JP2007507586A - 官能化ポリ(アリーレンエーテル)とエチレン−アルキル(メタ)アクリレートコポリマーを含む組成物、その製造方法並びにその製品 - Google Patents
官能化ポリ(アリーレンエーテル)とエチレン−アルキル(メタ)アクリレートコポリマーを含む組成物、その製造方法並びにその製品 Download PDFInfo
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- 0 C*c1c(*)c(*)c(*)c(*)c1* Chemical compound C*c1c(*)c(*)c(*)c(*)c1* 0.000 description 3
- NUOVDFQQFRDDQT-UHFFFAOYSA-N CC(C)[N-]([NH+]([IH][IH]N)[IH][I]=C)[I]1[IH]CC1 Chemical compound CC(C)[N-]([NH+]([IH][IH]N)[IH][I]=C)[I]1[IH]CC1 NUOVDFQQFRDDQT-UHFFFAOYSA-N 0.000 description 1
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- C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
- C08L71/08—Polyethers derived from hydroxy compounds or from their metallic derivatives
- C08L71/10—Polyethers derived from hydroxy compounds or from their metallic derivatives from phenols
- C08L71/12—Polyphenylene oxides
- C08L71/126—Polyphenylene oxides modified by chemical after-treatment
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- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/34—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from hydroxy compounds or their metallic derivatives
- C08G65/48—Polymers modified by chemical after-treatment
- C08G65/485—Polyphenylene oxides
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- C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
- C08F283/06—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polyethers, polyoxymethylenes or polyacetals
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- C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
- C08F283/06—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polyethers, polyoxymethylenes or polyacetals
- C08F283/08—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polyethers, polyoxymethylenes or polyacetals on to polyphenylene oxides
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- C08F290/00—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups
- C08F290/02—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups on to polymers modified by introduction of unsaturated end groups
- C08F290/06—Polymers provided for in subclass C08G
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- C08F290/00—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups
- C08F290/02—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups on to polymers modified by introduction of unsaturated end groups
- C08F290/06—Polymers provided for in subclass C08G
- C08F290/062—Polyethers
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- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/34—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from hydroxy compounds or their metallic derivatives
- C08G65/48—Polymers modified by chemical after-treatment
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
- C08L23/0869—Acids or derivatives thereof
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- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
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- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
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- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/02—Ethene
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- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/53—Phosphorus bound to oxygen bound to oxygen and to carbon only
- C08K5/5313—Phosphinic compounds, e.g. R2=P(:O)OR'
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- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/08—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving unsaturated carbon-to-carbon bonds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
- C08L71/08—Polyethers derived from hydroxy compounds or from their metallic derivatives
- C08L71/10—Polyethers derived from hydroxy compounds or from their metallic derivatives from phenols
- C08L71/12—Polyphenylene oxides
Abstract
【選択図】 なし
Description
式中、Qは一価、二価又は多価フェノールの残基、好ましくは一価又は二価フェノールの残基、さらに好ましくは一価フェノールの残基であり、yは1〜100であり、Jは次式の繰返し構造単位からなる。
5L三口丸底フラスコ中のトルエン溶液3Lに、ポリ(2,6−ジメチルフェニルエーテル)樹脂(固有粘度=0.30dL/g)1500g、無水メタクリル酸153g(1.0モル)及びジメチルアミノピリジン121g(1.0モル)を加えた。溶液を一晩加熱還流した。所望の生成物をメタノール中で沈殿させ、濾過によって単離した。得られた生成物(MAA−PPE)を80℃で一晩真空乾燥した。生成物の収量は1333gであった。生成物をリン官能化剤に曝露した後31P−NMR(CDCl3、2,3−ジオキサホスホラン)で分析したところ、検出可能な芳香族ヒドロキシ基は認められなかった(すなわち、ポリ(アリーレンエーテル)1g当たりヒドロキシル基5マイクロモル未満)。1H−NMR (CDCl3、TMS):2.07(s、6H、PPE CH3)、2.18(s、3H、メタクリレートCH3)、5.74(s、2H、メタクリレートCH2)、6.46(s、2H PPE Ar−H)、7.08(m、3H、PPE末端基)。
実施例1では、製造例Aで製造したメタクリレート封鎖ポリ(フェニレンエーテル)500gとAtofina社製のメチルアクリレート含有量6.5%のポリ(エチレン−コ−メチルアクリレート)(6.5%メチルアクリレート)500gとを含むブレンドを製造した。ブレンドを、Prism二軸押出機を用いて以下の設定(バレル温度140/170/240/270/270℃、ゾーン1/2/3/4/ノズル)で溶融コンパウンディングし、試験片をBoy Injection Molder(金型温度=40℃、バレル温度=ゾーン1/2/ノズルで160/210/200)で射出成形した。得られた試験片を用いて、最大荷重時引張強さ(MPa単位)及び破断点引張伸び(%)をASTM D638に準拠して測定した。表1に結果を示す。他の実施例及び比較例も同様に製造した。非官能化ポリ(アリーレンエーテル)は、製造例Aで使用した固有粘度0.30dL/gのポリ(2,6−ジメチルフェニルエーテル)樹脂であった。ポリ(エチレン−コ−メチルアクリレート)樹脂はすべてAtofina社から入手したもので、表1に記載のメチルアクリレート含有量を有するものであった。実施例7で使用した耐衝撃性改良剤KRATON(登録商標)G1701は、スチレン含有量約37重量%の水素添加スチレン−イソプレンコポリマーである。表1に組成及び特性をまとめた。結果は、官能化ポリ(アリーレンエーテル)を含む実施例1及び実施例2では、層間剥離を起こした非官能化ポリ(アリーレンエーテル)を含む比較例1及び比較例2に比べて、相溶性が向上していることを示している。結果は、メチルアクリレート含有量6.5%のポリ(エチレン−コ−メチルアクリレート)を含む実施例2の組成物は、比較例7の純PPE組成物に比べて、引張強さ及び伸びが向上していることも示している。結果は、さらに、耐衝撃性改良剤を含む実施例7では、高い衝撃強さを保持しつつ、顕著な引張伸びを呈することも示している。
実施例1の手順を用いて、さらに難燃剤を含む組成物を製造した。ポリ(エチレン−コ−メチルアクリレート)は、Atofina社から入手したメチルアクリレート含有量27重量%のものであった。ポリ(アリーレンエーテル)は、製造例Aで製造した固有粘度0.40dL/gの非官能化ポリ(2,6−ジメチルフェニルエーテル)樹脂であった。耐衝撃性改良剤は、Kraton Polymers社からKRATON(登録商標)G1701として市販の水素添加スチレン−イソプレン−スチレントリブロックコポリマーであった。ハロゲンフリーの難燃剤は、Clariant社からOP930として市販のアルミニウムトリス(ジエチルホスフィネート)であった。成分量はすべて重量%(wt%)で表す。オフセットでの引張強さ(MPa単位)、最大荷重時の引張強さ(MPa単位)、引張弾性率(MPa単位)及び破断点引張伸び(%)は、ASTM D638に準拠して測定した。ショアーA硬度はISO 868に準拠して測定した。燃焼性はUL−94試験に準拠して測定し、複数の試料を10秒間接炎し、燃焼が30秒以内に止まれば再度10秒間接炎した。望ましいUL−94 V−0評価には、試験片がいずれの接炎によっても10秒以上有炎燃焼しないこと、及び試験片の下300mmに配置された乾燥脱脂綿を着火させる有炎粒子を試験片が滴下しないことが求められる。標準偏差は、1回の試験で3枚の試料の測定値を反映したものである。表2に、組成及び特性をまとめた。結果は、難燃剤を17.5重量%含有する実施例10の組成物が、UL−94燃焼性試験で望ましいV−0評価を達成したことを示している。
Claims (10)
- 官能化ポリ(アリーレンエーテル)、及び
オレフィン−アルキル(メタ)アクリレートコポリマー
を含んでなる組成物。 - 前記官能化ポリ(アリーレンエーテル)が次の構造の封鎖ポリ(アリーレンエーテル)である、請求項1記載の組成物。
Q(J−K)y
式中、Qは一価、二価又は多価フェノールの残基であり、yは1〜100であり、Jは次式の繰返し構造単位からなり、
- 前記オレフィン−アルキル(メタ)アクリレートコポリマーが、(a)エチレン及びC3〜C8α−オレフィンから選択されるオレフィンと、(b)アルキル(メタ)アクリレート(ただし、アルキルはC1〜C8アルキルであり、(メタ)アクリレートはアクリレート又はメタクリレートを意味する。)との重合生成物である、請求項1記載の組成物。
- 前記オレフィン−アルキル(メタ)アクリレートコポリマーが、約60〜約95重量%のオレフィンと約5〜約40重量%のアルキル(メタ)アクリレートとの重合生成物である、請求項3記載の組成物。
- 前記オレフィン−アルキル(メタ)アクリレートコポリマーが、エチレン−メチルアクリレートコポリマー、エチレン−エチルアクリレートコポリマー、エチレン−メチルメタクリレートコポリマー、及びエチレン−エチルメタクリレートコポリマーからなる群から選択される、請求項1記載の組成物。
- さらに耐衝撃性改良剤を含む、請求項1記載の組成物。
- さらに難燃剤を含む、請求項1記載の組成物。
- 前記官能化ポリ(アリーレンエーテル)がメタクリレート封鎖ポリ(アリーレンエーテル)を含んでいて約25〜約95重量部で存在し、
前記オレフィン−アルキル(メタ)アクリレートコポリマーがエチレン−メチルアクリレートコポリマーを含んでいて約5〜約75重量部で存在し、
当該組成物が、約5〜約20重量部のアルケニル芳香族化合物と共役ジエンのコポリマーをさらに含んでおり、
当該組成物が、ハロゲンフリーの難燃剤約0.5〜約30重量部をさらに含んでおり、
上記重量部はすべて官能化ポリ(アリーレンエーテル)とオレフィン−アルキル(メタ)アクリレートコポリマーの合計100重量部を基準にしたものである、請求項1記載の組成物。 - 請求項1記載の組成物を含んでなる物品。
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US10/678,249 US7211639B2 (en) | 2003-10-03 | 2003-10-03 | Composition comprising functionalized poly(arylene ether) and ethylene-alkyl (meth)acrylate copolymer, method for the preparation thereof, and articles prepared therefrom |
PCT/US2004/028275 WO2005040279A1 (en) | 2003-10-03 | 2004-08-31 | Composition comprising functionalized poly(arylene ether) and ethylene-alkyl (meth)acrylate copolymer, method for the preparation thereof, and articles prepared therefrom |
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US (1) | US7211639B2 (ja) |
EP (1) | EP1678255B1 (ja) |
JP (1) | JP2007507586A (ja) |
KR (1) | KR100796108B1 (ja) |
CN (1) | CN100506915C (ja) |
WO (1) | WO2005040279A1 (ja) |
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WO2018221321A1 (ja) * | 2017-05-31 | 2018-12-06 | 住友化学株式会社 | 樹脂組成物及びその製造方法、並びに樹脂フィルム |
US10696843B2 (en) | 2015-11-06 | 2020-06-30 | Asahi Kasei Kabushiki Kaisha | Polyphenylene ether flame-retardant resin composition |
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US8859672B2 (en) | 2011-06-27 | 2014-10-14 | Sabic Global Technologies B.V. | Poly(arylene ether)-poly(hydroxy ether) block copolymer and method of making |
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- 2003-10-03 US US10/678,249 patent/US7211639B2/en not_active Expired - Fee Related
-
2004
- 2004-08-31 EP EP04782702A patent/EP1678255B1/en not_active Not-in-force
- 2004-08-31 CN CNB200480035191XA patent/CN100506915C/zh not_active Expired - Fee Related
- 2004-08-31 JP JP2006533864A patent/JP2007507586A/ja not_active Ceased
- 2004-08-31 WO PCT/US2004/028275 patent/WO2005040279A1/en not_active Application Discontinuation
- 2004-08-31 KR KR1020067007061A patent/KR100796108B1/ko not_active IP Right Cessation
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2015101730A (ja) * | 2013-11-27 | 2015-06-04 | ランクセス・ドイチュランド・ゲーエムベーハー | ポリエステル組成物 |
US10696843B2 (en) | 2015-11-06 | 2020-06-30 | Asahi Kasei Kabushiki Kaisha | Polyphenylene ether flame-retardant resin composition |
WO2018221321A1 (ja) * | 2017-05-31 | 2018-12-06 | 住友化学株式会社 | 樹脂組成物及びその製造方法、並びに樹脂フィルム |
JP2022026390A (ja) * | 2020-07-31 | 2022-02-10 | アイカ工業株式会社 | 樹脂組成物及びそれを用いた接着シート |
Also Published As
Publication number | Publication date |
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CN100506915C (zh) | 2009-07-01 |
KR20060083987A (ko) | 2006-07-21 |
EP1678255A1 (en) | 2006-07-12 |
KR100796108B1 (ko) | 2008-01-21 |
US7211639B2 (en) | 2007-05-01 |
CN1886458A (zh) | 2006-12-27 |
WO2005040279A1 (en) | 2005-05-06 |
US20050075472A1 (en) | 2005-04-07 |
EP1678255B1 (en) | 2012-11-14 |
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