JP2005002339A - 水素化処理法 - Google Patents
水素化処理法 Download PDFInfo
- Publication number
- JP2005002339A JP2005002339A JP2004169894A JP2004169894A JP2005002339A JP 2005002339 A JP2005002339 A JP 2005002339A JP 2004169894 A JP2004169894 A JP 2004169894A JP 2004169894 A JP2004169894 A JP 2004169894A JP 2005002339 A JP2005002339 A JP 2005002339A
- Authority
- JP
- Japan
- Prior art keywords
- hydrotreating
- hydrotreatment
- gas
- effluent
- stage
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 title claims abstract description 33
- 239000007789 gas Substances 0.000 claims abstract description 28
- 229930195733 hydrocarbon Natural products 0.000 claims abstract description 22
- 150000002430 hydrocarbons Chemical class 0.000 claims abstract description 22
- 239000004215 Carbon black (E152) Substances 0.000 claims abstract description 19
- 239000003054 catalyst Substances 0.000 claims abstract description 18
- 239000001257 hydrogen Substances 0.000 claims abstract description 16
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 16
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000007788 liquid Substances 0.000 claims abstract description 13
- 150000001875 compounds Chemical class 0.000 claims abstract description 8
- 230000003197 catalytic effect Effects 0.000 claims abstract description 4
- 238000000926 separation method Methods 0.000 claims description 2
- 239000000463 material Substances 0.000 abstract description 5
- 239000000203 mixture Substances 0.000 abstract description 4
- 239000012071 phase Substances 0.000 description 21
- 239000007791 liquid phase Substances 0.000 description 9
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 6
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 208000033830 Hot Flashes Diseases 0.000 description 4
- 206010060800 Hot flush Diseases 0.000 description 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 4
- 239000011593 sulfur Substances 0.000 description 4
- 229910052717 sulfur Inorganic materials 0.000 description 4
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 3
- 229910021529 ammonia Inorganic materials 0.000 description 3
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 238000011144 upstream manufacturing Methods 0.000 description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 239000002283 diesel fuel Substances 0.000 description 2
- 238000005984 hydrogenation reaction Methods 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 229910017464 nitrogen compound Inorganic materials 0.000 description 2
- 150000002830 nitrogen compounds Chemical class 0.000 description 2
- 238000010926 purge Methods 0.000 description 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 239000006103 coloring component Substances 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 238000011027 product recovery Methods 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G65/00—Treatment of hydrocarbon oils by two or more hydrotreatment processes only
- C10G65/02—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only
- C10G65/04—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including only refining steps
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G67/00—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only
- C10G67/02—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only plural serial stages only
- C10G67/04—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only plural serial stages only including solvent extraction as the refining step in the absence of hydrogen
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Abstract
【解決手段】炭化水素供給材料中の着色化合物を除去するための方法であって、次の段階、すなわち
──上記供給材料中に存在する水素化可能な化合物を水素化するのに有効な条件の下に、第一の水素化処理触媒の存在下に上記供給材料を水素化処理する段階、及び
──水素化処理条件下に第二の水素化処理反応器中で行われる第二の接触水素化処理段階で、上記第一水素化処理段階からの流出物を水素化処理する段階、
を含み、
この際、上記第一水素化処理段階からの流出物を、第二水素化処理段階の前に、気相と気液混合相とに分離し、そしてこの混合相を、水素を更に加えることなく、上記第二水素化処理段階で水素化処理する、上記方法。
【選択図】 図1
Description
Claims (3)
- 炭化水素供給材料中の着色化合物を除去するための方法であって、次の段階、すなわち
──上記供給材料中に存在する水素化可能な化合物を水素化するのに有効な条件の下に、第一の水素化処理触媒の存在下に上記供給材料を水素化処理する段階、及び
──水素化処理条件下に第二の水素化処理反応器中で行われる第二の接触水素化処理段階で、上記第一水素化処理段階からの流出物を水素化処理する段階、
を含み、
この際、上記第一水素化処理段階からの流出物を、第二水素化処理段階の前に、気相と気液混合相とに分離し、そしてこの混合相を、水素を更に加えることなく、上記第二水素化処理段階で水素化処理する、上記方法。 - 混合相中の気体と液体との間の体積比が、混合相中の水素化可能な化合物の量に対して少なくとも化学量論量である量の水素を混合相中に供するように調節される、請求項1の方法。
- 第一水素化処理段階からの流出物の分離が、第二の水素化処理反応器で行われる、請求項1の方法。
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DKPA200300858 | 2003-06-10 |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2005002339A true JP2005002339A (ja) | 2005-01-06 |
JP4546160B2 JP4546160B2 (ja) | 2010-09-15 |
Family
ID=33495512
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2004169894A Expired - Fee Related JP4546160B2 (ja) | 2003-06-10 | 2004-06-08 | 水素化処理法 |
Country Status (6)
Country | Link |
---|---|
US (1) | US7300567B2 (ja) |
JP (1) | JP4546160B2 (ja) |
KR (1) | KR101071881B1 (ja) |
CN (1) | CN100344734C (ja) |
AU (1) | AU2004202541B2 (ja) |
TW (1) | TWI296651B (ja) |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7569136B2 (en) * | 1997-06-24 | 2009-08-04 | Ackerson Michael D | Control system method and apparatus for two phase hydroprocessing |
US7431828B2 (en) * | 2005-07-06 | 2008-10-07 | Haldor Topsoe A/S | Process for desulphurization of a hydrocarbon stream with a reduced consumption of hydrogen |
CN100443571C (zh) * | 2005-09-28 | 2008-12-17 | 中国石油化工股份有限公司 | 一种柴油馏分深度脱硫和脱色的加氢方法 |
CN102029128B (zh) * | 2009-09-28 | 2012-06-27 | 中国石油化工股份有限公司 | 一种产物循环的加氢处理方法 |
WO2012100068A2 (en) | 2011-01-19 | 2012-07-26 | Process Dynamics, Inc. | Process for hydroprocessing of non-petroleum feestocks |
IN2013MU02162A (ja) * | 2013-06-25 | 2015-06-12 | Indian Oil Corp Ltd | |
FR3013721B1 (fr) * | 2013-11-28 | 2015-11-13 | Ifp Energies Now | Procede d'hydrotraitement de gazole mettant en oeuvre un enchainement de catalyseurs |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5403470A (en) * | 1993-01-28 | 1995-04-04 | Union Oil Company Of California | Color removal with post-hydrotreating |
JPH07300592A (ja) * | 1994-05-02 | 1995-11-14 | Jgc Corp | 石油類の処理方法 |
JPH0820782A (ja) * | 1994-07-11 | 1996-01-23 | Mitsui Eng & Shipbuild Co Ltd | 低硫黄軽油の製造方法 |
JP2000212578A (ja) * | 1999-01-27 | 2000-08-02 | Idemitsu Kosan Co Ltd | 低硫黄軽油の製造方法およびその方法により製造される軽油組成物 |
JP2002003863A (ja) * | 2000-06-23 | 2002-01-09 | Mitsui Eng & Shipbuild Co Ltd | 軽油の製造方法 |
JP2002513847A (ja) * | 1998-05-06 | 2002-05-14 | エクソンモービル リサーチ アンド エンジニアリング カンパニー | 三段同時流液体および蒸気水素処理 |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4755280A (en) * | 1985-07-31 | 1988-07-05 | Exxon Research And Engineering Company | Process for improving the color and oxidation stability of hydrocarbon streams containing multi-ring aromatic and hydroaromatic hydrocarbons |
CN1157315A (zh) * | 1996-02-13 | 1997-08-20 | 荆门石油化工研究院 | 一种一段串联加氢精制工艺 |
ES2218987T3 (es) * | 1998-03-14 | 2004-11-16 | Chevron U.S.A. Inc. | Procedimiento integrado de hidroconversion con flujo inverso de hidrogeno. |
CN1119395C (zh) * | 1999-03-19 | 2003-08-27 | 中国石油化工集团公司 | 一种馏分油两段加氢脱芳烃的方法 |
US20020148757A1 (en) * | 2001-02-08 | 2002-10-17 | Huff George A. | Hydrotreating of components for refinery blending of transportation fuels |
US6649042B2 (en) * | 2001-03-01 | 2003-11-18 | Intevep, S.A. | Hydroprocessing process |
-
2004
- 2004-06-08 JP JP2004169894A patent/JP4546160B2/ja not_active Expired - Fee Related
- 2004-06-08 TW TW093116392A patent/TWI296651B/zh not_active IP Right Cessation
- 2004-06-08 US US10/862,398 patent/US7300567B2/en not_active Expired - Fee Related
- 2004-06-09 AU AU2004202541A patent/AU2004202541B2/en not_active Ceased
- 2004-06-10 CN CNB200410063172XA patent/CN100344734C/zh not_active Expired - Fee Related
- 2004-06-10 KR KR1020040042537A patent/KR101071881B1/ko active IP Right Grant
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5403470A (en) * | 1993-01-28 | 1995-04-04 | Union Oil Company Of California | Color removal with post-hydrotreating |
JPH07300592A (ja) * | 1994-05-02 | 1995-11-14 | Jgc Corp | 石油類の処理方法 |
JPH0820782A (ja) * | 1994-07-11 | 1996-01-23 | Mitsui Eng & Shipbuild Co Ltd | 低硫黄軽油の製造方法 |
JP2002513847A (ja) * | 1998-05-06 | 2002-05-14 | エクソンモービル リサーチ アンド エンジニアリング カンパニー | 三段同時流液体および蒸気水素処理 |
JP2000212578A (ja) * | 1999-01-27 | 2000-08-02 | Idemitsu Kosan Co Ltd | 低硫黄軽油の製造方法およびその方法により製造される軽油組成物 |
JP2002003863A (ja) * | 2000-06-23 | 2002-01-09 | Mitsui Eng & Shipbuild Co Ltd | 軽油の製造方法 |
Also Published As
Publication number | Publication date |
---|---|
TWI296651B (en) | 2008-05-11 |
CN1572860A (zh) | 2005-02-02 |
AU2004202541B2 (en) | 2009-03-19 |
KR20040111024A (ko) | 2004-12-31 |
AU2004202541A1 (en) | 2005-01-06 |
KR101071881B1 (ko) | 2011-10-11 |
US7300567B2 (en) | 2007-11-27 |
JP4546160B2 (ja) | 2010-09-15 |
US20040251169A1 (en) | 2004-12-16 |
CN100344734C (zh) | 2007-10-24 |
TW200504194A (en) | 2005-02-01 |
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