JP2007051385A - 難燃性ポリエステル系繊維構造物 - Google Patents
難燃性ポリエステル系繊維構造物 Download PDFInfo
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- JP2007051385A JP2007051385A JP2005235905A JP2005235905A JP2007051385A JP 2007051385 A JP2007051385 A JP 2007051385A JP 2005235905 A JP2005235905 A JP 2005235905A JP 2005235905 A JP2005235905 A JP 2005235905A JP 2007051385 A JP2007051385 A JP 2007051385A
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- fiber structure
- flame
- phosphate
- flame retardant
- polyester fiber
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 239000000835 fiber Substances 0.000 title claims abstract description 64
- 229920000728 polyester Polymers 0.000 title claims abstract description 49
- 239000003063 flame retardant Substances 0.000 title claims abstract description 47
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims abstract description 35
- 229910019142 PO4 Inorganic materials 0.000 claims abstract description 19
- 239000010452 phosphate Substances 0.000 claims abstract description 19
- 150000001875 compounds Chemical class 0.000 claims abstract description 17
- -1 phosphate ester flame retardant compound Chemical class 0.000 claims description 36
- PTMHPRAIXMAOOB-UHFFFAOYSA-N phosphoramidic acid Chemical compound NP(O)(O)=O PTMHPRAIXMAOOB-UHFFFAOYSA-N 0.000 claims description 12
- 150000003014 phosphoric acid esters Chemical class 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 abstract description 9
- PTMHPRAIXMAOOB-UHFFFAOYSA-L phosphoramidate Chemical compound NP([O-])([O-])=O PTMHPRAIXMAOOB-UHFFFAOYSA-L 0.000 abstract description 2
- 238000012805 post-processing Methods 0.000 abstract description 2
- 238000000034 method Methods 0.000 description 19
- 239000004744 fabric Substances 0.000 description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 9
- 239000006185 dispersion Substances 0.000 description 9
- 238000012545 processing Methods 0.000 description 7
- 239000003795 chemical substances by application Substances 0.000 description 6
- 125000003118 aryl group Chemical group 0.000 description 5
- 238000004043 dyeing Methods 0.000 description 5
- 239000002736 nonionic surfactant Substances 0.000 description 5
- 238000005406 washing Methods 0.000 description 5
- VPWNQTHUCYMVMZ-UHFFFAOYSA-N 4,4'-sulfonyldiphenol Chemical compound C1=CC(O)=CC=C1S(=O)(=O)C1=CC=C(O)C=C1 VPWNQTHUCYMVMZ-UHFFFAOYSA-N 0.000 description 4
- APOXBWCRUPJDAC-UHFFFAOYSA-N bis(2,6-dimethylphenyl) hydrogen phosphate Chemical compound CC1=CC=CC(C)=C1OP(O)(=O)OC1=C(C)C=CC=C1C APOXBWCRUPJDAC-UHFFFAOYSA-N 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 229920002994 synthetic fiber Polymers 0.000 description 4
- 239000012209 synthetic fiber Substances 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- AMAHHZOOPQPKRY-UHFFFAOYSA-N anilino diphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)ONC1=CC=CC=C1 AMAHHZOOPQPKRY-UHFFFAOYSA-N 0.000 description 3
- 239000003945 anionic surfactant Substances 0.000 description 3
- 235000014113 dietary fatty acids Nutrition 0.000 description 3
- 239000000194 fatty acid Substances 0.000 description 3
- 229930195729 fatty acid Natural products 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 239000003960 organic solvent Substances 0.000 description 3
- 150000003871 sulfonates Chemical class 0.000 description 3
- CXICHLXHSUQFBP-UHFFFAOYSA-N 3-hydroxy-6,7,8,9-tetraphenyl-2,4-dioxa-3lambda5-phosphabicyclo[3.3.1]nona-1(9),5,7-triene 3-oxide Chemical compound O1P(O)(=O)OC(C(=C2C=3C=CC=CC=3)C=3C=CC=CC=3)=C(C=3C=CC=CC=3)C1=C2C1=CC=CC=C1 CXICHLXHSUQFBP-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- RZUMESFNTZTKAX-UHFFFAOYSA-N CC1=CC=CC(C)=C1C1=C(OP(O)(=O)O2)C(C=3C(=CC=CC=3C)C)=C(C=3C(=CC=CC=3C)C)C2=C1C1=C(C)C=CC=C1C Chemical compound CC1=CC=CC(C)=C1C1=C(OP(O)(=O)O2)C(C=3C(=CC=CC=3C)C)=C(C=3C(=CC=CC=3C)C)C2=C1C1=C(C)C=CC=C1C RZUMESFNTZTKAX-UHFFFAOYSA-N 0.000 description 2
- PFJYYGMOMPCFMV-UHFFFAOYSA-N CC1=CC=CC(C)=C1C1=C2C(C=3C(=CC=CC=3C)C)=C(C=3C(=CC=CC=3C)C)C(C=3C(=CC=CC=3C)C)=C1OP(O)(=O)O2 Chemical compound CC1=CC=CC(C)=C1C1=C2C(C=3C(=CC=CC=3C)C)=C(C=3C(=CC=CC=3C)C)C(C=3C(=CC=CC=3C)C)=C1OP(O)(=O)O2 PFJYYGMOMPCFMV-UHFFFAOYSA-N 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 2
- 229930182843 D-Lactic acid Natural products 0.000 description 2
- JVTAAEKCZFNVCJ-UWTATZPHSA-N D-lactic acid Chemical compound C[C@@H](O)C(O)=O JVTAAEKCZFNVCJ-UWTATZPHSA-N 0.000 description 2
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 2
- JVTAAEKCZFNVCJ-REOHCLBHSA-N L-lactic acid Chemical compound C[C@H](O)C(O)=O JVTAAEKCZFNVCJ-REOHCLBHSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 229920003232 aliphatic polyester Polymers 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- 239000002216 antistatic agent Substances 0.000 description 2
- MWVJKIZKNCNWHE-UHFFFAOYSA-N bis(1,6-dimethylcyclohexa-2,4-dien-1-yl) hydrogen phosphate Chemical compound C1(C(C=CC=C1)C)(C)OP(OC1(C(C=CC=C1)C)C)(O)=O MWVJKIZKNCNWHE-UHFFFAOYSA-N 0.000 description 2
- 239000013065 commercial product Substances 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical compound C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 description 2
- 239000001177 diphosphate Substances 0.000 description 2
- XPPKVPWEQAFLFU-UHFFFAOYSA-J diphosphate(4-) Chemical compound [O-]P([O-])(=O)OP([O-])([O-])=O XPPKVPWEQAFLFU-UHFFFAOYSA-J 0.000 description 2
- 235000011180 diphosphates Nutrition 0.000 description 2
- 239000000986 disperse dye Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 230000002708 enhancing effect Effects 0.000 description 2
- 229910052736 halogen Inorganic materials 0.000 description 2
- 150000002366 halogen compounds Chemical class 0.000 description 2
- 150000002367 halogens Chemical class 0.000 description 2
- 230000009931 harmful effect Effects 0.000 description 2
- 239000004745 nonwoven fabric Substances 0.000 description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
- 229920000139 polyethylene terephthalate Polymers 0.000 description 2
- 239000005020 polyethylene terephthalate Substances 0.000 description 2
- 239000000344 soap Substances 0.000 description 2
- 150000005846 sugar alcohols Polymers 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- KPGXUAIFQMJJFB-UHFFFAOYSA-H tungsten hexachloride Chemical compound Cl[W](Cl)(Cl)(Cl)(Cl)Cl KPGXUAIFQMJJFB-UHFFFAOYSA-H 0.000 description 2
- MFFNRVNPBJQZFO-UHFFFAOYSA-N (2,6-dimethylphenyl) dihydrogen phosphate Chemical compound CC1=CC=CC(C)=C1OP(O)(O)=O MFFNRVNPBJQZFO-UHFFFAOYSA-N 0.000 description 1
- OWICEWMBIBPFAH-UHFFFAOYSA-N (3-diphenoxyphosphoryloxyphenyl) diphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=C(OP(=O)(OC=2C=CC=CC=2)OC=2C=CC=CC=2)C=CC=1)(=O)OC1=CC=CC=C1 OWICEWMBIBPFAH-UHFFFAOYSA-N 0.000 description 1
- FEADEJBBYVOKAR-UHFFFAOYSA-N (benzylamino) diphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)ONCC1=CC=CC=C1 FEADEJBBYVOKAR-UHFFFAOYSA-N 0.000 description 1
- SJRYCCJBAYNKBK-UHFFFAOYSA-N (n-methylanilino) diphenyl phosphate Chemical compound C=1C=CC=CC=1N(C)OP(=O)(OC=1C=CC=CC=1)OC1=CC=CC=C1 SJRYCCJBAYNKBK-UHFFFAOYSA-N 0.000 description 1
- DEIGXXQKDWULML-UHFFFAOYSA-N 1,2,5,6,9,10-hexabromocyclododecane Chemical compound BrC1CCC(Br)C(Br)CCC(Br)C(Br)CCC1Br DEIGXXQKDWULML-UHFFFAOYSA-N 0.000 description 1
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 1
- QFJRGRPBOIFZIC-UHFFFAOYSA-N 3-hydroxy-6,7,8,9-tetraphenyl-2,4-dioxa-3lambda5-phosphabicyclo[3.2.2]nona-1(7),5,8-triene 3-oxide Chemical compound C=1C=CC=CC=1C1=C(C(C=2C=CC=CC=2)=C2C=3C=CC=CC=3)OP(O)(=O)OC2=C1C1=CC=CC=C1 QFJRGRPBOIFZIC-UHFFFAOYSA-N 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 229940126062 Compound A Drugs 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- NLDMNSXOCDLTTB-UHFFFAOYSA-N Heterophylliin A Natural products O1C2COC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC2C(OC(=O)C=2C=C(O)C(O)=C(O)C=2)C(O)C1OC(=O)C1=CC(O)=C(O)C(O)=C1 NLDMNSXOCDLTTB-UHFFFAOYSA-N 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- 241001024304 Mino Species 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- CYTYCFOTNPOANT-UHFFFAOYSA-N Perchloroethylene Chemical group ClC(Cl)=C(Cl)Cl CYTYCFOTNPOANT-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 229920000388 Polyphosphate Polymers 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- VKUJKQWLKXFTNC-UHFFFAOYSA-N [2,3-bis(2-methylphenyl)anilino] dihydrogen phosphate Chemical compound CC1=CC=CC=C1C1=CC=CC(NOP(O)(O)=O)=C1C1=CC=CC=C1C VKUJKQWLKXFTNC-UHFFFAOYSA-N 0.000 description 1
- BQPNUOYXSVUVMY-UHFFFAOYSA-N [4-[2-(4-diphenoxyphosphoryloxyphenyl)propan-2-yl]phenyl] diphenyl phosphate Chemical compound C=1C=C(OP(=O)(OC=2C=CC=CC=2)OC=2C=CC=CC=2)C=CC=1C(C)(C)C(C=C1)=CC=C1OP(=O)(OC=1C=CC=CC=1)OC1=CC=CC=C1 BQPNUOYXSVUVMY-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- UINZSQJVKLWNOU-UHFFFAOYSA-N amino diphenyl phosphate Chemical compound C=1C=CC=CC=1OP(=O)(ON)OC1=CC=CC=C1 UINZSQJVKLWNOU-UHFFFAOYSA-N 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 235000010290 biphenyl Nutrition 0.000 description 1
- 239000004305 biphenyl Substances 0.000 description 1
- 125000006267 biphenyl group Chemical group 0.000 description 1
- UQRSMZHDWDMLDH-UHFFFAOYSA-N bis(2-tert-butylphenyl) phenyl phosphate Chemical compound CC(C)(C)C1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C(C)(C)C)OC1=CC=CC=C1 UQRSMZHDWDMLDH-UHFFFAOYSA-N 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 208000018747 cerebellar ataxia with neuropathy and bilateral vestibular areflexia syndrome Diseases 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 150000001924 cycloalkanes Chemical class 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- 229940022769 d- lactic acid Drugs 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 239000002781 deodorant agent Substances 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- IJYLCYCYIZCJKG-UHFFFAOYSA-N diethylamino diphenyl phosphate Chemical compound C=1C=CC=CC=1OP(=O)(ON(CC)CC)OC1=CC=CC=C1 IJYLCYCYIZCJKG-UHFFFAOYSA-N 0.000 description 1
- AOVQQXYSSMNQLM-UHFFFAOYSA-N dimethylamino diphenyl phosphate Chemical compound C=1C=CC=CC=1OP(=O)(ON(C)C)OC1=CC=CC=C1 AOVQQXYSSMNQLM-UHFFFAOYSA-N 0.000 description 1
- RZHBMYQXKIDANM-UHFFFAOYSA-N dioctyl butanedioate;sodium Chemical compound [Na].CCCCCCCCOC(=O)CCC(=O)OCCCCCCCC RZHBMYQXKIDANM-UHFFFAOYSA-N 0.000 description 1
- ASMQGLCHMVWBQR-UHFFFAOYSA-M diphenyl phosphate Chemical compound C=1C=CC=CC=1OP(=O)([O-])OC1=CC=CC=C1 ASMQGLCHMVWBQR-UHFFFAOYSA-M 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 238000005108 dry cleaning Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- YYAPGVHZYALGDW-UHFFFAOYSA-N ethylamino diphenyl phosphate Chemical compound C=1C=CC=CC=1OP(=O)(ONCC)OC1=CC=CC=C1 YYAPGVHZYALGDW-UHFFFAOYSA-N 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 229930182470 glycoside Natural products 0.000 description 1
- 238000009499 grossing Methods 0.000 description 1
- 239000012760 heat stabilizer Substances 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000004611 light stabiliser Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- OWOQYZVZJSTUHQ-UHFFFAOYSA-N methylamino diphenyl phosphate Chemical compound C=1C=CC=CC=1OP(=O)(ONC)OC1=CC=CC=C1 OWOQYZVZJSTUHQ-UHFFFAOYSA-N 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- JLRGKSYTFYOYHZ-UHFFFAOYSA-N morpholin-4-yl diphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)ON1CCOCC1 JLRGKSYTFYOYHZ-UHFFFAOYSA-N 0.000 description 1
- GSGDTSDELPUTKU-UHFFFAOYSA-N nonoxybenzene Chemical compound CCCCCCCCCOC1=CC=CC=C1 GSGDTSDELPUTKU-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-N phosphoric acid Substances OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 1
- 235000011007 phosphoric acid Nutrition 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920001432 poly(L-lactide) Polymers 0.000 description 1
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- 239000005871 repellent Substances 0.000 description 1
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- 235000019698 starch Nutrition 0.000 description 1
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- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
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- 125000003944 tolyl group Chemical group 0.000 description 1
- SPUXJWDKFVXXBI-UHFFFAOYSA-N tris(2-tert-butylphenyl) phosphate Chemical compound CC(C)(C)C1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C(C)(C)C)OC1=CC=CC=C1C(C)(C)C SPUXJWDKFVXXBI-UHFFFAOYSA-N 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Landscapes
- Fireproofing Substances (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
【解決手段】ポリエステル系繊維構造物を構成する繊維が、本文中に示す式1のリン酸アミドと、同式2、同式3および同式4のリン酸エステル系難燃性化合物からなる群から選ばれた少なくとも1種の化合物とを含有することを特徴とする難燃性ポリエステル系繊維構造物。
【選択図】なし
Description
本発明における上記リン酸アミドおよび上記リン酸エステル系難燃性化合物の配合比は重量比で1:0.25〜1:1であることが好ましく、より好ましくは1:0.25〜1:0.75、である。配合比がこれ以上であれば、十分な難燃性能が得られない。
(1)難燃性能
難燃加工した布帛とこれを下記の条件で5回水洗濯または5回ドライクリーニング(DC)したものについて、JIS L 1091 A−1法(ミクロバーナー法)およびJIS L 1091D法(コイル法)にて難燃性能を評価した。ミクロバーナー法においては、1分間加熱、着炎後3秒加熱ともに、残炎が3秒以内、残塵が5秒以内、炭化面積が30cm2 以内のとき、区分3に合格であり、コイル法においては、接炎回数が3回以上であるとき、区分2に合格である。
JIS K 3371に従って、弱アルカリ性第1種洗剤を1g/Lの割合で用い、浴比1:40として、60℃±2℃で15分間水洗濯した後、40℃±2℃で5分間のすすぎを3回行ない、遠心脱水を2分間行ない、その後、60℃±5℃で熱風乾燥する1サイクルを5サイクル行った。
(DC)
試料1gにつき、テトラクロロエチレン12.6mL、チャージソープ0.265g(チャージソープの重量組成は、ノニオン系界面活性剤(ノニルフェニルエーテルのエチレンオキシド10モル付加物)/アニオン系界面活性剤(ジオクチル琥珀酸ナトリウム塩)/水=10/10/1)を用いて、30℃±2℃で15分間の処理を1サイクルとし、これを5サイクル行った。
(2)染色堅牢度
JIS L 0846に準拠して、難燃加工した布帛を染色堅牢度試験法B法によって試験を行い、汚染用グレースケールで測定した。摩擦試験機は学振形を用いた。
(試料ポリエステル繊維布帛)
経糸として90デシテックス48フィラメントのスルホン化芳香族ジカルボン酸変性ポリエチレンテレフタレートからなる変性ポリエステル繊維を用い、緯糸として150デシテックス48フィラメントのポリエステル繊維を用い、平織とした織物に通常の方法によって精練、プレセットを施したものを試料ポリエステル繊維布帛とした。
(難燃性化合物)
化合物A:式5に示す化合物(アニリノジフェニルホスフェート)を40重量%の濃度で含有する水分散液を使用した。
以下に示す条件で、液流染色機を用い、浴比1:20で130℃で45分の処理を行い、次に、通常の還元洗浄を行い、水洗後、乾燥し、170℃で1分間熱処理を行った。
={(加工後の繊維重量−加工前の繊維重量)/(加工前の繊維重量)}×100
実施例1から実施例6によれば、リン酸アミドと難燃性化合物のいずれか1種の組み合わせにより良好な難燃性能および耐久性を付与することができる。
Claims (3)
- 前記リン酸アミドと前記リン酸エステル系難燃性化合物の配合比が重量比で1:0.25〜1:1であり、また前記リン酸アミドと前記リン酸エステル系難燃性化合物との合計含有量がポリエステル系合成繊維構造物に対して、0.5重量%以上であることを特徴とする請求項1記載の難燃性ポリエステル系繊維構造物。
- 難燃性ポリエステル系繊維構造物の用途が、衣料、寝装具、カーテン、ロールカーテン、シート、シートカバー、緞帳、壁クロス、天井クロス、カーペット、テント、および養生シートから選ばれるいずれか一つの用途であることを特徴とする請求項1または2記載の難燃性ポリエステル系繊維構造物。
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