JP2004529769A5 - - Google Patents
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- Publication number
- JP2004529769A5 JP2004529769A5 JP2003505082A JP2003505082A JP2004529769A5 JP 2004529769 A5 JP2004529769 A5 JP 2004529769A5 JP 2003505082 A JP2003505082 A JP 2003505082A JP 2003505082 A JP2003505082 A JP 2003505082A JP 2004529769 A5 JP2004529769 A5 JP 2004529769A5
- Authority
- JP
- Japan
- Prior art keywords
- tin
- platinum
- solid
- carbonylation catalyst
- catalyst according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000003054 catalyst Substances 0.000 claims 14
- 238000005810 carbonylation reaction Methods 0.000 claims 13
- 239000007787 solid Substances 0.000 claims 12
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims 10
- 239000000203 mixture Substances 0.000 claims 8
- ATJFFYVFTNAWJD-UHFFFAOYSA-N tin hydride Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims 6
- 125000004432 carbon atoms Chemical group C* 0.000 claims 5
- 229910052697 platinum Inorganic materials 0.000 claims 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 4
- 229910052799 carbon Inorganic materials 0.000 claims 4
- OQBLGYCUQGDOOR-UHFFFAOYSA-L 1,3,2$l^{2}-dioxastannolane-4,5-dione Chemical compound O=C1O[Sn]OC1=O OQBLGYCUQGDOOR-UHFFFAOYSA-L 0.000 claims 2
- GZUXJHMPEANEGY-UHFFFAOYSA-N Bromomethane Chemical compound BrC GZUXJHMPEANEGY-UHFFFAOYSA-N 0.000 claims 2
- CLSUSRZJUQMOHH-UHFFFAOYSA-L Platinum(II) chloride Chemical compound Cl[Pt]Cl CLSUSRZJUQMOHH-UHFFFAOYSA-L 0.000 claims 2
- AXZWODMDQAVCJE-UHFFFAOYSA-L Tin(II) chloride Chemical group [Cl-].[Cl-].[Sn+2] AXZWODMDQAVCJE-UHFFFAOYSA-L 0.000 claims 2
- 125000000217 alkyl group Chemical group 0.000 claims 2
- 229910052736 halogen Inorganic materials 0.000 claims 2
- 150000002367 halogens Chemical class 0.000 claims 2
- CPELXLSAUQHCOX-UHFFFAOYSA-N hydrogen bromide Chemical compound Br CPELXLSAUQHCOX-UHFFFAOYSA-N 0.000 claims 2
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 claims 2
- OKKJLVBELUTLKV-UHFFFAOYSA-N methanol Chemical group OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims 2
- 239000000376 reactant Substances 0.000 claims 2
- 235000011150 stannous chloride Nutrition 0.000 claims 2
- LKKUYGGQEIJGDR-UHFFFAOYSA-N 1-iodopropane Chemical compound [CH2]CCI LKKUYGGQEIJGDR-UHFFFAOYSA-N 0.000 claims 1
- IQRUSQUYPCHEKN-UHFFFAOYSA-N 2-iodobutane Chemical compound CCC(C)I IQRUSQUYPCHEKN-UHFFFAOYSA-N 0.000 claims 1
- RDHPKYGYEGBMSE-UHFFFAOYSA-N Bromoethane Chemical compound CCBr RDHPKYGYEGBMSE-UHFFFAOYSA-N 0.000 claims 1
- KMGBZBJJOKUPIA-UHFFFAOYSA-N Butyl iodide Chemical compound CCCCI KMGBZBJJOKUPIA-UHFFFAOYSA-N 0.000 claims 1
- HVTICUPFWKNHNG-UHFFFAOYSA-N Ethyl iodide Chemical compound CCI HVTICUPFWKNHNG-UHFFFAOYSA-N 0.000 claims 1
- INQOMBQAUSQDDS-UHFFFAOYSA-N Methyl iodide Chemical compound IC INQOMBQAUSQDDS-UHFFFAOYSA-N 0.000 claims 1
- FLPZQPUGOOVZHK-UHFFFAOYSA-N [Pt].ClC1=C(Cl)CCC=CCC1 Chemical compound [Pt].ClC1=C(Cl)CCC=CCC1 FLPZQPUGOOVZHK-UHFFFAOYSA-N 0.000 claims 1
- 239000002253 acid Substances 0.000 claims 1
- 125000005599 alkyl carboxylate group Chemical group 0.000 claims 1
- 150000001350 alkyl halides Chemical class 0.000 claims 1
- 125000005233 alkylalcohol group Chemical group 0.000 claims 1
- -1 aryl carboxylate Chemical class 0.000 claims 1
- 125000003118 aryl group Chemical group 0.000 claims 1
- 150000001502 aryl halides Chemical class 0.000 claims 1
- TUOJAZRQYMQJER-UHFFFAOYSA-N benzonitrile;platinum Chemical compound [Pt].N#CC1=CC=CC=C1 TUOJAZRQYMQJER-UHFFFAOYSA-N 0.000 claims 1
- 150000001735 carboxylic acids Chemical class 0.000 claims 1
- 150000002148 esters Chemical class 0.000 claims 1
- 239000007789 gas Substances 0.000 claims 1
- 229910000042 hydrogen bromide Inorganic materials 0.000 claims 1
- 229910000039 hydrogen halide Inorganic materials 0.000 claims 1
- 239000012433 hydrogen halide Substances 0.000 claims 1
- 229910000043 hydrogen iodide Inorganic materials 0.000 claims 1
- 229940071870 hydroiodic acid Drugs 0.000 claims 1
- XJTQJERLRPWUGL-UHFFFAOYSA-N iodomethylbenzene Chemical compound ICC1=CC=CC=C1 XJTQJERLRPWUGL-UHFFFAOYSA-N 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- 239000000463 material Substances 0.000 claims 1
- 238000000034 method Methods 0.000 claims 1
- 229940102396 methyl bromide Drugs 0.000 claims 1
- MUMZUERVLWJKNR-UHFFFAOYSA-N oxoplatinum Chemical compound [Pt]=O MUMZUERVLWJKNR-UHFFFAOYSA-N 0.000 claims 1
- 229910003446 platinum oxide Inorganic materials 0.000 claims 1
- GBFHNZZOZWQQPA-UHFFFAOYSA-J platinum(4+);tetrachloride;dihydrochloride Chemical compound [H+].[H+].Cl[Pt-2](Cl)(Cl)(Cl)(Cl)Cl GBFHNZZOZWQQPA-UHFFFAOYSA-J 0.000 claims 1
- XAKYZBMFCZISAU-UHFFFAOYSA-N platinum;triphenylphosphane Chemical compound [Pt].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 XAKYZBMFCZISAU-UHFFFAOYSA-N 0.000 claims 1
- 239000011949 solid catalyst Substances 0.000 claims 1
- IUTCEZPPWBHGIX-UHFFFAOYSA-N tin(2+) Chemical compound [Sn+2] IUTCEZPPWBHGIX-UHFFFAOYSA-N 0.000 claims 1
Claims (12)
- 固体触媒担体材料を伴なった触媒有効量の白金及び錫を含む固体成分並びにハロゲン促進剤を含む触媒有効量の蒸気状成分を含んでなり、低級アルキルアルコール、低級アルキルアルコール生成性組成物及びそれらの混合物を含む反応体から気相カルボニル化法においてエステル及びカルボン酸を製造するのに有用な固体カルボニル化触媒。
- 前記固体担体が炭素である請求項１に記載の固体カルボニル化触媒。
- 前記炭素担体が活性炭である請求項２に記載の固体カルボニル化触媒。
- 前記触媒が白金及び錫をそれぞれ０．１〜１０重量％含む請求項１に記載の固体カルボニル化触媒。
- 前記触媒が白金及び錫をそれぞれ０．１〜２重量％含む請求項１に記載の固体カルボニル化触媒。
- 前記ハロゲン促進成分がＩ2、Ｂｒ2及びＣｌ2、ハロゲン化水素、気体ヨウ化水素酸、炭素数１２以下のハロゲン化アルキル及びハロゲン化アリール並びにそれらの混合物からなる群から選ばれる請求項１に記載のカルボニル化触媒。
- 前記ハロゲン促進剤がヨウ化水素、ヨウ化メチル、ヨウ化エチル、１−ヨードプロパン、２−ヨードブタン、１−ヨードブタン、臭化水素、臭化メチル、臭化エチル、ヨウ化ベンジル及びそれらの混合物からなる群から選ばれる請求項６に記載の固体カルボニル化触媒。
- 前記白金成分が塩化白金、酸化白金及びそれらの混合物からなる群から選ばれる請求項１に記載の固体カルボニル化触媒。
- 前記塩化白金が塩化白金酸；ジクロロジアンミン白金；ジクロロビス（トリフェニルホスフィン）白金；ジクロロ（１，５−シクロオクタジエン）白金；ジクロロビス（ベンゾニトリル）白金；二水素ヘキサクロロ白金酸塩及びそれらの混合物からなる群から選ばれる請求項８に記載の固体カルボニル化触媒。
- 前記錫成分が塩化錫（ＩＩ）、アルキルカルボン酸塩（炭素原子の少なくとも１つが錫に結合し、アルキル基の炭素数が１〜１０である）、アリールカルボン酸塩（炭素原子の少なくとも１つが錫に結合し、アリール基の炭素数が６〜２４である）、シュウ酸錫（ＩＩ）及びそれらの混合物からなる群から選ばれる請求項８に記載の固体カルボニル化触媒。
- 前記錫成分が塩化錫（ＩＩ）、シュウ酸錫（ＩＩ）及びそれらの混合物からなる群から選ばれる請求項８に記載の固体カルボニル化触媒。
- 前記反応体がメタノールである請求項１に記載のカルボニル化触媒。
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/884,775 US6903045B2 (en) | 2001-06-19 | 2001-06-19 | Tin promoted platinum catalyst for carbonylation of lower alkyl alcohols |
| PCT/US2002/018957 WO2002102506A1 (en) | 2001-06-19 | 2002-06-14 | Tin promoted platinum catalyst for carbonylation of lower alkyl alcohols |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2004529769A JP2004529769A (ja) | 2004-09-30 |
| JP2004529769A5 true JP2004529769A5 (ja) | 2006-01-05 |
| JP4365207B2 JP4365207B2 (ja) | 2009-11-18 |
Family
ID=25385366
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2003505082A Expired - Fee Related JP4365207B2 (ja) | 2001-06-19 | 2002-06-14 | 低級アルキルアルコールのカルボニル化用促進化白金触媒 |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US6903045B2 (ja) |
| EP (1) | EP1397206B1 (ja) |
| JP (1) | JP4365207B2 (ja) |
| CN (1) | CN1289189C (ja) |
| AT (1) | ATE306320T1 (ja) |
| DE (1) | DE60206623T2 (ja) |
| WO (1) | WO2002102506A1 (ja) |
Families Citing this family (55)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20060068986A1 (en) * | 2004-09-27 | 2006-03-30 | Dimascio Felice | Catalyst elements and methods of making and using |
| US20060110311A1 (en) * | 2004-11-03 | 2006-05-25 | Dimascio Felice | Catalyst composite and methods of making and using |
| US20060292059A1 (en) * | 2005-06-22 | 2006-12-28 | Dimascio Felice | Catalyst element and use thereof |
| US8637714B2 (en) | 2008-07-31 | 2014-01-28 | Celanese International Corporation | Process for producing ethanol over catalysts containing platinum and palladium |
| US8471075B2 (en) | 2008-07-31 | 2013-06-25 | Celanese International Corporation | Processes for making ethanol from acetic acid |
| US8304586B2 (en) | 2010-02-02 | 2012-11-06 | Celanese International Corporation | Process for purifying ethanol |
| US8546622B2 (en) * | 2008-07-31 | 2013-10-01 | Celanese International Corporation | Process for making ethanol from acetic acid using acidic catalysts |
| US8501652B2 (en) | 2008-07-31 | 2013-08-06 | Celanese International Corporation | Catalysts for making ethanol from acetic acid |
| US20100197486A1 (en) * | 2008-07-31 | 2010-08-05 | Celanese International Corporation | Catalysts for making ethyl acetate from acetic acid |
| US8309772B2 (en) | 2008-07-31 | 2012-11-13 | Celanese International Corporation | Tunable catalyst gas phase hydrogenation of carboxylic acids |
| US8338650B2 (en) | 2008-07-31 | 2012-12-25 | Celanese International Corporation | Palladium catalysts for making ethanol from acetic acid |
| US8309773B2 (en) | 2010-02-02 | 2012-11-13 | Calanese International Corporation | Process for recovering ethanol |
| US8680317B2 (en) * | 2008-07-31 | 2014-03-25 | Celanese International Corporation | Processes for making ethyl acetate from acetic acid |
| US8450535B2 (en) | 2009-07-20 | 2013-05-28 | Celanese International Corporation | Ethanol production from acetic acid utilizing a cobalt catalyst |
| US8710277B2 (en) * | 2009-10-26 | 2014-04-29 | Celanese International Corporation | Process for making diethyl ether from acetic acid |
| US8680321B2 (en) * | 2009-10-26 | 2014-03-25 | Celanese International Corporation | Processes for making ethanol from acetic acid using bimetallic catalysts |
| US8211821B2 (en) | 2010-02-01 | 2012-07-03 | Celanese International Corporation | Processes for making tin-containing catalysts |
| US8932372B2 (en) | 2010-02-02 | 2015-01-13 | Celanese International Corporation | Integrated process for producing alcohols from a mixed acid feed |
| US8344186B2 (en) | 2010-02-02 | 2013-01-01 | Celanese International Corporation | Processes for producing ethanol from acetaldehyde |
| US8569549B2 (en) | 2010-02-02 | 2013-10-29 | Celanese International Corporation | Catalyst supports having crystalline support modifiers |
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| US8222466B2 (en) | 2010-02-02 | 2012-07-17 | Celanese International Corporation | Process for producing a water stream from ethanol production |
| US8858659B2 (en) | 2010-02-02 | 2014-10-14 | Celanese International Corporation | Processes for producing denatured ethanol |
| US8728179B2 (en) | 2010-02-02 | 2014-05-20 | Celanese International Corporation | Ethanol compositions |
| US8460405B2 (en) | 2010-02-02 | 2013-06-11 | Celanese International Corporation | Ethanol compositions |
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| US8314272B2 (en) | 2010-02-02 | 2012-11-20 | Celanese International Corporation | Process for recovering ethanol with vapor separation |
| US8680343B2 (en) | 2010-02-02 | 2014-03-25 | Celanese International Corporation | Process for purifying ethanol |
| US8575403B2 (en) | 2010-05-07 | 2013-11-05 | Celanese International Corporation | Hydrolysis of ethyl acetate in ethanol separation process |
| US8754267B2 (en) | 2010-05-07 | 2014-06-17 | Celanese International Corporation | Process for separating acetaldehyde from ethanol-containing mixtures |
| US9024083B2 (en) | 2010-07-09 | 2015-05-05 | Celanese International Corporation | Process for the production of ethanol from an acetic acid feed and a recycled ethyl acetate feed |
| US8664454B2 (en) | 2010-07-09 | 2014-03-04 | Celanese International Corporation | Process for production of ethanol using a mixed feed using copper containing catalyst |
| WO2012148509A1 (en) | 2011-04-26 | 2012-11-01 | Celanese International Corporation | Process for producing ethanol using a stacked bed reactor |
| US9272970B2 (en) | 2010-07-09 | 2016-03-01 | Celanese International Corporation | Hydrogenolysis of ethyl acetate in alcohol separation processes |
| US8710279B2 (en) | 2010-07-09 | 2014-04-29 | Celanese International Corporation | Hydrogenolysis of ethyl acetate in alcohol separation processes |
| US8350098B2 (en) | 2011-04-04 | 2013-01-08 | Celanese International Corporation | Ethanol production from acetic acid utilizing a molybdenum carbide catalyst |
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| US8754268B2 (en) | 2011-04-26 | 2014-06-17 | Celanese International Corporation | Process for removing water from alcohol mixtures |
| US8895786B2 (en) | 2011-08-03 | 2014-11-25 | Celanese International Corporation | Processes for increasing alcohol production |
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| US8703868B2 (en) | 2011-11-28 | 2014-04-22 | Celanese International Corporation | Integrated process for producing polyvinyl alcohol or a copolymer thereof and ethanol |
| US9233899B2 (en) | 2011-12-22 | 2016-01-12 | Celanese International Corporation | Hydrogenation catalysts having an amorphous support |
| US9000234B2 (en) | 2011-12-22 | 2015-04-07 | Celanese International Corporation | Calcination of modified support to prepare hydrogenation catalysts |
| US8975200B2 (en) | 2012-01-06 | 2015-03-10 | Celanese International Corporation | Hydrogenation catalysts with cobalt-modified supports |
| US8981164B2 (en) | 2012-01-06 | 2015-03-17 | Celanese International Corporation | Cobalt and tin hydrogenation catalysts |
| US9024086B2 (en) | 2012-01-06 | 2015-05-05 | Celanese International Corporation | Hydrogenation catalysts with acidic sites |
| US9050585B2 (en) | 2012-02-10 | 2015-06-09 | Celanese International Corporation | Chemisorption of ethyl acetate during hydrogenation of acetic acid to ethanol |
| US8729311B2 (en) | 2012-02-10 | 2014-05-20 | Celanese International Corporaton | Catalysts for converting acetic acid to acetone |
| US8802903B2 (en) | 2012-03-13 | 2014-08-12 | Celanese International Corporation | Stacked bed reactor with diluents for producing ethanol |
| US8772553B2 (en) | 2012-10-26 | 2014-07-08 | Celanese International Corporation | Hydrogenation reaction conditions for producing ethanol |
| FR3039082B1 (fr) * | 2015-07-24 | 2017-07-21 | Ifp Energies Now | Catalyseur multi-metallique dope par du phosphore et un lanthanide |
| BR102019028273A2 (pt) * | 2019-12-30 | 2021-07-13 | Petróleo Brasileiro S.A. - Petrobras | Método para aplicação conjunta de removedor e inibidor de incrustação |
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-
2001
- 2001-06-19 US US09/884,775 patent/US6903045B2/en not_active Expired - Fee Related
-
2002
- 2002-06-14 AT AT02742103T patent/ATE306320T1/de not_active IP Right Cessation
- 2002-06-14 JP JP2003505082A patent/JP4365207B2/ja not_active Expired - Fee Related
- 2002-06-14 WO PCT/US2002/018957 patent/WO2002102506A1/en active IP Right Grant
- 2002-06-14 EP EP02742103A patent/EP1397206B1/en not_active Expired - Lifetime
- 2002-06-14 CN CN02808458.6A patent/CN1289189C/zh not_active Expired - Fee Related
- 2002-06-14 DE DE60206623T patent/DE60206623T2/de not_active Expired - Lifetime
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