JP2005517787A - 紫外線の影響に対して内容物を保護するための、ヒドロキシフェニルベンゾトリアゾール紫外線吸収剤を含む容器又はフィルム。 - Google Patents

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Publication number

JP2005517787A

JP2005517787A JP2003569723A JP2003569723A JP2005517787A JP 2005517787 A JP2005517787 A JP 2005517787A JP 2003569723 A JP2003569723 A JP 2003569723A JP 2003569723 A JP2003569723 A JP 2003569723A JP 2005517787 A JP2005517787 A JP 2005517787A

Authority

JP

Japan

Prior art keywords

group

carbon atoms

linear

alkyl group

tert

Prior art date

2002-02-19

Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)

Withdrawn

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• 239000006096 absorbing agent Substances 0.000 title claims abstract description 76
• ZCILGMFPJBRCNO-UHFFFAOYSA-N 4-phenyl-2H-benzotriazol-5-ol Chemical compound OC1=CC=C2NN=NC2=C1C1=CC=CC=C1 ZCILGMFPJBRCNO-UHFFFAOYSA-N 0.000 title claims abstract description 44
• 229920003023 plastic Polymers 0.000 claims abstract description 25
• 239000004033 plastic Substances 0.000 claims abstract description 25
• 238000006482 condensation reaction Methods 0.000 claims abstract description 17
• 239000002453 shampoo Substances 0.000 claims abstract description 15
• 235000013305 food Nutrition 0.000 claims abstract description 13
• 239000002537 cosmetic Substances 0.000 claims abstract description 5
• 239000003814 drug Substances 0.000 claims abstract description 5
• 125000004432 carbon atom Chemical group C* 0.000 claims description 303
• 125000000217 alkyl group Chemical group 0.000 claims description 156
• -1 glycidyloxy group Chemical group 0.000 claims description 126
• 239000000203 mixture Substances 0.000 claims description 97
• 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 70
• 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 66
• 125000003342 alkenyl group Chemical group 0.000 claims description 64
• 229920000642 polymer Polymers 0.000 claims description 47
• 125000003884 phenylalkyl group Chemical group 0.000 claims description 46
• 238000000034 method Methods 0.000 claims description 35
• 125000002947 alkylene group Chemical group 0.000 claims description 28
• 229920000728 polyester Polymers 0.000 claims description 26
• 125000000753 cycloalkyl group Chemical group 0.000 claims description 24
• 239000006097 ultraviolet radiation absorber Substances 0.000 claims description 21
• 150000001412 amines Chemical class 0.000 claims description 16
• 125000003118 aryl group Chemical group 0.000 claims description 16
• 239000000975 dye Substances 0.000 claims description 16
• 239000000047 product Substances 0.000 claims description 16
• 239000010410 layer Substances 0.000 claims description 14
• 239000004417 polycarbonate Substances 0.000 claims description 14
• 229920000515 polycarbonate Polymers 0.000 claims description 14
• 239000003381 stabilizer Substances 0.000 claims description 13
• RWRDLPDLKQPQOW-UHFFFAOYSA-N Pyrrolidine Chemical compound C1CCNC1 RWRDLPDLKQPQOW-UHFFFAOYSA-N 0.000 claims description 12
• 125000004433 nitrogen atom Chemical group N* 0.000 claims description 12
• 229920002647 polyamide Polymers 0.000 claims description 12
• 239000004952 Polyamide Substances 0.000 claims description 11
• JIHQDMXYYFUGFV-UHFFFAOYSA-N 1,3,5-triazine Chemical group C1=NC=NC=N1 JIHQDMXYYFUGFV-UHFFFAOYSA-N 0.000 claims description 10
• 239000000654 additive Substances 0.000 claims description 10
• 125000003710 aryl alkyl group Chemical group 0.000 claims description 10
• 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 10
• 239000000049 pigment Substances 0.000 claims description 10
• 150000001875 compounds Chemical class 0.000 claims description 9
• 239000000463 material Substances 0.000 claims description 9
• 230000005855 radiation Effects 0.000 claims description 9
• GLUUGHFHXGJENI-UHFFFAOYSA-N Piperazine Chemical compound C1CNCCN1 GLUUGHFHXGJENI-UHFFFAOYSA-N 0.000 claims description 8
• NQRYJNQNLNOLGT-UHFFFAOYSA-N Piperidine Chemical compound C1CCNCC1 NQRYJNQNLNOLGT-UHFFFAOYSA-N 0.000 claims description 8
• 125000004956 cyclohexylene group Chemical group 0.000 claims description 8
• 125000002768 hydroxyalkyl group Chemical group 0.000 claims description 8
• 125000005010 perfluoroalkyl group Chemical group 0.000 claims description 8
• 229920001328 Polyvinylidene chloride Polymers 0.000 claims description 7
• 125000004430 oxygen atom Chemical group O* 0.000 claims description 7
• 229920000098 polyolefin Polymers 0.000 claims description 7
• MAEDTQBZZXPXLZ-UHFFFAOYSA-N 6-methylheptyl 3-[3-tert-butyl-5-(5-chlorobenzotriazol-2-yl)-4-hydroxyphenyl]propanoate Chemical compound CC(C)(C)C1=CC(CCC(=O)OCCCCCC(C)C)=CC(N2N=C3C=C(Cl)C=CC3=N2)=C1O MAEDTQBZZXPXLZ-UHFFFAOYSA-N 0.000 claims description 6
• 229910052799 carbon Inorganic materials 0.000 claims description 6
• 125000004093 cyano group Chemical group *C#N 0.000 claims description 6
• 125000001153 fluoro group Chemical group F* 0.000 claims description 6
• 125000005843 halogen group Chemical group 0.000 claims description 6
• 230000009931 harmful effect Effects 0.000 claims description 6
• 229920002451 polyvinyl alcohol Polymers 0.000 claims description 6
• 239000004594 Masterbatch (MB) Substances 0.000 claims description 5
• 235000013405 beer Nutrition 0.000 claims description 5
• 125000000649 benzylidene group Chemical group [H]C(=[*])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 claims description 5
• 238000009833 condensation Methods 0.000 claims description 5
• 230000005494 condensation Effects 0.000 claims description 5
• 229920000554 ionomer Polymers 0.000 claims description 5
• 239000005033 polyvinylidene chloride Substances 0.000 claims description 5
• 230000000087 stabilizing effect Effects 0.000 claims description 5
• 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 claims description 5
• ACZGCWSMSTYWDQ-UHFFFAOYSA-N 3h-1-benzofuran-2-one Chemical class C1=CC=C2OC(=O)CC2=C1 ACZGCWSMSTYWDQ-UHFFFAOYSA-N 0.000 claims description 4
• OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 4
• 229920000219 Ethylene vinyl alcohol Polymers 0.000 claims description 4
• YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical group C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 claims description 4
• 239000004793 Polystyrene Substances 0.000 claims description 4
• 125000001118 alkylidene group Chemical group 0.000 claims description 4
• 239000003963 antioxidant agent Substances 0.000 claims description 4
• 125000005569 butenylene group Chemical group 0.000 claims description 4
• 125000005622 butynylene group Chemical group 0.000 claims description 4
• 125000001309 chloro group Chemical group Cl* 0.000 claims description 4
• 125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 4
• 239000004715 ethylene vinyl alcohol Substances 0.000 claims description 4
• 235000015203 fruit juice Nutrition 0.000 claims description 4
• 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 4
• JMGAGEUAMQQJAD-UHFFFAOYSA-N methyl 3-[3-tert-butyl-4-hydroxy-5-[5-(trifluoromethyl)benzotriazol-2-yl]phenyl]propanoate Chemical compound CC(C)(C)C1=CC(CCC(=O)OC)=CC(N2N=C3C=C(C=CC3=N2)C(F)(F)F)=C1O JMGAGEUAMQQJAD-UHFFFAOYSA-N 0.000 claims description 4
• VRBLLGLKTUGCSG-UHFFFAOYSA-N methyl 3-[3-tert-butyl-5-(5-chlorobenzotriazol-2-yl)-4-hydroxyphenyl]propanoate Chemical compound CC(C)(C)C1=CC(CCC(=O)OC)=CC(N2N=C3C=C(Cl)C=CC3=N2)=C1O VRBLLGLKTUGCSG-UHFFFAOYSA-N 0.000 claims description 4
• 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims description 4
• 125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 claims description 4
• XRBCRPZXSCBRTK-UHFFFAOYSA-N phosphonous acid Chemical class OPO XRBCRPZXSCBRTK-UHFFFAOYSA-N 0.000 claims description 4
• 229920002223 polystyrene Polymers 0.000 claims description 4
• 229920002635 polyurethane Polymers 0.000 claims description 4
• 239000004814 polyurethane Substances 0.000 claims description 4
• 229920000915 polyvinyl chloride Polymers 0.000 claims description 4
• 239000004800 polyvinyl chloride Substances 0.000 claims description 4
• 229940088594 vitamin Drugs 0.000 claims description 4
• 229930003231 vitamin Natural products 0.000 claims description 4
• 235000013343 vitamin Nutrition 0.000 claims description 4
• 239000011782 vitamin Substances 0.000 claims description 4
• 125000006839 xylylene group Chemical group 0.000 claims description 4
• CHGZWSKJRGGMNL-UHFFFAOYSA-N 2-[[4-hydroxy-3-[5-(trifluoromethyl)benzotriazol-2-yl]phenyl]methyl]-3-methyl-3-phenylbutanoic acid Chemical compound C=1C=C(O)C(N2N=C3C=C(C=CC3=N2)C(F)(F)F)=CC=1CC(C(O)=O)C(C)(C)C1=CC=CC=C1 CHGZWSKJRGGMNL-UHFFFAOYSA-N 0.000 claims description 3
• AYUCMOLWLQYVTG-UHFFFAOYSA-N 2-tert-butyl-3-(2-hydroxyethoxy)-6-[5-(trifluoromethyl)benzotriazol-2-yl]phenol Chemical compound C1=C(OCCO)C(C(C)(C)C)=C(O)C(N2N=C3C=C(C=CC3=N2)C(F)(F)F)=C1 AYUCMOLWLQYVTG-UHFFFAOYSA-N 0.000 claims description 3
• YVVFERCUUGXZLE-UHFFFAOYSA-N 2-tert-butyl-4-(2-hydroxyethyl)-6-[5-(trifluoromethyl)benzotriazol-2-yl]phenol Chemical compound CC(C)(C)C1=CC(CCO)=CC(N2N=C3C=C(C=CC3=N2)C(F)(F)F)=C1O YVVFERCUUGXZLE-UHFFFAOYSA-N 0.000 claims description 3
• RLVCEWCIXYRSGI-UHFFFAOYSA-N 2-tert-butyl-4-(3-hydroxypropyl)-6-[5-(trifluoromethyl)benzotriazol-2-yl]phenol Chemical compound CC(C)(C)C1=CC(CCCO)=CC(N2N=C3C=C(C=CC3=N2)C(F)(F)F)=C1O RLVCEWCIXYRSGI-UHFFFAOYSA-N 0.000 claims description 3
• VLHISVXXWDSAPT-UHFFFAOYSA-N 2-tert-butyl-6-(5-chlorobenzotriazol-2-yl)-3-(2-hydroxyethoxy)phenol Chemical compound C1=C(OCCO)C(C(C)(C)C)=C(O)C(N2N=C3C=C(Cl)C=CC3=N2)=C1 VLHISVXXWDSAPT-UHFFFAOYSA-N 0.000 claims description 3
• VVSRRKAMMMHQGB-UHFFFAOYSA-N 3-[3-[5-(benzenesulfonyl)benzotriazol-2-yl]-5-tert-butyl-4-hydroxyphenyl]propanoic acid Chemical compound CC(C)(C)C1=CC(CCC(O)=O)=CC(N2N=C3C=C(C=CC3=N2)S(=O)(=O)C=2C=CC=CC=2)=C1O VVSRRKAMMMHQGB-UHFFFAOYSA-N 0.000 claims description 3
• MMPCZTQLVSESIT-UHFFFAOYSA-N 3-[3-tert-butyl-4-hydroxy-5-[5-(trifluoromethyl)benzotriazol-2-yl]phenyl]propanoic acid Chemical compound CC(C)(C)C1=CC(CCC(O)=O)=CC(N2N=C3C=C(C=CC3=N2)C(F)(F)F)=C1O MMPCZTQLVSESIT-UHFFFAOYSA-N 0.000 claims description 3
• NFORJTXNUVBLOK-UHFFFAOYSA-N 3-[3-tert-butyl-5-(5-chlorobenzotriazol-2-yl)-4-hydroxyphenyl]propanoic acid Chemical compound CC(C)(C)C1=CC(CCC(O)=O)=CC(N2N=C3C=C(Cl)C=CC3=N2)=C1O NFORJTXNUVBLOK-UHFFFAOYSA-N 0.000 claims description 3
• WXQIQASTQGZHBP-UHFFFAOYSA-N 4-(2-hydroxyethyl)-2-(2-phenylpropan-2-yl)-6-[5-(trifluoromethyl)benzotriazol-2-yl]phenol Chemical compound C=1C(CCO)=CC(N2N=C3C=C(C=CC3=N2)C(F)(F)F)=C(O)C=1C(C)(C)C1=CC=CC=C1 WXQIQASTQGZHBP-UHFFFAOYSA-N 0.000 claims description 3
• YBGAHDSWZZNBNR-UHFFFAOYSA-N 4-(2-hydroxyethyl)-2-[5-(trifluoromethyl)benzotriazol-2-yl]phenol Chemical compound OCCC1=CC=C(O)C(N2N=C3C=C(C=CC3=N2)C(F)(F)F)=C1 YBGAHDSWZZNBNR-UHFFFAOYSA-N 0.000 claims description 3
• KUQMFMAFUWJWAR-UHFFFAOYSA-N 4-(3-hydroxypropyl)-2-(2-phenylpropan-2-yl)-6-[5-(trifluoromethyl)benzotriazol-2-yl]phenol Chemical compound C=1C(CCCO)=CC(N2N=C3C=C(C=CC3=N2)C(F)(F)F)=C(O)C=1C(C)(C)C1=CC=CC=C1 KUQMFMAFUWJWAR-UHFFFAOYSA-N 0.000 claims description 3
• WMBMNOPFBSLJLS-UHFFFAOYSA-N 4-(3-hydroxypropyl)-2-[5-(trifluoromethyl)benzotriazol-2-yl]phenol Chemical compound OCCCC1=CC=C(O)C(N2N=C3C=C(C=CC3=N2)C(F)(F)F)=C1 WMBMNOPFBSLJLS-UHFFFAOYSA-N 0.000 claims description 3
• JDVJWDQBRTUINM-UHFFFAOYSA-N 6-methylheptyl 3-[3-[5-(benzenesulfonyl)benzotriazol-2-yl]-5-tert-butyl-4-hydroxyphenyl]propanoate Chemical compound CC(C)(C)C1=CC(CCC(=O)OCCCCCC(C)C)=CC(N2N=C3C=C(C=CC3=N2)S(=O)(=O)C=2C=CC=CC=2)=C1O JDVJWDQBRTUINM-UHFFFAOYSA-N 0.000 claims description 3
• FXUZBFKATOWFLD-UHFFFAOYSA-N 6-methylheptyl 3-[3-tert-butyl-4-hydroxy-5-[5-(trifluoromethyl)benzotriazol-2-yl]phenyl]propanoate Chemical compound CC(C)(C)C1=CC(CCC(=O)OCCCCCC(C)C)=CC(N2N=C3C=C(C=CC3=N2)C(F)(F)F)=C1O FXUZBFKATOWFLD-UHFFFAOYSA-N 0.000 claims description 3
• 239000004593 Epoxy Substances 0.000 claims description 3
• 239000002216 antistatic agent Substances 0.000 claims description 3
• DQXBYHZEEUGOBF-UHFFFAOYSA-N but-3-enoic acid;ethene Chemical compound C=C.OC(=O)CC=C DQXBYHZEEUGOBF-UHFFFAOYSA-N 0.000 claims description 3
• 235000013365 dairy product Nutrition 0.000 claims description 3
• 239000003995 emulsifying agent Substances 0.000 claims description 3
• 239000005038 ethylene vinyl acetate Substances 0.000 claims description 3
• 239000000945 filler Substances 0.000 claims description 3
• 239000003063 flame retardant Substances 0.000 claims description 3
• 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 claims description 3
• RZXDTJIXPSCHCI-UHFFFAOYSA-N hexa-1,5-diene-2,5-diol Chemical compound OC(=C)CCC(O)=C RZXDTJIXPSCHCI-UHFFFAOYSA-N 0.000 claims description 3
• 239000000314 lubricant Substances 0.000 claims description 3
• 229910052751 metal Inorganic materials 0.000 claims description 3
• 239000002184 metal Substances 0.000 claims description 3
• GBOXOTNIFCMVNQ-UHFFFAOYSA-N methyl 2-[3-(benzotriazol-2-yl)-1,5-ditert-butyl-4-hydroxycyclohexa-2,4-dien-1-yl]sulfonylacetate Chemical compound COC(=O)CS(=O)(=O)C1(C(C)(C)C)CC(C(C)(C)C)=C(O)C(N2N=C3C=CC=CC3=N2)=C1 GBOXOTNIFCMVNQ-UHFFFAOYSA-N 0.000 claims description 3
• DSZKSKDGJMWOFG-UHFFFAOYSA-N methyl 3-[3-[5-(benzenesulfonyl)benzotriazol-2-yl]-5-tert-butyl-4-hydroxyphenyl]propanoate Chemical compound CC(C)(C)C1=CC(CCC(=O)OC)=CC(N2N=C3C=C(C=CC3=N2)S(=O)(=O)C=2C=CC=CC=2)=C1O DSZKSKDGJMWOFG-UHFFFAOYSA-N 0.000 claims description 3
• LBBKPOQRCNXAJD-UHFFFAOYSA-N methyl 3-[3-tert-butyl-5-(5-fluorobenzotriazol-2-yl)-4-hydroxyphenyl]propanoate Chemical compound CC(C)(C)C1=CC(CCC(=O)OC)=CC(N2N=C3C=C(F)C=CC3=N2)=C1O LBBKPOQRCNXAJD-UHFFFAOYSA-N 0.000 claims description 3
• 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 claims description 3
• 239000002667 nucleating agent Substances 0.000 claims description 3
• AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 claims description 3
• 229920001713 poly(ethylene-co-vinyl alcohol) Polymers 0.000 claims description 3
• 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 claims description 3
• 229920006149 polyester-amide block copolymer Polymers 0.000 claims description 3
• 229920002689 polyvinyl acetate Polymers 0.000 claims description 3
• 239000011118 polyvinyl acetate Substances 0.000 claims description 3
• SCUZVMOVTVSBLE-UHFFFAOYSA-N prop-2-enenitrile;styrene Chemical compound C=CC#N.C=CC1=CC=CC=C1 SCUZVMOVTVSBLE-UHFFFAOYSA-N 0.000 claims description 3
• 239000012744 reinforcing agent Substances 0.000 claims description 3
• 239000002356 single layer Substances 0.000 claims description 3
• 235000014214 soft drink Nutrition 0.000 claims description 3
• 229920000638 styrene acrylonitrile Polymers 0.000 claims description 3
• 235000013311 vegetables Nutrition 0.000 claims description 3
• 235000014101 wine Nutrition 0.000 claims description 3
• VOXZDWNPVJITMN-ZBRFXRBCSA-N 17β-estradiol Chemical compound OC1=CC=C2[C@H]3CC[C@](C)([C@H](CC4)O)[C@@H]4[C@@H]3CCC2=C1 VOXZDWNPVJITMN-ZBRFXRBCSA-N 0.000 claims description 2
• XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 claims description 2
• 239000002202 Polyethylene glycol Substances 0.000 claims description 2
• 230000000996 additive effect Effects 0.000 claims description 2
• 125000004450 alkenylene group Chemical group 0.000 claims description 2
• 125000004453 alkoxycarbonyl group Chemical group 0.000 claims description 2
• 125000004419 alkynylene group Chemical group 0.000 claims description 2
• 125000000732 arylene group Chemical group 0.000 claims description 2
• 125000004429 atom Chemical group 0.000 claims description 2
• 125000002993 cycloalkylene group Chemical group 0.000 claims description 2
• 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 claims description 2
• 239000004088 foaming agent Substances 0.000 claims description 2
• 150000002443 hydroxylamines Chemical class 0.000 claims description 2
• 239000000976 ink Substances 0.000 claims description 2
• 235000013372 meat Nutrition 0.000 claims description 2
• 239000003973 paint Substances 0.000 claims description 2
• 125000004193 piperazinyl group Chemical group 0.000 claims description 2
• 229920001223 polyethylene glycol Polymers 0.000 claims description 2
• 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims description 2
• RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims 1
• CNGYZEMWVAWWOB-VAWYXSNFSA-N 5-[[4-anilino-6-[bis(2-hydroxyethyl)amino]-1,3,5-triazin-2-yl]amino]-2-[(e)-2-[4-[[4-anilino-6-[bis(2-hydroxyethyl)amino]-1,3,5-triazin-2-yl]amino]-2-sulfophenyl]ethenyl]benzenesulfonic acid Chemical compound N=1C(NC=2C=C(C(\C=C\C=3C(=CC(NC=4N=C(N=C(NC=5C=CC=CC=5)N=4)N(CCO)CCO)=CC=3)S(O)(=O)=O)=CC=2)S(O)(=O)=O)=NC(N(CCO)CCO)=NC=1NC1=CC=CC=C1 CNGYZEMWVAWWOB-VAWYXSNFSA-N 0.000 claims 1
• 235000013361 beverage Nutrition 0.000 abstract description 4
• 229940079593 drug Drugs 0.000 abstract description 3
• 229920000139 polyethylene terephthalate Polymers 0.000 description 53
• 239000005020 polyethylene terephthalate Substances 0.000 description 52
• 239000010408 film Substances 0.000 description 32
• LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 29
• 229910052757 nitrogen Inorganic materials 0.000 description 20
• QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 19
• 238000010521 absorption reaction Methods 0.000 description 17
• UWSMKYBKUPAEJQ-UHFFFAOYSA-N 5-Chloro-2-(3,5-di-tert-butyl-2-hydroxyphenyl)-2H-benzotriazole Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC(N2N=C3C=C(Cl)C=CC3=N2)=C1O UWSMKYBKUPAEJQ-UHFFFAOYSA-N 0.000 description 15
• OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 15
• MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 15
• 238000000576 coating method Methods 0.000 description 14
• LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 12
• 239000012964 benzotriazole Substances 0.000 description 11
• OCWYEMOEOGEQAN-UHFFFAOYSA-N bumetrizole Chemical compound CC(C)(C)C1=CC(C)=CC(N2N=C3C=C(Cl)C=CC3=N2)=C1O OCWYEMOEOGEQAN-UHFFFAOYSA-N 0.000 description 11
• 238000004806 packaging method and process Methods 0.000 description 11
• YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 10
• 230000000052 comparative effect Effects 0.000 description 10
• 238000002845 discoloration Methods 0.000 description 10
• 238000009472 formulation Methods 0.000 description 10
• 239000007983 Tris buffer Substances 0.000 description 9
• KBPLFHHGFOOTCA-UHFFFAOYSA-N caprylic alcohol Natural products CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 8
• 238000006243 chemical reaction Methods 0.000 description 8
• 150000002009 diols Chemical class 0.000 description 8
• GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 8
• 239000000243 solution Substances 0.000 description 8
• UZUNCLSDTUBVCN-UHFFFAOYSA-N 2-(benzotriazol-2-yl)-6-(2-phenylpropan-2-yl)-4-(2,4,4-trimethylpentan-2-yl)phenol Chemical compound C=1C(C(C)(C)CC(C)(C)C)=CC(N2N=C3C=CC=CC3=N2)=C(O)C=1C(C)(C)C1=CC=CC=C1 UZUNCLSDTUBVCN-UHFFFAOYSA-N 0.000 description 7
• 150000001565 benzotriazoles Chemical class 0.000 description 7
• 238000000071 blow moulding Methods 0.000 description 7
• 150000002148 esters Chemical class 0.000 description 7
• 238000006068 polycondensation reaction Methods 0.000 description 7
• 230000004224 protection Effects 0.000 description 7
• 230000006641 stabilisation Effects 0.000 description 7
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• CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 6
• WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 6
• 125000005605 benzo group Chemical group 0.000 description 6
• 230000005540 biological transmission Effects 0.000 description 6
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