JP2006022264A - 熱可塑性樹脂組成物 - Google Patents
熱可塑性樹脂組成物 Download PDFInfo
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- JP2006022264A JP2006022264A JP2004203330A JP2004203330A JP2006022264A JP 2006022264 A JP2006022264 A JP 2006022264A JP 2004203330 A JP2004203330 A JP 2004203330A JP 2004203330 A JP2004203330 A JP 2004203330A JP 2006022264 A JP2006022264 A JP 2006022264A
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- thermoplastic resin
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Abstract
【課題】複屈折、吸水率が小さく、防湿性などが優れている環状オレフィン系重合体において、温度、湿度変化の際に光線透過率の低下や、微小なクラックの発生を、本来該樹脂が持っている良好な光学物性を損なわず防止すること。
【解決手段】特定構造のポリマーより選ばれる1種、または2種以上のポリマー100重量部に対し、[B]ペンタエリスルトールと炭素数9以上27以下の脂肪酸からなるエステルより選ばれる1種または2種以上の化合物を0.3乃至5.0重量部を含有してなる熱可塑性樹脂組成物。
【選択図】なし
Description
[B] ペンタエリスルトールと炭素数9以上27以下の脂肪酸からなるエステル
本発明の光学部品の原料として用いられる樹脂は特に限定されるものではないが、好ましくは前記一般化学式(1)で表現される環状オレフィン系共重合体からなる。
で表される二価の基であり、最も好ましくは、前記一般化学式(2)においてpが0または1である二価の基である。R1の構造は1種のみ用いても、2種以上併用しても構わない。
また本発明で用いられるポリマーは、本発明の成形方法によって得られる製品の良好な物性を損なわない範囲で、必要に応じて他の共重合可能なモノマーから誘導される繰り返し構造単位を有していてもよい。その共重合比は限定されないが、好ましくは20モル%以下、さらに好ましくは10モル%以下であり、それ以上共重合させた場合、光学物性を損ない、高精度の光学部品が得られない恐れがある。また、共重合の種類は限定されないが、ランダムコポリマーが好ましい。
本発明の光学部品に用いられるポリマーの分子量は限定されるものではないが、好ましくは135℃のデカリン中で測定される極限粘度[η]が、0.03〜10dl/g、さらに好ましくは0.05〜5dl/gであり、最も好ましくは0.10〜2dl/gである。
なお、ポリマーのガラス転移温度(以下Tgと記載)は70℃以上であることが好ましく、さらに好ましくは70〜250℃であり、最も好ましくは100〜200℃である。
なお、TgはDSC, 粘弾性測定等、通常公知の方法で測定することができる。
このポリマーは本発明の光学部品の良好な諸物性を損なわない範囲内で、グラフト変性など、公知の様々な方法により変性して用いることができる。
炭素数9以上27以下の脂肪酸は、この範囲を超えて炭素数が少ない場合は、樹脂との親和性が不足するため均一に混ぜることが難しくなり、炭素数が多い場合は、温度・湿度変化の際の光線透過率の低下や、微小なクラックの発生の防止効果が少なくなる。
RCOOCH2C(CH2OH)3 (2)
式中、Rは炭素数9以上27以下、さらに好ましくは11以上23以下、最も好ましくは14以上20以下の飽和炭化水素基である。
本発明においては、必要に応じて、さらに他の樹脂を配合してなる樹脂組成物を用いることもできる。他の樹脂は、本発明の目的を損なわない範囲で添加される。
(1)1個または2個の不飽和結合を有する炭化水素から誘導される重合体。具体的には、例えばポリエチレン、ポリプロピレン、ポリメチルブテン-1、ポリ4-メチルペンテン-1、ポリブテン-1およびポリスチレンなどのポリオレフィンが挙げられる。なおこれらのポリオレフィンは架橋構造を有していてもよい。
本発明で用いる樹脂組成物には、上述の成分に加えてさらに、本発明の樹脂組成物の良好な特性を損なわない範囲で、公知の耐候安定剤、耐熱安定剤、帯電防止剤、難燃剤、スリップ剤、アンチブロッキング剤、防曇剤、滑剤、染料、顔料、天然油、合成油、ワックス、有機または無機の充填剤などが配合されていてもよい。
溶融流れ指数(MFR)
ASTM D1238に準じ260℃、荷重2.16kgで測定。
軟化温度(TMA)
デュポン社製 Thermo Mechanical Analyzerを用いて、厚さ1mmのシートの熱変形挙動により測定した。シート上に石英製針を乗せ、荷重49gをかけ、5℃/分の速度で昇温し、針がシート中に0.635mm侵入した温度をTMAとした。
ガラス転移温度(Tg)
SEIKO電子工業(株)製DSC−20を用いて昇温速度10℃/分で測定した。
ヘイズ(HAZE)
3mm厚の角板を射出成形により成形し、ASTMD1003に基づいて測定した。
400nm分光光線透過率(T400)
3mm厚の角板を射出成形により成形し、光線透過率分光光線度計を用いて、400nmにおける光線透過率を測定した。
チーグラー触媒を用いて、エチレン−テトラシクロ[4.4.0.12,5.17,10]ドデセン−3共重合体を重合した。物性値は次の通り。
合成例番号 MFR TMA Tg
( 単 位 ) (g/10分) ( ℃ ) ( ℃ )
合成例1 2 167 155
合成例2 36 147 137
合成例3 15 135 124
ペンタエリスルトールと各種脂肪酸から得られるエステル化合物として、次のものを用いた。
合成例番号 原料脂肪酸 得られた化合物
合成例4 ラウリン酸 ペンタエリスリトールモノラウレート
合成例5 ステアリン酸 ペンタエリスリトールモノステアレート
合成例6 ステアリン酸 ペンタエリスリトールジステアレート
合成例8 オレイン酸 ペンタエリスリトールモノオレエート
合成例8 カプロン酸 ペンタエリスリトールモノカプレート
合成例番号 アルコール 原料脂肪酸 得られた化合物
合成例9 ソルビタン ステアリン酸 ソルビタンモノステアレート
合成例10 グリセリン ラウリン酸 グリセリンモノラウレート
合成例1〜5の樹脂に対して、表に示す重量比の合成例6〜10の化合物とを混合して、樹脂の酸化を防ぐため窒素気流下で30mmφの単軸押出機を用いて溶融混合しペレットとした。
それぞれのペレットを120℃窒素下で16時間乾燥させた後、これを原料として、窒素気流下での射出成形により3mm厚の平板を得た。その光学物性を次の表にまとめて示す。
その結果を次に示す。
Claims (4)
- 請求項1記載の[B]の化学構造が、一般化学式(2)で表されることを特徴とする、請求項1記載の熱可塑性樹脂組成物。
RCOOCH2C(CH2OH)3 (2)
(式中、Rは炭素数8以上26以下の飽和炭化水素基である) - 請求項1記載の[A]および[B]を配合し、請求項1乃至2記載の熱可塑性樹脂組成物を製造する際に、[A]、[B]をそれぞれ別々に溶融状態として、押出機に装入することを特徴とする請求項1乃至2記載の熱可塑性樹脂組成物の製造方法。
- 請求項3記載の製造方法により得られる請求項1乃至2記載の熱可塑性樹脂組成物。
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2009209166A (ja) * | 2008-02-29 | 2009-09-17 | Nippon Zeon Co Ltd | 光学用樹脂組成物及び光学部品 |
JP2010184955A (ja) * | 2009-02-10 | 2010-08-26 | Mitsui Chemicals Inc | 樹脂組成物、ペンタエリスリトール誘導体組成物およびその製造方法 |
Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH11142645A (ja) * | 1997-11-07 | 1999-05-28 | Gunze Ltd | 偏光板用保護膜及びそれを用いてなる偏光板 |
JP2001074915A (ja) * | 1999-06-29 | 2001-03-23 | Mitsui Chemicals Inc | トーリックレンズ |
JP2002105131A (ja) * | 2000-09-28 | 2002-04-10 | Mitsui Chemicals Inc | 環状オレフィン系重合体 |
JP2003311773A (ja) * | 2002-04-26 | 2003-11-05 | Mitsui Chemicals Inc | 光学部品及びその成形方法 |
JP2003311737A (ja) * | 2002-04-26 | 2003-11-05 | Mitsui Chemicals Inc | 環状オレフィン系重合体の成形方法 |
JP2004144954A (ja) * | 2002-10-23 | 2004-05-20 | Konica Minolta Holdings Inc | プラスチック製光学素子及び光ピックアップ装置 |
JP2004161975A (ja) * | 2002-09-26 | 2004-06-10 | Jsr Corp | 射出成形体 |
JP2004197067A (ja) * | 2002-10-23 | 2004-07-15 | Konica Minolta Holdings Inc | 環状オレフィン樹脂、プラスチック製光学素子及び光ピックアップ装置 |
-
2004
- 2004-07-09 JP JP2004203330A patent/JP4855657B2/ja active Active
Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH11142645A (ja) * | 1997-11-07 | 1999-05-28 | Gunze Ltd | 偏光板用保護膜及びそれを用いてなる偏光板 |
JP2001074915A (ja) * | 1999-06-29 | 2001-03-23 | Mitsui Chemicals Inc | トーリックレンズ |
JP2002105131A (ja) * | 2000-09-28 | 2002-04-10 | Mitsui Chemicals Inc | 環状オレフィン系重合体 |
JP2003311773A (ja) * | 2002-04-26 | 2003-11-05 | Mitsui Chemicals Inc | 光学部品及びその成形方法 |
JP2003311737A (ja) * | 2002-04-26 | 2003-11-05 | Mitsui Chemicals Inc | 環状オレフィン系重合体の成形方法 |
JP2004161975A (ja) * | 2002-09-26 | 2004-06-10 | Jsr Corp | 射出成形体 |
JP2004144954A (ja) * | 2002-10-23 | 2004-05-20 | Konica Minolta Holdings Inc | プラスチック製光学素子及び光ピックアップ装置 |
JP2004197067A (ja) * | 2002-10-23 | 2004-07-15 | Konica Minolta Holdings Inc | 環状オレフィン樹脂、プラスチック製光学素子及び光ピックアップ装置 |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2009209166A (ja) * | 2008-02-29 | 2009-09-17 | Nippon Zeon Co Ltd | 光学用樹脂組成物及び光学部品 |
JP2010184955A (ja) * | 2009-02-10 | 2010-08-26 | Mitsui Chemicals Inc | 樹脂組成物、ペンタエリスリトール誘導体組成物およびその製造方法 |
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