JP2005516981A - トリアゾール類及びアルコキシル化アミン類を含んでなる配合物 - Google Patents
トリアゾール類及びアルコキシル化アミン類を含んでなる配合物 Download PDFInfo
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- JP2005516981A JP2005516981A JP2003565243A JP2003565243A JP2005516981A JP 2005516981 A JP2005516981 A JP 2005516981A JP 2003565243 A JP2003565243 A JP 2003565243A JP 2003565243 A JP2003565243 A JP 2003565243A JP 2005516981 A JP2005516981 A JP 2005516981A
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- JP
- Japan
- Prior art keywords
- fungicidal
- formula
- propiconazole
- triazoles
- wood
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 239000000203 mixture Substances 0.000 title claims abstract description 79
- 150000003852 triazoles Chemical class 0.000 title claims abstract description 37
- 150000001412 amines Chemical class 0.000 title claims abstract description 34
- 238000009472 formulation Methods 0.000 title claims abstract description 22
- 230000000855 fungicidal effect Effects 0.000 claims abstract description 103
- 239000002023 wood Substances 0.000 claims abstract description 31
- 239000000463 material Substances 0.000 claims abstract description 21
- 230000000694 effects Effects 0.000 claims abstract description 6
- -1 Tetraconazole tetrazole Chemical class 0.000 claims description 36
- STJLVHWMYQXCPB-UHFFFAOYSA-N propiconazole Chemical compound O1C(CCC)COC1(C=1C(=CC(Cl)=CC=1)Cl)CN1N=CN=C1 STJLVHWMYQXCPB-UHFFFAOYSA-N 0.000 claims description 26
- 239000005822 Propiconazole Substances 0.000 claims description 25
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- UFNOUKDBUJZYDE-UHFFFAOYSA-N 2-(4-chlorophenyl)-3-cyclopropyl-1-(1H-1,2,4-triazol-1-yl)butan-2-ol Chemical compound C1=NC=NN1CC(O)(C=1C=CC(Cl)=CC=1)C(C)C1CC1 UFNOUKDBUJZYDE-UHFFFAOYSA-N 0.000 claims description 7
- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 claims description 7
- 239000007983 Tris buffer Substances 0.000 claims description 7
- PXMNMQRDXWABCY-UHFFFAOYSA-N 1-(4-chlorophenyl)-4,4-dimethyl-3-(1H-1,2,4-triazol-1-ylmethyl)pentan-3-ol Chemical compound C1=NC=NN1CC(O)(C(C)(C)C)CCC1=CC=C(Cl)C=C1 PXMNMQRDXWABCY-UHFFFAOYSA-N 0.000 claims description 6
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- IJJVMEJXYNJXOJ-UHFFFAOYSA-N fluquinconazole Chemical compound C=1C=C(Cl)C=C(Cl)C=1N1C(=O)C2=CC(F)=CC=C2N=C1N1C=NC=N1 IJJVMEJXYNJXOJ-UHFFFAOYSA-N 0.000 claims description 3
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Classifications
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/372—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen containing etherified or esterified hydroxy groups ; Polyethers of low molecular weight
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- A—HUMAN NECESSITIES
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- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
- A01N43/647—Triazoles; Hydrogenated triazoles
- A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/35—Heterocyclic compounds
- D06M13/352—Heterocyclic compounds having five-membered heterocyclic rings
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/34—Organic impregnating agents
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/34—Organic impregnating agents
- B27K3/343—Heterocyclic compounds
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/34—Organic impregnating agents
- B27K3/50—Mixtures of different organic impregnating agents
Abstract
Description
アザコナゾール(azaconazole) 1−[[2−(2,4−ジクロロフェニル)−1,3−ジオキソラン−2−イル]メチル]−1H−1,2,4−トリアゾール、
ブロムコナゾール(bromuconazole) 1−[[4−ブロモ−2−(2,4−ジクロロフェニル)テトラヒドロ−2−フラニル]メチル]−1H−1,2,4−トリアゾール、
シプロコナゾール(cyproconazole) α−(4−クロロフェニル)−α−(1−シクロプロピルエチル)−1H−1,2,4−トリアゾール−1−エタノール、
ジフェノコナゾール(difenoconazole) 1−[[2−[2−クロロ−4−(4−クロロフェノキシ)フェニル]−4−メチル−1,3−ジオキソラン−2−イル]メチル]−1H−1,2,4−トリアゾール、
エポキシコナゾール(epoxiconazole) 1−[[(2R,3S)−3−(2−クロロフェニル)−2−(4−フルオロフェニル)オキシラニル]メチル]−1H−1,2,4−トリアゾール、
フェンブコナゾール(fenbuconazole) α−[2−(4−クロロフェニル)エチル]−α−フェニル−1H−1,2,4−トリアゾール−1−プロパンニトリル、
フルキンコナゾール(fluquinconazole) 3−(2,4−ジクロロフェニル)−6−フルオロ−2−(1H−1,2,4−トリアゾール−1−イル)−4(3H)−キナゾリノン、
フルシラゾール(flusilazole) 1−[[ビス(4−フルオロフェニル)メチルシリル]−メチル]−1H−1,2,4−トリアゾール、
ヘキサコナゾール(hexaconazole) α−ブチル−α−(2,4−ジクロロフェニル)−1H−1,2,4−トリアゾール−1−エタノール、
ケトコナゾール(ketoconazole) 1−アセチル−4−[4−[[(2R,4S)−2−(2,4−ジクロロフェニル)−2−(1H−イミダゾール−1−イルメチル)−1,3−ジオキソラン−4−イル]メトキシ]フェニル]−ピペラジン、
メトコナゾール(metconazole) 5−[(4−クロロフェニル)メチル]−2,2−ジメチル−1−(1H−1,2,4−トリアゾール−1−イルメチル)−シクロペンタノール、
ペンコナゾール(penconazole) 1−[2−(2,4−ジクロロフェニル)ペンチル]−1H−1,2,4−トリアゾール、
プロピコナゾール(propiconazole) 1−[[2−(2,4−ジクロロフェニル)−4−プロピル−1,3−ジオキソラン−2−イル]メチル]−1H−1,2,4−トリアゾール、
テブコナゾール(tebuconazole) α−[2−(4−クロロフェニル)エチル]−α−(1,1−ジメチルエチル)−1H−1,2,4−トリアゾール−1−エタノール、
テトラコナゾール(tetraconazole) 1−[2−(2,4−ジクロロフェニル)−3−(1,1,2,2−テトラフルオロエトキシ)プロピル]−1H−1,2,4−トリアゾール、
トリチコナゾール(triticonazole) 5−(4−クロロフェニル)メチレン)−2,2−ジメチル−1−(1H−1,2,4−トリアゾール−1−イルメチル)シクロペンタノール
が含まれるものとする。
R1はC8−20アルキルであり;
R2は−[CH2CH(X)O]bH (a−1)
又は
nは1〜4の整数であり;
それぞれa、b及びcは独立して1〜20であることができる整数であり;
各Xは独立して水素、メチル、エチル及びフェニルより成る群から選ばれる]
を有する。
a)nは整数2又は3であり、好ましくはnは3である;
b)Xは水素である;
c)RはC10−20アルキル、好ましくはココアルキル(cocoalkyl)又はタロウアルキル(tallowalkyl)である。
木材−変色性菌・カビ:
1:子嚢菌類(Ascomycetes):セラトシスチス(Ceratocystis)、例えばセラトシスチス・ミノル(Ceratocystis minor)
アウレオバシジウム(Aureobasidium)、例えばアウレオバシジウム・プルランス(Aureobasidium pullulans)
スクレロフォマ(Sclerophoma)、例えばスクレロフォマ・ピチオフィラ(Sclerophoma pithyophila)
クラドスポリウム(Cladosporium)、例えばクラドスポリウム・ヘルバルム(Cladosporium herbarum)
2:不完全菌類(Deuteromycetes):フンジ・インペルフェクチ(Fungi imperfecti)
アスペルギルス(Aspergillus)、例えばアスペルギルス・ニゲル(Aspergillus niger)
ダクチリウム(Dactylium)、例えばダクチリウム・フサリオイデス(Dactylium fusarioides)
ペニシリウム(Penicillium)、例えばP.ブレビカウレ(P.brevicaule)、P.バリアビレ(P.variabile)、P.フニクロスム(P.funiculosum)又はP.グラウクム(P.glaucum)
スコプラリア(Scopularia)、例えばスコプラリア・フィコミセス(Scopularia phycomyces)
トリコデルマ(Trichoderma)、例えばトリコデルマ・ビリデ(Trichoderma viride)又はトリコデルマ・リグノルム(Trichoderma lignorum)
アルテルナリア(Alternaria)、例えばアルテルナリア・テニウス(Alternaria tenius)、アルテルナリア・アルテルナタ(Alternaria alternata)
3:接合菌類(Zygomycetes):
ムコル(Mucor)、例えばムコル・スピノルス(Mucor spinorus)。
木材−破壊性菌・カビ
1:腐敗病菌・カビ:カエトミウム(Chaetomium)、例えばCh.グロボスム(Ch.globosum)又はCh.アルバ−アレヌルム(Ch.alba−arenulum)
フミコラ(Humicola)、例えばフミコラ・グリセア(Humicola grisea)
ペツリエラ(Petriella)、例えばペツリエラ・セチフェラ(Petriella setifera)
ツリクルス(Trichurus)、例えばツリクルス・スピラリス(Trichurus spiralis)
2:白色及び褐色核菌病菌・カビ:
コニオフォラ(Coniophora)、例えばコニオフォラ・プテアナ(Coniophora puteana)
コリオルス(Coriolus)、例えばコリオルス・ベルシコロル(Coriolus versicolor)
ドンキオポリア(Donkioporia)、例えばドンキオポリア・エクスパンサ(Donkioporia expansa)
グレノスポラ(Glenospora)、例えばグレノスポラ・グラフィイ(Glenospora graphii)
グロエオフィルム(Gloeophyllum)、例えばGl.アビエチヌム(Gl.abietinum)、Gl.アドラツム(Gl.adoratum)、Gl.プロタクツム(Gl.protactum)、Gl.セピアラウム(Gl.sepiarium)又はGl.ツラベウム(Gl.trabeum)
レンチヌス(Lentinus)、例えばL.シアチフォルメス(L.cyathiformes)、L.エドデス(L.edodes)、L.レピデウス(L.lepideus)、L.グリヌス(L.grinus)又はL.スクアロロスス(L.squarrolosus)
パクシルス(Paxillus)、例えばパクシルス・パヌオイデス(Paxillus panuoides)
プレウロツス(Pleurotus)、例えばプレウロチス・オスツレアツス(Pleurotis ostreatus)
ポリア(Poria)、例えばP.モンチコラ(P.monticola)、P.プラセンタ(P.placenta)、P.パイランチイ(P.vaillantii)又はP.バポラリア(P.vaporaria)
セルプラ(Serpula)(メルリウス(Merulius))、例えばセルプラ・ヒマントイデス(Serpula himantoides)又はセルプラ・ラクリマンス(Serpula lacrymans)
ステレウム(Stereum)、例えばステレウム・ヒルスツム(Stereum hirsutum)
ツリコフィトン(Trychophyton)、例えばツリコフィトン・メンタグロフィテス(Trychophyton mentagrophytes)
チロミセス(Tyromyces)、例えばチロミセス・パルスツリス(Tyromyces palustris)。
殺菌・殺カビ剤:
2−アミノブタン;2−アニリノ−4−メチル−6−シクロプロピル−ピリミジン;2,6−ジ−クロロ−N−(4−トリフルオロメチルベンジル)ベンズアミド;(E)−2−メトキシイミノ−N−メチル−2−(2−フェノキシフェニル)−アセトアミド;8−ヒドロキシキノリンサルフェート;(E)−2−{2−[6−(2−シアノフェノキシ)−ピリミジン−4−イルオキシ]−フェニル}−3−メトキシアクリル酸メチル;(E)−メトキシイミノ[アルファ−(o−トリルオキシ)−o−トリル]酢酸メチル;2−フェニルフェノール(OPP)、アルジモルフ(aldimorph)、アンプロピルフォス(ampropylfos)、アニラジン(anilazine)、ベナラキシル(benalaxyl)、ベノダニル(benodanil)、ベノミル(benomyl)、ビナパクリル(binapacryl)、ビフェニル(biphenyl)、ビテルタノル(bitertanol)、ブラスチシジン−S(blasticidin−S)、ブピリメート(bupirimate)、ブチオベート(buthiobate)、カルシウムポリスルフィド、カプタフォル(captafol)、カプタン(captan)、カルベンダジン(carbendazim)、カルボキシン(carboxin)、キノメチオネート(quinomethionate)、クロロネブ(chloroneb)、クロロピクリン(chloropicrin)、クロロタロニル(chlorothalonil)、クロゾリネート(chlozolinate)、クフラネブ(cufraneb)、シモキサニル(cymoxanil)、シプロフラム(cyprofuram)、ジクロロフェン(dichlorophen)、ジクロブトラゾール(diclobutrazole)、ジクロフルアニド(diclofluanid)、ジクロメジン(diclomezin)、ジクロラン(dicloran)、ジエトフェンカルブ(diethofencarb)、ジメチリモル(dimethirimol)、ジメトモルフ(dimethomorph)、ジノカプ(dinocap)、ジフェニルアミン、ジピリチオン(dipyrithione)、ジタリンフォス(ditalimfos)、ジチアノン(dithianon)、ドジン(dodine)、ドラゾキソロン(drazoxolon)、エジフェンフォス(edifenphos)、エチリモル(ethirimol)、フェナリモル(fenarimol)、フェンフラム(fenfuram)、フェニトロパン(fenitropan)、フェンピクロニル(fenpiclonil)、フェンプロピジン(fenpropidin)、フェンプロピモルフ(fenpropimorph)、フェンチンアセテート(fentin acetate)、フェンチンヒドロキシド(fentin hydroxide)、フェルバム(ferbam)、フェリムゾン(ferimzone)、フルアジナム(fluazinam)、フルジオキソニル(fludioxonil)、フルオロミド(fluoromide)、フルスルファミド(flusulfamide)、フルトラニル(flutolanil)、フルツリアフォル(flutriafol)、フォルペト(folpet)、フォセチル−アルミニウム(fosetyl−aluminium)、フタリド(fthalide)、フララキシル(furalaxyl)、フルメシクロクス(furmecyclox)、グアザチン(guazatine)、ヘキサクロロベンゼン、ヒメキサゾール(hymexazole)、イマザリル(imazalil)、イミノクタジン(iminoctadine)、イプロベンフォス(iprobenfos)(IBP)、イプロジオン(iprodione)、イソプロチオラン(isoprothiolane)、カスガマイシン(kasugamycin)、銅調剤、例えば:水酸化銅、ナフテン酸銅、オキシ塩化銅、硫酸銅、酸化銅、オキシン−銅及びボルドー混合物(Bordeaux mixture)、マンコッパー(mancopper)、マンコゼブ(mancozeb)、マネブ(maneb)、メパニピリム(mepanipyrim)、メプロニル(mepronil)、メタラキシル(metalaxyl)、メタスルホカルブ(methasulfocarb)、メトフロキサム(methfuroxam)、メチラム(metiram)、メトスルホバクス(metsulfovax)、ミクロブタニル(myclobutanil)、ニッケルジメチルジチオカルバメート、ニトロタル−イソプロピル(nitrothal−isopropyl)、ヌアリモル(nuarimol)、オフレース(ofurace)、オキサジキシル(oxadixyl)、オキサモカルブ(oxamocarb)、オキシカルボキシン(oxycarboxin)、ペフラゾエート(pefurazoate)、ペンシクロン(pencycuron)、フォスジフェン(phosdiphen)、ピマリシン(pimaricin)、ピペラリン(piperalin)、ポリオキシン(polyoxin)、プロクロラツ(prochloraz)、プロシミドン(procymidone)、プロパモカルブ(propamocarb)、プロピネブ(propineb)、ピラゾフォス(pyrazophos)、ピリフェノクス(pyrifenox)、ピリメタニル(pyrimethanil)、ピロクイロン(pyroquilon)、クイントゼン(quintozene)(PCNB)、硫黄及び硫黄調剤、テクロフタラム(tecloftalam)、テクナゼン(tecnazene)、チアベンダゾール(thiabendazole)、チシオフェン(thicyofen)、チオファネート−メチル(thiophanate−methyl)、チラム(thiram)、トルクロフォス−メチル(tolclophos−methyl)、トリルフルアニド(tolylfluanid)、トリアジメフォン(triadimefon)、トリアジメノル(triadimenol)、トリアゾキシド(triazoxide)、トリクラミド(trichlamide)、トリデモルフ(tridemorph)、トリフルミゾール(triflumizole)、トリフォリン(triforine)、バリダマイシン A(validamycin A)、ビンクロゾリン(vinclozolin)、ジネブ(zineb)、ジラム(ziram);イソチア−及びベンズイソチアゾロン誘導体、例えば1,2−ベンズイソチアゾロン(BIT);オキサチアジン類、例えばベトキサジン(bethoxazin)(すなわち3−(ベンゾ[b]チエン−2−イル)−5,6−ジヒドロ−1,4,2−オキサチアジン,4−オキシド);ストロビルリン類(strobilurines)、例えばアゾキシストロビン(azoxystrobin)、メトミノストロビン(metominostrobin)、ピラクロストロビン(pyraclostrobin)、クレソキシム−メチル(kresoxim−methyl)、トリフロキシストロビン(trifloxystrobin)及びピコキシストロビン(picoxystrobin)。
殺バクテリア剤:
ブロノポル(bronopol)、ジクロロフェン(dichlorophen)、ニトラピリン(nitrapyrin)、ニッケルジメチルジチオカルバメート、カスガマイシン(kasugamycin)、オクチリノン(octhilinone)、フランカルボン酸、オキシテトラサイクリン、ストレプトマイシン(streptomycin)、テクロフタラム(tecloftalam)、硫酸銅及び他の銅調剤。
殺虫剤/殺ダニ剤/殺線虫剤:
アバメクチン(abamectin)、AC 303 630、アセフェート(acephate)、アクリナツリン(acrinathrin)、アラニカルブ(alanycarb)、アルジカルブ(aldicarb)、アルファメツリン(alphamethrin)、アミトラツ(amitraz)、アベルメクチン(avermectin)、AZ 60541、アザジラクチン(azadirachtin)、アジンフォス A(azinphos A)、アジンフォス M、アゾシクロチン(azocyclotin)、バシルス・ツリンギエンシス(Bacillus thuringiensis)、ベンジオカルブ(bendiocarb)、ベンフラカルブ(benfuracarb)、ベンスルタプ(bensultap)、ベータ−シフルツリン(beta−cyfluthrin)、ビフェンツリン(bifenthrin)、BPMC、ブロフェンプロクス(brofenprox)、ブロモフォス A(bromophos A)、ブフェンカルブ(bufencarb)、ブプロフェジン(buprofezin)、ブトカルボキシン(butocarboxin)、ブチルピリダベン(butylpyridaben)、カズサフォス(cadusafos)、カルバリル(carbaryl)、カルボフラン(carbofuran)、カルボフェノチオン(carbophenothion)、カルボスルファン(carbosulfan)、カルタプ(cartap)、CGA 157 419、CGA 184699、クロエトカルブ(chloethocarb)、クロレトキシフォス(chlorethoxyfos)、クロルフェンビンフォス(chlorfenvinphos)、クロルフルアズロン(chlorfluazuron)、クリオルメフォス(chliormephos)、クロルフェナピル(chlorfenapyr)、クロルピリフォス(chlorpyrifos)、クロルピリフォス M、シス−レスメツリン(cis−resmethrin)、クロシツリン(clocythrin)、クロフェンテジン(clofentezine)、シアノフォス(cyanophos)、シクロプロツリン(cycloprothrin)、シフルツリン(cyfluthrin)、シハロツリン(cyhalothrin)、シヘキサチン(cyhexatin)、シペルメツリン(cypermethrin)、シロマジン(cyromazine)、デルタメツリン(deltamethrin)、デメトン−M(demeton−M)、デメトン−S、デメトン−S−メチル、ジアフェンチウロン(diafenthiuron)、ジアジノン(diazinon)、ジクロフェンチオン(dichlofenthion)、ジクロルボス(dichlorvos)、ジクリフォス(dicliphos)、ジクロトフォス(dicrotophos)、ジエチオン(diethion)、ジフルベンズロン(diflubenzuron)、ジメトエート(dimethoate)、ジメチルビンフォス(dimethylvinphos)、ジオキサチオン(dioxathion)、ジスルフォトン(disulfoton)、エジフェンフォス(edifenphos)、エマメクチン(emamectin)、エスフェンバレレート(esfenvalerate)、エチオフェンカルブ(ethiofencarb)、エチオン(ethion)、エトフェンプロクス(ethofenprox)、エトプロフォス(ethoprophos)、エツリムフォス(etrimphos)、フェナミフォス(fenamiphos)、フェナザクイン(fenazaquin)、フェンブタチン オキシド(fenbutatin oxide)、フェニトロチオン(fenitrothion)、フェノブカルブ(fenobucarb)、フェノチオカルブ(fenothiocarb)、フェノキシカルブ(fenoxycarb)、フェンプロパツリン(fenpropathrin)、フェンピラド(fenpyrad)、フェンピロキシメート(fenpyroximate)、フェンチオン(fenthion)、フェンバレレート(fenvalerate)、フィプロニル(fipronil)、フルアジナム(fluazinam)、フルシクロクスロン(flucycloxuron)、フルシツリネート(flucythrinate)、フルフェノクスロン(flufenoxuron)、フルフェンプロクス(flufenprox)、フルバリネート(fluvalinate)、フォノフォス(fonophos)、フォルモチオン(formothion)、フォスチアゼート(fosthiazate)、フブフェンプロクス(fubfenprox)、フラチオカルブ(furathiocarb)、HCH、ヘプテノフォス(heptenophos)、ヘキサフルムロン(hexaflumuron)、ヘキシチアゾクス(hexythiazox)、イミダクロプリド(imidacloprid)、イプロベンフォス(iprobenfos)、イサゾフォス(isazophos)、イソフェンフォス(isofenphos)、イソプロカルブ(isoprocarb)、イソキサチオン(isoxathion)、イベメクチン(ivemectin)、ラムダ−シハロツリン(lambda−cyhalothrin)、ルフェヌロン(lufenuron)、マラチオン(malathion)、メカルバム(mecarbam)、メルビンフォス(mervinphos)、メスルフェンフォス(mesulfenphos)、メタルデヒド(metaldehyde)、メタクリフォス(methacrifos)、メタミドフォス(methamidophos)、メチダチオン(methidathion)、メチオカルブ(methiocarb)、メトミル(methomyl)、メトルカルブ(metolcarb)、ミルベメクチン(milbemectin)、モノクロトフォス(monocrotophos)、モキシデクチン(moxidectin)、ナレド(naled)、NC 184、NI 25、ニテンピラム(nitenpyram)、オメトエート(omethoate)、オキサミル(oxamyl)、オキシデメトン M(oxydemethon M)、オキシデプロフォス(oxydeprofos)、パラチオン A(parathion A)、パラチオン M、ペルメツリン(permethrin)、フェントエート(phenthoate)、フォレート(phorate)、フォサロン(phosalone)、フォスメト(phosmet)、フォスファムドン(phosphamdon)、フォキシム(phoxim)、ピリミカルブ(pirimicarb)、ピリミフォス M(pirimiphos M)、ピリミフォス A、プロフェノフォス(profenofos)、プロメカルブ(promecarb)、プロパフォス(propaphos)、プロポクスル(propoxur)、プロチオフォス(prothiofos)、プロトエート(prothoate)、ピメトロジン(pymetrozin)、ピラクロフォス(pyrachlophos)、ピリダフェンチオン(pyridaphenthion)、ピレスメツリン(pyresmethrin)、ピレツルム(pyrethrum)、ピリダベン(pyridaben)、ピリミジフェン(pyrimidifen)、ピリプロキシフェン(pyriproxifen)、クイナルフォス(quinalphos)、RH 5992、サリチオン(salithion)、セブフォス(sebufos)、シラフルオフェン(silafluofen)、スルフォテプ(sulfotep)、スルプロフォス(sulprofos)、テブフェノジド(tebufenozid)、テブフェンピラド(tebufenpyrad)、テブピリミフォス(tebupirimiphos)、テフルベンズロン(teflubenzuron)、テフルツリン(tefluthrin)、テメフォス(temephos)、テルバム(terbam)、テルブフォス(terbufos)、テトラクロルビンフォス(tetrachlorvinphos)、チアフェノクス(thiafenox)、チアメトキサム(thiamethoxam)、チオジカルブ(thiodicarb)、チオファノクス(thiofanox)、チオメトン(thiomethon)、チオナジン(thionazin)、ツリンギエンシン(thuringiensin)、トラロメツリン(tralomethrin)、トリアラテン(triarathen)、トリアゾフォス(triazophos)、トリアズロン(triazuron)、トリクロルフォン(trichlorfon)、トリフルムロン(triflumuron)、トリメタカルブ(trimethacarb)、バミドチオン(vamidothion)、XMC、キシリルカルブ(xylylcarb)、ゼータメツリン(zetamethrin)。
オーブン乾燥されたスコットランド松(ピヌス・シルベスツリス(Pinus sylvestris),509kg/m3)及びぶな(ファグス・シルバチカ(Fagus sylvatica),637kg/m3)のブロック(40x15x5mm)を、5%のプロピコナゾール及び20%のN,N’,N’−トリス(2−ヒドロキシエチル)−N−ココアルキル−1,3−ジアミノ−プロパンを含有する配合物の水性希釈液で真空処理した。処理されるブロック中に吸収される該水性希釈液の量に依存して、活性成分、すなわちプロピコナゾール及びN,N’,N’−トリス(2−ヒドロキシエチル)−N−ココアルキル−1,3−ジアミノ−プロパンの量を決定し、吸収される活性成分のg/m3(ga.i./m3)において表すことができる。
試験モデル:冬コムギの木、コルブス(Corvus)品種に試験溶液を流れ落ちるまでスプレー噴霧した。処理された植物をガラス室中でインキュベーションし、乾燥後にエリシフェ・グラミニスの分生子をふりかけた。
試験溶液:1)8、16,20及び24ppmのプロピコナゾールを含むスプレー溶液が得られるまで市販のプロピコナゾール配合物「TiltR 250 EC」を希釈することにより、水溶液を調製した。
結果及び結論
標準植物はE.グラミニスに100%感染し、24ppmにおけるプロピコナゾールはE.グラミニスに対して80%活性であった。
・1/10まで下がった比率における「エトジュオミーン C/13」との16ppmのプロピコナゾールの組み合わせはほとんど完全に活性(98%)であったが、16ppmにおけるプロピコナゾールは50%活性であった。
・1/10まで下がった比率における「エトジュオミーン C/13」との8ppmのプロピコナゾールの組み合わせは約80%活性であったが、8ppmにおけるプロピコナゾールは25%活性であった。
Claims (13)
- R2が基の式(a−1)である請求項1に従う使用。
- R2が基の式(a−2)である請求項1に従う使用。
- 式(I)のアルコキシル化アミンがN,N’,N’−トリス(2−ヒドロキシエチル)−N−ココアルキル−1,3−ジアミノ−プロパンである請求項1に従う使用。
- 殺菌・殺カビ性トリアゾールがアザコナゾール(azaconazole)、ブロムコナゾール(bromuconazole)、シプロコナゾール(cyproconazole)、ジフェノコナゾール(difenoconazole)、エポキシコナゾール(epoxiconazole)、フェンブコナゾール(fenbuconazole)、フルキンコナゾール(fluquinconazole)、フルシラゾール(flusilazole)、ヘキサコナゾール(hexaconazole)、ケトコナゾール(ketoconazole)、メトコナゾール(metconazole)、ペンコナゾール(penconazole)、プロピコナゾール(propiconazole)、テブコナゾール(tebuconazole)、テトラコナゾール(tetraconazole)及びトリチコナゾール(triticonazole)から選ばれる請求項1〜4のいずれかに従う使用。
- 殺菌・殺カビ性トリアゾールがプロピコナゾールである請求項5に従う使用。
- アザコナゾール、ブロムコナゾール、シプロコナゾール、ジフェノコナゾール、エポキシコナゾール、フェンブコナゾール、フルキンコナゾール、フルシラゾール、ヘキサコナゾール、ケトコナゾール、メトコナゾール、ペンコナゾール、プロピコナゾール、テブコナゾール、テトラコナゾール及びトリチコナゾールから選ばれる1種もしくはそれより多い殺菌・殺カビ性トリアゾール類及び請求項1で定義されている式(I)のアルコキシル化アミン;ならびに担体を含んでなる殺菌・殺カビ性組成物。
- 殺菌・殺カビ性トリアゾールがプロピコナゾールである請求項7に従う組成物。
- 殺菌・殺カビ性トリアゾール類がシプロコナゾール及びプロピコナゾールの混合物である請求項7に従う組成物。
- 式(I)のアルコキシル化アミンがN,N’,N’−トリス(2−ヒドロキシエチル)−N−ココアルキル−1,3−ジアミノ−プロパンである請求項7〜9のいずれかに従う組成物。
- 殺菌・殺カビ性トリアゾール対式(I)のアルコキシル化アミン類の比率が5:1〜1:200、好ましくは2:1〜1:20の範囲である請求項7〜10のいずれかに従う組成物。
- 1種もしくはそれより多い殺菌・殺カビ性トリアゾール類及び式(I)のアルコキシル化アミン類を担体と緊密に混合することを特徴とする請求項7〜11のいずれかで特許請求されている組成物の調製法。
- 木材、木材製品又は生分解性材料に請求項7〜11のいずれかで特許請求されている組成物を適用することを含んでなる、木材、木材製品又は生分解性材料の保存の方法。
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Patent Citations (3)
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JPS6051102A (ja) * | 1983-08-31 | 1985-03-22 | Hokko Chem Ind Co Ltd | 安定化された農園芸用殺菌剤 |
JPS61151102A (ja) * | 1984-12-26 | 1986-07-09 | Hokko Chem Ind Co Ltd | 安定化された農園芸用殺菌剤 |
JP2004523491A (ja) * | 2000-12-04 | 2004-08-05 | シンジェンタ パーティシペーションズ アクチェンゲゼルシャフト | マイクロエマルジョン化可能な農薬組成物 |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2009506907A (ja) * | 2005-09-01 | 2009-02-19 | ジヤンセン・フアーマシユーチカ・ナームローゼ・フエンノートシヤツプ | 撥水性を改善するためのアルコキシ化アミンの使用 |
Also Published As
Publication number | Publication date |
---|---|
ATE324041T1 (de) | 2006-05-15 |
AU2003206827A1 (en) | 2003-09-02 |
RU2004126697A (ru) | 2006-01-27 |
SI1473996T1 (sl) | 2006-10-31 |
DE60304832T2 (de) | 2006-12-28 |
WO2003065807A1 (en) | 2003-08-14 |
US20050080089A1 (en) | 2005-04-14 |
CA2474004C (en) | 2011-02-01 |
US20100099724A1 (en) | 2010-04-22 |
US8338338B2 (en) | 2012-12-25 |
IL163325A (en) | 2010-11-30 |
CA2474004A1 (en) | 2003-08-14 |
DE60304832D1 (de) | 2006-06-01 |
PL370299A1 (en) | 2005-05-16 |
US7662748B2 (en) | 2010-02-16 |
JP4848119B2 (ja) | 2011-12-28 |
ES2262973T3 (es) | 2006-12-01 |
BR0307334A (pt) | 2004-12-07 |
AU2003206827B2 (en) | 2007-08-16 |
NO20043700L (no) | 2004-09-02 |
CN1627900A (zh) | 2005-06-15 |
HK1079401A1 (en) | 2006-04-07 |
DK1473996T3 (da) | 2006-08-21 |
EP1473996A1 (en) | 2004-11-10 |
EP1473996B1 (en) | 2006-04-26 |
MY130685A (en) | 2007-07-31 |
CN100399897C (zh) | 2008-07-09 |
PL206765B1 (pl) | 2010-09-30 |
RU2312498C2 (ru) | 2007-12-20 |
PT1473996E (pt) | 2006-09-29 |
NZ534780A (en) | 2005-04-29 |
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