JP2004504282A - α−オレフィン類の製造方法 - Google Patents
α−オレフィン類の製造方法 Download PDFInfo
- Publication number
- JP2004504282A JP2004504282A JP2002512099A JP2002512099A JP2004504282A JP 2004504282 A JP2004504282 A JP 2004504282A JP 2002512099 A JP2002512099 A JP 2002512099A JP 2002512099 A JP2002512099 A JP 2002512099A JP 2004504282 A JP2004504282 A JP 2004504282A
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- Prior art keywords
- carbon group
- hydrogen
- group
- halogen
- ethylene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000004711 α-olefin Substances 0.000 title claims abstract description 33
- 238000004519 manufacturing process Methods 0.000 title claims description 17
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims abstract description 57
- 239000005977 Ethylene Substances 0.000 claims abstract description 57
- 238000000034 method Methods 0.000 claims abstract description 57
- 239000007788 liquid Substances 0.000 claims abstract description 36
- 239000003054 catalyst Substances 0.000 claims abstract description 27
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 24
- 238000006384 oligomerization reaction Methods 0.000 claims abstract description 19
- 238000006243 chemical reaction Methods 0.000 claims abstract description 11
- 229910052742 iron Inorganic materials 0.000 claims abstract description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 93
- 229910052739 hydrogen Inorganic materials 0.000 claims description 52
- 239000001257 hydrogen Substances 0.000 claims description 52
- 125000006413 ring segment Chemical group 0.000 claims description 52
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 43
- 125000001183 hydrocarbyl group Chemical group 0.000 claims description 33
- 229910052736 halogen Inorganic materials 0.000 claims description 30
- 150000002367 halogens Chemical class 0.000 claims description 25
- 150000001875 compounds Chemical class 0.000 claims description 19
- 125000000524 functional group Chemical group 0.000 claims description 16
- -1 R 14 Chemical compound 0.000 claims description 15
- 239000000203 mixture Substances 0.000 claims description 13
- 239000002904 solvent Substances 0.000 claims description 11
- 125000003107 substituted aryl group Chemical group 0.000 claims description 10
- 150000002431 hydrogen Chemical class 0.000 claims description 9
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 9
- 125000004953 trihalomethyl group Chemical group 0.000 claims description 9
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 8
- 125000005843 halogen group Chemical group 0.000 claims description 7
- 125000001309 chloro group Chemical group Cl* 0.000 claims description 6
- NALBLJLOBICXRH-UHFFFAOYSA-N dinitrogen monohydride Chemical group N=[N] NALBLJLOBICXRH-UHFFFAOYSA-N 0.000 claims description 6
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 5
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims description 5
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 5
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 claims description 5
- 229910052782 aluminium Inorganic materials 0.000 claims description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 3
- 150000004698 iron complex Chemical class 0.000 claims description 3
- 239000000126 substance Substances 0.000 abstract description 6
- 239000003599 detergent Substances 0.000 abstract description 2
- 239000000543 intermediate Substances 0.000 abstract description 2
- 239000000178 monomer Substances 0.000 abstract description 2
- 229920000642 polymer Polymers 0.000 abstract 1
- 238000001816 cooling Methods 0.000 description 15
- 239000012071 phase Substances 0.000 description 14
- 239000000047 product Substances 0.000 description 12
- 150000001336 alkenes Chemical class 0.000 description 11
- 125000003118 aryl group Chemical group 0.000 description 11
- 239000007789 gas Substances 0.000 description 10
- 125000004429 atom Chemical group 0.000 description 8
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 8
- 229910052799 carbon Inorganic materials 0.000 description 7
- 239000007791 liquid phase Substances 0.000 description 6
- 125000004432 carbon atom Chemical group C* 0.000 description 4
- 125000000217 alkyl group Chemical group 0.000 description 3
- 125000001246 bromo group Chemical group Br* 0.000 description 3
- 230000003197 catalytic effect Effects 0.000 description 3
- 239000002826 coolant Substances 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 125000005842 heteroatom Chemical group 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 3
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 2
- 239000012190 activator Substances 0.000 description 2
- 150000001721 carbon Chemical group 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 125000001072 heteroaryl group Chemical group 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 125000001424 substituent group Chemical group 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- GGQQNYXPYWCUHG-RMTFUQJTSA-N (3e,6e)-deca-3,6-diene Chemical compound CCC\C=C\C\C=C\CC GGQQNYXPYWCUHG-RMTFUQJTSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 150000004703 alkoxides Chemical group 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical group [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 125000000753 cycloalkyl group Chemical group 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000002939 deleterious effect Effects 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 125000001153 fluoro group Chemical group F* 0.000 description 1
- 238000011010 flushing procedure Methods 0.000 description 1
- 238000004508 fractional distillation Methods 0.000 description 1
- 150000004678 hydrides Chemical group 0.000 description 1
- QIUBLANJVAOHHY-UHFFFAOYSA-N hydrogen isocyanide Chemical group [NH+]#[C-] QIUBLANJVAOHHY-UHFFFAOYSA-N 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 125000002346 iodo group Chemical group I* 0.000 description 1
- 150000002505 iron Chemical class 0.000 description 1
- 239000003446 ligand Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- CPOFMOWDMVWCLF-UHFFFAOYSA-N methyl(oxo)alumane Chemical compound C[Al]=O CPOFMOWDMVWCLF-UHFFFAOYSA-N 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 150000002815 nickel Chemical class 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 230000003606 oligomerizing effect Effects 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Chemical group 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 125000004434 sulfur atom Chemical group 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 150000003623 transition metal compounds Chemical class 0.000 description 1
- 150000003624 transition metals Chemical group 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
- C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
- C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
- C07C2/08—Catalytic processes
- C07C2/26—Catalytic processes with hydrides or organic compounds
- C07C2/32—Catalytic processes with hydrides or organic compounds as complexes, e.g. acetyl-acetonates
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- C07C2531/22—Organic complexes
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US21888800P | 2000-07-18 | 2000-07-18 | |
| PCT/US2001/022628 WO2002006192A1 (en) | 2000-07-18 | 2001-07-18 | MANUFACTURING PROCESS FOR α-OLEFINS |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2004504282A true JP2004504282A (ja) | 2004-02-12 |
| JP2004504282A5 JP2004504282A5 (enExample) | 2008-08-28 |
Family
ID=22816892
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2002512099A Pending JP2004504282A (ja) | 2000-07-18 | 2001-07-18 | α−オレフィン類の製造方法 |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US6534691B2 (enExample) |
| EP (1) | EP1311464B1 (enExample) |
| JP (1) | JP2004504282A (enExample) |
| KR (1) | KR100780226B1 (enExample) |
| CN (1) | CN100374398C (enExample) |
| AU (1) | AU2001273556A1 (enExample) |
| BR (1) | BR0112568A (enExample) |
| DE (1) | DE60130342T2 (enExample) |
| WO (1) | WO2002006192A1 (enExample) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004511437A (ja) * | 2000-08-03 | 2004-04-15 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | α−オレフィンの連続製造方法 |
| JP2013095671A (ja) * | 2011-10-28 | 2013-05-20 | Mitsui Chemicals Inc | オレフィンの製造方法 |
| JP2013518834A (ja) * | 2010-02-02 | 2013-05-23 | リンデ アクチエンゲゼルシャフト | 線状αオレフィンを製造する方法 |
| CN105693448A (zh) * | 2016-03-18 | 2016-06-22 | 浙江大学 | 一种乙烯齐聚的多釜串联工艺 |
| CN105732254A (zh) * | 2016-03-18 | 2016-07-06 | 浙江大学 | 一种乙烯齐聚制备线性α-烯烃的操作方法 |
| JP2018108983A (ja) * | 2016-12-22 | 2018-07-12 | アクセンス | 洗浄デバイスを採用するオレフィンのオリゴマー化方法 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6710006B2 (en) * | 2000-02-09 | 2004-03-23 | Shell Oil Company | Non-symmetrical ligands and catalyst systems thereof for ethylene oligomerization to linear alpha olefins |
| US7037988B2 (en) * | 2000-10-03 | 2006-05-02 | Shell Oil Company | Process for the co-oligomerisation of ethylene and alpha olefins |
| EP1427740B1 (en) * | 2001-08-01 | 2006-11-02 | Shell Internationale Researchmaatschappij B.V. | Ligands and catalyst systems thereof for ethylene oligomerisation to linear alpha olefins rung |
| US7053259B2 (en) * | 2002-09-17 | 2006-05-30 | E. I. Du Pont De Nemours And Company | Process of producing α-olefins |
| AU2003271645A1 (en) * | 2002-09-25 | 2004-04-19 | Shell Internationale Research Maatschappij B.V. | Process for making a linear alpha-olefin oligomer using a heat exchanger |
| EP1542797B1 (en) * | 2002-09-25 | 2006-05-31 | Shell Internationale Researchmaatschappij B.V. | Catalyst systems for ethylene oligomerisation to linear alpha olefins |
| RU2339604C2 (ru) * | 2002-09-25 | 2008-11-27 | Шелл Интернэшнл Рисерч Маатсхаппий Б.В. | Способ получения линейного альфа-олефинового олигомера с использованием теплообменника |
| US20040143147A1 (en) * | 2002-11-08 | 2004-07-22 | Ittel Steven Dale | Process for producing alpha-olefins |
| US20050014983A1 (en) * | 2003-07-07 | 2005-01-20 | De Boer Eric Johannes Maria | Process for producing linear alpha olefins |
| US7022787B2 (en) * | 2003-09-25 | 2006-04-04 | E. I. Du Pont De Nemours And Company | Olefin polymerization catalyst |
| US20050187418A1 (en) * | 2004-02-19 | 2005-08-25 | Small Brooke L. | Olefin oligomerization |
| US7384886B2 (en) * | 2004-02-20 | 2008-06-10 | Chevron Phillips Chemical Company Lp | Methods of preparation of an olefin oligomerization catalyst |
| US9550841B2 (en) | 2004-02-20 | 2017-01-24 | Chevron Phillips Chemical Company Lp | Methods of preparation of an olefin oligomerization catalyst |
| US20070043181A1 (en) * | 2005-08-19 | 2007-02-22 | Knudsen Ronald D | Methods of preparation of an olefin oligomerization catalyst |
| US20050187098A1 (en) * | 2004-02-20 | 2005-08-25 | Knudsen Ronald D. | Methods of preparation of an olefin oligomerization catalyst |
| WO2005090371A1 (en) | 2004-03-24 | 2005-09-29 | Shell Internationale Research Maatschappij B.V. | Transition metal complexes |
| US7442819B2 (en) * | 2004-07-09 | 2008-10-28 | E. I. Du Pont De Nemours And Company | Catalysts for olefin polymerization or oligomerization |
| AR049714A1 (es) * | 2004-07-13 | 2006-08-30 | Shell Int Research | Proceso de preparacion de alfa olefinas lineales |
| EP1831225A2 (en) | 2004-11-19 | 2007-09-12 | The Regents of the University of California | Anti-inflammatory pyrazolopyrimidines |
| PL1869020T3 (pl) | 2005-03-29 | 2011-05-31 | Icos Corp | Pochodne heteroarylomocznika użyteczne w hamowaniu działania CHK1 |
| US7271121B2 (en) * | 2005-07-21 | 2007-09-18 | Chevron Phillips Chemical Company Lp | Diimine metal complexes, methods of synthesis, and methods of using in oligomerization and polymerization |
| US7727926B2 (en) * | 2005-07-21 | 2010-06-01 | Chevron Phillips Chemical Company Lp | Diimine metal complexes, methods of synthesis, and method of using in oligomerization and polymerization |
| US7268096B2 (en) * | 2005-07-21 | 2007-09-11 | Chevron Phillips Chemical Company Lp | Diimine metal complexes, methods of synthesis, and methods of using in oligomerization and polymerization |
| KR20090017498A (ko) | 2006-04-04 | 2009-02-18 | 더 리젠트스 오브 더 유니이버시티 오브 캘리포니아 | Pi3 키나제 길항물질 |
| WO2009046448A1 (en) | 2007-10-04 | 2009-04-09 | Intellikine, Inc. | Chemical entities and therapeutic uses thereof |
| US7902415B2 (en) * | 2007-12-21 | 2011-03-08 | Chevron Phillips Chemical Company Lp | Processes for dimerizing or isomerizing olefins |
| US8193182B2 (en) | 2008-01-04 | 2012-06-05 | Intellikine, Inc. | Substituted isoquinolin-1(2H)-ones, and methods of use thereof |
| WO2009088990A1 (en) | 2008-01-04 | 2009-07-16 | Intellikine, Inc. | Certain chemical entities, compositions and methods |
| US8993580B2 (en) | 2008-03-14 | 2015-03-31 | Intellikine Llc | Benzothiazole kinase inhibitors and methods of use |
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| US9944661B2 (en) | 2016-08-09 | 2018-04-17 | Chevron Phillips Chemical Company Lp | Olefin hydroboration |
| KR101928079B1 (ko) * | 2016-12-12 | 2018-12-11 | 한화케미칼 주식회사 | 디시클로펜타디엔계 수지의 제조 방법 및 디시클로펜타디엔계 수지 |
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| US10407360B2 (en) | 2017-12-22 | 2019-09-10 | Chevron Phillips Chemical Company Lp | Ethylene oligomerization processes |
| US10633306B2 (en) * | 2017-06-06 | 2020-04-28 | Liquidpower Specialty Products Inc. | Method of increasing alpha-olefin content |
| KR102592638B1 (ko) | 2019-08-21 | 2023-10-23 | 주식회사 엘지화학 | 알파 올레핀 제조 방법 및 알파 올레핀 제조 장치 |
| EP4386035A4 (en) | 2021-08-10 | 2025-07-30 | Nippon Catalytic Chem Ind | POLYALKYLENE OXIDE-CONTAINING COMPOUND |
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| JP2004511437A (ja) * | 2000-08-03 | 2004-04-15 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | α−オレフィンの連続製造方法 |
| JP2013518834A (ja) * | 2010-02-02 | 2013-05-23 | リンデ アクチエンゲゼルシャフト | 線状αオレフィンを製造する方法 |
| US9896391B2 (en) | 2010-02-02 | 2018-02-20 | Linde Aktiengesellschaft | Process for preparing linear α-olefins |
| JP2013095671A (ja) * | 2011-10-28 | 2013-05-20 | Mitsui Chemicals Inc | オレフィンの製造方法 |
| CN105693448A (zh) * | 2016-03-18 | 2016-06-22 | 浙江大学 | 一种乙烯齐聚的多釜串联工艺 |
| CN105732254A (zh) * | 2016-03-18 | 2016-07-06 | 浙江大学 | 一种乙烯齐聚制备线性α-烯烃的操作方法 |
| CN105693448B (zh) * | 2016-03-18 | 2018-06-19 | 浙江大学 | 一种乙烯齐聚的多釜串联工艺 |
| CN105732254B (zh) * | 2016-03-18 | 2019-01-08 | 浙江大学 | 一种乙烯齐聚制备线性α-烯烃的操作方法 |
| JP2018108983A (ja) * | 2016-12-22 | 2018-07-12 | アクセンス | 洗浄デバイスを採用するオレフィンのオリゴマー化方法 |
| JP7025916B2 (ja) | 2016-12-22 | 2022-02-25 | アクセンス | 洗浄デバイスを採用するオレフィンのオリゴマー化方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| KR100780226B1 (ko) | 2007-11-27 |
| CN1443149A (zh) | 2003-09-17 |
| EP1311464A1 (en) | 2003-05-21 |
| EP1311464B1 (en) | 2007-09-05 |
| CN100374398C (zh) | 2008-03-12 |
| US20020016521A1 (en) | 2002-02-07 |
| WO2002006192A1 (en) | 2002-01-24 |
| KR20030020385A (ko) | 2003-03-08 |
| DE60130342D1 (de) | 2007-10-18 |
| US6534691B2 (en) | 2003-03-18 |
| DE60130342T2 (de) | 2008-05-29 |
| BR0112568A (pt) | 2003-07-29 |
| AU2001273556A1 (en) | 2002-01-30 |
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