JP2005532442A5 - - Google Patents
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- Publication number
- JP2005532442A5 JP2005532442A5 JP2004518602A JP2004518602A JP2005532442A5 JP 2005532442 A5 JP2005532442 A5 JP 2005532442A5 JP 2004518602 A JP2004518602 A JP 2004518602A JP 2004518602 A JP2004518602 A JP 2004518602A JP 2005532442 A5 JP2005532442 A5 JP 2005532442A5
- Authority
- JP
- Japan
- Prior art keywords
- general formula
- block copolymer
- polymerization
- monomer
- radical
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 claims description 16
- 229920001400 block copolymer Polymers 0.000 claims description 6
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 4
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 claims description 2
- 235000019400 benzoyl peroxide Nutrition 0.000 claims description 2
- 239000000178 monomer Substances 0.000 claims 6
- 150000003254 radicals Chemical class 0.000 claims 5
- 238000006116 polymerization reaction Methods 0.000 claims 4
- 150000001875 compounds Chemical class 0.000 claims 3
- 230000000977 initiatory effect Effects 0.000 claims 3
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims 2
- 125000003118 aryl group Chemical group 0.000 claims 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims 2
- 239000003999 initiator Substances 0.000 claims 2
- 239000000203 mixture Substances 0.000 claims 2
- 230000000379 polymerizing effect Effects 0.000 claims 2
- 229920002554 vinyl polymer Polymers 0.000 claims 2
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 claims 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 claims 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims 1
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 claims 1
- 125000000217 alkyl group Chemical group 0.000 claims 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims 1
- 238000006243 chemical reaction Methods 0.000 claims 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 claims 1
- 150000002976 peresters Chemical class 0.000 claims 1
- 150000002978 peroxides Chemical class 0.000 claims 1
- 238000010526 radical polymerization reaction Methods 0.000 claims 1
- IZMUYZWVFCIQJQ-UHFFFAOYSA-N 2-methyl-2-(2,2,6,6-tetramethylpiperidin-1-yl)oxypropanenitrile Chemical compound N#CC(C)(C)ON1C(C)(C)CCCC1(C)C IZMUYZWVFCIQJQ-UHFFFAOYSA-N 0.000 description 1
- 239000004342 Benzoyl peroxide Substances 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT001495A ITMI20021495A1 (it) | 2002-07-09 | 2002-07-09 | Procedimento per la preparazione di copolimeri a blocchi. |
| PCT/EP2003/006837 WO2004005361A1 (en) | 2002-07-09 | 2003-06-26 | Process for the preparation of block copolymers |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2005532442A JP2005532442A (ja) | 2005-10-27 |
| JP2005532442A5 true JP2005532442A5 (enExample) | 2010-03-11 |
| JP4477493B2 JP4477493B2 (ja) | 2010-06-09 |
Family
ID=30012500
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2004518602A Expired - Fee Related JP4477493B2 (ja) | 2002-07-09 | 2003-06-26 | ブロックコポリマーの製造方法 |
Country Status (15)
| Country | Link |
|---|---|
| US (1) | US7388052B2 (enExample) |
| EP (1) | EP1519970B1 (enExample) |
| JP (1) | JP4477493B2 (enExample) |
| CN (1) | CN1308363C (enExample) |
| AT (1) | ATE376562T1 (enExample) |
| AU (1) | AU2003242772A1 (enExample) |
| BR (1) | BR0312348B1 (enExample) |
| CA (1) | CA2491048C (enExample) |
| DE (1) | DE60317066T2 (enExample) |
| ES (1) | ES2295643T3 (enExample) |
| IT (1) | ITMI20021495A1 (enExample) |
| MX (1) | MXPA04012791A (enExample) |
| PL (1) | PL209004B1 (enExample) |
| RU (1) | RU2320675C2 (enExample) |
| WO (1) | WO2004005361A1 (enExample) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ITMI20040752A1 (it) * | 2004-04-16 | 2004-07-16 | Polimeri Europa Spa | Procedimento per la preparazione di co polimeri vinilaromatici aggraffati su elastometro in modo controllato |
| US8357759B2 (en) * | 2005-08-26 | 2013-01-22 | CID Centro de Investigación y Desarrollo Tecnológico S.A. de C.V. | Reactive block copolymers |
| US20100311920A1 (en) * | 2005-08-26 | 2010-12-09 | Cid Centro De Investigacion Y Desarrollo Tecnologico Sa De Cv | Using Reactive Block Copolymers as Chain Extenders and Surface Modifiers |
| US8344058B2 (en) * | 2005-08-26 | 2013-01-01 | CID Centro de Investigación y Desarrollo Technológico S.A. de C.V. | Reactive block copolymers as additives for the preparation of silicate-polymer composites |
| US8557907B2 (en) * | 2005-08-26 | 2013-10-15 | Macro-M S.A. De C.V. | Reactive block copolymers for the preparation of inorganic tubule-polymer composites |
| EP1919962B1 (en) * | 2005-08-30 | 2010-04-21 | Basf Se | Polymers obtained via nitroxyl radical polymerization |
| US20100311849A1 (en) | 2006-08-23 | 2010-12-09 | Cid Centro De Investigacion Y Desarrollo Tecnologico Sa De Cv | Using Reactive Block Copolymers as Chain Extenders and Surface Modifiers |
| JP5229167B2 (ja) * | 2009-09-04 | 2013-07-03 | 株式会社リコー | ラジカル重合用組成物及びポリマーの製造方法 |
| ITMI20121973A1 (it) | 2012-11-20 | 2014-05-21 | Versalis Spa | Composizione polimerica autoestinguente |
| FR3008986B1 (fr) * | 2013-07-25 | 2016-12-30 | Arkema France | Procede de controle de la periode caracterisant la morphologie obtenue a partir d'un melange de copolymere a blocs et de (co) polymeres de l'un des blocs |
| CN106604941A (zh) * | 2014-03-07 | 2017-04-26 | 巴斯夫欧洲公司 | 可控自由基聚合 |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0876414B1 (de) * | 1996-01-25 | 1999-08-25 | Basf Aktiengesellschaft | Blockcopolymere |
| US6281311B1 (en) * | 1997-03-31 | 2001-08-28 | Pmd Holdings Corp. | Controlled free radical polymerization process |
| US6111025A (en) * | 1997-06-24 | 2000-08-29 | The Lubrizol Corporation | Block copolymer surfactants prepared by stabilized free-radical polymerization |
| FR2781487B1 (fr) * | 1998-07-10 | 2000-12-08 | Atochem Elf Sa | Polymerisation en emulsion en presence d'un radical libre stable |
| DE69909235T2 (de) | 1998-10-26 | 2004-04-22 | The Lubrizol Corp., Wickliffe | Radialpolymere die mit einem stabilisierten freiradikalischen verfahren hergestellt sind |
| US20020010267A1 (en) * | 1999-03-09 | 2002-01-24 | Symyx Technologies, Inc., A Delaware Corporation | Block copolymers |
| US6569162B2 (en) * | 2001-03-29 | 2003-05-27 | Ding Sheng He | Passively self-cooled electrode design for ablation catheters |
| TW572896B (en) * | 2000-05-26 | 2004-01-21 | Ciba Sc Holding Ag | Process for the synthesis of amine ethers from secondary amino oxides |
| TW574236B (en) * | 2000-09-25 | 2004-02-01 | Ciba Sc Holding Ag | Process for controlled radical polymerization in aqueous dispersion |
-
2002
- 2002-07-09 IT IT001495A patent/ITMI20021495A1/it unknown
-
2003
- 2003-06-26 RU RU2004138077/04A patent/RU2320675C2/ru active
- 2003-06-26 EP EP03762534A patent/EP1519970B1/en not_active Expired - Lifetime
- 2003-06-26 ES ES03762534T patent/ES2295643T3/es not_active Expired - Lifetime
- 2003-06-26 AT AT03762534T patent/ATE376562T1/de not_active IP Right Cessation
- 2003-06-26 CA CA2491048A patent/CA2491048C/en not_active Expired - Fee Related
- 2003-06-26 PL PL373261A patent/PL209004B1/pl unknown
- 2003-06-26 MX MXPA04012791A patent/MXPA04012791A/es active IP Right Grant
- 2003-06-26 JP JP2004518602A patent/JP4477493B2/ja not_active Expired - Fee Related
- 2003-06-26 DE DE60317066T patent/DE60317066T2/de not_active Expired - Lifetime
- 2003-06-26 BR BRPI0312348-0A patent/BR0312348B1/pt not_active IP Right Cessation
- 2003-06-26 AU AU2003242772A patent/AU2003242772A1/en not_active Abandoned
- 2003-06-26 US US10/518,550 patent/US7388052B2/en not_active Expired - Lifetime
- 2003-06-26 WO PCT/EP2003/006837 patent/WO2004005361A1/en not_active Ceased
- 2003-06-26 CN CNB038160951A patent/CN1308363C/zh not_active Expired - Fee Related
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