JP2005525428A5 - - Google Patents
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- Publication number
- JP2005525428A5 JP2005525428A5 JP2004505321A JP2004505321A JP2005525428A5 JP 2005525428 A5 JP2005525428 A5 JP 2005525428A5 JP 2004505321 A JP2004505321 A JP 2004505321A JP 2004505321 A JP2004505321 A JP 2004505321A JP 2005525428 A5 JP2005525428 A5 JP 2005525428A5
- Authority
- JP
- Japan
- Prior art keywords
- group
- mercaptides
- branched
- carbon atoms
- linear
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 30
- -1 branched Chemical group 0.000 claims description 30
- 150000004703 alkoxides Chemical class 0.000 claims description 17
- 150000001875 compounds Chemical class 0.000 claims description 17
- 150000001540 azides Chemical class 0.000 claims description 16
- 125000003709 fluoroalkyl group Chemical group 0.000 claims description 16
- 150000004820 halides Chemical class 0.000 claims description 16
- 150000004678 hydrides Chemical class 0.000 claims description 16
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 15
- 125000004432 carbon atom Chemical group C* 0.000 claims description 15
- 125000004122 cyclic group Chemical group 0.000 claims description 15
- 238000000034 method Methods 0.000 claims description 15
- 229910052760 oxygen Inorganic materials 0.000 claims description 15
- 239000001301 oxygen Substances 0.000 claims description 15
- 150000001913 cyanates Chemical class 0.000 claims description 14
- 239000012948 isocyanate Substances 0.000 claims description 14
- 150000002513 isocyanates Chemical class 0.000 claims description 14
- 239000012038 nucleophile Substances 0.000 claims description 14
- 150000003573 thiols Chemical class 0.000 claims description 14
- 150000003335 secondary amines Chemical class 0.000 claims description 13
- 150000003567 thiocyanates Chemical class 0.000 claims description 13
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 claims description 12
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 claims description 9
- 239000002841 Lewis acid Substances 0.000 claims description 6
- 150000007517 lewis acids Chemical class 0.000 claims description 6
- 239000000178 monomer Substances 0.000 claims description 5
- 150000002825 nitriles Chemical class 0.000 claims description 5
- 125000004407 fluoroaryl group Chemical group 0.000 claims description 4
- 125000001424 substituent group Chemical group 0.000 claims description 4
- 229920001577 copolymer Polymers 0.000 claims description 3
- 150000001412 amines Chemical class 0.000 claims description 2
- 238000006467 substitution reaction Methods 0.000 claims description 2
- 239000002904 solvent Substances 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- 125000000217 alkyl group Chemical group 0.000 description 3
- 229910018287 SbF 5 Inorganic materials 0.000 description 2
- ZQBFAOFFOQMSGJ-UHFFFAOYSA-N hexafluorobenzene Chemical compound FC1=C(F)C(F)=C(F)C(F)=C1F ZQBFAOFFOQMSGJ-UHFFFAOYSA-N 0.000 description 2
- 125000005010 perfluoroalkyl group Chemical group 0.000 description 2
- BQCIDUSAKPWEOX-UHFFFAOYSA-N 1,1-Difluoroethene Chemical compound FC(F)=C BQCIDUSAKPWEOX-UHFFFAOYSA-N 0.000 description 1
- 229920001410 Microfiber Polymers 0.000 description 1
- ZMZDMBWJUHKJPS-UHFFFAOYSA-M Thiocyanate anion Chemical compound [S-]C#N ZMZDMBWJUHKJPS-UHFFFAOYSA-M 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 125000004104 aryloxy group Chemical group 0.000 description 1
- SBZXBUIDTXKZTM-UHFFFAOYSA-N diglyme Chemical compound COCCOCCOC SBZXBUIDTXKZTM-UHFFFAOYSA-N 0.000 description 1
- XUCNUKMRBVNAPB-UHFFFAOYSA-N fluoroethene Chemical group FC=C XUCNUKMRBVNAPB-UHFFFAOYSA-N 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical group 0.000 description 1
- ZMZDMBWJUHKJPS-UHFFFAOYSA-N hydrogen thiocyanate Natural products SC#N ZMZDMBWJUHKJPS-UHFFFAOYSA-N 0.000 description 1
- 239000003658 microfiber Substances 0.000 description 1
- 125000006340 pentafluoro ethyl group Chemical group FC(F)(F)C(F)(F)* 0.000 description 1
- 239000002798 polar solvent Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 description 1
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US38052802P | 2002-05-14 | 2002-05-14 | |
| PCT/US2003/015107 WO2003097588A2 (en) | 2002-05-14 | 2003-05-14 | Fluorosulfates of hexafluoroisobutylene and its higher homologs and their derivatives |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2009260902A Division JP5149885B2 (ja) | 2002-05-14 | 2009-11-16 | ヘキサフルオロイソブチレンおよびそのより高い同族体およびそれらの誘導体のフルオロスルファート |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2005525428A JP2005525428A (ja) | 2005-08-25 |
| JP2005525428A5 true JP2005525428A5 (enExample) | 2006-06-15 |
| JP4472519B2 JP4472519B2 (ja) | 2010-06-02 |
Family
ID=29549973
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2004505321A Expired - Fee Related JP4472519B2 (ja) | 2002-05-14 | 2003-05-14 | ヘキサフルオロイソブチレンおよびそのより高い同族体およびそれらの誘導体のフルオロスルファート |
| JP2009260902A Expired - Fee Related JP5149885B2 (ja) | 2002-05-14 | 2009-11-16 | ヘキサフルオロイソブチレンおよびそのより高い同族体およびそれらの誘導体のフルオロスルファート |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2009260902A Expired - Fee Related JP5149885B2 (ja) | 2002-05-14 | 2009-11-16 | ヘキサフルオロイソブチレンおよびそのより高い同族体およびそれらの誘導体のフルオロスルファート |
Country Status (7)
| Country | Link |
|---|---|
| US (6) | US7276624B2 (enExample) |
| EP (1) | EP1513801B1 (enExample) |
| JP (2) | JP4472519B2 (enExample) |
| CN (5) | CN101085752B (enExample) |
| DE (1) | DE60336720D1 (enExample) |
| RU (1) | RU2004136314A (enExample) |
| WO (1) | WO2003097588A2 (enExample) |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7276624B2 (en) * | 2002-05-14 | 2007-10-02 | E. I. Du Pont De Nemours And Company | Fluorosulfates of hexafluoroisobutylene and its higher homologs |
| EP2377610A3 (en) * | 2004-12-22 | 2012-02-08 | E. I. Du Pont De Nemours And Company | Process for increasing the fluorine content by photochemical reactions |
| EP1855795A1 (en) * | 2004-12-22 | 2007-11-21 | E.I.Du pont de nemours and company | Functionalized copolymers of terminally functionalized perfluoro (alkyl vinyl ether) reactor wall for photochemical reactions, process for increasing fluorine content in hydrocarbons and halohydrocarbons and olefin production |
| WO2008055940A2 (en) * | 2006-11-09 | 2008-05-15 | Boehringer Ingelheim International Gmbh | Combination therapy with sglt-2 inhibitors and their pharmaceutical compositions |
| JP5136070B2 (ja) * | 2008-01-15 | 2013-02-06 | 旭硝子株式会社 | パーフルオロアリルブロミドの製造方法 |
| EP2326239B1 (en) * | 2008-07-03 | 2017-06-21 | Masimo Laboratories, Inc. | Protrusion for improving spectroscopic measurement of blood constituents |
| JP5440692B2 (ja) * | 2010-03-29 | 2014-03-12 | ダイキン工業株式会社 | ３−クロロ−ペンタフルオロプロペンの製造方法 |
| RU2430914C1 (ru) * | 2010-04-09 | 2011-10-10 | Федеральное государственное унитарное предприятие "Ордена Ленина и ордена Трудового Красного Знамени научно-исследовательский институт синтетического каучука имени академика С.В. Лебедева" | Перфтор[(2-фторсульфат)этилаллиловый] эфир |
| US8940846B2 (en) * | 2010-07-01 | 2015-01-27 | Solvay Specialty Polymers Italy S.P.A. | Process for the treatment of sulfonyl fluoride polymers |
| CN102225980B (zh) * | 2011-04-29 | 2012-11-21 | 内蒙古三爱富万豪氟化工有限公司 | 一种含氟醚端基结构的聚偏氟乙烯树脂及其制备方法 |
| JP5793996B2 (ja) * | 2011-06-29 | 2015-10-14 | セントラル硝子株式会社 | フルオロ硫酸芳香環エステル類の製造方法 |
| JP6868623B2 (ja) * | 2015-12-02 | 2021-05-12 | スリーエム イノベイティブ プロパティズ カンパニー | アリル末端不飽和ヒドロフルオロアミン及びアリル末端不飽和ヒドロフルオロエーテル化合物並びにこれらの使用方法 |
| WO2017195070A1 (en) * | 2016-05-09 | 2017-11-16 | 3M Innovative Properties Company | Hydrofluoroolefins and methods of using same |
| CN107286061A (zh) * | 2017-06-09 | 2017-10-24 | 武汉理工大学 | 一种酚类化合物脱氧还原方法 |
| US12116336B2 (en) * | 2018-12-06 | 2024-10-15 | Lts Lohmann Therapie-Systeme Ag | Method for the recycling or disposal of halocarbons |
| CN114644539B (zh) * | 2022-04-01 | 2023-07-14 | 安徽农业大学 | 一种含烯烃的二氟芳氧醚的合成方法及其在农药中的用途 |
Family Cites Families (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2352554A (en) * | 1939-06-02 | 1944-06-27 | Redington Co F B | Stamp feeding and gluing mechanism |
| US2852554A (en) | 1956-07-12 | 1958-09-16 | Du Pont | Alpha-sulfopolyfluoromonocarboxylic acids and derivatives hydrolyzable thereto |
| US3862978A (en) * | 1967-08-24 | 1975-01-28 | Dow Chemical Co | Catalytic synthesis of organic halogen compounds from an ethylenically unsaturated compound and a halogenated organic compound |
| US3655786A (en) * | 1968-09-10 | 1972-04-11 | Allied Chem | Process for preparing fluoroisobutylenes and novel product |
| CA930749A (en) * | 1968-09-10 | 1973-07-24 | Allied Chemical Corporation | Process for preparing fluoroisobutylene |
| US3706723A (en) | 1970-04-29 | 1972-12-19 | Allied Chem | Copolymer of 3,3,3 - trifluoro-2-trifluoromethyl propene and vinylidene fluoride |
| US4131740A (en) | 1977-04-20 | 1978-12-26 | E. I. Du Pont De Nemours And Company | Alkyl perfluoro-ω-fluoroformyl esters and their preparation |
| US4235804A (en) | 1978-08-08 | 1980-11-25 | E. I. Du Pont De Nemours And Company | Preparation of perfluoroallyl fluorosulfate |
| GB2027709B (en) * | 1978-08-08 | 1983-01-06 | Du Pont | Perfluoroallyl fluorosulphate and its sultone and processes for their preparation |
| US4273728A (en) * | 1979-03-14 | 1981-06-16 | E. I. Du Pont De Nemours And Company | Polyfluoroallyloxy compounds, their preparation and copolymers therefrom |
| DE3464866D1 (en) | 1983-03-07 | 1987-08-27 | Ausimont Usa | A process of rotational molding fluoropolymers |
| US4704324A (en) * | 1985-04-03 | 1987-11-03 | The Dow Chemical Company | Semi-permeable membranes prepared via reaction of cationic groups with nucleophilic groups |
| KR100287451B1 (ko) | 1994-06-09 | 2001-04-16 | 이노우에 노리유끼 | 불소 함유 올레핀, 불소 함유 중합체 및 그 중합체를 사용한 열가소성 수지 조성물 [fluoroolefin, fluoropolymer, and thermoplastic resin composition containing the polymer] |
| US6025092A (en) | 1998-02-13 | 2000-02-15 | E. I. Du Pont De Nemours And Company | Fluorinated ionomers and their uses |
| KR100615497B1 (ko) | 1999-03-16 | 2006-08-25 | 이 아이 듀폰 디 네모아 앤드 캄파니 | 플라스틱 렌즈 및 장치용 저반사성 플루오로중합체 층 |
| JP2003514955A (ja) | 1999-11-17 | 2003-04-22 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | 紫外および真空紫外透過性重合体組成物およびそれらの使用 |
| IT1318488B1 (it) | 2000-04-21 | 2003-08-25 | Ausimont Spa | Fluorovinileteri e polimeri da essi ottenibili. |
| JP2004536171A (ja) | 2001-05-14 | 2004-12-02 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | 紫外線及び真空紫外線の透明性を必要とする適用での部分フッ素化ポリマーの使用 |
| US6713567B2 (en) | 2001-07-13 | 2004-03-30 | E. I. Du Pont De Nemours And Company | Method for forming fluorinated ionomers |
| US6653515B2 (en) * | 2001-12-14 | 2003-11-25 | Ballard Power Systems Inc. | Synthesis of α, β, β-trifluorostyrene via in-situ formation of trifluorovinyl metal halide |
| US7276624B2 (en) * | 2002-05-14 | 2007-10-02 | E. I. Du Pont De Nemours And Company | Fluorosulfates of hexafluoroisobutylene and its higher homologs |
| US7129009B2 (en) * | 2002-05-14 | 2006-10-31 | E. I. Du Pont De Nemours And Company | Polymer-liquid compositions useful in ultraviolet and vacuum ultraviolet uses |
-
2003
- 2003-05-09 US US10/435,003 patent/US7276624B2/en not_active Expired - Lifetime
- 2003-05-14 RU RU2004136314/04A patent/RU2004136314A/ru not_active Application Discontinuation
- 2003-05-14 CN CN2007101278550A patent/CN101085752B/zh not_active Expired - Fee Related
- 2003-05-14 JP JP2004505321A patent/JP4472519B2/ja not_active Expired - Fee Related
- 2003-05-14 EP EP03728891A patent/EP1513801B1/en not_active Expired - Lifetime
- 2003-05-14 CN CNB038108488A patent/CN100334074C/zh not_active Expired - Fee Related
- 2003-05-14 CN CN2007101278546A patent/CN101085754B/zh not_active Expired - Fee Related
- 2003-05-14 DE DE60336720T patent/DE60336720D1/de not_active Expired - Lifetime
- 2003-05-14 WO PCT/US2003/015107 patent/WO2003097588A2/en not_active Ceased
- 2003-05-14 CN CN2007101278565A patent/CN101085753B/zh not_active Expired - Fee Related
- 2003-05-14 CN CNA2007101278531A patent/CN101092378A/zh active Pending
-
2007
- 2007-03-22 US US11/726,488 patent/US7531689B2/en not_active Expired - Fee Related
- 2007-03-22 US US11/726,485 patent/US7579499B2/en not_active Expired - Fee Related
- 2007-03-22 US US11/726,772 patent/US20070167589A1/en not_active Abandoned
- 2007-03-22 US US11/726,449 patent/US7301059B2/en not_active Expired - Lifetime
-
2009
- 2009-04-22 US US12/428,041 patent/US20090203865A1/en not_active Abandoned
- 2009-11-16 JP JP2009260902A patent/JP5149885B2/ja not_active Expired - Fee Related
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