JP2007296464A5 - - Google Patents

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Publication number

JP2007296464A5

JP2007296464A5 JP2006126030A JP2006126030A JP2007296464A5 JP 2007296464 A5 JP2007296464 A5 JP 2007296464A5 JP 2006126030 A JP2006126030 A JP 2006126030A JP 2006126030 A JP2006126030 A JP 2006126030A JP 2007296464 A5 JP2007296464 A5 JP 2007296464A5

Authority

JP

Japan

Prior art keywords

humic substance

composite porous

porous body

phosphoric acid

humic

Prior art date

2006-04-28

Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)

Granted

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• 239000000126 substance Substances 0.000 claims description 44
• NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 38
• VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 35
• 239000000378 calcium silicate Substances 0.000 claims description 22
• 229910052918 calcium silicate Inorganic materials 0.000 claims description 22
• 239000002131 composite material Substances 0.000 claims description 22
• 239000003463 adsorbent Substances 0.000 claims description 19
• 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 19
• OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 claims description 16
• 239000000377 silicon dioxide Substances 0.000 claims description 16
• 229910052588 hydroxylapatite Inorganic materials 0.000 claims description 15
• XYJRXVWERLGGKC-UHFFFAOYSA-D pentacalcium;hydroxide;triphosphate Chemical compound [OH-].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O XYJRXVWERLGGKC-UHFFFAOYSA-D 0.000 claims description 15
• 239000011575 calcium Substances 0.000 claims description 14
• 239000002245 particle Substances 0.000 claims description 13
• 239000011148 porous material Substances 0.000 claims description 10
• XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
• 238000004519 manufacturing process Methods 0.000 claims description 7
• 239000007864 aqueous solution Substances 0.000 claims description 6
• 238000001027 hydrothermal synthesis Methods 0.000 claims description 6
• 239000000463 material Substances 0.000 claims description 3
• 230000035699 permeability Effects 0.000 claims description 3
• OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 2
• 239000011574 phosphorus Substances 0.000 claims description 2
• 229910052698 phosphorus Inorganic materials 0.000 claims description 2
• 238000001179 sorption measurement Methods 0.000 description 27
• OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 12
• 239000002002 slurry Substances 0.000 description 8
• 230000000694 effects Effects 0.000 description 7
• ZZUFCTLCJUWOSV-UHFFFAOYSA-N furosemide Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC(C(O)=O)=C1NCC1=CC=CO1 ZZUFCTLCJUWOSV-UHFFFAOYSA-N 0.000 description 7
• OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 5
• 229910052791 calcium Inorganic materials 0.000 description 5
• -1 calcium silicate compound Chemical class 0.000 description 5
• OMOVVBIIQSXZSZ-UHFFFAOYSA-N [6-(4-acetyloxy-5,9a-dimethyl-2,7-dioxo-4,5a,6,9-tetrahydro-3h-pyrano[3,4-b]oxepin-5-yl)-5-formyloxy-3-(furan-3-yl)-3a-methyl-7-methylidene-1a,2,3,4,5,6-hexahydroindeno[1,7a-b]oxiren-4-yl] 2-hydroxy-3-methylpentanoate Chemical compound CC12C(OC(=O)C(O)C(C)CC)C(OC=O)C(C3(C)C(CC(=O)OC4(C)COC(=O)CC43)OC(C)=O)C(=C)C32OC3CC1C=1C=COC=1 OMOVVBIIQSXZSZ-UHFFFAOYSA-N 0.000 description 4
• 238000006243 chemical reaction Methods 0.000 description 4
• 230000000052 comparative effect Effects 0.000 description 4
• 239000007788 liquid Substances 0.000 description 4
• 229910052586 apatite Inorganic materials 0.000 description 3
• 238000000034 method Methods 0.000 description 3
• VSIIXMUUUJUKCM-UHFFFAOYSA-D pentacalcium;fluoride;triphosphate Chemical compound [F-].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O VSIIXMUUUJUKCM-UHFFFAOYSA-D 0.000 description 3
• 239000002994 raw material Substances 0.000 description 3
• 239000000243 solution Substances 0.000 description 3
• 239000002253 acid Substances 0.000 description 2
• AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 2
• 239000000920 calcium hydroxide Substances 0.000 description 2
• 229910001861 calcium hydroxide Inorganic materials 0.000 description 2
• 235000011116 calcium hydroxide Nutrition 0.000 description 2
• 239000000843 powder Substances 0.000 description 2
• 238000003756 stirring Methods 0.000 description 2
• PUKLDDOGISCFCP-JSQCKWNTSA-N 21-Deoxycortisone Chemical compound C1CC2=CC(=O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@@](C(=O)C)(O)[C@@]1(C)CC2=O PUKLDDOGISCFCP-JSQCKWNTSA-N 0.000 description 1
• QJZYHAIUNVAGQP-UHFFFAOYSA-N 3-nitrobicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid Chemical compound C1C2C=CC1C(C(=O)O)C2(C(O)=O)[N+]([O-])=O QJZYHAIUNVAGQP-UHFFFAOYSA-N 0.000 description 1
• 239000004254 Ammonium phosphate Substances 0.000 description 1
• 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
• FCYKAQOGGFGCMD-UHFFFAOYSA-N Fulvic acid Natural products O1C2=CC(O)=C(O)C(C(O)=O)=C2C(=O)C2=C1CC(C)(O)OC2 FCYKAQOGGFGCMD-UHFFFAOYSA-N 0.000 description 1
• 241001465754 Metazoa Species 0.000 description 1
• BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
• 229910019142 PO4 Inorganic materials 0.000 description 1
• 235000011941 Tilia x europaea Nutrition 0.000 description 1
• 238000010306 acid treatment Methods 0.000 description 1
• 229910000148 ammonium phosphate Inorganic materials 0.000 description 1
• 235000019289 ammonium phosphates Nutrition 0.000 description 1
• UUVBYOGFRMMMQL-UHFFFAOYSA-N calcium;phosphoric acid Chemical compound [Ca].OP(O)(O)=O UUVBYOGFRMMMQL-UHFFFAOYSA-N 0.000 description 1
• 230000015556 catabolic process Effects 0.000 description 1
• 150000001875 compounds Chemical class 0.000 description 1
• 238000007796 conventional method Methods 0.000 description 1
• 238000002425 crystallisation Methods 0.000 description 1
• 230000008025 crystallization Effects 0.000 description 1
• 238000000354 decomposition reaction Methods 0.000 description 1
• 238000006731 degradation reaction Methods 0.000 description 1
• MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 description 1
• 229940095100 fulvic acid Drugs 0.000 description 1
• 239000002509 fulvic acid Substances 0.000 description 1
• 239000004021 humic acid Substances 0.000 description 1
• 239000004571 lime Substances 0.000 description 1
• 230000000813 microbial effect Effects 0.000 description 1
• 239000000203 mixture Substances 0.000 description 1
• 235000021317 phosphate Nutrition 0.000 description 1
• 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
• 230000000704 physical effect Effects 0.000 description 1
• 102000004169 proteins and genes Human genes 0.000 description 1
• 108090000623 proteins and genes Proteins 0.000 description 1
• 230000035484 reaction time Effects 0.000 description 1
• RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
• 235000012239 silicon dioxide Nutrition 0.000 description 1
• 239000001488 sodium phosphate Substances 0.000 description 1
• 229910000162 sodium phosphate Inorganic materials 0.000 description 1
• 239000007787 solid Substances 0.000 description 1
• 239000002594 sorbent Substances 0.000 description 1
• 239000002344 surface layer Substances 0.000 description 1
• RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1