JP2004530272A - 二酸化炭素除去と一体化した燃料処理装置、燃料電池スタック及び廃ガス酸化装置 - Google Patents
二酸化炭素除去と一体化した燃料処理装置、燃料電池スタック及び廃ガス酸化装置 Download PDFInfo
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- JP2004530272A JP2004530272A JP2002583321A JP2002583321A JP2004530272A JP 2004530272 A JP2004530272 A JP 2004530272A JP 2002583321 A JP2002583321 A JP 2002583321A JP 2002583321 A JP2002583321 A JP 2002583321A JP 2004530272 A JP2004530272 A JP 2004530272A
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- gas
- hydrogen
- farikirdite
- carbon dioxide
- reforming catalyst
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- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 title claims abstract description 169
- 229910002092 carbon dioxide Inorganic materials 0.000 title claims abstract description 84
- 239000001569 carbon dioxide Substances 0.000 title claims abstract description 84
- 239000000446 fuel Substances 0.000 title claims abstract description 80
- 239000002912 waste gas Substances 0.000 title claims description 75
- 239000007800 oxidant agent Substances 0.000 title claims description 16
- 239000007789 gas Substances 0.000 claims abstract description 138
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 102
- 238000000034 method Methods 0.000 claims abstract description 94
- 239000003054 catalyst Substances 0.000 claims abstract description 93
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- 239000001257 hydrogen Substances 0.000 claims abstract description 88
- 238000002407 reforming Methods 0.000 claims abstract description 71
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims abstract description 50
- 229910002091 carbon monoxide Inorganic materials 0.000 claims abstract description 50
- 238000006243 chemical reaction Methods 0.000 claims abstract description 50
- 229930195733 hydrocarbon Natural products 0.000 claims abstract description 36
- 150000002430 hydrocarbons Chemical class 0.000 claims abstract description 36
- 239000000463 material Substances 0.000 claims abstract description 36
- 239000004215 Carbon black (E152) Substances 0.000 claims abstract description 32
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 27
- IATRAKWUXMZMIY-UHFFFAOYSA-N strontium oxide Chemical compound [O-2].[Sr+2] IATRAKWUXMZMIY-UHFFFAOYSA-N 0.000 claims abstract description 26
- 229910000514 dolomite Inorganic materials 0.000 claims abstract description 25
- 239000010459 dolomite Substances 0.000 claims abstract description 25
- 229910021532 Calcite Inorganic materials 0.000 claims abstract description 24
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims abstract description 24
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- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims abstract description 16
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 claims abstract description 15
- 239000000920 calcium hydroxide Substances 0.000 claims abstract description 15
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- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 14
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- 229910052865 lawsonite Inorganic materials 0.000 claims abstract description 13
- 229910000018 strontium carbonate Inorganic materials 0.000 claims abstract description 13
- UUCCCPNEFXQJEL-UHFFFAOYSA-L strontium dihydroxide Chemical compound [OH-].[OH-].[Sr+2] UUCCCPNEFXQJEL-UHFFFAOYSA-L 0.000 claims abstract description 13
- 229910001866 strontium hydroxide Inorganic materials 0.000 claims abstract description 13
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 claims abstract description 11
- LEDMRZGFZIAGGB-UHFFFAOYSA-L strontium carbonate Chemical compound [Sr+2].[O-]C([O-])=O LEDMRZGFZIAGGB-UHFFFAOYSA-L 0.000 claims abstract description 10
- 229910000513 benstonite Inorganic materials 0.000 claims abstract description 9
- CXUJOBCFZQGUGO-UHFFFAOYSA-F calcium trimagnesium tetracarbonate Chemical compound [Mg++].[Mg++].[Mg++].[Ca++].[O-]C([O-])=O.[O-]C([O-])=O.[O-]C([O-])=O.[O-]C([O-])=O CXUJOBCFZQGUGO-UHFFFAOYSA-F 0.000 claims abstract description 9
- 229910052871 clinozoisite Inorganic materials 0.000 claims abstract description 9
- GDVKFRBCXAPAQJ-UHFFFAOYSA-A dialuminum;hexamagnesium;carbonate;hexadecahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Al+3].[Al+3].[O-]C([O-])=O GDVKFRBCXAPAQJ-UHFFFAOYSA-A 0.000 claims abstract description 9
- 229910000515 huntite Inorganic materials 0.000 claims abstract description 9
- 229910001701 hydrotalcite Inorganic materials 0.000 claims abstract description 9
- 229960001545 hydrotalcite Drugs 0.000 claims abstract description 9
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- 239000010948 rhodium Substances 0.000 claims abstract description 8
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 7
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229910052707 ruthenium Inorganic materials 0.000 claims abstract description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract 4
- 229910052799 carbon Inorganic materials 0.000 claims abstract 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 41
- 229910052661 anorthite Inorganic materials 0.000 claims description 18
- GWWPLLOVYSCJIO-UHFFFAOYSA-N dialuminum;calcium;disilicate Chemical compound [Al+3].[Al+3].[Ca+2].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] GWWPLLOVYSCJIO-UHFFFAOYSA-N 0.000 claims description 18
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- 229910000512 ankerite Inorganic materials 0.000 claims description 8
- 230000003647 oxidation Effects 0.000 claims description 7
- FBPFZTCFMRRESA-FSIIMWSLSA-N L-glucitol Chemical compound OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 claims description 4
- 230000001172 regenerating effect Effects 0.000 claims description 4
- 229910052712 strontium Inorganic materials 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 claims description 3
- CKFGINPQOCXMAZ-UHFFFAOYSA-N methanediol Chemical compound OCO CKFGINPQOCXMAZ-UHFFFAOYSA-N 0.000 claims 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims 2
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 claims 2
- 229910000041 hydrogen chloride Inorganic materials 0.000 claims 2
- 229910000859 α-Fe Inorganic materials 0.000 claims 2
- 238000006057 reforming reaction Methods 0.000 abstract description 5
- 150000001875 compounds Chemical class 0.000 abstract description 4
- 208000035484 Cellulite Diseases 0.000 abstract 1
- 206010049752 Peau d'orange Diseases 0.000 abstract 1
- 230000003796 beauty Effects 0.000 abstract 1
- 230000036232 cellulite Effects 0.000 abstract 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 28
- 239000000203 mixture Substances 0.000 description 17
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- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 10
- 238000010438 heat treatment Methods 0.000 description 10
- 150000002431 hydrogen Chemical class 0.000 description 8
- 238000002474 experimental method Methods 0.000 description 5
- 229910052500 inorganic mineral Inorganic materials 0.000 description 5
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- 229910052757 nitrogen Inorganic materials 0.000 description 5
- 238000000629 steam reforming Methods 0.000 description 5
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 4
- 239000011575 calcium Substances 0.000 description 4
- 229910000019 calcium carbonate Inorganic materials 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 238000000746 purification Methods 0.000 description 4
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 3
- 238000013461 design Methods 0.000 description 3
- 239000001307 helium Substances 0.000 description 3
- 229910052734 helium Inorganic materials 0.000 description 3
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 3
- BDAGIHXWWSANSR-NJFSPNSNSA-N hydroxyformaldehyde Chemical compound O[14CH]=O BDAGIHXWWSANSR-NJFSPNSNSA-N 0.000 description 3
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- 239000002994 raw material Substances 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
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- 239000001294 propane Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 2
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- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
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- 235000019738 Limestone Nutrition 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
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- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- BULLHNJGPPOUOX-UHFFFAOYSA-N chloroacetone Chemical compound CC(=O)CCl BULLHNJGPPOUOX-UHFFFAOYSA-N 0.000 description 1
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- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
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- C01B2203/0425—In-situ adsorption process during hydrogen production
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0435—Catalytic purification
- C01B2203/044—Selective oxidation of carbon monoxide
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0435—Catalytic purification
- C01B2203/0445—Selective methanation
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0465—Composition of the impurity
- C01B2203/047—Composition of the impurity the impurity being carbon monoxide
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
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Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US28468401P | 2001-04-18 | 2001-04-18 | |
| PCT/US2002/012368 WO2002085783A2 (en) | 2001-04-18 | 2002-04-18 | Integrated fuel processor, fuel cell stack and tail gas oxidizer with carbon dioxide removal |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2004530272A true JP2004530272A (ja) | 2004-09-30 |
| JP2004530272A5 JP2004530272A5 (enExample) | 2005-12-22 |
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| JP2002583321A Pending JP2004530272A (ja) | 2001-04-18 | 2002-04-18 | 二酸化炭素除去と一体化した燃料処理装置、燃料電池スタック及び廃ガス酸化装置 |
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| Country | Link |
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| US (1) | US6682838B2 (enExample) |
| EP (1) | EP1390292A2 (enExample) |
| JP (1) | JP2004530272A (enExample) |
| KR (1) | KR100952343B1 (enExample) |
| CN (2) | CN102101648A (enExample) |
| AU (1) | AU2002338422B2 (enExample) |
| BR (1) | BR0208933A (enExample) |
| CA (2) | CA2444029C (enExample) |
| MX (1) | MXPA03009451A (enExample) |
| NO (1) | NO20034656D0 (enExample) |
| WO (1) | WO2002085783A2 (enExample) |
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| JP2006524629A (ja) * | 2003-04-04 | 2006-11-02 | テキサコ ディベラップメント コーポレイション | 燃料プロセッサ制御システム用先出しシャットダウンの追跡 |
| JP2007076954A (ja) * | 2005-09-14 | 2007-03-29 | Toshiba Corp | エタノールからの水素製造方法 |
| US7201889B2 (en) | 2002-01-25 | 2007-04-10 | Kabushiki Kaisha Toshiba | Fuel reforming method and system |
| JP2008546616A (ja) * | 2005-06-14 | 2008-12-25 | サソール テクノロジー(プロプライエタリー)リミテッド | 合成ガスの製造方法及び変換方法 |
| WO2011019694A3 (en) * | 2009-08-10 | 2011-06-30 | David Randolph Smith | Method and apparatus to sequester co2 gas |
| JP2011192609A (ja) * | 2010-03-16 | 2011-09-29 | Denso Corp | エネルギー変換装置 |
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| TWI679342B (zh) * | 2018-11-01 | 2019-12-11 | 黃恆信 | 催化生質氣體之熱電共生發電機及其用於烴類及生質燃料脫硫之方法 |
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| US3115394A (en) * | 1961-05-29 | 1963-12-24 | Consolidation Coal Co | Process for the production of hydrogen |
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-
2002
- 2002-04-18 WO PCT/US2002/012368 patent/WO2002085783A2/en not_active Ceased
- 2002-04-18 KR KR1020037013609A patent/KR100952343B1/ko not_active Expired - Fee Related
- 2002-04-18 MX MXPA03009451A patent/MXPA03009451A/es active IP Right Grant
- 2002-04-18 CA CA2444029A patent/CA2444029C/en not_active Expired - Fee Related
- 2002-04-18 CA CA2689689A patent/CA2689689C/en not_active Expired - Fee Related
- 2002-04-18 US US10/126,679 patent/US6682838B2/en not_active Expired - Lifetime
- 2002-04-18 BR BR0208933-5A patent/BR0208933A/pt not_active Application Discontinuation
- 2002-04-18 EP EP02764238A patent/EP1390292A2/en not_active Withdrawn
- 2002-04-18 CN CN2010106137245A patent/CN102101648A/zh active Pending
- 2002-04-18 AU AU2002338422A patent/AU2002338422B2/en not_active Ceased
- 2002-04-18 CN CNA028084268A patent/CN1514802A/zh active Pending
- 2002-04-18 JP JP2002583321A patent/JP2004530272A/ja active Pending
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2003
- 2003-10-17 NO NO20034656A patent/NO20034656D0/no not_active Application Discontinuation
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7201889B2 (en) | 2002-01-25 | 2007-04-10 | Kabushiki Kaisha Toshiba | Fuel reforming method and system |
| JP2006524629A (ja) * | 2003-04-04 | 2006-11-02 | テキサコ ディベラップメント コーポレイション | 燃料プロセッサ制御システム用先出しシャットダウンの追跡 |
| JP4778891B2 (ja) * | 2003-04-04 | 2011-09-21 | テキサコ ディベラップメント コーポレイション | 燃料プロセッサ制御システム用先出しシャットダウンの追跡 |
| KR101098268B1 (ko) | 2003-04-04 | 2011-12-26 | 텍사코 디벨롭먼트 코포레이션 | 연료 처리장치 제어 시스템을 위한 퍼스트아웃 정지 추적 |
| JP2008546616A (ja) * | 2005-06-14 | 2008-12-25 | サソール テクノロジー(プロプライエタリー)リミテッド | 合成ガスの製造方法及び変換方法 |
| JP2007076954A (ja) * | 2005-09-14 | 2007-03-29 | Toshiba Corp | エタノールからの水素製造方法 |
| WO2011019694A3 (en) * | 2009-08-10 | 2011-06-30 | David Randolph Smith | Method and apparatus to sequester co2 gas |
| JP2011192609A (ja) * | 2010-03-16 | 2011-09-29 | Denso Corp | エネルギー変換装置 |
Also Published As
| Publication number | Publication date |
|---|---|
| CA2689689C (en) | 2012-07-03 |
| NO20034656L (no) | 2003-10-17 |
| KR20040038911A (ko) | 2004-05-08 |
| NO20034656D0 (no) | 2003-10-17 |
| WO2002085783A3 (en) | 2002-12-12 |
| AU2002338422B2 (en) | 2008-06-19 |
| EP1390292A2 (en) | 2004-02-25 |
| CA2689689A1 (en) | 2002-10-31 |
| CA2444029A1 (en) | 2002-10-31 |
| CN102101648A (zh) | 2011-06-22 |
| CA2444029C (en) | 2010-03-30 |
| US6682838B2 (en) | 2004-01-27 |
| US20020155329A1 (en) | 2002-10-24 |
| BR0208933A (pt) | 2005-05-10 |
| WO2002085783A2 (en) | 2002-10-31 |
| CN1514802A (zh) | 2004-07-21 |
| MXPA03009451A (es) | 2004-02-12 |
| KR100952343B1 (ko) | 2010-04-13 |
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