JP2004520455A - 特性が改善されたポリオレフィン組成物 - Google Patents
特性が改善されたポリオレフィン組成物 Download PDFInfo
- Publication number
- JP2004520455A JP2004520455A JP2002546627A JP2002546627A JP2004520455A JP 2004520455 A JP2004520455 A JP 2004520455A JP 2002546627 A JP2002546627 A JP 2002546627A JP 2002546627 A JP2002546627 A JP 2002546627A JP 2004520455 A JP2004520455 A JP 2004520455A
- Authority
- JP
- Japan
- Prior art keywords
- olefin
- ethylene
- copolymer
- propylene
- polyolefin composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 61
- 229920000098 polyolefin Polymers 0.000 title claims abstract description 26
- 239000004711 α-olefin Substances 0.000 claims abstract description 63
- 229920000642 polymer Polymers 0.000 claims abstract description 53
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims abstract description 45
- 239000005977 Ethylene Substances 0.000 claims abstract description 44
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims abstract description 40
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims abstract description 40
- 229920000089 Cyclic olefin copolymer Polymers 0.000 claims abstract description 26
- 239000011159 matrix material Substances 0.000 claims abstract description 18
- 229920001971 elastomer Polymers 0.000 claims abstract description 17
- 229920001519 homopolymer Polymers 0.000 claims abstract description 17
- 229920001577 copolymer Polymers 0.000 claims abstract description 14
- 229920001038 ethylene copolymer Polymers 0.000 claims abstract description 8
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 7
- 229920001155 polypropylene Polymers 0.000 claims description 19
- -1 polypropylene Polymers 0.000 claims description 18
- 239000004743 Polypropylene Substances 0.000 claims description 14
- 238000000034 method Methods 0.000 claims description 12
- 239000000155 melt Substances 0.000 claims description 11
- 238000004806 packaging method and process Methods 0.000 claims description 11
- 238000001125 extrusion Methods 0.000 claims description 8
- 238000002156 mixing Methods 0.000 claims description 8
- 239000000654 additive Substances 0.000 claims description 7
- 150000001336 alkenes Chemical class 0.000 claims description 5
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 5
- 229920005606 polypropylene copolymer Polymers 0.000 claims description 5
- 238000001746 injection moulding Methods 0.000 claims description 4
- 150000002978 peroxides Chemical class 0.000 claims description 4
- 239000003381 stabilizer Substances 0.000 claims description 4
- 238000000071 blow moulding Methods 0.000 claims description 3
- 239000000945 filler Substances 0.000 claims description 3
- 238000000748 compression moulding Methods 0.000 claims description 2
- 238000010096 film blowing Methods 0.000 claims description 2
- 238000003856 thermoforming Methods 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims 1
- 230000003287 optical effect Effects 0.000 description 14
- 238000006116 polymerization reaction Methods 0.000 description 6
- 239000003054 catalyst Substances 0.000 description 5
- 239000002667 nucleating agent Substances 0.000 description 5
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 4
- 238000002347 injection Methods 0.000 description 4
- 239000007924 injection Substances 0.000 description 4
- 239000012968 metallocene catalyst Substances 0.000 description 4
- 229920005629 polypropylene homopolymer Polymers 0.000 description 4
- 239000008096 xylene Substances 0.000 description 4
- YWEWWNPYDDHZDI-JJKKTNRVSA-N (1r)-1-[(4r,4ar,8as)-2,6-bis(3,4-dimethylphenyl)-4,4a,8,8a-tetrahydro-[1,3]dioxino[5,4-d][1,3]dioxin-4-yl]ethane-1,2-diol Chemical compound C1=C(C)C(C)=CC=C1C1O[C@H]2[C@@H]([C@H](O)CO)OC(C=3C=C(C)C(C)=CC=3)O[C@H]2CO1 YWEWWNPYDDHZDI-JJKKTNRVSA-N 0.000 description 3
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- 229910019142 PO4 Inorganic materials 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 239000000806 elastomer Substances 0.000 description 3
- 239000006025 fining agent Substances 0.000 description 3
- 230000008014 freezing Effects 0.000 description 3
- 238000007710 freezing Methods 0.000 description 3
- 235000021317 phosphate Nutrition 0.000 description 3
- 229920001384 propylene homopolymer Polymers 0.000 description 3
- 229920005604 random copolymer Polymers 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- MKYBYDHXWVHEJW-UHFFFAOYSA-N N-[1-oxo-1-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propan-2-yl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(C(C)NC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 MKYBYDHXWVHEJW-UHFFFAOYSA-N 0.000 description 2
- JKIJEFPNVSHHEI-UHFFFAOYSA-N Phenol, 2,4-bis(1,1-dimethylethyl)-, phosphite (3:1) Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C JKIJEFPNVSHHEI-UHFFFAOYSA-N 0.000 description 2
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 description 2
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 2
- 235000013539 calcium stearate Nutrition 0.000 description 2
- 239000008116 calcium stearate Substances 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 2
- 238000012685 gas phase polymerization Methods 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- LLQHSBBZNDXTIV-UHFFFAOYSA-N 6-[5-[[4-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]piperazin-1-yl]methyl]-4,5-dihydro-1,2-oxazol-3-yl]-3H-1,3-benzoxazol-2-one Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)N1CCN(CC1)CC1CC(=NO1)C1=CC2=C(NC(O2)=O)C=C1 LLQHSBBZNDXTIV-UHFFFAOYSA-N 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- 101100079886 Lactobacillus johnsonii (strain CNCM I-12250 / La1 / NCC 533) nfr2 gene Proteins 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 101100023124 Schizosaccharomyces pombe (strain 972 / ATCC 24843) mfr2 gene Proteins 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- FQUNFJULCYSSOP-UHFFFAOYSA-N bisoctrizole Chemical compound N1=C2C=CC=CC2=NN1C1=CC(C(C)(C)CC(C)(C)C)=CC(CC=2C(=C(C=C(C=2)C(C)(C)CC(C)(C)C)N2N=C3C=CC=CC3=N2)O)=C1O FQUNFJULCYSSOP-UHFFFAOYSA-N 0.000 description 1
- 238000012662 bulk polymerization Methods 0.000 description 1
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000008395 clarifying agent Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- GDVKFRBCXAPAQJ-UHFFFAOYSA-A dialuminum;hexamagnesium;carbonate;hexadecahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Al+3].[Al+3].[O-]C([O-])=O GDVKFRBCXAPAQJ-UHFFFAOYSA-A 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 239000005003 food packaging material Substances 0.000 description 1
- 238000005194 fractionation Methods 0.000 description 1
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- 229960001545 hydrotalcite Drugs 0.000 description 1
- 229910001701 hydrotalcite Inorganic materials 0.000 description 1
- 238000010102 injection blow moulding Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229920001684 low density polyethylene Polymers 0.000 description 1
- 239000004702 low-density polyethylene Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- 150000001451 organic peroxides Chemical class 0.000 description 1
- 229920006280 packaging film Polymers 0.000 description 1
- 239000012785 packaging film Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 238000005057 refrigeration Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000003352 sequestering agent Substances 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 230000000707 stereoselective effect Effects 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 235000012222 talc Nutrition 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/04—Monomers containing three or four carbon atoms
- C08F10/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/06—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
- C08F297/08—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/06—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
- C08F297/08—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
- C08F297/083—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins the monomers being ethylene or propylene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/14—Copolymers of propene
- C08L23/142—Copolymers of propene at least partially crystalline copolymers of propene with other olefins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
- C08F210/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/02—Heterophasic composition
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms
- C08L23/0815—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms with aliphatic 1-olefins containing one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/16—Ethene-propene or ethene-propene-diene copolymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2308/00—Chemical blending or stepwise polymerisation process with the same catalyst
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2314/00—Polymer mixtures characterised by way of preparation
- C08L2314/06—Metallocene or single site catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP00126051A EP1211289A1 (en) | 2000-11-29 | 2000-11-29 | Polyolefin compositions with improved properties |
| PCT/EP2001/013717 WO2002044272A1 (en) | 2000-11-29 | 2001-11-26 | Polyolefin compositions with improved properties |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2008055487A Division JP2008138222A (ja) | 2000-11-29 | 2008-03-05 | 特性が改善されたポリオレフィン組成物 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2004520455A true JP2004520455A (ja) | 2004-07-08 |
| JP2004520455A5 JP2004520455A5 (enExample) | 2007-10-04 |
Family
ID=8170523
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2002546627A Pending JP2004520455A (ja) | 2000-11-29 | 2001-11-26 | 特性が改善されたポリオレフィン組成物 |
| JP2008055487A Withdrawn JP2008138222A (ja) | 2000-11-29 | 2008-03-05 | 特性が改善されたポリオレフィン組成物 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2008055487A Withdrawn JP2008138222A (ja) | 2000-11-29 | 2008-03-05 | 特性が改善されたポリオレフィン組成物 |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US6930149B2 (enExample) |
| EP (3) | EP1211289A1 (enExample) |
| JP (2) | JP2004520455A (enExample) |
| KR (1) | KR100822656B1 (enExample) |
| CN (1) | CN1225501C (enExample) |
| AT (2) | ATE378377T1 (enExample) |
| AU (2) | AU2002223685B2 (enExample) |
| DE (2) | DE60131460T2 (enExample) |
| DK (1) | DK1358266T3 (enExample) |
| ES (2) | ES2296832T3 (enExample) |
| WO (1) | WO2002044272A1 (enExample) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2009545470A (ja) * | 2006-07-31 | 2009-12-24 | トータル・ペトロケミカルズ・リサーチ・フエリユイ | 射出延伸ブロー成形用のポリオレフィン組成物 |
| JP2015500152A (ja) * | 2011-12-05 | 2015-01-05 | ボレアリス・アクチェンゲゼルシャフトBorealis Ag | フィルム押出法における生産量の増加 |
| JP2016508078A (ja) * | 2012-12-12 | 2016-03-17 | ボレアリス・アクチェンゲゼルシャフトBorealis Ag | 押出ブロー成形ボトル |
| JP2020525559A (ja) * | 2017-06-26 | 2020-08-27 | ボレアリス エージー | 優れた外観を備えるポリプロピレン組成物 |
Families Citing this family (65)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10212654B4 (de) * | 2001-03-30 | 2012-06-14 | Jnc Corporation | Propylenpolymerzusammensetzung und geschäumte Formlinge daraus |
| JP2005533920A (ja) | 2002-07-24 | 2005-11-10 | バセル ポリオレフィン ジーエムビーエイチ | プロピレンポリマー組成物の製造の少なくとも2段階方法 |
| EP1428853A1 (en) * | 2002-12-09 | 2004-06-16 | Borealis Technology OY | Propylene polymer composition with improved balance of mechanical and optical properties |
| EP1428854A1 (en) * | 2002-12-09 | 2004-06-16 | Borealis Technology OY | Propylene polymer composition with improved balance of mechanical and optical properties |
| ATE491745T1 (de) * | 2003-05-15 | 2011-01-15 | Borealis Tech Oy | Polyolefin-zusammensetzung |
| EP1510547A1 (en) * | 2003-08-13 | 2005-03-02 | Borealis Technology OY | Novel polypropylene compositions with improved resistance to stress whitening |
| US7452919B2 (en) | 2004-05-27 | 2008-11-18 | Sunoco, Inc. (R&M) | Clarity, low haze polymer |
| EP1619217B1 (en) * | 2004-07-20 | 2010-09-15 | Borealis Technology Oy | Cable with thermoplastic insulation |
| US20070010626A1 (en) * | 2005-07-11 | 2007-01-11 | Shankernarayanan Manivakkam J | Polyethylene compositions |
| ES2404700T3 (es) * | 2006-04-26 | 2013-05-28 | Borealis Technology Oy | Un artículo de poliolefina transparente que está sometido a un tratamiento térmico |
| ES2338910T5 (es) * | 2006-05-26 | 2014-03-28 | Borealis Technology Oy | Composición de poliolefina con resistencia al emblanquecimiento por tensión mejorada |
| ES2558869T3 (es) * | 2006-06-30 | 2016-02-09 | Borealis Technology Oy | Composición de poliolefinas adecuada para botellas con alta resistencia al impacto y transparencia |
| KR101273049B1 (ko) * | 2006-12-29 | 2013-06-10 | 주식회사 효성 | 폴리올레핀계 수지조성물 및 이를 포함하는 다층 필름 |
| US20090186999A1 (en) * | 2008-01-22 | 2009-07-23 | Fina Technology, Inc. | Low melt flow rate (MFR) propylene based polymers for injection stretch blow molding |
| US20100249354A1 (en) * | 2009-03-26 | 2010-09-30 | Fina Technology, Inc. | Injection stretch blow molded articles and syndiotactic polymers for use therein |
| US9090000B2 (en) * | 2009-03-26 | 2015-07-28 | Fina Technology, Inc. | Injection stretch blow molded articles and random copolymers for use therein |
| EP2251375A1 (en) * | 2009-05-07 | 2010-11-17 | Borealis AG | Thermoplastic polyolefin compounds with decreased flaming sensitivity |
| CN102428136B (zh) * | 2009-05-19 | 2014-11-12 | 普立万公司 | 具有出色食品接触适应性的热塑性弹性体 |
| EP2275485B1 (en) * | 2009-06-22 | 2011-06-08 | Borealis AG | Heterophasic polypropylene copolymer composition |
| US9587043B2 (en) | 2009-11-11 | 2017-03-07 | Borealis Ag | Polymer composition and a power cable comprising the polymer composition |
| WO2011057926A1 (en) | 2009-11-11 | 2011-05-19 | Borealis Ag | A polymer composition comprising a polyolefin produced in a high pressure process, a high pressure process and an article |
| CN102666602B (zh) | 2009-11-11 | 2015-11-25 | 博瑞立斯有限公司 | 具有有利的电性能的可交联的聚合物组合物和电缆 |
| JP5739442B2 (ja) | 2009-11-11 | 2015-06-24 | ボレアリス エージー | ケーブルおよびその製造法 |
| ES2398654T3 (es) | 2010-09-16 | 2013-03-20 | Borealis Ag | Material polímero rígido y de alto flujo con buenas propiedades de transparencia e impacto |
| ES2750266T3 (es) | 2010-11-03 | 2020-03-25 | Borealis Ag | Una composición de polímero y un cable de alimentación que comprende la composición de polímero |
| PL2471858T3 (pl) | 2010-12-06 | 2017-08-31 | Borealis Ag | Polipropylen heterofazowy o zwiększonej sztywności i przezroczystości oraz odpowiedniej wytrzymałości na uderzenie |
| EP2492310B1 (en) * | 2011-02-28 | 2016-11-23 | Borealis AG | Heterophasic polyolefin composition having improved flowability and impact strength |
| EP2492309A1 (en) * | 2011-02-28 | 2012-08-29 | Borealis AG | Heterophasic polyolefin composition having improved flowability and impact strength |
| EP2508562B1 (en) * | 2011-03-28 | 2018-06-13 | Borealis AG | Polypropylene composition for extrusion blown molded bottles |
| US9978478B2 (en) | 2011-05-04 | 2018-05-22 | Borealis Ag | Polymer composition for electrical devices |
| CA2834812A1 (en) | 2011-05-04 | 2012-11-08 | Borealis Ag | Polymer composition for electrical devices |
| RU2613330C2 (ru) | 2011-05-04 | 2017-03-16 | Бореалис Аг | Полимерная композиция для электротехнических устройств |
| US8829094B2 (en) * | 2011-12-22 | 2014-09-09 | Fina Technology, Inc. | Use of nucleation in ICP resins |
| CN102632600B (zh) * | 2012-04-25 | 2014-11-19 | 昆明东方塑纸包装有限公司 | 应用高分子材料制造低温保鲜袋的方法 |
| CN104736628B (zh) * | 2012-09-19 | 2019-06-21 | 沙特基础工业公司 | 用于制备包含非均相丙烯共聚物和滑石的组合物的方法 |
| EP2746295A1 (en) * | 2012-12-21 | 2014-06-25 | Borealis AG | Transparent thin wall packaging material with improved stiffness and flowability |
| US8871868B2 (en) | 2013-01-09 | 2014-10-28 | Braskem America, Inc. | Propylene impact copolymers having good optical properties |
| US9115279B2 (en) | 2013-03-15 | 2015-08-25 | Asahi Kasei Plastics North America, Inc. | Polypropylene compounds with high impact performance and improved stress whitening resistance |
| PL2824141T3 (pl) * | 2013-07-09 | 2016-12-30 | Zastosowanie kompozycji poliolefinowej do redukcji zapadnięć | |
| WO2015076987A1 (en) * | 2013-11-22 | 2015-05-28 | Exxonmobil Chemical Patents Inc. | Reverse staged impact copolymers |
| US9376559B2 (en) | 2013-11-22 | 2016-06-28 | Exxonmobil Chemical Patents Inc. | Reverse staged impact copolymers |
| CN106459488B (zh) * | 2014-03-14 | 2019-09-13 | 美利肯公司 | 改性的多相聚烯烃组合物 |
| CN116102818A (zh) * | 2014-10-27 | 2023-05-12 | 北欧化工股份公司 | 具有优越电性能的聚合物组合物以及电缆 |
| EP3015503A1 (en) | 2014-10-27 | 2016-05-04 | Borealis AG | Heterophasic polypropylene with improved stiffness/impact balance |
| EP3212710B2 (en) * | 2014-10-27 | 2023-12-27 | Borealis AG | Polymer composition for cable applications with advantageous electrical properties |
| CN107207658B (zh) * | 2014-12-19 | 2022-11-01 | 博里利斯股份公司 | 用于w&c应用的具有有利电性能的聚合物组合物 |
| US10723892B2 (en) * | 2015-03-31 | 2020-07-28 | Dow Global Technologies Llc | Spray dried polyolefin elastomer powder for rotational molding processes |
| EA036127B1 (ru) * | 2015-05-29 | 2020-10-01 | Бореалис Аг | Композиция сополимера пропилена |
| CN107922695B (zh) * | 2015-08-10 | 2021-06-15 | Sabic环球技术有限责任公司 | 包含多相丙烯共聚物的组合物 |
| MX2018008161A (es) | 2015-12-30 | 2018-08-28 | Braskem America Inc | Composicion polimerica transparente y resistente a impacto y articulo fabricado. |
| EP3246358A1 (en) * | 2016-05-18 | 2017-11-22 | Borealis AG | Soft and transparent propylene copolymers |
| WO2017198633A1 (en) | 2016-05-18 | 2017-11-23 | Borealis Ag | Soft polypropylene composition |
| CN107880405A (zh) * | 2016-09-29 | 2018-04-06 | 中国石油化工股份有限公司 | 一种低拉伸断裂伸长率抗冲聚丙烯树脂 |
| ES2958562T3 (es) * | 2017-02-03 | 2024-02-09 | Borealis Ag | Uso de una composición polimérica para la producción de artículos con capacidad de pintado y apariencia superficial mejoradas |
| CN109135067A (zh) * | 2017-06-27 | 2019-01-04 | 阿布扎比聚合物有限责任公司(博禄) | 用于制造高压管的聚丙烯组合物 |
| EP3502177B1 (en) * | 2017-12-20 | 2020-02-12 | Borealis AG | Polypropylene composition |
| WO2019119392A1 (en) * | 2017-12-22 | 2019-06-27 | Borouge Compounding Shanghai Co., Ltd. | Soft polyolefin composition |
| CN113242883B (zh) | 2018-11-07 | 2023-09-22 | 北欧化工公司 | 抗冲击性和抗致白性改善的聚烯烃组合物 |
| CN113056508B (zh) | 2018-11-23 | 2023-08-04 | 博里利斯股份公司 | 具有改善的光学性能和抗致白性的聚丙烯组合物 |
| EP3770211A4 (en) * | 2018-12-05 | 2022-03-23 | Guangdong Tianan New Material Co., Ltd | POLYPROPYLENE FILM AND POLYPROPYLENE COMPOSITE FILM |
| WO2020207825A1 (en) | 2019-04-12 | 2020-10-15 | Borealis Ag | Low stress whitening polypropylene composition |
| CN114423817B (zh) | 2019-09-20 | 2023-09-12 | 北欧化工公司 | 性能特征改善的多相丙烯聚合物组合物 |
| EP4038137B1 (en) * | 2019-10-01 | 2023-07-12 | Borealis AG | Polymer composition suitable for making blown films |
| EP4038138B1 (en) | 2019-10-02 | 2025-09-17 | Borealis GmbH | Polymer composition suitable for making blown films |
| KR102528749B1 (ko) * | 2019-11-28 | 2023-05-03 | 롯데케미칼 주식회사 | 폴리올레핀계 수지 조성물 및 이로부터 제조된 의료용 호스 |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT1227893B (it) | 1988-12-14 | 1991-05-14 | Himont Inc Centerville Road Ne | Composizioni polipropileniche aventi buona trasparenza e migliorata resistenza all'urto |
| EP0593221B1 (en) * | 1992-10-15 | 1998-08-05 | Mitsubishi Chemical Corporation | Propylene resin compositions |
| US5331047A (en) * | 1993-02-17 | 1994-07-19 | Himont Incorporated | Olefin polymer films |
| CA2162946C (en) * | 1994-11-21 | 2004-01-06 | Kazuyuki Watanabe | Propylene block copolymer and process for producing the same |
| US5929147A (en) | 1996-06-18 | 1999-07-27 | Montell North America Inc. | Embrittlement-resistant polyolefin composition and flexible articles therefrom |
| JP3347958B2 (ja) * | 1996-11-26 | 2002-11-20 | 日本ポリケム株式会社 | プロピレン系樹脂組成物 |
| GB0008690D0 (en) * | 2000-04-07 | 2000-05-31 | Borealis Polymers Oy | Process |
| WO2002053374A1 (en) * | 2001-01-02 | 2002-07-11 | Dow Global Technologies Inc. | Peelable seal and method of making and using same |
-
2000
- 2000-11-29 EP EP00126051A patent/EP1211289A1/en not_active Withdrawn
-
2001
- 2001-11-26 AU AU2002223685A patent/AU2002223685B2/en not_active Ceased
- 2001-11-26 DK DK01998593T patent/DK1358266T3/da active
- 2001-11-26 CN CNB018223273A patent/CN1225501C/zh not_active Expired - Fee Related
- 2001-11-26 DE DE60131460T patent/DE60131460T2/de not_active Expired - Lifetime
- 2001-11-26 ES ES01998593T patent/ES2296832T3/es not_active Expired - Lifetime
- 2001-11-26 EP EP01998593A patent/EP1358266B1/en not_active Expired - Lifetime
- 2001-11-26 DE DE60142860T patent/DE60142860D1/de not_active Expired - Lifetime
- 2001-11-26 AT AT01998593T patent/ATE378377T1/de not_active IP Right Cessation
- 2001-11-26 JP JP2002546627A patent/JP2004520455A/ja active Pending
- 2001-11-26 AU AU2368502A patent/AU2368502A/xx active Pending
- 2001-11-26 US US10/433,202 patent/US6930149B2/en not_active Expired - Lifetime
- 2001-11-26 EP EP06113874A patent/EP1702956B1/en not_active Expired - Lifetime
- 2001-11-26 KR KR1020037007169A patent/KR100822656B1/ko not_active Expired - Fee Related
- 2001-11-26 WO PCT/EP2001/013717 patent/WO2002044272A1/en not_active Ceased
- 2001-11-26 AT AT06113874T patent/ATE478118T1/de not_active IP Right Cessation
- 2001-11-26 ES ES06113874T patent/ES2348383T3/es not_active Expired - Lifetime
-
2008
- 2008-03-05 JP JP2008055487A patent/JP2008138222A/ja not_active Withdrawn
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2009545470A (ja) * | 2006-07-31 | 2009-12-24 | トータル・ペトロケミカルズ・リサーチ・フエリユイ | 射出延伸ブロー成形用のポリオレフィン組成物 |
| JP2015500152A (ja) * | 2011-12-05 | 2015-01-05 | ボレアリス・アクチェンゲゼルシャフトBorealis Ag | フィルム押出法における生産量の増加 |
| US9228068B2 (en) | 2011-12-05 | 2016-01-05 | Borealis Ag | Increased output of a film extrusion process |
| JP2016508078A (ja) * | 2012-12-12 | 2016-03-17 | ボレアリス・アクチェンゲゼルシャフトBorealis Ag | 押出ブロー成形ボトル |
| US9394073B2 (en) | 2012-12-12 | 2016-07-19 | Borealis Ag | Extrusion blow molded bottles |
| JP2020525559A (ja) * | 2017-06-26 | 2020-08-27 | ボレアリス エージー | 優れた外観を備えるポリプロピレン組成物 |
| US11377543B2 (en) | 2017-06-26 | 2022-07-05 | Borealis Ag | Polypropylene composition with excellent surface appearance |
Also Published As
| Publication number | Publication date |
|---|---|
| KR20030066685A (ko) | 2003-08-09 |
| ES2348383T3 (es) | 2010-12-03 |
| EP1702956A3 (en) | 2006-11-22 |
| EP1702956B1 (en) | 2010-08-18 |
| US6930149B2 (en) | 2005-08-16 |
| ES2296832T3 (es) | 2008-05-01 |
| DE60131460T2 (de) | 2008-09-04 |
| DE60142860D1 (de) | 2010-09-30 |
| WO2002044272A1 (en) | 2002-06-06 |
| EP1211289A1 (en) | 2002-06-05 |
| KR100822656B1 (ko) | 2008-04-17 |
| EP1358266A1 (en) | 2003-11-05 |
| CN1487973A (zh) | 2004-04-07 |
| US20040210002A1 (en) | 2004-10-21 |
| CN1225501C (zh) | 2005-11-02 |
| ATE478118T1 (de) | 2010-09-15 |
| EP1702956A2 (en) | 2006-09-20 |
| JP2008138222A (ja) | 2008-06-19 |
| AU2368502A (en) | 2002-06-11 |
| AU2002223685B2 (en) | 2006-06-08 |
| EP1358266B1 (en) | 2007-11-14 |
| DK1358266T3 (da) | 2008-03-10 |
| ATE378377T1 (de) | 2007-11-15 |
| DE60131460D1 (de) | 2007-12-27 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP2004520455A (ja) | 特性が改善されたポリオレフィン組成物 | |
| AU2002223685A1 (en) | Polyolefin compositions with improved properties | |
| EP2449026B1 (en) | High Flow Polypropylene Composition | |
| ES2242000T3 (es) | Polimero de propileno heterofasico. | |
| CN101379127B (zh) | 聚丙烯组合物 | |
| JP2004520455A5 (enExample) | ||
| CN108350239B (zh) | 多相聚丙烯组合物 | |
| US10584237B2 (en) | Modified polypropylene and polymer blends thereof | |
| EP2989158B1 (en) | Propylene random copolymer composition for pipe applications | |
| WO2020217829A1 (ja) | プロピレン樹脂組成物及び成形体 | |
| CN110770292B (zh) | 包含异相丙烯共聚物的组合物 | |
| EP1849826A1 (en) | A transparent polyolefin article which is subjected to a heat treatment | |
| JP2002212358A (ja) | 容器用ポリプロピレン樹脂組成物、容器の製造方法、および容器 | |
| KR20190111910A (ko) | 개선된 산소 장벽 속성을 가진 비-배향된 필름의 제조 방법 | |
| KR20190124202A (ko) | 개선된 산소 장벽 속성을 갖는 비-배향된 필름을 위한 폴리올레핀 조성물 | |
| JP2004002694A (ja) | 射出成形用プロピレン系樹脂組成物およびそれからなる射出成形体 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20041122 |
|
| A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20070207 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20070220 |
|
| A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20070521 |
|
| A602 | Written permission of extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A602 Effective date: 20070528 |
|
| A524 | Written submission of copy of amendment under article 19 pct |
Free format text: JAPANESE INTERMEDIATE CODE: A524 Effective date: 20070820 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A821 Effective date: 20070820 |
|
| A02 | Decision of refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A02 Effective date: 20071106 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20080305 |
|
| A911 | Transfer to examiner for re-examination before appeal (zenchi) |
Free format text: JAPANESE INTERMEDIATE CODE: A911 Effective date: 20080501 |
|
| A912 | Re-examination (zenchi) completed and case transferred to appeal board |
Free format text: JAPANESE INTERMEDIATE CODE: A912 Effective date: 20080530 |