11-14 | 1980-06-24 | The United States Of America As Represented By The Secretary Of The Army | Ammonia-cyanoborane, sodium iodide complex |
| US4709083A (en) * | 1986-05-19 | 1987-11-24 | The United States Of America As Represented By The Secretary Of The Army | Method of making boron analogues |
| US5280119A (en) * | 1991-11-01 | 1994-01-18 | Boron Biologicals, Inc. | Heterocyclic amine-boranes, and method of inhibiting DNA topoisomerase activity and/or combatting inflammation, hyperlipidemia, and/or neoplasia using amine-borane compounds |
| AU5159393A (en) * | 1992-09-18 | 1994-04-12 | Schering Corporation | Process for preparing felbamate, 2-phenyl-1,3-propanediol and intermediates |
| US6086837A (en) | 1997-04-24 | 2000-07-11 | Bechtel Bwxt Idaho, Llc | Method of synthesizing enriched decaborane for use in generating boron neutron capture therapy pharmaceuticals |
| AU2002335988A1 (en) | 2001-11-19 | 2003-06-10 | Applied Materials, Inc. | Ion imlantation method and apparatus |
| WO2004003973A2 (en) | 2002-06-26 | 2004-01-08 | Semequip Inc. | Ion implantation device and method |
| US7247286B2 (en) * | 2003-02-25 | 2007-07-24 | Rohm And Haas Company | Process for production of sodium borohydride from sodium aluminum hydride with recycle of byproducts |
| TWI372725B (en) * | 2004-01-30 | 2012-09-21 | Semequip Inc | Methods of synthesis of isotopically enriched borohydride and methods of synthesis of isotopically enriched boranes |
-
2005
- 2005-01-20 TW TW094101637A patent/TWI372725B/zh not_active IP Right Cessation
- 2005-01-28 CN CN2005800034011A patent/CN101001829B/zh not_active Expired - Fee Related
- 2005-01-28 US US11/047,165 patent/US7641879B2/en not_active Expired - Fee Related
- 2005-01-28 KR KR1020067017015A patent/KR101169515B1/ko not_active Expired - Fee Related
- 2005-01-28 JP JP2006551484A patent/JP4869947B2/ja not_active Expired - Fee Related
- 2005-01-28 WO PCT/US2005/002629 patent/WO2005074531A2/en not_active Ceased
-
2009
- 2009-12-31 US US12/650,730 patent/US8084007B2/en not_active Expired - Fee Related
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