JP2004509989A5 - - Google Patents
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- Publication number
- JP2004509989A5 JP2004509989A5 JP2002529170A JP2002529170A JP2004509989A5 JP 2004509989 A5 JP2004509989 A5 JP 2004509989A5 JP 2002529170 A JP2002529170 A JP 2002529170A JP 2002529170 A JP2002529170 A JP 2002529170A JP 2004509989 A5 JP2004509989 A5 JP 2004509989A5
- Authority
- JP
- Japan
- Prior art keywords
- nitroxyl
- oligomer
- polymer
- group
- radical
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229920000642 polymer Polymers 0.000 description 7
- 150000003254 radicals Chemical class 0.000 description 7
- 239000012986 chain transfer agent Substances 0.000 description 6
- -1 nitroxyl radicals Chemical class 0.000 description 6
- 239000003999 initiator Substances 0.000 description 5
- 239000000178 monomer Substances 0.000 description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 4
- 150000002019 disulfides Chemical class 0.000 description 4
- ODUCDPQEXGNKDN-UHFFFAOYSA-N nitroxyl Chemical compound O=N ODUCDPQEXGNKDN-UHFFFAOYSA-N 0.000 description 4
- 238000010526 radical polymerization reaction Methods 0.000 description 4
- 150000003568 thioethers Chemical class 0.000 description 4
- 238000000034 method Methods 0.000 description 3
- YLFIGGHWWPSIEG-UHFFFAOYSA-N aminoxyl Chemical compound [O]N YLFIGGHWWPSIEG-UHFFFAOYSA-N 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 230000000977 initiatory effect Effects 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 230000000379 polymerizing effect Effects 0.000 description 2
- BWGNESOTFCXPMA-UHFFFAOYSA-N Dihydrogen disulfide Chemical compound SS BWGNESOTFCXPMA-UHFFFAOYSA-N 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 125000002228 disulfide group Chemical group 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP00810880 | 2000-09-25 | ||
| PCT/EP2001/010782 WO2002024762A1 (en) | 2000-09-25 | 2001-09-18 | Composition and process for enhancing controlled free radical polymerization |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2004509989A JP2004509989A (ja) | 2004-04-02 |
| JP2004509989A5 true JP2004509989A5 (enExample) | 2008-11-06 |
Family
ID=8174934
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2002529170A Pending JP2004509989A (ja) | 2000-09-25 | 2001-09-18 | 制御された遊離ラジカル重合を高める組成物および方法 |
Country Status (12)
| Country | Link |
|---|---|
| US (2) | US7074860B2 (enExample) |
| EP (1) | EP1320554B2 (enExample) |
| JP (1) | JP2004509989A (enExample) |
| KR (1) | KR100778770B1 (enExample) |
| AT (1) | ATE319749T1 (enExample) |
| AU (1) | AU2002213932A1 (enExample) |
| CA (1) | CA2423194A1 (enExample) |
| DE (1) | DE60117841T3 (enExample) |
| ES (1) | ES2258555T5 (enExample) |
| MX (1) | MXPA03002465A (enExample) |
| TW (1) | TWI225492B (enExample) |
| WO (1) | WO2002024762A1 (enExample) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20100210800A1 (en) * | 2004-03-24 | 2010-08-19 | Ciba Corporation | Method of preparing ethylene polymers by controlled high pressure polymerization |
| WO2007016499A2 (en) * | 2005-08-02 | 2007-02-08 | Arkema Inc. | Methods of producing vinyl aromatic polymers using (meth)acrylic macroinitiators |
| JP5825819B2 (ja) * | 2011-04-13 | 2015-12-02 | 住友ゴム工業株式会社 | ジエン系重合体及びその製造方法 |
Family Cites Families (33)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR930000892B1 (ko) † | 1983-07-11 | 1993-02-11 | 커몬웰스 사이언티픽 앤드 인더스트리얼 리셔치 오가니제이숀 | 신규의 개시제를 사용하여 중합체 또는 공중합체를 제조하는방법 |
| EP0500575B1 (en) † | 1989-11-01 | 1997-06-11 | Commonwealth Scientific And Industrial Research Organisation | Control of molecular weight and end group functionality in polymers using unsaturated peroxy compounds as chain transfer agents |
| US5010114A (en) * | 1990-01-16 | 1991-04-23 | The Mead Corporation | Microsuspension polymerization |
| DE4236316A1 (en) * | 1991-10-31 | 1993-05-06 | Takeda Chemical Industries Ltd | Copolymer lattices, useful as binders in paper coating compsns. - by two=stage emulsion polymerisation of monomer mixt., with hydrophilic chain transfer agent and hydrophobic agent in second stage |
| US5322912A (en) | 1992-11-16 | 1994-06-21 | Xerox Corporation | Polymerization processes and toner compositions therefrom |
| JP3203995B2 (ja) * | 1993-12-24 | 2001-09-04 | ジェイエスアール株式会社 | 感放射線性樹脂組成物 |
| US5412047A (en) | 1994-05-13 | 1995-05-02 | Xerox Corporation | Homoacrylate polymerization processes with oxonitroxides |
| DE69506280T2 (de) † | 1994-12-14 | 1999-08-12 | The Dow Chemical Co., Midland, Mich. | Herstellung von polystyrol mit hohem molekulargewicht durch vinylsäurekatalysierte frei-radikalische polymerisation |
| US5610249A (en) | 1995-01-24 | 1997-03-11 | Kansai Paint Co., Ltd. | Process for production of styrene or styrene derivative polymer of narrow molecular weight distrubition |
| FR2730240A1 (fr) | 1995-02-07 | 1996-08-09 | Atochem Elf Sa | Stabilisation d'un polymere par un radical libre stable |
| US5608023A (en) | 1995-03-30 | 1997-03-04 | Xerox Corporation | Rate enhanced polymerization processes |
| US5627248A (en) * | 1995-09-26 | 1997-05-06 | The Dow Chemical Company | Difunctional living free radical polymerization initiators |
| DE69717327T2 (de) * | 1996-02-22 | 2003-08-21 | Kao Corp., Tokio/Tokyo | Wässrige Tinte für Tintenstrahldruck |
| HU220138B (hu) † | 1996-03-29 | 2001-11-28 | The Dow Chemical Co. | Szabadgyökös tömbpolimerizálási eljárás kaucsukkal módosított polimerek vinil-aromás monomerekből való előállítására |
| KR970064016U (ko) * | 1996-05-31 | 1997-12-11 | 브이시알의 전면 패널 | |
| AU4773997A (en) | 1996-09-25 | 1998-04-17 | Akzo Nobel N.V. | No-compounds for pseudo-living radical polymerization |
| US20010000256A1 (en) | 1996-11-20 | 2001-04-12 | Atofina | Polymerization in the presence of a stable free radical and of an iniferter |
| FR2755969B1 (fr) * | 1996-11-20 | 1998-12-24 | Atochem Elf Sa | Polymerisation en presence d'un radical libre stable et d'un iniferter |
| KR100504055B1 (ko) | 1997-01-10 | 2005-07-27 | 이 아이 듀폰 디 네모아 앤드 캄파니 | 중합체 분자량 및 구조의 조절 방법 |
| DE69834482T2 (de) * | 1997-03-11 | 2007-05-03 | Nippon Zeon Co., Ltd. | Verfahren zur herstellung konjugierter diene |
| US6281311B1 (en) | 1997-03-31 | 2001-08-28 | Pmd Holdings Corp. | Controlled free radical polymerization process |
| CH693416A5 (de) † | 1998-03-09 | 2003-07-31 | Ciba Sc Holding Ag | 1-Alkoxypolyalkylpiperidinderivate und ihre Verwendung als Polymerisationsregler. |
| TW400337B (en) * | 1998-03-17 | 2000-08-01 | Akzo Nobel Nv | Process to make low-molecular weight sma |
| ES2242393T3 (es) * | 1998-04-27 | 2005-11-01 | Kaneka Corporation | Composicion de resina que contiene un polimero de injerto multicapa. |
| FR2779437B1 (fr) * | 1998-06-03 | 2004-10-15 | Atochem Elf Sa | Polymere vinylaromatique choc par polymerisation d'un monomere vinylaromatique en presence d'un radical libre stable et d'un amorceur de polymerisation |
| JP4665270B2 (ja) * | 1999-08-27 | 2011-04-06 | 日油株式会社 | 高分子ラジカル重合開始剤、その製造方法およびそれを用いて得られるグラフトポリマー |
| WO2000007981A1 (en) | 1998-07-31 | 2000-02-17 | Ciba Specialty Chemicals Holding Inc. | Open chain alkoxyamine compounds and their use as polymerization regulators |
| DE69927839T2 (de) † | 1998-09-03 | 2006-05-11 | Ciba Speciality Chemicals Holding Inc. | Propfung von äthylenisch ungesättigten monomeren auf polymeren |
| TWI225483B (en) | 1998-10-16 | 2004-12-21 | Ciba Sc Holding Ag | Heterocyclic alkoxyamines as regulators in controlled radical polymerization process |
| GB9827080D0 (en) * | 1998-12-10 | 1999-02-03 | Ici Ltd | Production of vinylic polymers |
| WO2001009204A2 (en) † | 1999-07-31 | 2001-02-08 | Symyx Technologies, Inc. | Controlled-architecture polymers and use thereof as separation media |
| US6716948B1 (en) * | 1999-07-31 | 2004-04-06 | Symyx Technologies, Inc. | Controlled-architecture polymers and use thereof as separation media |
| US6713552B1 (en) * | 1999-08-23 | 2004-03-30 | Rohm And Haas Company | Pressure sensitive adhesive with improved peel strength and tack |
-
2001
- 2001-08-07 TW TW090119232A patent/TWI225492B/zh not_active IP Right Cessation
- 2001-09-18 AT AT01982310T patent/ATE319749T1/de not_active IP Right Cessation
- 2001-09-18 DE DE60117841T patent/DE60117841T3/de not_active Expired - Lifetime
- 2001-09-18 ES ES01982310T patent/ES2258555T5/es not_active Expired - Lifetime
- 2001-09-18 US US10/381,223 patent/US7074860B2/en not_active Expired - Fee Related
- 2001-09-18 KR KR1020037003445A patent/KR100778770B1/ko not_active Expired - Fee Related
- 2001-09-18 WO PCT/EP2001/010782 patent/WO2002024762A1/en not_active Ceased
- 2001-09-18 EP EP01982310A patent/EP1320554B2/en not_active Expired - Lifetime
- 2001-09-18 JP JP2002529170A patent/JP2004509989A/ja active Pending
- 2001-09-18 CA CA002423194A patent/CA2423194A1/en not_active Abandoned
- 2001-09-18 MX MXPA03002465A patent/MXPA03002465A/es active IP Right Grant
- 2001-09-18 AU AU2002213932A patent/AU2002213932A1/en not_active Abandoned
-
2005
- 2005-12-12 US US11/299,470 patent/US7323517B2/en not_active Expired - Fee Related
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