KR20040096558A - 자외선 방사선 효과로 부터 내용물을 보호하기 위한히드록시페닐벤조트리아졸 자외선 흡수제를 포함하는 용기또는 필름 - Google Patents

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Publication number

KR20040096558A

KR20040096558A KR10-2004-7012327A KR20047012327A KR20040096558A KR 20040096558 A KR20040096558 A KR 20040096558A KR 20047012327 A KR20047012327 A KR 20047012327A KR 20040096558 A KR20040096558 A KR 20040096558A

Authority

KR

South Korea

Prior art keywords

carbon atoms

alkyl

straight

tert

phenyl

Prior art date

2002-02-19

Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)

Withdrawn

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• 239000006096 absorbing agent Substances 0.000 title claims abstract description 91
• ZCILGMFPJBRCNO-UHFFFAOYSA-N 4-phenyl-2H-benzotriazol-5-ol Chemical compound OC1=CC=C2NN=NC2=C1C1=CC=CC=C1 ZCILGMFPJBRCNO-UHFFFAOYSA-N 0.000 title claims abstract description 35
• 230000005855 radiation Effects 0.000 title claims abstract description 12
• 230000000694 effects Effects 0.000 title description 2
• 229920003023 plastic Polymers 0.000 claims abstract description 25
• 239000004033 plastic Substances 0.000 claims abstract description 24
• 235000013305 food Nutrition 0.000 claims abstract description 20
• 238000006482 condensation reaction Methods 0.000 claims abstract description 19
• 239000002453 shampoo Substances 0.000 claims abstract description 13
• 239000002537 cosmetic Substances 0.000 claims abstract description 5
• 239000003814 drug Substances 0.000 claims abstract description 5
• 125000004432 carbon atom Chemical group C* 0.000 claims description 209
• 125000000217 alkyl group Chemical group 0.000 claims description 151
• -1 glycidyloxy group Chemical group 0.000 claims description 104
• 239000000203 mixture Substances 0.000 claims description 101
• 239000001257 hydrogen Substances 0.000 claims description 70
• 229910052739 hydrogen Inorganic materials 0.000 claims description 70
• 125000003342 alkenyl group Chemical group 0.000 claims description 66
• 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 64
• 125000003884 phenylalkyl group Chemical group 0.000 claims description 48
• 229920000642 polymer Polymers 0.000 claims description 48
• 150000002431 hydrogen Chemical class 0.000 claims description 47
• 238000000034 method Methods 0.000 claims description 34
• 125000000753 cycloalkyl group Chemical group 0.000 claims description 30
• 229920000728 polyester Polymers 0.000 claims description 27
• 125000002947 alkylene group Chemical group 0.000 claims description 26
• 150000001875 compounds Chemical class 0.000 claims description 26
• UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 23
• VOXZDWNPVJITMN-ZBRFXRBCSA-N 17β-estradiol Chemical compound OC1=CC=C2[C@H]3CC[C@](C)([C@H](CC4)O)[C@@H]4[C@@H]3CCC2=C1 VOXZDWNPVJITMN-ZBRFXRBCSA-N 0.000 claims description 16
• 125000003118 aryl group Chemical group 0.000 claims description 16
• 239000000975 dye Substances 0.000 claims description 16
• 150000001412 amines Chemical class 0.000 claims description 15
• 239000003381 stabilizer Substances 0.000 claims description 15
• 239000000047 product Substances 0.000 claims description 13
• 239000004952 Polyamide Substances 0.000 claims description 12
• RWRDLPDLKQPQOW-UHFFFAOYSA-N Pyrrolidine Chemical compound C1CCNC1 RWRDLPDLKQPQOW-UHFFFAOYSA-N 0.000 claims description 12
• 229920002647 polyamide Polymers 0.000 claims description 12
• 239000004417 polycarbonate Substances 0.000 claims description 12
• 229920000515 polycarbonate Polymers 0.000 claims description 12
• 235000012054 meals Nutrition 0.000 claims description 11
• 125000004433 nitrogen atom Chemical group N* 0.000 claims description 11
• JIHQDMXYYFUGFV-UHFFFAOYSA-N 1,3,5-triazine Chemical group C1=NC=NC=N1 JIHQDMXYYFUGFV-UHFFFAOYSA-N 0.000 claims description 10
• 238000000576 coating method Methods 0.000 claims description 10
• 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 10
• 239000000049 pigment Substances 0.000 claims description 10
• 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 9
• GLUUGHFHXGJENI-UHFFFAOYSA-N Piperazine Chemical compound C1CNCCN1 GLUUGHFHXGJENI-UHFFFAOYSA-N 0.000 claims description 8
• NQRYJNQNLNOLGT-UHFFFAOYSA-N Piperidine Chemical compound C1CCNCC1 NQRYJNQNLNOLGT-UHFFFAOYSA-N 0.000 claims description 8
• 125000004956 cyclohexylene group Chemical group 0.000 claims description 8
• 125000005010 perfluoroalkyl group Chemical group 0.000 claims description 8
• MAEDTQBZZXPXLZ-UHFFFAOYSA-N 6-methylheptyl 3-[3-tert-butyl-5-(5-chlorobenzotriazol-2-yl)-4-hydroxyphenyl]propanoate Chemical compound CC(C)(C)C1=CC(CCC(=O)OCCCCCC(C)C)=CC(N2N=C3C=C(Cl)C=CC3=N2)=C1O MAEDTQBZZXPXLZ-UHFFFAOYSA-N 0.000 claims description 7
• 229910052736 halogen Inorganic materials 0.000 claims description 7
• 150000002367 halogens Chemical class 0.000 claims description 7
• 125000004430 oxygen atom Chemical group O* 0.000 claims description 7
• 229920000098 polyolefin Polymers 0.000 claims description 7
• 230000008569 process Effects 0.000 claims description 7
• 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 claims description 7
• 229920001328 Polyvinylidene chloride Polymers 0.000 claims description 6
• 125000004093 cyano group Chemical group *C#N 0.000 claims description 6
• 125000001153 fluoro group Chemical group F* 0.000 claims description 6
• ACZGCWSMSTYWDQ-UHFFFAOYSA-N 3h-1-benzofuran-2-one Chemical class C1=CC=C2OC(=O)CC2=C1 ACZGCWSMSTYWDQ-UHFFFAOYSA-N 0.000 claims description 5
• 235000013405 beer Nutrition 0.000 claims description 5
• 230000009931 harmful effect Effects 0.000 claims description 5
• 230000000087 stabilizing effect Effects 0.000 claims description 5
• 125000006699 (C1-C3) hydroxyalkyl group Chemical group 0.000 claims description 4
• VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 4
• 239000005977 Ethylene Substances 0.000 claims description 4
• 229920000219 Ethylene vinyl alcohol Polymers 0.000 claims description 4
• YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical group C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 claims description 4
• 239000004793 Polystyrene Substances 0.000 claims description 4
• 125000001118 alkylidene group Chemical group 0.000 claims description 4
• 239000003963 antioxidant agent Substances 0.000 claims description 4
• 125000005569 butenylene group Chemical group 0.000 claims description 4
• 125000005622 butynylene group Chemical group 0.000 claims description 4
• 229920002678 cellulose Polymers 0.000 claims description 4
• 125000001309 chloro group Chemical group Cl* 0.000 claims description 4
• 239000011248 coating agent Substances 0.000 claims description 4
• 239000004715 ethylene vinyl alcohol Substances 0.000 claims description 4
• 235000015203 fruit juice Nutrition 0.000 claims description 4
• 125000002768 hydroxyalkyl group Chemical group 0.000 claims description 4
• JMGAGEUAMQQJAD-UHFFFAOYSA-N methyl 3-[3-tert-butyl-4-hydroxy-5-[5-(trifluoromethyl)benzotriazol-2-yl]phenyl]propanoate Chemical compound CC(C)(C)C1=CC(CCC(=O)OC)=CC(N2N=C3C=C(C=CC3=N2)C(F)(F)F)=C1O JMGAGEUAMQQJAD-UHFFFAOYSA-N 0.000 claims description 4
• VRBLLGLKTUGCSG-UHFFFAOYSA-N methyl 3-[3-tert-butyl-5-(5-chlorobenzotriazol-2-yl)-4-hydroxyphenyl]propanoate Chemical compound CC(C)(C)C1=CC(CCC(=O)OC)=CC(N2N=C3C=C(Cl)C=CC3=N2)=C1O VRBLLGLKTUGCSG-UHFFFAOYSA-N 0.000 claims description 4
• 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims description 4
• 125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 claims description 4
• AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 claims description 4
• 229920002223 polystyrene Polymers 0.000 claims description 4
• 229920002635 polyurethane Polymers 0.000 claims description 4
• 239000004814 polyurethane Substances 0.000 claims description 4
• 229920002451 polyvinyl alcohol Polymers 0.000 claims description 4
• 229920000915 polyvinyl chloride Polymers 0.000 claims description 4
• 239000004800 polyvinyl chloride Substances 0.000 claims description 4
• 239000000725 suspension Substances 0.000 claims description 4
• 229930003231 vitamin Natural products 0.000 claims description 4
• 239000011782 vitamin Substances 0.000 claims description 4
• 235000013343 vitamin Nutrition 0.000 claims description 4
• 229940088594 vitamin Drugs 0.000 claims description 4
• CHGZWSKJRGGMNL-UHFFFAOYSA-N 2-[[4-hydroxy-3-[5-(trifluoromethyl)benzotriazol-2-yl]phenyl]methyl]-3-methyl-3-phenylbutanoic acid Chemical compound C=1C=C(O)C(N2N=C3C=C(C=CC3=N2)C(F)(F)F)=CC=1CC(C(O)=O)C(C)(C)C1=CC=CC=C1 CHGZWSKJRGGMNL-UHFFFAOYSA-N 0.000 claims description 3
• AYUCMOLWLQYVTG-UHFFFAOYSA-N 2-tert-butyl-3-(2-hydroxyethoxy)-6-[5-(trifluoromethyl)benzotriazol-2-yl]phenol Chemical compound C1=C(OCCO)C(C(C)(C)C)=C(O)C(N2N=C3C=C(C=CC3=N2)C(F)(F)F)=C1 AYUCMOLWLQYVTG-UHFFFAOYSA-N 0.000 claims description 3
• YVVFERCUUGXZLE-UHFFFAOYSA-N 2-tert-butyl-4-(2-hydroxyethyl)-6-[5-(trifluoromethyl)benzotriazol-2-yl]phenol Chemical compound CC(C)(C)C1=CC(CCO)=CC(N2N=C3C=C(C=CC3=N2)C(F)(F)F)=C1O YVVFERCUUGXZLE-UHFFFAOYSA-N 0.000 claims description 3
• RLVCEWCIXYRSGI-UHFFFAOYSA-N 2-tert-butyl-4-(3-hydroxypropyl)-6-[5-(trifluoromethyl)benzotriazol-2-yl]phenol Chemical compound CC(C)(C)C1=CC(CCCO)=CC(N2N=C3C=C(C=CC3=N2)C(F)(F)F)=C1O RLVCEWCIXYRSGI-UHFFFAOYSA-N 0.000 claims description 3
• VLHISVXXWDSAPT-UHFFFAOYSA-N 2-tert-butyl-6-(5-chlorobenzotriazol-2-yl)-3-(2-hydroxyethoxy)phenol Chemical compound C1=C(OCCO)C(C(C)(C)C)=C(O)C(N2N=C3C=C(Cl)C=CC3=N2)=C1 VLHISVXXWDSAPT-UHFFFAOYSA-N 0.000 claims description 3
• VVSRRKAMMMHQGB-UHFFFAOYSA-N 3-[3-[5-(benzenesulfonyl)benzotriazol-2-yl]-5-tert-butyl-4-hydroxyphenyl]propanoic acid Chemical compound CC(C)(C)C1=CC(CCC(O)=O)=CC(N2N=C3C=C(C=CC3=N2)S(=O)(=O)C=2C=CC=CC=2)=C1O VVSRRKAMMMHQGB-UHFFFAOYSA-N 0.000 claims description 3
• MMPCZTQLVSESIT-UHFFFAOYSA-N 3-[3-tert-butyl-4-hydroxy-5-[5-(trifluoromethyl)benzotriazol-2-yl]phenyl]propanoic acid Chemical compound CC(C)(C)C1=CC(CCC(O)=O)=CC(N2N=C3C=C(C=CC3=N2)C(F)(F)F)=C1O MMPCZTQLVSESIT-UHFFFAOYSA-N 0.000 claims description 3
• WXQIQASTQGZHBP-UHFFFAOYSA-N 4-(2-hydroxyethyl)-2-(2-phenylpropan-2-yl)-6-[5-(trifluoromethyl)benzotriazol-2-yl]phenol Chemical compound C=1C(CCO)=CC(N2N=C3C=C(C=CC3=N2)C(F)(F)F)=C(O)C=1C(C)(C)C1=CC=CC=C1 WXQIQASTQGZHBP-UHFFFAOYSA-N 0.000 claims description 3
• YBGAHDSWZZNBNR-UHFFFAOYSA-N 4-(2-hydroxyethyl)-2-[5-(trifluoromethyl)benzotriazol-2-yl]phenol Chemical compound OCCC1=CC=C(O)C(N2N=C3C=C(C=CC3=N2)C(F)(F)F)=C1 YBGAHDSWZZNBNR-UHFFFAOYSA-N 0.000 claims description 3
• WMBMNOPFBSLJLS-UHFFFAOYSA-N 4-(3-hydroxypropyl)-2-[5-(trifluoromethyl)benzotriazol-2-yl]phenol Chemical compound OCCCC1=CC=C(O)C(N2N=C3C=C(C=CC3=N2)C(F)(F)F)=C1 WMBMNOPFBSLJLS-UHFFFAOYSA-N 0.000 claims description 3
• JDVJWDQBRTUINM-UHFFFAOYSA-N 6-methylheptyl 3-[3-[5-(benzenesulfonyl)benzotriazol-2-yl]-5-tert-butyl-4-hydroxyphenyl]propanoate Chemical compound CC(C)(C)C1=CC(CCC(=O)OCCCCCC(C)C)=CC(N2N=C3C=C(C=CC3=N2)S(=O)(=O)C=2C=CC=CC=2)=C1O JDVJWDQBRTUINM-UHFFFAOYSA-N 0.000 claims description 3
• FXUZBFKATOWFLD-UHFFFAOYSA-N 6-methylheptyl 3-[3-tert-butyl-4-hydroxy-5-[5-(trifluoromethyl)benzotriazol-2-yl]phenyl]propanoate Chemical compound CC(C)(C)C1=CC(CCC(=O)OCCCCCC(C)C)=CC(N2N=C3C=C(C=CC3=N2)C(F)(F)F)=C1O FXUZBFKATOWFLD-UHFFFAOYSA-N 0.000 claims description 3
• 239000004604 Blowing Agent Substances 0.000 claims description 3
• 239000002216 antistatic agent Substances 0.000 claims description 3
• DQXBYHZEEUGOBF-UHFFFAOYSA-N but-3-enoic acid;ethene Chemical compound C=C.OC(=O)CC=C DQXBYHZEEUGOBF-UHFFFAOYSA-N 0.000 claims description 3
• CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical class [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 claims description 3
• 239000001913 cellulose Substances 0.000 claims description 3
• 235000013365 dairy product Nutrition 0.000 claims description 3
• 239000003995 emulsifying agent Substances 0.000 claims description 3
• 239000005038 ethylene vinyl acetate Substances 0.000 claims description 3
• 239000000945 filler Substances 0.000 claims description 3
• 239000003063 flame retardant Substances 0.000 claims description 3
• 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 claims description 3
• RZXDTJIXPSCHCI-UHFFFAOYSA-N hexa-1,5-diene-2,5-diol Chemical compound OC(=C)CCC(O)=C RZXDTJIXPSCHCI-UHFFFAOYSA-N 0.000 claims description 3
• 150000002443 hydroxylamines Chemical class 0.000 claims description 3
• 239000000314 lubricant Substances 0.000 claims description 3
• 229910052751 metal Inorganic materials 0.000 claims description 3
• 239000002184 metal Substances 0.000 claims description 3
• GBOXOTNIFCMVNQ-UHFFFAOYSA-N methyl 2-[3-(benzotriazol-2-yl)-1,5-ditert-butyl-4-hydroxycyclohexa-2,4-dien-1-yl]sulfonylacetate Chemical compound COC(=O)CS(=O)(=O)C1(C(C)(C)C)CC(C(C)(C)C)=C(O)C(N2N=C3C=CC=CC3=N2)=C1 GBOXOTNIFCMVNQ-UHFFFAOYSA-N 0.000 claims description 3
• DSZKSKDGJMWOFG-UHFFFAOYSA-N methyl 3-[3-[5-(benzenesulfonyl)benzotriazol-2-yl]-5-tert-butyl-4-hydroxyphenyl]propanoate Chemical compound CC(C)(C)C1=CC(CCC(=O)OC)=CC(N2N=C3C=C(C=CC3=N2)S(=O)(=O)C=2C=CC=CC=2)=C1O DSZKSKDGJMWOFG-UHFFFAOYSA-N 0.000 claims description 3
• LBBKPOQRCNXAJD-UHFFFAOYSA-N methyl 3-[3-tert-butyl-5-(5-fluorobenzotriazol-2-yl)-4-hydroxyphenyl]propanoate Chemical compound CC(C)(C)C1=CC(CCC(=O)OC)=CC(N2N=C3C=C(F)C=CC3=N2)=C1O LBBKPOQRCNXAJD-UHFFFAOYSA-N 0.000 claims description 3
• 125000000325 methylidene group Chemical group [H]C([H])=* 0.000 claims description 3
• XRBCRPZXSCBRTK-UHFFFAOYSA-N phosphonous acid Chemical class OPO XRBCRPZXSCBRTK-UHFFFAOYSA-N 0.000 claims description 3
• 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 claims description 3
• 229920002689 polyvinyl acetate Polymers 0.000 claims description 3
• 239000011118 polyvinyl acetate Substances 0.000 claims description 3
• 239000005033 polyvinylidene chloride Substances 0.000 claims description 3
• 239000012744 reinforcing agent Substances 0.000 claims description 3
• 235000014214 soft drink Nutrition 0.000 claims description 3
• 235000014101 wine Nutrition 0.000 claims description 3
• NFORJTXNUVBLOK-UHFFFAOYSA-N 3-[3-tert-butyl-5-(5-chlorobenzotriazol-2-yl)-4-hydroxyphenyl]propanoic acid Chemical compound CC(C)(C)C1=CC(CCC(O)=O)=CC(N2N=C3C=C(Cl)C=CC3=N2)=C1O NFORJTXNUVBLOK-UHFFFAOYSA-N 0.000 claims description 2
• KUQMFMAFUWJWAR-UHFFFAOYSA-N 4-(3-hydroxypropyl)-2-(2-phenylpropan-2-yl)-6-[5-(trifluoromethyl)benzotriazol-2-yl]phenol Chemical compound C=1C(CCCO)=CC(N2N=C3C=C(C=CC3=N2)C(F)(F)F)=C(O)C=1C(C)(C)C1=CC=CC=C1 KUQMFMAFUWJWAR-UHFFFAOYSA-N 0.000 claims description 2
• 239000002202 Polyethylene glycol Substances 0.000 claims description 2
• 125000004450 alkenylene group Chemical group 0.000 claims description 2
• 125000004453 alkoxycarbonyl group Chemical group 0.000 claims description 2
• 230000003078 antioxidant effect Effects 0.000 claims description 2
• 125000000732 arylene group Chemical group 0.000 claims description 2
• 125000002993 cycloalkylene group Chemical group 0.000 claims description 2
• 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 claims description 2
• 239000000976 ink Substances 0.000 claims description 2
• 125000004193 piperazinyl group Chemical group 0.000 claims description 2
• 229920001713 poly(ethylene-co-vinyl alcohol) Polymers 0.000 claims description 2
• 229920006149 polyester-amide block copolymer Polymers 0.000 claims description 2
• 229920001223 polyethylene glycol Polymers 0.000 claims description 2
• 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims description 2
• LCIYFINKFGDAHD-UHFFFAOYSA-N azepane;3-nitrobenzoic acid Chemical compound C1CCCNCC1.OC(=O)C1=CC=CC([N+]([O-])=O)=C1 LCIYFINKFGDAHD-UHFFFAOYSA-N 0.000 claims 2
• LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical group COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 claims 1
• 229940079593 drug Drugs 0.000 claims 1
• 150000002118 epoxides Chemical class 0.000 claims 1
• 125000001425 triazolyl group Chemical group 0.000 claims 1
• 235000013361 beverage Nutrition 0.000 abstract description 4
• 239000005020 polyethylene terephthalate Substances 0.000 description 46
• 229920000139 polyethylene terephthalate Polymers 0.000 description 46
• 229910052757 nitrogen Inorganic materials 0.000 description 34
• LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 32
• 239000010408 film Substances 0.000 description 31
• QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 19
• 238000010521 absorption reaction Methods 0.000 description 18
• OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 15
• MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 15
• 238000002845 discoloration Methods 0.000 description 14
• LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 12
• 239000002324 mouth wash Substances 0.000 description 12
• 239000012964 benzotriazole Substances 0.000 description 11
• 150000002148 esters Chemical class 0.000 description 11
• 239000010410 layer Substances 0.000 description 11
• 229940051866 mouthwash Drugs 0.000 description 10
• YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 9
• 150000001565 benzotriazoles Chemical class 0.000 description 9
• 230000000052 comparative effect Effects 0.000 description 9
• 238000009472 formulation Methods 0.000 description 9
• 238000004806 packaging method and process Methods 0.000 description 9
• ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 8
• 239000002253 acid Substances 0.000 description 8
• KBPLFHHGFOOTCA-UHFFFAOYSA-N caprylic alcohol Natural products CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 8
• 150000002009 diols Chemical class 0.000 description 8
• GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 8
• 239000000243 solution Substances 0.000 description 8
• 239000007983 Tris buffer Substances 0.000 description 7
• 239000007859 condensation product Substances 0.000 description 7
• 238000006068 polycondensation reaction Methods 0.000 description 7
• CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 6
• WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 6
• 125000005605 benzo group Chemical group 0.000 description 6
• 238000000071 blow moulding Methods 0.000 description 6
• 238000000605 extraction Methods 0.000 description 6
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• 229920005989 resin Polymers 0.000 description 6
• 239000011347 resin Substances 0.000 description 6
• 230000006641 stabilisation Effects 0.000 description 6
• 238000011105 stabilization Methods 0.000 description 6
• KKEYFWRCBNTPAC-UHFFFAOYSA-N terephthalic acid group Chemical group C(C1=CC=C(C(=O)O)C=C1)(=O)O KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 6
• GUCMKIKYKIHUTM-UHFFFAOYSA-N 3,3,5,5-tetramethyl-1-[2-(3,3,5,5-tetramethyl-2-oxopiperazin-1-yl)ethyl]piperazin-2-one Chemical compound O=C1C(C)(C)NC(C)(C)CN1CCN1C(=O)C(C)(C)NC(C)(C)C1 GUCMKIKYKIHUTM-UHFFFAOYSA-N 0.000 description 5
• UWSMKYBKUPAEJQ-UHFFFAOYSA-N 5-Chloro-2-(3,5-di-tert-butyl-2-hydroxyphenyl)-2H-benzotriazole Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC(N2N=C3C=C(Cl)C=CC3=N2)=C1O UWSMKYBKUPAEJQ-UHFFFAOYSA-N 0.000 description 5
• FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 5
• FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 5
• KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 5
• 239000000654 additive Substances 0.000 description 5
• 239000007795 chemical reaction product Substances 0.000 description 5
• DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical compound C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 description 5
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