JP2005536832A5 - - Google Patents
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- JP2005536832A5 JP2005536832A5 JP2003544828A JP2003544828A JP2005536832A5 JP 2005536832 A5 JP2005536832 A5 JP 2005536832A5 JP 2003544828 A JP2003544828 A JP 2003544828A JP 2003544828 A JP2003544828 A JP 2003544828A JP 2005536832 A5 JP2005536832 A5 JP 2005536832A5
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- JP
- Japan
- Prior art keywords
- anion
- group
- lithium
- mixtures
- aqueous
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- -1 imidazolinide anion Chemical class 0.000 claims 50
- 239000000203 mixture Substances 0.000 claims 33
- 150000001450 anions Chemical class 0.000 claims 27
- 239000011255 nonaqueous electrolyte Substances 0.000 claims 19
- 150000004703 alkoxides Chemical class 0.000 claims 15
- 125000000217 alkyl group Chemical group 0.000 claims 12
- 125000003118 aryl group Chemical group 0.000 claims 12
- 229910052744 lithium Inorganic materials 0.000 claims 12
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims 9
- 239000007983 Tris buffer Substances 0.000 claims 8
- JBFYUZGYRGXSFL-UHFFFAOYSA-N imidazolide Chemical compound C1=C[N-]C=N1 JBFYUZGYRGXSFL-UHFFFAOYSA-N 0.000 claims 8
- 239000012736 aqueous medium Substances 0.000 claims 7
- 150000003839 salts Chemical class 0.000 claims 7
- 239000002841 Lewis acid Substances 0.000 claims 6
- 125000004429 atom Chemical group 0.000 claims 6
- 125000004432 carbon atom Chemical group C* 0.000 claims 6
- URSLCTBXQMKCFE-UHFFFAOYSA-N dihydrogenborate Chemical compound OB(O)[O-] URSLCTBXQMKCFE-UHFFFAOYSA-N 0.000 claims 6
- 150000004820 halides Chemical class 0.000 claims 6
- 229910052739 hydrogen Inorganic materials 0.000 claims 6
- 150000007517 lewis acids Chemical class 0.000 claims 6
- 229920000642 polymer Polymers 0.000 claims 6
- 125000001424 substituent group Chemical group 0.000 claims 6
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims 5
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims 5
- YEJRWHAVMIAJKC-UHFFFAOYSA-N 4-Butyrolactone Chemical group O=C1CCCO1 YEJRWHAVMIAJKC-UHFFFAOYSA-N 0.000 claims 4
- XTHFKEDIFFGKHM-UHFFFAOYSA-N Dimethoxyethane Chemical compound COCCOC XTHFKEDIFFGKHM-UHFFFAOYSA-N 0.000 claims 4
- KMTRUDSVKNLOMY-UHFFFAOYSA-N Ethylene carbonate Chemical compound O=C1OCCO1 KMTRUDSVKNLOMY-UHFFFAOYSA-N 0.000 claims 4
- LLLBNLSOWVYRGV-UHFFFAOYSA-N FB(F)F.FB(F)F.FB(F)F.FB(F)F.[Li] Chemical compound FB(F)F.FB(F)F.FB(F)F.FB(F)F.[Li] LLLBNLSOWVYRGV-UHFFFAOYSA-N 0.000 claims 4
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims 4
- 229910052799 carbon Inorganic materials 0.000 claims 4
- 150000004649 carbonic acid derivatives Chemical class 0.000 claims 4
- 229910052736 halogen Inorganic materials 0.000 claims 4
- 150000002367 halogens Chemical class 0.000 claims 4
- 150000002596 lactones Chemical class 0.000 claims 4
- 239000007788 liquid Substances 0.000 claims 4
- 239000003960 organic solvent Substances 0.000 claims 4
- 239000002798 polar solvent Substances 0.000 claims 4
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 claims 4
- IVRMZWNICZWHMI-UHFFFAOYSA-N Azide Chemical compound [N-]=[N+]=[N-] IVRMZWNICZWHMI-UHFFFAOYSA-N 0.000 claims 3
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims 3
- QGJOPFRUJISHPQ-UHFFFAOYSA-N Carbon disulfide Chemical compound S=C=S QGJOPFRUJISHPQ-UHFFFAOYSA-N 0.000 claims 3
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 claims 3
- 230000002378 acidificating effect Effects 0.000 claims 3
- 229910052782 aluminium Inorganic materials 0.000 claims 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims 3
- 125000000129 anionic group Chemical group 0.000 claims 3
- HYGWNUKOUCZBND-UHFFFAOYSA-N azanide Chemical compound [NH2-] HYGWNUKOUCZBND-UHFFFAOYSA-N 0.000 claims 3
- 229910052796 boron Inorganic materials 0.000 claims 3
- 150000001875 compounds Chemical class 0.000 claims 3
- 125000004122 cyclic group Chemical group 0.000 claims 3
- 125000000524 functional group Chemical group 0.000 claims 3
- 125000001475 halogen functional group Chemical group 0.000 claims 3
- 125000001183 hydrocarbyl group Chemical group 0.000 claims 3
- 239000001257 hydrogen Substances 0.000 claims 3
- 125000002883 imidazolyl group Chemical group 0.000 claims 3
- 230000037431 insertion Effects 0.000 claims 3
- 238000003780 insertion Methods 0.000 claims 3
- 150000002641 lithium Chemical group 0.000 claims 3
- 125000001181 organosilyl group Chemical group [SiH3]* 0.000 claims 3
- 229920006395 saturated elastomer Polymers 0.000 claims 3
- 238000006467 substitution reaction Methods 0.000 claims 3
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 claims 2
- LXBGSDVWAMZHDD-UHFFFAOYSA-N 2-methyl-1h-imidazole Chemical compound CC1=NC=CN1 LXBGSDVWAMZHDD-UHFFFAOYSA-N 0.000 claims 2
- XLSZMDLNRCVEIJ-UHFFFAOYSA-N 4-methylimidazole Chemical compound CC1=CNC=N1 XLSZMDLNRCVEIJ-UHFFFAOYSA-N 0.000 claims 2
- JKKNNTCEYUIOPD-UHFFFAOYSA-N B(F)(F)F.B(F)(F)F.[Li] Chemical compound B(F)(F)F.B(F)(F)F.[Li] JKKNNTCEYUIOPD-UHFFFAOYSA-N 0.000 claims 2
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 claims 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 2
- OIFBSDVPJOWBCH-UHFFFAOYSA-N Diethyl carbonate Chemical compound CCOC(=O)OCC OIFBSDVPJOWBCH-UHFFFAOYSA-N 0.000 claims 2
- OJBZCQNOWSVYQG-UHFFFAOYSA-N [Li+].Cc1cnc[n-]1.COB(OC)OC.COB(OC)OC Chemical compound [Li+].Cc1cnc[n-]1.COB(OC)OC.COB(OC)OC OJBZCQNOWSVYQG-UHFFFAOYSA-N 0.000 claims 2
- NINXHAIKYVRFLS-UHFFFAOYSA-N [Li+].FB(F)F.FB(F)F.Cc1cnc[n-]1 Chemical compound [Li+].FB(F)F.FB(F)F.Cc1cnc[n-]1 NINXHAIKYVRFLS-UHFFFAOYSA-N 0.000 claims 2
- OKVJWADVFPXWQD-UHFFFAOYSA-N difluoroborinic acid Chemical compound OB(F)F OKVJWADVFPXWQD-UHFFFAOYSA-N 0.000 claims 2
- IEJIGPNLZYLLBP-UHFFFAOYSA-N dimethyl carbonate Chemical compound COC(=O)OC IEJIGPNLZYLLBP-UHFFFAOYSA-N 0.000 claims 2
- 125000002147 dimethylamino group Chemical group [H]C([H])([H])N(*)C([H])([H])[H] 0.000 claims 2
- PYSLFXYFNIUQLE-UHFFFAOYSA-N dimethylaminooxyboronic acid Chemical compound CN(C)OB(O)O PYSLFXYFNIUQLE-UHFFFAOYSA-N 0.000 claims 2
- QKIUAMUSENSFQQ-UHFFFAOYSA-N dimethylazanide Chemical compound C[N-]C QKIUAMUSENSFQQ-UHFFFAOYSA-N 0.000 claims 2
- 150000002148 esters Chemical class 0.000 claims 2
- 150000002170 ethers Chemical class 0.000 claims 2
- JBTWLSYIZRCDFO-UHFFFAOYSA-N ethyl methyl carbonate Chemical compound CCOC(=O)OC JBTWLSYIZRCDFO-UHFFFAOYSA-N 0.000 claims 2
- 150000004675 formic acid derivatives Chemical class 0.000 claims 2
- VEEWLDHUUOZMIP-UHFFFAOYSA-N lithium 2-methylimidazol-3-ide trifluoroborane Chemical compound [Li+].FB(F)F.FB(F)F.Cc1ncc[n-]1 VEEWLDHUUOZMIP-UHFFFAOYSA-N 0.000 claims 2
- SSIIXSPVJXPKDB-UHFFFAOYSA-N lithium 2-propan-2-ylimidazol-3-ide trifluoroborane Chemical compound [Li+].FB(F)F.FB(F)F.CC(C)c1ncc[n-]1 SSIIXSPVJXPKDB-UHFFFAOYSA-N 0.000 claims 2
- SRDMTFVMBZQLAW-UHFFFAOYSA-N lithium 2-propan-2-ylimidazol-3-ide trimethyl borate Chemical compound [Li+].COB(OC)OC.COB(OC)OC.CC(C)c1ncc[n-]1 SRDMTFVMBZQLAW-UHFFFAOYSA-N 0.000 claims 2
- COMPEMJBDGAOBM-UHFFFAOYSA-N lithium benzimidazol-1-ide trifluoroborane Chemical compound [Li+].FB(F)F.FB(F)F.c1nc2ccccc2[n-]1 COMPEMJBDGAOBM-UHFFFAOYSA-N 0.000 claims 2
- JBHFLHZGAFJGMY-UHFFFAOYSA-N lithium di(propan-2-yl)azanide trifluoroborane Chemical compound [Li+].FB(F)F.FB(F)F.CC(C)[N-]C(C)C JBHFLHZGAFJGMY-UHFFFAOYSA-N 0.000 claims 2
- QRASYCCOEWJWDQ-UHFFFAOYSA-N lithium di(propan-2-yl)azanide trimethyl borate Chemical compound [Li+].COB(OC)OC.COB(OC)OC.CC(C)[N-]C(C)C QRASYCCOEWJWDQ-UHFFFAOYSA-N 0.000 claims 2
- UZCICJMYACCAJK-UHFFFAOYSA-N lithium dimethylazanide trifluoroborane Chemical compound [Li+].C[N-]C.FB(F)F.FB(F)F UZCICJMYACCAJK-UHFFFAOYSA-N 0.000 claims 2
- DNPHNZQJEBKLAV-UHFFFAOYSA-N lithium dimethylazanide trimethyl borate Chemical compound [Li+].C[N-]C.COB(OC)OC.COB(OC)OC DNPHNZQJEBKLAV-UHFFFAOYSA-N 0.000 claims 2
- 229910003002 lithium salt Inorganic materials 0.000 claims 2
- 159000000002 lithium salts Chemical class 0.000 claims 2
- CQXLQXQSNAMYKR-UHFFFAOYSA-N lithium;imidazol-3-ide;trifluoroborane Chemical compound [Li+].FB(F)F.FB(F)F.C1=C[N-]C=N1 CQXLQXQSNAMYKR-UHFFFAOYSA-N 0.000 claims 2
- 150000002825 nitriles Chemical class 0.000 claims 2
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 claims 2
- 229920000767 polyaniline Polymers 0.000 claims 2
- 239000007787 solid Substances 0.000 claims 2
- 150000003457 sulfones Chemical class 0.000 claims 2
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 claims 2
- 229910052723 transition metal Inorganic materials 0.000 claims 2
- LENZDBCJOHFCAS-UHFFFAOYSA-N tris Chemical compound OCC(N)(CO)CO LENZDBCJOHFCAS-UHFFFAOYSA-N 0.000 claims 2
- HYZJCKYKOHLVJF-UHFFFAOYSA-N 1H-benzimidazole Chemical compound C1=CC=C2NC=NC2=C1 HYZJCKYKOHLVJF-UHFFFAOYSA-N 0.000 claims 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims 1
- DDVIWPUIHPUIIZ-UHFFFAOYSA-N FB(OC1=NC=CN1)F Chemical compound FB(OC1=NC=CN1)F DDVIWPUIHPUIIZ-UHFFFAOYSA-N 0.000 claims 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 1
- 229910000733 Li alloy Inorganic materials 0.000 claims 1
- ZFEJIGIJORJAIH-UHFFFAOYSA-N N-difluoroboranyloxy-N-methylmethanamine Chemical compound B(ON(C)C)(F)F ZFEJIGIJORJAIH-UHFFFAOYSA-N 0.000 claims 1
- 239000004698 Polyethylene Substances 0.000 claims 1
- KLTWGRFNJPLFDA-UHFFFAOYSA-N benzimidazolide Chemical compound C1=CC=C2[N-]C=NC2=C1 KLTWGRFNJPLFDA-UHFFFAOYSA-N 0.000 claims 1
- 150000004770 chalcogenides Chemical class 0.000 claims 1
- 239000002131 composite material Substances 0.000 claims 1
- 230000005611 electricity Effects 0.000 claims 1
- 230000005518 electrochemistry Effects 0.000 claims 1
- 125000001033 ether group Chemical group 0.000 claims 1
- 229910002804 graphite Inorganic materials 0.000 claims 1
- 239000010439 graphite Substances 0.000 claims 1
- 239000001989 lithium alloy Substances 0.000 claims 1
- 239000012528 membrane Substances 0.000 claims 1
- 229910052751 metal Inorganic materials 0.000 claims 1
- 239000002184 metal Substances 0.000 claims 1
- 229910044991 metal oxide Inorganic materials 0.000 claims 1
- 150000004706 metal oxides Chemical class 0.000 claims 1
- 229920000573 polyethylene Polymers 0.000 claims 1
- 239000005373 porous glass Substances 0.000 claims 1
- 239000000126 substance Substances 0.000 claims 1
- 229910000314 transition metal oxide Inorganic materials 0.000 claims 1
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US34708301P | 2001-11-09 | 2001-11-09 | |
| PCT/US2002/035785 WO2003043102A2 (en) | 2001-11-09 | 2002-11-07 | Non-aqueous electrolytes for lithium electrochemical cells |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2005536832A JP2005536832A (ja) | 2005-12-02 |
| JP2005536832A5 true JP2005536832A5 (https=) | 2010-04-15 |
| JP4679819B2 JP4679819B2 (ja) | 2011-05-11 |
Family
ID=38561997
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2003544828A Expired - Fee Related JP4679819B2 (ja) | 2001-11-09 | 2002-11-07 | リチウム電気化学的電池用の非水性電解質 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US6852446B2 (https=) |
| EP (1) | EP1442489B1 (https=) |
| JP (1) | JP4679819B2 (https=) |
| CA (1) | CA2466350C (https=) |
| DE (1) | DE60233745D1 (https=) |
| WO (1) | WO2003043102A2 (https=) |
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2002
- 2002-11-07 JP JP2003544828A patent/JP4679819B2/ja not_active Expired - Fee Related
- 2002-11-07 US US10/289,784 patent/US6852446B2/en not_active Expired - Lifetime
- 2002-11-07 WO PCT/US2002/035785 patent/WO2003043102A2/en not_active Ceased
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- 2002-11-07 DE DE60233745T patent/DE60233745D1/de not_active Expired - Lifetime
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