JP2007138008A - 光拡散性ポリカーボネート樹脂組成物およびそれからなる光拡散板 - Google Patents
光拡散性ポリカーボネート樹脂組成物およびそれからなる光拡散板 Download PDFInfo
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- JP2007138008A JP2007138008A JP2005333552A JP2005333552A JP2007138008A JP 2007138008 A JP2007138008 A JP 2007138008A JP 2005333552 A JP2005333552 A JP 2005333552A JP 2005333552 A JP2005333552 A JP 2005333552A JP 2007138008 A JP2007138008 A JP 2007138008A
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- Prior art keywords
- light
- polycarbonate resin
- light diffusing
- resin composition
- ultraviolet absorber
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 229920005668 polycarbonate resin Polymers 0.000 title claims abstract description 35
- 239000004431 polycarbonate resin Substances 0.000 title claims abstract description 35
- 239000000203 mixture Substances 0.000 title claims abstract description 17
- 238000009792 diffusion process Methods 0.000 title abstract description 9
- 239000006097 ultraviolet radiation absorber Substances 0.000 claims abstract description 30
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 28
- 238000002156 mixing Methods 0.000 claims description 12
- 229920005989 resin Polymers 0.000 claims description 7
- 239000011347 resin Substances 0.000 claims description 7
- 125000004432 carbon atom Chemical group C* 0.000 claims description 6
- 238000000465 moulding Methods 0.000 claims description 4
- 239000004973 liquid crystal related substance Substances 0.000 claims description 3
- 229920006352 transparent thermoplastic Polymers 0.000 claims description 2
- 238000013329 compounding Methods 0.000 abstract description 3
- 230000000052 comparative effect Effects 0.000 description 14
- -1 4-hydroxy-3,5-dichlorophenyl Chemical group 0.000 description 8
- 238000004040 coloring Methods 0.000 description 8
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- 238000012360 testing method Methods 0.000 description 8
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- 239000003063 flame retardant Substances 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 5
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- 238000004383 yellowing Methods 0.000 description 2
- HCNHNBLSNVSJTJ-UHFFFAOYSA-N 1,1-Bis(4-hydroxyphenyl)ethane Chemical compound C=1C=C(O)C=CC=1C(C)C1=CC=C(O)C=C1 HCNHNBLSNVSJTJ-UHFFFAOYSA-N 0.000 description 1
- BCMCBBGGLRIHSE-UHFFFAOYSA-N 1,3-benzoxazole Chemical compound C1=CC=C2OC=NC2=C1 BCMCBBGGLRIHSE-UHFFFAOYSA-N 0.000 description 1
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- MXSKJYLPNPYQHH-UHFFFAOYSA-N 2,4-dimethyl-6-(1-methylcyclohexyl)phenol Chemical compound CC1=CC(C)=C(O)C(C2(C)CCCCC2)=C1 MXSKJYLPNPYQHH-UHFFFAOYSA-N 0.000 description 1
- IYAZLDLPUNDVAG-UHFFFAOYSA-N 2-(benzotriazol-2-yl)-4-(2,4,4-trimethylpentan-2-yl)phenol Chemical compound CC(C)(C)CC(C)(C)C1=CC=C(O)C(N2N=C3C=CC=CC3=N2)=C1 IYAZLDLPUNDVAG-UHFFFAOYSA-N 0.000 description 1
- PQJZHMCWDKOPQG-UHFFFAOYSA-N 2-anilino-2-oxoacetic acid Chemical compound OC(=O)C(=O)NC1=CC=CC=C1 PQJZHMCWDKOPQG-UHFFFAOYSA-N 0.000 description 1
- CVEPFOUZABPRMK-UHFFFAOYSA-N 2-methylprop-2-enoic acid;styrene Chemical compound CC(=C)C(O)=O.C=CC1=CC=CC=C1 CVEPFOUZABPRMK-UHFFFAOYSA-N 0.000 description 1
- HXIQYSLFEXIOAV-UHFFFAOYSA-N 2-tert-butyl-4-(5-tert-butyl-4-hydroxy-2-methylphenyl)sulfanyl-5-methylphenol Chemical compound CC1=CC(O)=C(C(C)(C)C)C=C1SC1=CC(C(C)(C)C)=C(O)C=C1C HXIQYSLFEXIOAV-UHFFFAOYSA-N 0.000 description 1
- CKNCVRMXCLUOJI-UHFFFAOYSA-N 3,3'-dibromobisphenol A Chemical compound C=1C=C(O)C(Br)=CC=1C(C)(C)C1=CC=C(O)C(Br)=C1 CKNCVRMXCLUOJI-UHFFFAOYSA-N 0.000 description 1
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- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 150000003462 sulfoxides Chemical class 0.000 description 1
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- JUWGUJSXVOBPHP-UHFFFAOYSA-B titanium(4+);tetraphosphate Chemical compound [Ti+4].[Ti+4].[Ti+4].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O JUWGUJSXVOBPHP-UHFFFAOYSA-B 0.000 description 1
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 1
- 238000005809 transesterification reaction Methods 0.000 description 1
- 238000002834 transmittance Methods 0.000 description 1
- XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2011040723A (ja) * | 2009-07-15 | 2011-02-24 | Sumitomo Chemical Co Ltd | 太陽電池用封止材 |
| CN107418180A (zh) * | 2017-05-27 | 2017-12-01 | 深圳市绿自然生物降解科技有限公司 | 一种高刚性光扩散pc材料及其制备方法与应用 |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0925403A (ja) * | 1995-07-07 | 1997-01-28 | Nippon Oil & Fats Co Ltd | 耐候性ポリカーボネート系樹脂組成物 |
| WO1998024848A1 (en) * | 1996-11-22 | 1998-06-11 | Mitsui Chemicals, Inc. | Thermoplastic resin composition and film made from the composition |
| JP2000239512A (ja) * | 1998-12-24 | 2000-09-05 | Asahi Denka Kogyo Kk | ポリカーボネート樹脂成形物 |
| WO2004111692A1 (ja) * | 2003-06-17 | 2004-12-23 | Teijin Chemicals Ltd. | 直下型バックライト式液晶表示装置および光拡散板 |
| JP2005247999A (ja) * | 2004-03-04 | 2005-09-15 | Mitsubishi Engineering Plastics Corp | 光拡散性樹脂組成物 |
| JP2005284237A (ja) * | 2004-03-05 | 2005-10-13 | Sumitomo Dow Ltd | 光拡散板用ポリカーボネート樹脂組成物およびそれからなる液晶ディスプレイ用光拡散板 |
| JP2006117822A (ja) * | 2004-10-22 | 2006-05-11 | Idemitsu Kosan Co Ltd | ポリカーボネート系光拡散性樹脂組成物 |
-
2005
- 2005-11-18 JP JP2005333552A patent/JP2007138008A/ja active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0925403A (ja) * | 1995-07-07 | 1997-01-28 | Nippon Oil & Fats Co Ltd | 耐候性ポリカーボネート系樹脂組成物 |
| WO1998024848A1 (en) * | 1996-11-22 | 1998-06-11 | Mitsui Chemicals, Inc. | Thermoplastic resin composition and film made from the composition |
| JP2000239512A (ja) * | 1998-12-24 | 2000-09-05 | Asahi Denka Kogyo Kk | ポリカーボネート樹脂成形物 |
| WO2004111692A1 (ja) * | 2003-06-17 | 2004-12-23 | Teijin Chemicals Ltd. | 直下型バックライト式液晶表示装置および光拡散板 |
| JP2005247999A (ja) * | 2004-03-04 | 2005-09-15 | Mitsubishi Engineering Plastics Corp | 光拡散性樹脂組成物 |
| JP2005284237A (ja) * | 2004-03-05 | 2005-10-13 | Sumitomo Dow Ltd | 光拡散板用ポリカーボネート樹脂組成物およびそれからなる液晶ディスプレイ用光拡散板 |
| JP2006117822A (ja) * | 2004-10-22 | 2006-05-11 | Idemitsu Kosan Co Ltd | ポリカーボネート系光拡散性樹脂組成物 |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2011040723A (ja) * | 2009-07-15 | 2011-02-24 | Sumitomo Chemical Co Ltd | 太陽電池用封止材 |
| CN107418180A (zh) * | 2017-05-27 | 2017-12-01 | 深圳市绿自然生物降解科技有限公司 | 一种高刚性光扩散pc材料及其制备方法与应用 |
| CN107418180B (zh) * | 2017-05-27 | 2023-05-26 | 蓝小平 | 一种高刚性光扩散pc材料及其制备方法与应用 |
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