JP2005526027A5 - - Google Patents
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- JP2005526027A5 JP2005526027A5 JP2003565984A JP2003565984A JP2005526027A5 JP 2005526027 A5 JP2005526027 A5 JP 2005526027A5 JP 2003565984 A JP2003565984 A JP 2003565984A JP 2003565984 A JP2003565984 A JP 2003565984A JP 2005526027 A5 JP2005526027 A5 JP 2005526027A5
- Authority
- JP
- Japan
- Prior art keywords
- group
- formula
- atom
- represent
- represented
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Links
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 20
- -1 methoxy, ethoxy, methylthio, ethylthio Chemical group 0.000 claims description 14
- 125000005843 halogen group Chemical group 0.000 claims description 7
- 125000004093 cyano group Chemical group *C#N 0.000 claims description 3
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims description 3
- 125000004769 (C1-C4) alkylsulfonyl group Chemical group 0.000 claims description 2
- 125000004767 (C1-C4) haloalkoxy group Chemical group 0.000 claims description 2
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 claims description 2
- 125000000882 C2-C6 alkenyl group Chemical group 0.000 claims description 2
- 125000000753 cycloalkyl group Chemical group 0.000 claims description 2
- 125000004441 haloalkylsulfonyl group Chemical group 0.000 claims description 2
- SNOOUWRIMMFWNE-UHFFFAOYSA-M sodium;6-[(3,4,5-trimethoxybenzoyl)amino]hexanoate Chemical compound [Na+].COC1=CC(C(=O)NCCCCCC([O-])=O)=CC(OC)=C1OC SNOOUWRIMMFWNE-UHFFFAOYSA-M 0.000 claims description 2
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical group [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims 10
- 229910052801 chlorine Inorganic materials 0.000 claims 7
- 229910052731 fluorine Inorganic materials 0.000 claims 7
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 7
- WGLLSSPDPJPLOR-UHFFFAOYSA-N 2,3-dimethylbut-2-ene Chemical group CC(C)=C(C)C WGLLSSPDPJPLOR-UHFFFAOYSA-N 0.000 claims 6
- 125000001309 chloro group Chemical group Cl* 0.000 claims 6
- 125000001153 fluoro group Chemical group F* 0.000 claims 6
- 125000000335 thiazolyl group Chemical group 0.000 claims 6
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 claims 6
- 239000002253 acid Substances 0.000 claims 4
- 239000011230 binding agent Substances 0.000 claims 4
- 150000001642 boronic acid derivatives Chemical class 0.000 claims 4
- 125000001028 difluoromethyl group Chemical group [H]C(F)(F)* 0.000 claims 4
- 239000003085 diluting agent Substances 0.000 claims 4
- 238000000034 method Methods 0.000 claims 4
- 244000005700 microbiome Species 0.000 claims 4
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical group [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 claims 3
- 229910052740 iodine Inorganic materials 0.000 claims 3
- 125000005034 trifluormethylthio group Chemical group FC(S*)(F)F 0.000 claims 3
- BPONVVSBNSWOGF-UHFFFAOYSA-N 4-(difluoromethyl)-1,3-thiazole-2-carboxylic acid Chemical compound OC(=O)C1=NC(C(F)F)=CS1 BPONVVSBNSWOGF-UHFFFAOYSA-N 0.000 claims 2
- 239000004067 bulking agent Substances 0.000 claims 2
- 239000003054 catalyst Substances 0.000 claims 2
- 125000004786 difluoromethoxy group Chemical group [H]C(F)(F)O* 0.000 claims 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims 2
- 150000005171 halobenzenes Chemical class 0.000 claims 2
- 229910052736 halogen Inorganic materials 0.000 claims 2
- 238000004519 manufacturing process Methods 0.000 claims 2
- FTWUXYZHDFCGSV-UHFFFAOYSA-N n,n'-diphenyloxamide Chemical compound C=1C=CC=CC=1NC(=O)C(=O)NC1=CC=CC=C1 FTWUXYZHDFCGSV-UHFFFAOYSA-N 0.000 claims 2
- 239000004094 surface-active agent Substances 0.000 claims 2
- 125000000876 trifluoromethoxy group Chemical group FC(F)(F)O* 0.000 claims 2
- AOPBDRUWRLBSDB-UHFFFAOYSA-N 2-bromoaniline Chemical compound NC1=CC=CC=C1Br AOPBDRUWRLBSDB-UHFFFAOYSA-N 0.000 claims 1
- UBPDKIDWEADHPP-UHFFFAOYSA-N 2-iodoaniline Chemical compound NC1=CC=CC=C1I UBPDKIDWEADHPP-UHFFFAOYSA-N 0.000 claims 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims 1
- OSFPHMZQBQZLAY-UHFFFAOYSA-N OBO.NC1=CC=CC=C1 Chemical class OBO.NC1=CC=CC=C1 OSFPHMZQBQZLAY-UHFFFAOYSA-N 0.000 claims 1
- 125000004450 alkenylene group Chemical group 0.000 claims 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims 1
- 229910052794 bromium Inorganic materials 0.000 claims 1
- 150000003857 carboxamides Chemical class 0.000 claims 1
- 239000000460 chlorine Substances 0.000 claims 1
- 125000001559 cyclopropyl group Chemical group [H]C1([H])C([H])([H])C1([H])* 0.000 claims 1
- 239000011737 fluorine Substances 0.000 claims 1
- 125000004785 fluoromethoxy group Chemical group [H]C([H])(F)O* 0.000 claims 1
- 150000002367 halogens Chemical group 0.000 claims 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 claims 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims 1
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 claims 1
- 125000002816 methylsulfanyl group Chemical group [H]C([H])([H])S[*] 0.000 claims 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 claims 1
- 238000002360 preparation method Methods 0.000 claims 1
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 claims 1
- 125000003866 trichloromethyl group Chemical group ClC(Cl)(Cl)* 0.000 claims 1
- WTVXIBRMWGUIMI-UHFFFAOYSA-N trifluoro($l^{1}-oxidanylsulfonyl)methane Chemical group [O]S(=O)(=O)C(F)(F)F WTVXIBRMWGUIMI-UHFFFAOYSA-N 0.000 claims 1
- 125000003652 trifluoroethoxy group Chemical group FC(CO*)(F)F 0.000 claims 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- 125000003710 aryl alkyl group Chemical group 0.000 description 1
- PQIOSYKVBBWRRI-UHFFFAOYSA-N methylphosphonyl difluoride Chemical group CP(F)(F)=O PQIOSYKVBBWRRI-UHFFFAOYSA-N 0.000 description 1
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10204391A DE10204391A1 (de) | 2002-02-04 | 2002-02-04 | Difluormethylthiazolylcarboxanilide |
| PCT/EP2003/000589 WO2003066610A1 (de) | 2002-02-04 | 2003-01-22 | Difluormethyl thiazolyl carboxanilide |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2005526027A JP2005526027A (ja) | 2005-09-02 |
| JP2005526027A5 true JP2005526027A5 (https=) | 2010-04-22 |
| JP4559735B2 JP4559735B2 (ja) | 2010-10-13 |
Family
ID=27588322
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2003565984A Expired - Fee Related JP4559735B2 (ja) | 2002-02-04 | 2003-01-22 | ジフルオロメチルチアゾリルカルボキサニリド |
Country Status (19)
| Country | Link |
|---|---|
| US (1) | US7388097B2 (https=) |
| EP (1) | EP1474407B1 (https=) |
| JP (1) | JP4559735B2 (https=) |
| KR (1) | KR100958680B1 (https=) |
| CN (1) | CN100503586C (https=) |
| AT (1) | ATE476427T1 (https=) |
| AU (1) | AU2003244431A1 (https=) |
| BR (1) | BR0307432B1 (https=) |
| CA (1) | CA2474902A1 (https=) |
| CO (1) | CO5611065A2 (https=) |
| DE (2) | DE10204391A1 (https=) |
| ES (1) | ES2347870T3 (https=) |
| MX (1) | MXPA04007465A (https=) |
| NZ (1) | NZ534454A (https=) |
| PL (1) | PL216410B1 (https=) |
| RU (1) | RU2319697C2 (https=) |
| UA (1) | UA79266C2 (https=) |
| WO (1) | WO2003066610A1 (https=) |
| ZA (1) | ZA200406146B (https=) |
Families Citing this family (57)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| PL368164A1 (en) * | 2001-07-16 | 2005-03-21 | Ortho-Mcneil Pharmaceutical, Inc. | Carbamate compounds for use in preventing or treating neuropathic pain and cluster and migraine headache-associated pain |
| DE10246959A1 (de) * | 2002-10-09 | 2004-04-22 | Bayer Cropscience Ag | Thiazolylbiphenylamide |
| DE10250110A1 (de) * | 2002-10-28 | 2004-05-13 | Bayer Cropscience Ag | Thiazol-(bi)cycloalkyl-carboxanilide |
| GB0230155D0 (en) * | 2002-12-24 | 2003-02-05 | Syngenta Participations Ag | Chemical compounds |
| DE10347090A1 (de) | 2003-10-10 | 2005-05-04 | Bayer Cropscience Ag | Synergistische fungizide Wirkstoffkombinationen |
| DE10349501A1 (de) | 2003-10-23 | 2005-05-25 | Bayer Cropscience Ag | Synergistische fungizide Wirkstoffkombinationen |
| EP1713114B1 (en) * | 2004-02-03 | 2018-09-19 | Nikon Corporation | Exposure apparatus and device manufacturing method |
| CN1946695B (zh) * | 2004-04-26 | 2012-04-04 | 拜尔农科股份公司 | 可用作杀真菌剂的2-吡啶基环烷基羧酰胺衍生物 |
| BRPI0510815A (pt) * | 2004-05-13 | 2007-11-27 | Basf Ag | misturas fungicidas para combater fungos nocivos, agente, processo para combater fungos nocivos fitopatogênicos, semente, e, uso do compostos |
| DE102004041532A1 (de) * | 2004-08-27 | 2006-03-02 | Bayer Cropscience Ag | Biphenylthiazolcarboxamide |
| DE102004041530A1 (de) * | 2004-08-27 | 2006-03-02 | Bayer Cropscience Ag | Biphenylthiazolcarboxamide |
| DE102004041531A1 (de) | 2004-08-27 | 2006-03-02 | Bayer Cropscience Ag | Verfahren zum Herstellen von Biphenylaminen |
| DE102004059725A1 (de) | 2004-12-11 | 2006-06-22 | Bayer Cropscience Ag | 2-Alkyl-cycloalk(en)yl-carboxamide |
| DE102005007160A1 (de) * | 2005-02-16 | 2006-08-24 | Basf Ag | Pyrazolcarbonsäureanilide, Verfahren zu ihrer Herstellung und sie enthaltende Mittel zur Bekämpfung von Schadpilzen |
| MX2007013791A (es) * | 2005-05-18 | 2008-01-24 | Basf Ag | Anilidas de acido tiazolcarboxilico. |
| DE102005025989A1 (de) * | 2005-06-07 | 2007-01-11 | Bayer Cropscience Ag | Carboxamide |
| DE102005026482A1 (de) | 2005-06-09 | 2006-12-14 | Bayer Cropscience Ag | Wirkstoffkombinationen |
| EA201270781A1 (ru) | 2005-06-09 | 2013-09-30 | Байер Кропсайенс Аг | Комбинации биологически активных веществ |
| DE102005035300A1 (de) * | 2005-07-28 | 2007-02-01 | Bayer Cropscience Ag | Synergistische fungizide Wirkstoffkombinationen |
| WO2007031283A2 (de) | 2005-09-13 | 2007-03-22 | Basf Se | Verfahren zum schutz vor phytopathogenen mit kiralaxyl, entsprechende verwendung und mittel hierzu |
| DE102005060462A1 (de) * | 2005-12-17 | 2007-06-28 | Bayer Cropscience Ag | Biphenylcarboxamide |
| AU2007224495A1 (en) * | 2006-03-14 | 2007-09-20 | Basf Se | Method of inducing virus tolerance of plants |
| WO2007104658A2 (en) * | 2006-03-14 | 2007-09-20 | Basf Se | Method of inducing tolerance of plants against bacterioses |
| TWI435863B (zh) | 2006-03-20 | 2014-05-01 | Nihon Nohyaku Co Ltd | Ｎ-２-（雜）芳基乙基甲醯胺衍生物及含該衍生物之蟲害防治劑 |
| WO2007110354A2 (en) | 2006-03-24 | 2007-10-04 | Basf Se | Method for combating phytopathogenic fungi |
| TW200810694A (en) * | 2006-05-03 | 2008-03-01 | Basf Ag | Use of arylcarboxylic acid biphenylamides for seed treatment |
| DE102006023263A1 (de) * | 2006-05-18 | 2007-11-22 | Bayer Cropscience Ag | Synergistische Wirkstoffkombinationen |
| NZ597711A (en) * | 2007-02-05 | 2013-04-26 | Basf Se | Fungicidal mixtures comprising substituted 1-methylpyrazol-4-ylcarboxanilides, particularly Bixafen |
| EP2109366A2 (en) * | 2007-02-06 | 2009-10-21 | Basf Se | Pesticidal mixtures |
| EP2109362A2 (en) * | 2007-02-14 | 2009-10-21 | Basf Se | Method of inducing virus tolerance of plants |
| CN101674729A (zh) * | 2007-03-20 | 2010-03-17 | 巴斯夫欧洲公司 | 保护大豆以防真菌侵染的方法 |
| CL2008001930A1 (es) * | 2007-06-29 | 2009-09-25 | Basf Se | Metodo para incrementar la resistencia de una planta o de una semilla de la misma al estres abiotico que comprende el tratamiento de la semilla con al menos un fungicida de estrobilurina; y uso de dichos compuestos. |
| DE102007045920B4 (de) | 2007-09-26 | 2018-07-05 | Bayer Intellectual Property Gmbh | Synergistische Wirkstoffkombinationen |
| JP2011502970A (ja) * | 2007-11-02 | 2011-01-27 | ビーエーエスエフ ソシエタス・ヨーロピア | 菌類感染から穀類を保護する方法 |
| AU2009218428B2 (en) * | 2008-02-28 | 2013-09-26 | Basf Se | Method for protecting cereals from being infected by fungi |
| AR074623A1 (es) | 2008-05-02 | 2011-02-02 | Basf Se | Procedimiento para la preparacion de esteres de acido 2-(aminometiliden)-3-oxobutirico, sustituidos por halogeno |
| AR073932A1 (es) | 2008-05-02 | 2010-12-15 | Basf Se | Compuestos de esteres de acido 2-(aminometiliden)-4,4-difluoro-3- oxobutirico y procedimiento para su preparacion |
| DK2288597T3 (en) | 2008-05-05 | 2015-01-26 | Basf Se | PROCESS FOR THE PREPARATION OF 1,3,4-SUBSTITUTED pyrazole |
| BRPI0912385A2 (pt) * | 2008-05-08 | 2015-07-28 | Basf Se | Método para proteger plantas de soja de serem infectadas por fungos nocivos, composição fungicida, agente fungicida, semente, e, uso de uma composição |
| UA101382C2 (ru) * | 2008-07-04 | 2013-03-25 | Басф Се | Фунгицидные смеси, содержащие замещенные 1-метилпиразол-4-илкарбоксанилиды |
| MX2011000209A (es) * | 2008-07-21 | 2011-03-01 | Basf Se | Procedimiento para la obtencion de esteres de acido pirazolcarboxilicos disustituidos en 1,3. |
| MX2011009732A (es) | 2009-03-25 | 2011-09-29 | Bayer Cropscience Ag | Combinaciones de principios activos sinergicas. |
| KR20120051015A (ko) | 2009-07-16 | 2012-05-21 | 바이엘 크롭사이언스 아게 | 페닐 트리아졸을 함유하는 상승적 활성 물질 배합물 |
| EP2496561B1 (en) | 2009-11-05 | 2014-06-04 | Basf Se | Process for preparing aminale and their use for preparing 1,3-disubstituted pyrazole compounds |
| EP2496560B1 (en) | 2009-11-05 | 2015-04-22 | Basf Se | Process for preparing 1,3-disubstituted pyrazole compounds |
| BR112013014913A2 (pt) | 2010-12-20 | 2016-07-19 | Basf Se | misturas pesticidas, composição pesticida ou parasiticida, método para proteger os vegetais do ataque ou da infestação por insetos, para o controle dos insetos, para o controle dos fungos fitopatogênicos prejudiciais, para a proteção dos vegetais dos fungos fitopatogênicos prejudiciais, para a proteção do material de propagação dos vegetais, para a proteção dos animais contra a infestação ou infecção por parasitas, para o tratamento dos aminais infectados ou infectados por parasitas e utilização |
| CN103987261A (zh) | 2011-09-02 | 2014-08-13 | 巴斯夫欧洲公司 | 包含芳基喹唑啉酮化合物的农业混合物 |
| EP3646731A1 (en) | 2012-06-20 | 2020-05-06 | Basf Se | Pesticidal mixtures comprising a pyrazole compound |
| EP2891492B1 (en) | 2012-08-30 | 2022-11-09 | The University of Tokyo | Endoparasite control agent |
| EP3143994A1 (en) | 2012-08-30 | 2017-03-22 | The University of Tokyo | Endoparasite control agent and use thereof |
| CN103848797B (zh) * | 2014-03-13 | 2016-04-06 | 南开大学 | 2-(1-胺基-乙基)-n-苯基噻唑-4-甲酰胺化合物成盐方法及应用 |
| CN105646122B (zh) * | 2015-01-30 | 2017-11-07 | 中国科学院上海有机化学研究所 | 一种含二氟甲硫基的化合物、其制备方法及应用 |
| EP2910126A1 (en) | 2015-05-05 | 2015-08-26 | Bayer CropScience AG | Active compound combinations having insecticidal properties |
| EP3178813A1 (en) | 2015-12-09 | 2017-06-14 | Basf Se | Method for preparing halogenated 3-oxocarboxylates carrying a 2-alkoxymethylidene or a 2-dialkylaminomethylidene group |
| CN109422704A (zh) * | 2018-11-26 | 2019-03-05 | 南开大学 | 一类4位取代噻唑酰胺衍生物及其制备方法和用途 |
| CN110128346A (zh) * | 2019-05-17 | 2019-08-16 | 南开大学 | 一类联芳酰胺吡唑衍生物及其制备方法和用途 |
| US20240336634A1 (en) * | 2021-07-22 | 2024-10-10 | The Government of the United States of America as represented by the Department of Veterans Affairs | Agonists of tyro3 as protection against podocyte injury in kidney glomerular disease |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4837242A (en) * | 1987-01-20 | 1989-06-06 | Sumitomo Chemical Company, Limited | Thiazoles and pyrazoles as fungicides |
| US5045554A (en) * | 1988-11-29 | 1991-09-03 | Monsanto Company | Substituted thiazoles and their use as fungicides |
| IL103614A (en) * | 1991-11-22 | 1998-09-24 | Basf Ag | Carboxamides for controlling botrytis and certain novel such compounds |
| DE19531813A1 (de) * | 1995-08-30 | 1997-03-06 | Basf Ag | Bisphenylamide |
| JPH09132567A (ja) * | 1995-11-08 | 1997-05-20 | Mitsui Toatsu Chem Inc | ピラゾールカルボン酸アニリド誘導体およびこれを有効成分とする農園芸用殺菌剤 |
| DE19629828A1 (de) * | 1996-07-24 | 1998-01-29 | Bayer Ag | Carbanilide |
| GB9817548D0 (en) * | 1998-08-12 | 1998-10-07 | Novartis Ag | Organic compounds |
| RU2259356C2 (ru) * | 1999-12-09 | 2005-08-27 | Зингента Партисипейшнс Аг | Пиразолкарбоксамидные и пиразолтиоамидные производные в качестве фунгицидов |
| GB0001447D0 (en) * | 2000-01-21 | 2000-03-08 | Novartis Ag | Organic compounds |
| JP2001302605A (ja) * | 2000-04-20 | 2001-10-31 | Sumitomo Chem Co Ltd | ビフェニル化合物およびその用途 |
| MXPA03000688A (es) * | 2000-07-24 | 2004-11-01 | Bayer Cropscience Ag | Bifenilcarboxiamidas. |
-
2002
- 2002-02-04 DE DE10204391A patent/DE10204391A1/de not_active Withdrawn
-
2003
- 2003-01-22 PL PL371582A patent/PL216410B1/pl not_active IP Right Cessation
- 2003-01-22 AT AT03737263T patent/ATE476427T1/de not_active IP Right Cessation
- 2003-01-22 AU AU2003244431A patent/AU2003244431A1/en not_active Abandoned
- 2003-01-22 NZ NZ534454A patent/NZ534454A/en unknown
- 2003-01-22 MX MXPA04007465A patent/MXPA04007465A/es active IP Right Grant
- 2003-01-22 US US10/502,994 patent/US7388097B2/en not_active Expired - Fee Related
- 2003-01-22 KR KR1020047011698A patent/KR100958680B1/ko not_active Expired - Fee Related
- 2003-01-22 JP JP2003565984A patent/JP4559735B2/ja not_active Expired - Fee Related
- 2003-01-22 UA UA20040907251A patent/UA79266C2/uk unknown
- 2003-01-22 BR BRPI0307432-3B1A patent/BR0307432B1/pt not_active IP Right Cessation
- 2003-01-22 ES ES03737263T patent/ES2347870T3/es not_active Expired - Lifetime
- 2003-01-22 EP EP03737263A patent/EP1474407B1/de not_active Expired - Lifetime
- 2003-01-22 WO PCT/EP2003/000589 patent/WO2003066610A1/de not_active Ceased
- 2003-01-22 RU RU2004126867/04A patent/RU2319697C2/ru not_active IP Right Cessation
- 2003-01-22 CN CNB038076802A patent/CN100503586C/zh not_active Expired - Fee Related
- 2003-01-22 DE DE50312946T patent/DE50312946D1/de not_active Expired - Lifetime
- 2003-01-22 CA CA002474902A patent/CA2474902A1/en not_active Abandoned
-
2004
- 2004-08-02 ZA ZA200406146A patent/ZA200406146B/en unknown
- 2004-09-02 CO CO04086402A patent/CO5611065A2/es not_active Application Discontinuation
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